BERRI TM
BIO-ENVIRONMENTAL RESOURCE RECOVERY INTERNATIONAL, LLC
BERRI
TM
BIO-ENVIRONMENTAL RESOURCE RECOVERY INTERNATIONAL, LLC
BERRI™ (Bio-Environmental Resource Recovery International), currently a Limited Liability Company registered in Washington State and headquartered in Walla Walla, WA, is a uniquely innovative bio-tech company. BERRI transforms hazardous landfill materials into safe, nutrient-filled dirt, and improves soil, water, and air quality to enhance health. BERRI’s bio-remediation methods recycle our planet’s resources that are hidden in unusable and hazardous bi-products found in the agricultural industry, the petroleum industry, and municipal landfills. BERRI is capable of dealing with a wide range of waste materials that typically are harmful to the environment and frequently are a significant health hazard. Most of these materials eventually find their way into large and often poorly managed landfills that do not conform to regulatory oversight procedures— particularly true in less industrialized nations. Tests have successfully proven that the scientific process used by BERRI can digest large bovine carcasses, break down almost everything found in a landfill, and remediate soils heavily contaminated with industrial oils and tars. This procedure is made possible by a scientific process BERRI has termed MARS® (Microbially Accelerated Regeneration Science).
ADVANTAGES OF THE BERRI MARS PROCESS: 1. Minimizes odors within hours 2. Produces rich soil in 60-70 days 3. Exterminates pathogens 4. Annihilates carcinogens 5. Disassembles toxins 6. Destroys parasites/bacteria 7. Kills weed seeds 8. Has minimal or no leachate 9. Binds heavy metals 10. Has no methane emissions 11. Is a cheaper alternative to chemical oxidation or incineration 12. Works in acidic or alkaline soil 13. Reduces labor and equipment costs
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AREAS BERRI HAS DEMONSTRATED REVOLUTIONARY CAPABILITIES: Initial Test—From May through July 2007, testing done at Rattlesnake Ridge Landfill, Bingham County, Idaho, demonstrated the accelerated composting of dead bovine specimens, manure, and green waste. Chips made from plywood containing formaldehyde, creosote coated railroad ties, and tree trimmings provided porosity. Diapers, catalogs, tire pieces, other miscellaneous MSW, large amounts of grass clippings, and leather were also processed. The end result was toxic free, extremely high quality organic compost. Toxic Waste—From September to October 2008, BERRI demonstrated its ability to render polyaromatic hydrocarbons in oil sludge non-toxic. Hydrocarbons were eliminated and high concentrations of dibenzofurans were rendered non-detectable. Dibenzofurans are closely related to PCBs and dioxin. Sewage Treatment—From to September to November 2009, testing done at Rexburg, Idaho, Water Reclamation Plant demonstrated the ability of the MARS process to convert biosolids to high quality, nutrient rich compost, with no traces of any pathogens. Municipal Solid Waste— From August to November 2010, testing done at Rattlesnake Ridge Landfill in Bingham County, Idaho, BERRI demonstrated the MARS process ability to convert municipal sound waste to usable soil/compost. With the MARS process and recycling, BERRI can reduce the amount of MSW that needs to be buried at a landfill by over 80 percent. PCBs, diesel fuel, gasoline, adhesives, leather, and many pesticides were completely eliminated. See preliminary test results in the last few pages of this brochure.
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INITIAL TEST Initial Test • From May through July, 2007 done at Ra:lesnake Ridge • Tes6ng Landfill, Bingham County, Idaho
Ingredients Processed • Dead bovine specimens • Manure waste including tree trimmings and grass • Green clippings
2007, Bingham County, Idaho 1,400-‐lb Bovines Using the BERRI MARS process, these were
gone in 30 days (except for large bones)
• Chips made from plywood containing formaldehyde, and creosote coated railroad 6es.
catalogs, 6re pieces, and other • Diapers, miscellaneous MSW
• Leather
Garbage Remedia=on Windrows Turned
Within 24 hours -- no rotting-carcass odors {& temperatures in windrows >66oC (150o F)}
This is a look after 20 days. There were 98 carcasses in this windrow. It smelled great!
The 2007 project turned MSW & 300 carcasses into black dirt • Laboratory analyses verified • Pathogen death (animal & plant) • Pes=cide diges=on • Cresol disassembly • Formaldehyde destruc=on
Microbial Diges=on of Persistent Clopyralid Pes=cide • 3,6-Dichloro-pyridine-2-carboxylic acid (Clopyralid)
• Clopyralid persists in compost (ending recycling!) • Phytotoxic to dicots after 18 mo. of composting • Best-known example – 1990s, State of Washington • Chlorinated, ring-structure pesticides
Bio-Stimulant Soil Amendment
Microbial Diges=on of Persistent Picloram Pes=cide • 4-‐amino-‐3,5,6-‐trichloropyridine-‐2-‐carboxylic acid (Picloram) ½ life = 300 days • Picloram is described as the most persistent of its family of herbicides. • Manure of animals that have grazed on Picloram-‐treated grass is phytotoxic to dicotyledons.
Compost and bones, all that’s left after 60 days
Laboratory Analyses Verified • Pathogen death (animal & plant) • Pes=cide diges=on • Cresol disassembly • Formaldehyde destruc=on
Results of Laboratory Analyses Human Pathogen Species
Escherichia coli
Not detected
Salmonella sp.
Not detected
Staphylococcus aureus
Not detected
TOXIC WASTE Rapid Bioremedia,on of Soil Contaminated with Petroleum Hydrocarbons & Polychlorinated Dibenzofurans
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Review of Evidence Related to Bioremedia,on of Hydrocarbons and Phenolics • Methylphenols (cresols) eliminated • Chlorinated picolinate biodegraded • Shredded ,res (2007) decomposed
Tar Pond Bioremedia,on Bench Test
• Furans are described as not biodegradable • 135 polychlorinated dibenzofurans (differing in the number and locations of chlorine atoms) • Dibenzofurans do not dissolve in water • Dibenzofurans persist unchanged in the environment attached to particles of soil • Accumulate in animal tissue • Add 1 oxygen; produce dioxin. Remove 1 oxygen; produce PCB.
PAH-digesting Microbes
PAH-‐contaminated Soil
Tar Pond Hydrocarbons (ppm) » Before MARS
• TPH
AKer MARS
160,000
N.D. N.D. • PAH 321,600 N.D. • Dibenzofurans 11,000 N.D. • Naphthalene 71,000
• Total HCs 481,114 N.D.
SEWAGE TREATMENT Bio-‐Environmental Resource Recovery Interna5onal (BERRI)
DISHA Research Project
DISHA Project’s Target Material
Human Sewage Solids Precipitated After Aerobic Digestion
Straw & Wood Chips:
To Build Absorbent Bed
The word “disha” is Nepalese for human sewage sludge
Rexburg, Idaho Water Reclama;on Plant Use of MARS Inoculant & MARS Process as a Process to Further Reduce Pathogens October, 2009 MARS = Microbially Accelerated Regenera;on Science DISHA = Demonstra;on, Innova;ve, Safe, Hygienic Amendment
Construction & Demolition Wallboard Was Hauled to the Site to be Mixed With the Sewage Sludge
High Temperatures Kill Germs
Temperatures were recorded aXer a short period of probe inser;on. Measured degrees rose for many more minutes.
Laboratory Analyses Results Nitrogen (N), Phosphorus (P), Potassium (K)
From: Energy Laboratories – Analy2cal Excellence Since 1952 Windrows #1 #2 #3 #4 Means lb/ton lb/ton lb/ton lb/ton lb/ton N 64 72 56 64 64 P 44 33 34 34 35 K 23 25 22 22 23
Sludge Mixed With Wood Chips & Wallboard On Absorbent Bed
High Temperatures Produce a Need for Added Water
One Week After Windrows Were Assembled 14, 2009. No Leachate Ever! Photograph Taken on October
Pasteurization – the temperature of the sewage sludge is maintained at 70oC (158oF) or higher for 30 minutes or longer. (Federal EPA)
Turning Windrows Enhances Oxygenation Five Turnings to Comply With National Organic Program
Results of Laboratory Analyses Micronutrients
Analysis by IAS Laboratories
Ca
S Mg Na Fe Zn Mn Cu B
% 4.8
% % % ppm ppm ppm ppm ppm 4.5 0.8 0.15 7600 450 250 120 83
Results of Laboratory Analyses Human Pathogen Species
Escherichia coli
Not detected
Salmonella sp.
Not detected
Staphylococcus aureus
Not detected
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MUNICIPAL SOLID WASTE — INFORMATION — BERRI — A Revolutionary Perspective on Municipal Landfill Materials (MLMs) Using MARSTM (Microbially Accelerated Recovery Science)
u u u
Solve Compliance Problems Recycle Resources Create New Revenue Source
BERRI Solves Landfill Challenges u u
Mosquito Pools, Pathogens, Flies
u
Leachate, Surface Water, Aquifers
u
Air Quality (odors, H2S, methane)
Transportation
u
New Monitoring Wells
u
New Liners, Membranes, etc.
u u
Analytical Laboratory Fees Covering Daily With Clean Dirt
BERRI MARSTM Process Benefits ü Reduced labor, fuel, & equipment costs ü Windrows turned much less frequently ü
Time-savings & space-savings
ü It is totally aerobic ü Odor and dust control
ü It creates exodigestive enzymes
u u u u u u
Landfill Becomes a BERRI MARSTM
BERRI Reduces Escalating Costs u
Space, NIMBY, Rising Land Prices
BERRI Eliminates These Landfill Concerns
Resource Recovery Park u u u u u u
Contaminants Become Resources Nuisance Materials are Resources Operational Costs are Reduced Liner and Cell Costs Reduced Landfill Increases Airspace Create Revenue From Soil/Nutrients
Putting BERRI MARSTM Micro-organisms to Work
u
Formulated, Proprietary Microbes Thermophilic (131o to 160o F) High temperatures for > 30 days Eliminate Pathogens, Herbicides Eliminate Carcinogens, Mutagens Comply with EPA, 40-CFR part 503
u
Recycle 80% to 90% of landfill debris
u u u u u
BERRI MARSTM Additional Financial Advantages Micro-Nutrients & Humates Finished Soil u Save on Cost of New Burial Cells u Save on Haz. Mat. Costs u Reduce Greenhouse Gas Emissions
Actual Example of Financial Benefit
u Harvest
u
u Sell
u
– Sell Carbon Credits
u u u u u
A much-superior bio-processing method
Common Household Garbage Diapers, Sewage Sludge Pathogens (human, animal, plant) Wallboard / Drywall / Sheetrock Engineered Wood (aldehydes) Treated Wood (creosote, P.C.P)
Cheyenne, Wyoming (small city) Cheyenne projected 10 yrs. life 8 yr. later (2005), 5 yr. of space! Not one cubic yard of space added The city had started composting! Diverted food, yard trimmings 1st yr.: 32,662 x $17.50=$571,585
MUNICIPAL SOLID WASTE — TEST MSW Bio-‐processing Test Autumn 2010 Ra:lesnake Landfill
Conducted by BERRI, LLC For State of Idaho Dept. of Environmental Quality Thanks to Bingham County for use of research site
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Six Windrow Sites Were Engineered to be Lined for Test Purposes
Membranes Were Connected to Leachate-‐CollecHon Drums
MUNICIPAL SOLID WASTE — TEST (CONTINUED) Leachate-‐CollecHon Drum Down-‐Gradient from Sealed, Gravel-‐Filled
Funnel of HDPE Membrane
Windrow LocaHons Were Centered Over High-‐Density Polyethylene Membranes
Whatever Trucks Brought Was Shredded (Unsorted)
Shredded MSW to Form Windrows
With Tanned Leather Added
Other Hazardous Chemicals Added (Solvents, Diesel Fuel, Gasoline)
Highest Temp. Measured was 182.8o F /~ 84oC
Windrows of Shredded MSW Were Treated With BERRI-Grown Inoculants
First Turning of Windrows (October 18, 2010 – aYer 2 weeks)
MSW is Becoming Black Dirt (From Windrow Interior aYer 4 Weeks)
Six Windrow Beds Were Created Ready to Receive MSW
Shredded & Compacted MSW for Research Windrows
Carcinogens on EPA 215 & PesHcides Were Added
Second Turning of Windrows Lost Heat in Zero Temp. 2 hr. Later, > than EPA limit
Windrow with Extra Toxins After 4 wks (Oct. 27, 2010)
From Windrow #2 AYer 5 Weeks
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PRELIMINARY MSW LABORATORY REPORT
LABORATORY ANALYTICAL
LABORATORY ANALYTICAL REPORT
Prepared by Billings, MT Bra
Prepared by Billings, MT Branch Client: Project: Lab ID: Client Sample ID:
Berri LLC Composte for Hazardous Material B10120920-001 Compost Analysis
Analyses
Result
Client: Project: Lab ID: Client Sample ID:
Units
7.9
wt%
ND 5 289 ND ND 369 ND 216 13 11 ND ND ND 6 9 156
mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND ND
mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg mg/kg
METALS, TOTAL - EPA SW846 Antimony Arsenic Barium Beryllium Cadmium Chromium Cobalt Copper Lead Nickel Selenium Silver Thallium Tin Vanadium Zinc
SEMI-VOLATILE ORGANIC COMPOUNDS 1,2,4,5-Tetrachlorobenzene 1,2,4-Trichlorobenzene 1,2-Dichlorobenzene 1,3,5-Trinitrobenzene 1,3-Dichlorobenzene 1,3-Dinitrobenzene 1,4-Benzenediamine 1,4-Dichlorobenzene 1,4-Naphthoquinone 1-Methylnaphthalene 1-Naphthylamine 2,3,4,6-Tetrachlorophenol 2,4,5-Trichlorophenol 2,4,6-Trichlorophenol 2,4-Dichlorophenol 2,4-Dimethylphenol 2,4-Dinitrophenol 2,4-Dinitrotoluene 2,6-Dichlorophenol 2,6-Dinitrotoluene 2-Acetylaminofluorene 2-Chloronaphthalene
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Report Definitions:
RL
MCL/ QCL
Result Date Analysis Units/ By
Method
Qualifier
SEMI-VOLATILE ORGANIC COMPOUNDS
PHYSICAL CHARACTERISTICS Moisture
Analyses Qualifiers
Berri LLC Report Date: 12/17/10 Composte for Hazardous Material Provided Collection Date: Not B10120920-001 DateReceived: 12/09/10 Compost Analysis Matrix: Solid
2-Chlorophenol0.2 SW3550A 2-Methylnaphthalene 2-Naphthylamine 2-Nitroaniline 5 SW6010B 2-Nitrophenol 5 SW6010B 2-Picoline 5 SW6010B 3,3´-Dichlorobenzidine 5 SW6010B 3,3´-Dimethylbenzidine 1 SW6010B 3-Methylcholanthrene 5 SW6010B 3-Nitroaniline 5 SW6010B 4,6-Dinitro-2-methylphenol 5 SW6010B 4-Aminobiphenyl5 SW6010B 4-Bromophenyl phenyl ether 5 SW6010B 4-Chloro-2-methylphenol 5 SW6010B 4-Chloro-3-methylphenol 5 SW6010B 4-Chlorophenol 5 SW6010B 4-Chlorophenyl phenyl ether 5 SW6010B 4-Nitroaniline 1 SW6010B 4-Nitrophenol 5 SW6010B 4-Nitroquinoline-n-oxide 5-Nitro-o-toluidine 7,12-Dimethylbenz(a)anthracene 1.7 SW8270C a,a-Dimethylphenethylamine 1.7 SW8270C Acenaphthene 1.7 SW8270C Acenaphthylene 1.7 SW8270C Acetophenone 1.7 SW8270C Aniline 1.7 SW8270C Anthracene P SW8270C Aramite 1.7 SW8270C Azobenzene 1.7 SW8270C Benzidine 1.7 SW8270C Benzo(a)anthracene 1.7 SW8270C Benzo(a)pyrene 1.7 SW8270C Benzo(b)fluoranthene 1.7 SW8270C Benzo(g,h,i)perylene 1.7 SW8270C Benzo(k)fluoranthene 1.7 SW8270C Benzyl alcohol 1.7 SW8270C bis(-2-chloroethoxy)Methane 17 SW8270C bis(-2-chloroethyl)Ether 1.7 SW8270C bis(2-chloroisopropyl)Ether 1.7 SW8270C bis(2-ethylhexyl)Phthalate 1.7 SW8270C Butylbenzylphthalate 1.7 SW8270C Chlorobenzilate 1.7 SW8270C
ND mg/kg/ amn 12/13/10 05:35 ND mg/kg ND mg/kg ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg/ rlh 12/14/10 00:44 ND mg/kg 12/14/10 00:44 / rlh ND mg/kg ND mg/kg ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm 13 mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm ND mg/kg 12/10/10 21:14 / dsm
RL - Analyte reporting level. limit. contaminant Report MCL - Maximum Definitions: - Quality control limit.limit. ND - NotQCL detected at the reporting P - Poor method performance. Method validations have P - Poor method performance. Method validations have shown no recoveries at low levels or erratic method shown no recoveries at low levels or erratic method
P
RL - Analyte reporting limit.
M
QCL - Quality control limit.
N
PRELIMIN PRELIMINARY
Client Sample ID: Compost Analysis Analyses
Result
Client Sample ID: Compost AnalysisMatrix: Solid Units
Analyses Qualifiers
RL
QCL
Method
Result Analysis Date / By Units
Qualifiers
MCL/ COMPOUNDS Result Units Analyses SEMI-VOLATILE ORGANIC Qualifiers SEMI-VOLATILE ORGANIC COMPOUNDS Analyses Result QCL Method Analyses Result Units AnalysisUnits Date / By Qualifiers Qualifiers RL Parathion ND mg/kg Chrysene ND SW8270C mg/kg 1.7 12/10/10 21:14 / dsm SEMI-VOLATILE p-Chloroaniline 1.7ORGANIC COMPOUNDS ND mg/kg 12/10/10 21:14 / dsm Diallate ND mg/kg SW8270C SEMI-VOLATILE ORGANIC COMPOUNDS ND SEMI-VOLATILE ORGANIC COMPOUNDS Parathion mg/kg mg/kg Pentachlorobenzene ND 1.7 12/10/10 21:14 / dsm mg/kg Dibenzo(a,h)anthracene ND SW8270C Parathion ND mg/kg Parathion ND mg/kg SW8270C 12/10/10 21:14 / dsm p-Chloroaniline 1.7 ND mg/kg Pentachloronitrobenzene ND mg/kg 1.7 12/10/10 21:14 / dsm Dibenzofuran ND mg/kg SW8270C p-Chloroaniline ND mg/kg p-Chloroaniline ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Pentachlorobenzene ND mg/kg mg/kg Pentachlorophenol ND 1.7 12/10/10 21:14 / dsm mg/kg Diethyl phthalate ND SW8270C Pentachlorobenzene ND mg/kg Pentachlorobenzene ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Pentachloronitrobenzene ND mg/kg Phenacetin ND mg/kg 1.7 12/10/10 21:14 / dsm Dimethoate ND mg/kg SW8270C Pentachloronitrobenzene ND mg/kg Pentachloronitrobenzene ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Pentachlorophenol ND mg/kg Phenanthrene ND mg/kg 1.7 12/10/10 21:14 / dsm Dimethyl phthalate ND mg/kg SW8270C Pentachlorophenol ND mg/kg Pentachlorophenol ND mg/kg 17 SW8270C 12/10/10 21:14 / dsm Phenacetin ND mg/kg Phenol ND mg/kg 1.7 12/10/10 21:14 / dsm Di-n-butyl phthalate ND mg/kg SW8270C Phenacetin ND mg/kg Phenacetin ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Phenanthrene ND mg/kg Phorate ND mg/kg 1.7 12/10/10 21:14 / dsm mg/kg Di-n-octyl phthalate ND SW8270C Phenanthrene ND mg/kg Phenanthrene ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Phenol ND mg/kg Pronamide ND mg/kg 1.7 12/10/10 21:14 / dsm Diphenylamine ND mg/kg SW8270C Phenol ND mg/kg Phenol ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Phorate ND mg/kg Pyrene ND mg/kg 1.7 12/10/10 21:14 / dsm Disulfoton ND mg/kg SW8270C Phorate ND mg/kg Phorate ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Pronamide ND mg/kg Pyridine ND mg/kg 1.7 12/10/10 21:14 / dsm Ethyl methanesulfonate ND mg/kg SW8270C Pronamide ND mg/kg Pronamide ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Pyrene ND mg/kg Safrole ND mg/kg 1.7 12/10/10 21:14 / dsm Famphur ND mg/kg SW8270C Pyrene ND mg/kg Pyrene ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Pyridine ND mg/kg Sulfotep ND mg/kg 1.7 12/10/10 21:14 / dsm Fluoranthene ND mg/kg SW8270C Pyridine ND mg/kg Pyridine ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Safrole ND mg/kg Thionazin ND mg/kg 1.7 12/10/10 21:14 / dsm Fluorene ND mg/kg SW8270C Safrole ND mg/kg Safrole ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Sulfotep ND mg/kg Surr: 2,4,6-Tribromophenol 81.0 %REC 1.7 12/10/10 21:14 / dsm Hexachlorobenzene ND mg/kg SW8270C Sulfotep ND mg/kg Sulfotep ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Thionazin ND mg/kg Surr: 2-Fluorobiphenyl 72.0 %REC 1.7 12/10/10 21:14 / dsm Hexachlorobutadiene ND mg/kg SW8270C Thionazin ND mg/kg Thionazin ND mg/kg 1.7 SW8270C 12/10/10 21:14 / dsm Surr: 2-Fluorophenol 2,4,6-Tribromophenol 81.0 %REC Surr: 66.0 %REC 1.7 12/10/10 21:14 / dsm Hexachlorocyclopentadiene ND mg/kg SW8270C Surr: 2,4,6-Tribromophenol 81.0 %REC 1 Surr: 2,4,6-Tribromophenol 81.0 %REC 19-122 SW8270C 12/10/10 21:14 / dsm Surr: Nitrobenzene-d5 2-Fluorobiphenyl 72.0 %REC %REC Surr: 52.0 1.7 12/10/10 21:14 / dsm Hexachloroethane ND mg/kg SW8270C Surr: 2-Fluorobiphenyl 72.0 %REC 3 Surr: 2-Fluorobiphenyl 72.0 %REC 30-115 SW8270C 12/10/10 21:14 / dsm Surr: 2-Fluorophenol 66.0 %REC Surr: 70.0 %REC P Phenol-d5 12/10/10 21:14 / dsm Hexachlorophene ND mg/kg SW8270C Surr: 2-Fluorophenol 66.0 %REC 2 Surr: 2-Fluorophenol 66.0 %REC 25-121 SW8270C 12/10/10 21:14 / dsm Surr: Terphenyl-d14 Nitrobenzene-d5 52.0 %REC Surr: 72.0 %REC 1.7 12/10/10 21:14 / dsm Hexachloropropene ND mg/kg SW8270C Surr: Nitrobenzene-d5 52.0 %REC 2 Surr: Nitrobenzene-d5 52.0 %REC 23-120 SW8270C 12/10/10 21:14 / dsm Surr: Phenol-d5 70.0 %REC - The sample extract would not concentrate to 1 mL and12/10/10 was brought to a /2 dsm mL final volume. The 1.7 Indeno(1,2,3-cd)pyrene ND mg/kg SW8270C - The sample extract would not concentrate to 1 mL and was brought to21:14 a 2 /mL final Surr: Phenol-d5 70.0 %REC Surr: Phenol-d5 70.0 %REC 24-113 SW8270C 12/10/10 21:14 dsm due to non-target compound sample matrix interference. The Reporting Limit reflects the sample2 Surr: Terphenyl-d14 1.7 extract was diluted 21:14 / dsm Isophorone ND mg/kg SW8270C volume. The sample an additional72.0 512/10/10 times at%REC analysis Surr: Terphenyl-d14 72.0 %REC Surr: Terphenyl-d14 72.0 %REC 18-137 SW8270C 12/10/10 21:14 dsm - The samplecompound extract not concentrate to 1 mL and was brought to /areflects mL final volume. The1 due to non-target sample matrix interference. The12/10/10 Reporting Limit 1.7 would 21:14 /2 dsm Isosafrole ND mg/kg SW8270C POLYCHLORINATED BIPHENYLS (PCBS) -due Thetosample extract would concentrate to 1 mL and was brought to aLimit 2 mLreflects final volume. The - The sample extract would not concentrate to 1 mL and was brought to a 2 mL final volume. The sample extractnot was diluted an additional 5 times atReporting analysis non-target compound sample matrix interference. The the sample the sample extract final volume and the additional dilution. 1.7 12/10/10 21:14Limit / dsm m+p-Cresols mg/kgLimit reflects SW8270C due non-target compound sample interference. The Reporting reflects the sample due to non-target compound sample matrix interference. ND The Reporting the to sample extract final volume and matrix the additional dilution. Aroclor 1016 ND mg/kg P 1221 12/10/10 21:14 / dsm Methapyrilene ND mg/kg SW8270C POLYCHLORINATED BIPHENYLS (PCBS) ND Aroclor mg/kg POLYCHLORINATED BIPHENYLS (PCBS) ND POLYCHLORINATED BIPHENYLS (PCBS) ND 1.7 12/10/10 21:14 / dsm Methyl methanesulfonate mg/kg SW8270C Aroclor 1016 mg/kg Aroclor 1232 ND mg/kg Aroclor ND mg/kg Aroclor ND SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 / dsm Methyl1016 parathion ND mg/kg mg/kg SW8270C Aroclor1016 1221 0.017 ND mg/kg Aroclor 1242 ND mg/kg Aroclor 1221 ND mg/kg Aroclor 1221 ND 0.017 SW8082 12/15/10 09:19 1.7 12/10/10 21:14 / dsm Naphthalene ND mg/kg mg/kg SW8270C Aroclor 1248 1232 ND mg/kg/ ldw Aroclor ND mg/kg Aroclor 1232 ND mg/kg Aroclor 1232 ND 0.017 SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 Nitrobenzene ND mg/kg mg/kg SW8270C Aroclor 1254 1242 ND mg/kg / dsm Aroclor ND mg/kg Aroclor 1242 ND mg/kg Aroclor 1242 ND 0.017 SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 / dsm n-Nitrosodiethylamine ND mg/kg mg/kg SW8270C Aroclor 1248 ND mg/kg Aroclor 1260 ND mg/kg Aroclor 1248 ND mg/kg Aroclor 1248 ND 0.017 SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 n-Nitrosodimethylamine ND mg/kg mg/kg SW8270C Aroclor 1254 ND mg/kg Aroclor 1262 ND mg/kg / dsm Aroclor ND mg/kg Aroclor 1254 ND SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 / dsm n-Nitroso-di-n-butylamine ND mg/kg mg/kg SW8270C Aroclor1254 1260 0.017 ND mg/kg Aroclor 1268 ND mg/kg Aroclor 1260 ND mg/kg Aroclor 1260 ND mg/kg 0.017 SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 / dsm n-Nitroso-di-n-propylamine ND mg/kg SW8270C Aroclor ND mg/kg Surr: 1262 Decachlorobiphenyl 87.0 %REC Aroclor 1262 0.017 ND mg/kg Aroclor 1262 ND SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 / dsm n-Nitrosodiphenylamine ND mg/kg mg/kg SW8270C Aroclor ND mg/kg Surr: 1268 Tetrachloro-m-xylene 76.0 %REC Aroclor 1268 ND mg/kg Aroclor 1268 ND 0.017 SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 dsma Copper Clean-u n-Nitrosomethylethylamine ND mg/kg mg/kg SW8270C Surr: Decachlorobiphenyl 87.0 %REC -The sample extract received a Sulfuric Acid Clean-up (EPA Method 3665)/ and Surr: 87.0 %REC 5 Surr: Decachlorobiphenyl 87.0 50-126 SW8082 12/15/10 09:19 / ldw 1.7 12/10/10 21:14 / dsm n-Nitrosomorpholine ND %REC mg/kg SW8270C Surr: Decachlorobiphenyl Tetrachloro-m-xylene 76.0 %REC Surr: Tetrachloro-m-xylene 76.0 %REC Surr: Tetrachloro-m-xylene 76.0 %REC 42-115 SW8082 12/15/10 09:19 / ldw HERBICIDES, CHLORINATED 1.7 received a Sulfuric 12/10/10 21:14 dsma Copper Clean-u4 n-Nitrosopiperidine ND mg/kg SW8270C -The sample extract Acid Clean-up (EPA Method 3665)/ and -The sample extract received a Sulfuric Acid Clean-up (EPA Method -The sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and -The sample extract received a Sulfuric Acid Clean-up (EPA Method 3665) and a Copper Clean-up (EPA Method 3660) prior to analysis. 12/10/10 21:14 / dsma Copper Clean-u n-Nitrosopyrrolidine ND mg/kg SW8270C 2,4,5-T 3665) and a1.7 mg/kg Copper Clean-up (EPA Method 3660) ND prior to analysis. HERBICIDES, 1.7 12/10/10 21:14 / dsm o,o,o-Triethyl phosphorothioate ND mg/kg SW8270C 2,4,5-TP (Silvex) CHLORINATED 0.042 mg/kg HERBICIDES, CHLORINATED HERBICIDES, CHLORINATED 2,4,5-T ND mg/kg 1.7 12/10/10 21:14 / dsm o-Cresol ND mg/kg SW8270C 2,4-D ND mg/kg 2,4,5-T ND mg/kg 0 2,4,5-T ND mg/kg 0.0040 SW8151A 12/16/10 18:03 / ldw 2,4,5-TP 0.042 mg/kg 12/10/10 21:14 / dsm o-Toluidine ND mg/kg SW8270C Dinoseb (Silvex) 1.7 ND mg/kg 0 2,4,5-TP (Silvex) 0.042 mg/kg 2,4,5-TP (Silvex) 0.042 mg/kg 0.0040 SW8151A 12/16/10 18:03 / ldw 2,4-D ND mg/kg 1.7 12/10/10 21:14 / dsm p-(dimethylamino)Azobenzene ND mg/kg SW8270C Surr: DCAA 56.0 %REC 2,4-D ND mg/kg 2,4-D ND mg/kg 0.020 SW8151A 12/16/10 18:03 Dinoseb ND mg/kg/ ldw Dinoseb ND mg/kg Dinoseb ND mg/kg SW8151A 12/16/10 18:03 Surr: DCAA 0.020 56.0 %REC/ ldw RL - Analytecontaminant reporting limit. MC RL - Analyte reporting limit. - Maximum level. 12/16/10 Report Report 5 Surr: DCAAMCL 56.0 %REC Surr: DCAA 56.0 %REC 53-114 SW8151A 18:03 / ldw Definitions: ND - Not Definitions: QCLdetected - Qualityatcontrol limit. limit. ND QCL - Quality control limit. the reporting RL - Analyte reporting limit. MC Report P - Poor method performance. Method validations have - Analyte reporting limit. MC Report RL - Analyte reporting limit. MCL - RL Maximum contaminant level. Report Definitions: QCL Quality control limit. ND shown no recoveries at low levels or erratic method Definitions:ND - Not Definitions: QCL - Quality limit. limit. ND QCL - Quality control limit. detected at control the reporting performance.
PRELIMIN PRELIMINARY PRELIMIN PRELIMINARY
NOTE: Where “Surr:” appears, these are surrogate compounds-compounds that were added by Energy Labs to show the test instrument was working and its effect on the sample matrix when the sample was analyzed. The “%rec” shows the percent recovery of the surrogate compounds that were added.
9
WASHINGTON STATE DEPARTMENT OF ECOLOGY STANDARDS FOR SOIL BERRI’s Results
CHEMICAL PARAMETER
Sediment Quality Standards WAC 173-204-320 (a)
Sediment Impact Zone Maximum Level, WAC 173204-420 (a); and Sediment Cleanup Screening Level/ Minimum Cleanup Level, WAC 173-204-520 (a)
MG/KG DRY WEIGHT (PARTS PER MILLION (PPM) DRY)
MG/KG DRY WEIGHT (PARTS PER MILLION (PPM) DRY)
ARSENIC
5
57
93
CADMIUM
ND
5.1
6.7
369*
260
270
216
390
390
13
450
530
MERCURY
N/A
0.41
0.59
SILVER
ND
6.1
6.1
ZINC
156
410
960
MG/KG ORGANIC CARBON (c) (PPM CARBON)
MG/KG ORGANIC CARBON (c) (PPM CARBON)
CHROMIUM COPPER LEAD
LPAH (b,d)
N/A
370
780
NAPHTHALENE
ND
99
170
ACENAPHTHYLENE
ND
66
66
ACENAPHTHENE
ND
16
57
FLUORENE
ND
23
79
PHENANTHRENE
ND
100
480
ANTHRACENE
ND
220
1200
2-METHYLNAPHTHALENE
ND
38
64
HPAH (b,e)
N/A
960
5300
FLUORANTHENE
ND
160
1200
PYRENE
ND
1,000
1400
BENZ(A)ANTHRACENE
ND
110
270
CHRYSENE
ND
110
460
TOTAL BENZOFLUORANTHENES (b,f)
ND
230
450
BENZO(A)PYRENE
ND
99
210
INDENO (1,2,3,-C,D) PYRENE
ND
34
88
DIBENZO (A,H) ANTHRACENE
ND
12
33
BENZO(G,H,I)PERYLENE
ND
31
78
1,2-DICHLOROBENZENE
ND
2.3
2.3
1,4-DICHLOROBENZENE
ND
3.1
9
1,2,4-TRICHLOROBENZENE
ND
0.81
1.8
HEXACHLOROBENZENE
ND
0.38
2.3
DIMETHYL PHTHALATE
ND
53
53
DIETHYL PHTHALATE
ND
61
110
10
DI-N-BUTYL PHTHALATE
ND
220
1700
BUTYL BENZYL PHTHALATE
ND
4.9
64
13
47
78
DI-N-OCTYL PHTHALATE
ND
58
4500
DIBENZOFURAN
ND
15
58
HEXACHLOROBUTADIENE
ND
3.9
6.2
N-NITROSODIPHENYLAMINE
ND
11
11
TOTAL PCBs (b)
N/A
BIS (2-ETHYLHEXYL) PHTHALATE
12
65
UG/KG DRY WEIGHT (PARTS PER BILLION (PPB) DRY)
UG/KG DRY WEIGHT (PARTS PER BILLION (PPB) DRY)
PHENOL
ND
420
1200
2-METHYLPHENOL
N/A
63
63
4-METHYLPHENOL
N/A
670
670
2,4-DIMETHYL PHENOL
ND
29
29
PENTACHLOROPHENOL
ND
360
690
BENZYL ALCOHOL
ND
57
73
BENZOIC ACID
N/A
650
650
Source: http://www.ecy.wa.gov/programs/tcp/smu/sed_chem.htm#a
*The chromium sulfate level is high because of the leather added to the Municipal Solid Waste test.
265,000
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11
NOTES:
BERRI-LLC.COM 184 PANORAMA LANE, WALLA WALLA, WA 99362 DAVE DRESSLER: (509) 540-9014 — DR. TED CARPENTER: (208) 200-2477