This book of collected papers aims to show new applications of Smarandache function in the study of some well known classes of numbers, like prime numbers, Poulet numbers, Carmichael numbers, Sophie Germain primes etc. Beside the well known notions of number theory, we defined in these papers the following new concepts: “Smarandache-Coman divisors of order k of a composite integer n with m prime factors”, “Smarandache-Coman congruence on primes”, “Smarandache-Germain primes”, “Coman-Smarandache criterion for primality”, “Smarandache-Korselt criterion”, “Smarandache-Coman constants”.