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Safety Data Sheet According To Regulation (EC) No 1907/2006 (REACH)

TAFTEED Version: Form No:

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IDENTIFICATION OF THE PRODUCT AND OF THE COMPANY/UNDERTAKING

1.1 Product Identifier Substance Name TAFTEED 122001 Product No Rock and Concrete Breaking System Description 1.2 Relevant Identified Uses Of The Product And Uses Advised Against Relevant Identified Uses Used as Rock and Concrete Breaking System in the following application areas; - Road construction - Excavation at housing sites - Bridge demolition, - Mass excavation, - Dimension Stone, - Boulder Breaking, - Trenching, - Tunneling and Shaft Sinking, - Underwater excavation, - Reinforced concrete demolition - Silo Cleaning and Rathole Opening, - Interior Breaking Uses Advised Against Do not use other than its main functions, the original usage parameters and preparations. See chapter 16 for a general overview 1.3 Details Of The Supplier Of The Safety Data Sheet Supplier (Manufacturer) TAFTEED LIMITED Address Qwamar Tradıng Buıldıng,3rd Floor, No:6 Tortola, Road Town, BRITISH VIRGIN ISLANDS Telephone + 90 312 496 48 24 Fax + 90 312 496 48 24 vasfi@gelicat.com Company E-mail Company Web Page www.tafteed.com 1.4 Information Providing Authority About Safety Data Sheet Y.Vasfi OZALP – Mechanical Engineer 1.5 Emergency Telephone Number Company Emergency + 90 312 496 48 24 2. HAZARDS IDENTIFICATION 2.1 Classification Of The Substance 2.1.1 Classification According to Regulation (EC) No 1272/2008  Oxidising solids, Category 2, H272  Corrosive to metals, Category 1, H290  Acute toxicity (inhalation), Category 4, H332  Acute toxicity (oral), Category 4, H302  Reproductive toxicity FD, Category 1B, H360FD www.tafteed.com

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 Hazardous to the aquatic environment: Chronic hazard, Category 2, H411 2.1.2 Classification According to Regulation to 67/548/EC  Harmful by inhalation and if swallowed.(Xn;R20/22)  Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.(N;R51/53)  May impair fertility.(T;R60)  May cause harm to the unborn child.(T;R61) 2.2 Label elements 2.2.1. Labeling According to Regulation (EC) No 1272/2008 [CLP1/GHS2] Product Identifier Hazard Component for Labeling  Potassium Chlorate [KClO3]  Diammonium oxalate monohydrate [C2H10N2O5]  Diboron Trioxide [B2O3]  Disodium Tetraborate Decahydrate Hazard Pictograms

Signal Word Hazard Statement(s)

Supplementary Statement(s) Precautionary Statement(s)

DANGER H272 H290 H302 H332 H360FD H411 NONE

May intensify fire; oxidizer.

May be corrosive to metals Harmful if swallowed.

Harmful if inhaled.

May damage fertility. Suspected of damaging the unborn child.

Toxic to aquatic life with long lasting effects.

Prevention P202 P210 P234 P261 P270

Do not handle until all safety precautions have been read and understood.

Keep away from heat/sparks/open flames/hot surfaces. - No smoking Keep only in original container.

Avoid breathing dust.

Do not eat, drink or smoke when using this product.

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P271 P273 P280 P281

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Use only outdoors or in a well-ventilated area.

Avoid release to the environment.

Wear protectic gloves/protective clothing/eye protection/face protection .

Use personal protective equipment as required.

Response P301+P312 P304+P340 P308+P313 P390 P391

IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

IF exposed or concerned: Get medical advice/attention.

Absorb spillage to prevent material damage.

Collect spillage

Storage P405 P406

Store locked up.

Store in corrosive resist and container with a resistant inner liner.

Disposal P501

Dispose of contents/container to in accordance with local/regional/national/international regulations. ..

2.2.2. Labeling According to Regulation to 67/548/EEC Hazard Component for Labeling · Potassium Chlorate [KClO3] · Diammonium oxalate monohydrate [C2H10N2O5] · Diboron Trioxide [B2O3] · Disodium Tetraborate Decahydrate Hazard Symbols  T-Toxic  N-Dangerous for Environment

Risk Phrases Harmful by inhalation and if swallowed.

R20/22 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic R51/53 environment.

May impair fertility R60 May cause harm to the unborn child.

R61 Safety Phrases Keep locked up.

S01 Keep away from combustible material.

S17 Do not empty into drains, dispose of this material and its container at hazardous S29/56 or special waste collection point.

Wear suitable protective clothing.

S36 If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre.

S46 (show this container or label). www.tafteed.com

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Avoid exposure - obtain special instructions before use.

S53 This material and its container must be disposed of as hazardous waste.

S60 2.2.3. Special Rules For Supplemental Label Elements For Certain Mixtures None.

2.2.4. Additional Labeling Not required.

2.3 Hazard Identification This product is harmful by inhalation and if swallowed, may impair fertility and may cause harm to the unborn child.

2.3.1 Skin Contact The material can produce chemical burns following direct contact with the skin.

Open cuts, abraded or irritated skin should not be exposed to this material.

Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects.

2.3.2 Eye Contact When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty-four hours or more after instillation.

2.3.3 Ingestion Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal or may produce serious damage to the health of the individual.

The material can produce chemical burns within the oral cavity and gastrointestinal tract following ingestion.

2.3.4 Inhalation This product is harmful by inhalation.

Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further disability if excessive concentrations of particulate are inhaled.

2.3.5 Long term effects There is sufficient evidence to provide a strong presumption that human exposure to the material may result in developmental toxicity, generally on the basis of: - clear results in appropriate animal studies where effects have been observed in the absence of marked maternal toxicity, or at around the same dose levels as other toxic effects but which are not secondary non-specific consequences of the other toxic effects.

Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.

Chronic and/or sub-lethal exposure to inorganic chlorate may have deleterious effects on human health, such as redness of the eyes and skin (including dermatitis), sore throat, abdominal pain, blue lips or skin, diarrhea, nausea, vomiting, shortness of breath, and unconsciousness.

2.3.6 Adverse Environmental Effects Toxic to aquatic life Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Â

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2.3.7

Physical and chemical hazards : No particular fire or explosion hazard 2.4 Additional Information Caution - substance not yet tested completely Full text of R-, H- and EUH-phrases: see section 16 3. COMPOSITION/INFORMATION ON INGREDIENTS 3.1 Description Of The Substance Solid Powder Mixture Of The Following Substances With The Nonhazardous Raw Materials 3.2 Hazardous ingredients NAME

EINECS NO

CAS NO.

CONTENT

Potassium Chlorate [KClO3]

223-289-7

3811-04-9

>50

CLASSIFICATION CLP

O; R9 Xn; R20/22 N; R51-53

Diammonium oxalate monohydrate [C2H10N2O5]

214-202-3

6009-70-7

15-30

Diboron Trioxide [B2O3]

215-125-8

1303-86-2

5-15

Disodium Tetraborate Decahydrate

215-540-4

1303-96-4

1-5

Xn; R21/22

WARNING Acute Tox. 4;H312 Acute Tox. 4;H302

Repr. Cat. 2; R60-

DANGER Repr. 1B;H360FD

Repr. Cat. 2; R60-

DANGER Repr. 1B;H360FD

61

61

DANGER Ox. Sol. 1;H271 Acute Tox. 4;H332 Acute Tox. 4;H302 Aquatic Chronic 2;H411

3.3 Additional information · Full text of R-, H- and EUH-phrases: see section 16.

4. FIRST AID MEASURES 4.1 Description of first aid measures 4.1.1 General information · Show this safety data sheet to the doctor in attendance.

4.1.2 Following inhalation  If fumes or combustion products are inhaled remove from contaminated area.  Lay patient down. Keep warm and rested.  Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid procedures.  Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. Perform CPR if necessary.  Transport to hospital, or doctor.  Inhalation of vapours or aerosols (mists, fumes) may cause lung oedema.  Corrosive substances may cause lung damage (e.g. lung oedema, fluid in the lungs).  As this reaction may be delayed up to 24 hours after exposure, affected individuals need complete rest (preferably in semi-recumbent posture) and must be kept under medical

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observation even if no symptoms are (yet) manifested.

Before any such manifestation, the administration of a spray containing a dexamethasone derivative or beclomethasone derivative may be considered.  This must definitely be left to a doctor or person authorised by him/her.

(ICSC13719) 4.1.3 Following skin contact If skin or hair contact occurs:  Immediately flush body and clothes with large amounts of water, using safety shower if available.  Quickly remove all contaminated clothing, including footwear.  Wash skin and hair with running water. Continue flushing with water until advised to stop by the Poisons Information Centre.  Transport to hospital, or doctor.

4.1.4 Following eye contact  Immediately hold eyelids apart and flush the eye continuously with running water.  Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids.  Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15 minutes.  Transport to hospital or doctor without delay. · Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

4.1.5 Following ingestion · For advice, contact a Poisons Information Centre or a doctor at once. · Urgent hospital treatment is likely to be needed. · If swallowed do NOT induce vomiting. · If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and prevent aspiration. · Observe the patient carefully. · Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious. · Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably drink. · Transport to hospital or doctor without delay.

4.1.6 Self-protection of the first aider · Protect skin and eyes. · Wear protective cloths.

4.1.7 Notes for the doctor · Treat symptomatically. · Exposed workers should be medically examined regularly with emphasis on respiratory system. Individuals with pulmonary disease should be precluded from exposure.

4.2 Indication of any immediate medical attention and special treatment needed  Treatment must be prompt.  Give immediately by mouth, a dilute solution of any soluble calcium salt; calcium lactate, 

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lime water, finely pulverised chalk or plaster suspended in a large volume of water or milk.

Large amounts of calcium are required to inactivate oxalate by precipitating it as the insoluble calcium salt. Do NOT give an emetic drug.

Perform gastric lavage carefully or not at all if severe mucosal injury is evident. Dilute lime water (calcium hydroxide) makes a good lavage fluid if used in large quantity.

Administer a slow intravenous injection of 10-20 ml of calcium gluconate (10% solution) or of calcium chloride (5% solution). This injection may be repeated frequently to prevent hypocalcaemic tetany. Calcium gluconate (10 m) may also be given intramuscularly every few hours. Calcium compounds are never given subcutaneously; even the intramuscular route is hazardous in infants because of the incidence of sloughing.

In severe cases parathyroid extract (100 USP units) should be given intramuscularly.

Morphine may be necessary to control pain.

Treat shock by cautious intravenous injection of isotonic saline solution. Check for metabolic acidosis and infuse sodium bicarbonate if necessary.

Watch for oedema of the glottis late formation of oesophageal stricture.

Useful demulcents by mouth include milk of magnesia, bismuth subcarbonate, and mineral oil.

Prophylactic and therapeutic measures in anticipation of renal damage.

[GOSSELIN SMITH HODGE: Clinical Toxicology of Commercial Products]  Oxalates are readily metabolized to oxalic acid in the body. Oxalic acid is excreted in the urine at a rate of 8-40 mg/day in healthy normal men and women. About half is excreted as oxalic acid and half as magnesium, calcium or other salts. Ingested oxalic acid is also excreted in the feces. In rats, approximately half of ingested oxalic acid is destroyed by bacterial action and about 25% is excreted unchanged in the feces. In humans, calcium oxalate is deposited in the kidneys as crystals and may be deposited in non-crystalline form, bound to lipid, in the liver and other body tissues.   

For chlorates: For severe intoxication: Empty the stomach by lavage and aspiration or by emesis, give demulcents or sweetened drinks and maintain respiration.

Pethidine may be given if required. A 1% solution of sodium thiosulfate may be used for lavage and may also be given by intravenous infusion.

Haemodialysis, peritoneal dialysis or exchange perfusions may be of value in removing chlorate from the blood. Forced diuresis should not be attempted if there is inadequate urine input.

MARTINDALE: The Extra Pharmacopoeia, 27th Edition 



The high sensitivity of glucose-6-phosphate dehydrogenase to denaturation by chlorate explains the inefficacy of methylene blue to reduce methaemoglobin formed, as the antidotal effect of methylene blue depends on NADPH formed mainly by the oxidation of glucose-6phosphate.

The observed changes occur only in the presence of methaemoglobin which forms a destabilizing complex with chlorate. Methaemoglobin thus auto catalytically increases

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methaemoglobin formation and destruction of the erythrocyte.

Treatment regime for bromates may also act as a guide for chlorate poisonings.        

Syrup of ipecac or gastric lavage with tap water or perhaps a 1% solution of sodium thiosulfate Administer a demulcent and an analgesic like meperidine (Demerol). Avoid morphine.

If readily available, the prompt use of haemodialysis or peritoneal lavage may serve to remove absorbed but unreacted chlorate in significant amounts.

Administer oxygen. If methaemoglobinaemia becomes severe a replacement transfusion with whole blood may become necessary.

DO NOT attempt to correct methaemoglobinaemia with methylene blue as the dye may enhance the toxicity.

Sodium thiosulfate solution (100 to 500 ml of 1%) by intravenous drip has been recommended by some authors.

Correct dehydration by infusing intravenously a glucose solution (5% in water). Avoid electrolytes (except as above) unless acid-base imbalance or shock becomes severe.

Supportive treatment of acute renal failure. [GOSSELIN et al, Clinical Toxicology of Commercial Products, Fifth Edition]

Depending on the degree of exposure, periodic medical examination is indicated. The symptoms of lung oedema often do not manifest until a few hours have passed and they are aggravated by physical effort. Rest and medical observation is therefore essential. Immediate administration of an appropriate spray, by a doctor or a person authorised by him/her should be considered.

(ICSC24419/24421 5. FIRE-FIGHTING MEASURES 5.1 General Information and Flammable Properties  Noncombustible.  Not considered a significant fire risk, however containers may burn.

5.2 Extinguishing media: FOR SMALL FIRE:  USE FLOODING QUANTITIES OF WATER.  DO NOT use dry chemical, CO2, foam or halogenated-type extinguishers.

FOR LARGE FIRE  Flood fire area with water from a protected position 5.3 Special hazards arising from the product Fire Incompatibility:  Avoid storage with reducing agents.  Avoid any contamination of this material as it is very reactive and any contamination is potentially hazardous 5.4 Advice for fire-fighters Fire Fighting: · Alert Fire Brigade and tell them location and nature of hazard.

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· May be violently or explosively reactive. · Wear full body protective clothing with breathing apparatus. · Prevent, by any means available, spillage from entering drains or water courses. · Fight fire from a safe distance, with adequate cover. · Extinguishers should be used only by trained personnel. · Use water delivered as a fine spray to control fire and cool adjacent area. · DO NOT approach containers suspected to be hot. · Cool fire exposed containers with water spray from a protected location. · If safe to do so, remove containers from path of fire. · If fire gets out of control withdraw personnel and warn against entry. · Equipment should be thoroughly decontaminated after use Fire/Explosion Hazard: · Will not burn but increases intensity of fire. · Heating may cause expansion or decomposition leading to violent rupture of containers. · Heat affected containers remain hazardous. · Contact with combustibles such as wood, paper, oil or finely divided metal may produce spontaneous combustion or violent decomposition. · May emit irritating, poisonous or corrosive fumes.

5.5 Additional information · If involved in a fire, keep containers cool with water spray. · If safe to do so, remove containers from path of fire. · Consider evacuation.

6. ACCIDENTAL RELEASE MEASURES 6.1 Personal precautions, protective equipment and emergency procedures Personal Protective Equipment · Gloves, boots (chemical resistant).Breathing apparatus.

Minor Spills: · Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills before discharge or disposal of material. · Check regularly for spills and leaks. · Clean up all spills immediately. · No smoking, naked lights, ignition sources. · Avoid all contact with any organic matter including fuel, solvents, sawdust, paper or cloth and other incompatible materials, as ignition may result. · Avoid breathing dust or vapours and all contact with skin and eyes. · Control personal contact by using protective equipment. · Contain and absorb spill with dry sand, earth, inert material or vermiculite. · DO NOT use sawdust as fire may result. · Scoop up solid residues and seal in labeled drums for disposal. · Neutralize/decontaminate area.

Major Spills: · Clear area of personnel and move upwind. · Alert Fire Brigade and tell them location and nature of hazard. · May be violently or explosively reactive. www.tafteed.com

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· · · · · · · · · · · · ·

Wear full body protective clothing with breathing apparatus.

Prevent, by any means available, spillage from entering drains or water courses.

No smoking, flames or ignition sources.

Increase ventilation.

Contain spill with sand, earth or other clean, inert materials.

NEVER USE organic absorbents such as sawdust, paper or cloth.

Use spark-free and explosion-proof equipment.

Collect any recoverable product into labeled containers for possible recycling.

Avoid contamination with organic matter to prevent subsequent fire and explosion.

DO NOT mix fresh with recovered material.

Collect residues and seal in labeled drums for disposal.

Wash area and prevent runoff into drains.

Decontaminate equipment and launder all protective clothing before storage and reuse. · If contamination of drains or waterways occurs advise emergency services.

6.2 Environmental precautions · If contamination of sewers or waterways has occurred advise emergency services or local regulatory body. · Spillages or uncontrolled discharges into watercourses must be alerted to the Environmental Agency or other appropriate regulatory body. · See section 12 6.3 Methods and material for containment and cleaning up 6.3.1 For containment Minor Spills:  Clean up all spills immediately.  Avoid contact with skin and eyes.  Control personal contact by using protective equipment.  Use dry clean up procedures and avoid generating dust.  Place in a suitable, labeled container for waste disposal.

Major Spills:

Moderate hazard.

     

CAUTION: Advise personnel in area.

Alert Emergency Services and tell them location and nature of hazard.

Control personal contact by wearing protective clothing.

Prevent, by any means available, spillage from entering drains or water courses.

Recover product wherever possible.

IF DRY: Use dry clean up procedures and avoid generating dust. Collect residues and place in sealed plastic bags or other containers for disposal.  IF WET: Vacuum/shovel up and place in labeled containers for disposal.  ALWAYS: Wash area down with large amounts of water and prevent runoff into drains.  If contamination of drains or waterways occurs, advise Emergency Services.

6.3.2 For cleaning up · Clean mechanically.

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6.3.3 Other information · Keep in suitable, closed containers for disposal.

6.4 Reference to other sections · See Section 13.

7. HANDLING AND STORAGE 7.1 Precautions for safe handling 7.1.1 Protective measures Personal preventions  Avoid personal contact and inhalation of dust, mist or vapours.  Provide adequate ventilation.  Always wear protective equipment and wash off any spillage from clothing.  Keep material away from light, heat, flammables or combustibles.  Keep cool, dry and away from incompatible materials.  Avoid physical damage to containers.  DO NOT repack or return unused portions to original containers. Withdraw only sufficient amounts for immediate use.  Contamination can lead to decomposition leading to possible intense heat and fire.  When handling NEVER smoke, eat or drink.  Always wash hands with soap and water after handling.  Use only good occupational work practice.  Observe manufacturer's storing and handling directions.

Fire preventions  See section 5 Dust generation preventions:  Check the amounts in atmosphere where the people work in accordance with the professional exposure limits.

Environmental precautions:  Ensure adequate ventilation.

Other Information:  Store in original containers.  Keep containers securely sealed as supplied.  Store in a cool, well ventilated area.  Keep dry.  Store under cover and away from sunlight.  Store away from flammable or combustible materials, debris and waste. Contact may cause fire or violent reaction.  Store away from incompatible materials and foodstuff containers.  DO NOT stack on wooden floors or pallets.  Protect containers from physical damage.  Check regularly for leaks.  Observe manufacturer's storage and handling recommendations

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In addition, Goods of Class 5.1, packing group II should be:  stored in piles so that  the height of the pile does not exceed 1 metre  the maximum quantity in a pile or building does not exceed 1000 tonnes unless the area is provided with automatic fire extinguishers  the maximum height of a pile does not exceed 3 metres where the room is provided with automatic fire extinguishers or 2 meters if not.  the minimum distance between piles is not less than 2 metres where the room is provided with automatic fire extinguishers or 3 meters if not.  the minimum distance to walls is not less than 1 metre.

7.1.2 Advice on general occupational hygiene  Do not to eat, drink and smoke in work areas;  Wash hands after use;  Remove contaminated clothing and protective equipment before entering eating areas.

7.2 Conditions for safe storage, including any incompatibilities Suitable container:  DO NOT use aluminium or galvanised containers  DO NOT repack. Use containers supplied by manufacturer only.

For low viscosity materials  Drums and jerricans must be of the non-removable head type.  Where a can is to be used as an inner package, the can must have a screwed enclosure.

For materials with a viscosity of at least 2680 cSt. (23 deg. C) and solids:  Removable head packaging and  cans with friction closures may be used.

Where combination packages are used, and the inner packages are of glass, there must be sufficient inert cushioning material in contact with inner and outer packages *.  In addition, where inner packagings are glass and contain liquids of packing group I and II there must be sufficient inert absorbent to absorb any spillage *.  unless the outer packaging is a close fitting moulded plastic box and the substances are not incompatible with the plastic.

Storage incompatibility:  Inorganic oxidising agents can react with reducing agents to generate heat and products that may be gaseous (causing pressurization of closed containers). The products may themselves be capable of further reactions (such as combustion in the air).  Organic compounds in general have some reducing power and can in principle react with compounds in this class. Actual reactivity varies greatly with the identity of the organic compound.  Inorganic oxidising agents can react violently with active metals, cyanides, esters, and thiocyanates.  Inorganic reducing agents react with oxidizing agents to generate heat and products that may be flammable, combustible, or otherwise reactive. Their reactions with oxidizing agents may be violent.  Incidents involving interaction of active oxidants and reducing agents, either by design or www.tafteed.com

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accident, are usually very energetic and examples of socalled redox reactions.

Contact with acids produces toxic fumes Avoid any contamination of this material as it is very reactive and any contamination is potentially hazardous Intimate mixtures of chlorates, bromates or iodates of barium, cadmium, calcium, magnesium, potassium, sodium or zinc, with finely divided aluminium, arsenic, copper, carbon, phosphorus, sulfur, hydrides of alkali- and alkaline earth-metals; sulfides of antimony, arsenic, copper or tin; metal cyanides, thiocyanates; or impure manganese dioxide may react explosively or violently, either spontaneously (especially in the presence of moisture) or on initiation by heat, impact or friction, sparks or addition of sulfuric acid.

BRETHERICKS HANDBOOK OF REACTIVE CHEMICAL HAZARDS, 4th Edition  Avoid storage with reducing agents.  Segregate chlorates from organic matter, acids, poisonous gases, flammables, corrosives, aluminium and ammonium salts and any other combustible material.  Mixtures of chlorates with fibrous and absorbent organic materials such as wood, paper, leather, flour, sawdust, sugar, shellac, may be ignited or caused to explode by static sparks, friction or shock.  The extreme hazardous nature of mixtures of metal chlorates with phosphorus or sulfur, apart from being powerful explosives, are dangerously sensitive to friction or shock; spontaneous ignition occasionally occurs.  Mixtures with sucrose, lactose, chromium, sulfur dioxide, sodium amide, zirconium, germanium and titanium explode on heating.  Forms incompatible sometimes explosive mixtures with thorium dicarbide, strontium hydride, hydrogen iodide, fluorine, cyanoguanidine, cyanides, dinickel trioxide, powdered carbon, aqua regia and ruthenium, nitric acid, manganese dioxide and potassium hydroxide or boron.  Chlorates should not be allowed to come into contact with ammonium salts, aluminium and other powdered metals, phosphorous, silicon, sulfur, sulfides, sulfuric acid, nitrobenzene, iodides and tartaric acid  Mixtures with hydrocarbons, metal phosphides (Zn, Ag, Al, Cu, Hg, Mg, etc), metal thiocyanates, metal sulfides, arsenic, carbon, phosphorous,sulfur, ammonium salts, powdered metals, arsenic trioxide, phosphorous, silicon, sulfur, sulfides, sulfites and hyposulfites are easily ignited (by friction impact or heat) and are potentially explosive.  Metal chlorates in contact with strong acids liberate explosive chlorine dioxide gas. With concentrated sulfuric acid a violent explosion can occur unless effective cooling is used.

Mixing potassium chlorate and concentrated sulfuric acid results in an explosion with optimum temperature range being 120-130. Heating a moist mixture of metal chlorate and a dibasic organic acid (tartaric or citric acid) liberates chlorine dioxide diluted with carbon dioxide.  Fusion of chlorates with metal cyanides may lead to an explosion.  Chlorates containing 1-2% bromate or sulfur are liable to spontaneous explosion.  Chlorates releases oxygen, chlorine and chlorine dioxide when heated above 300 deg. C..  In presence of moisture may release oxygen and ozone

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Package Material Incompatibilities:  No data available Shelf life:  The minimum shelf life is three (3) years, in plastic bags, dry medium (60% or less relative humidity)  Shelf life can extend to 5 or more years if it is kept well dry.

7.3 Specific end uses · See section 1.2 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Control parameters 8.1.1 Derived No Effect Level (DNEL) 

No data available

8.1.2 Occupational exposure limits 

No data available

8.2 Exposure controls 8.2.1 Appropriate engineering controls: · Local exhaust ventilation usually required. If risk of overexposure exists, wear approved respirator. Correct fit is essential to obtain adequate protection.

Supplied-air type respirator may be required in special circumstances. Correct fit is essential to ensure adequate protection. · An approved self contained breathing apparatus (SCBA) may be required in some situations. · Provide adequate ventilation in warehouse or closed storage area. Air contaminants generated in the workplace possess varying "escape" velocities which, in turn, determine the "capture velocities" of fresh circulating air required to effectively remove the contaminant.

Type of Contaminant: Solvent vapours, degreasing etc., evaporating from tank (in still air). aerosols, fumes from pouring operations, intermittent container filling, low speed conveyer transfers, welding, spray drift, plating acid fumes, pickling (released at low velocity into zone of active generation)

Air Speed: 0.25-0.5 m/s (50-100 f/min.)

0.5-1 m/s (100-200 f/min.)

direct spray, spray painting in shallow booths, drum 1-2.5 m/s (200-500 f/min.) filling, conveyer loading, crusher dusts, gas discharge (active generation into zone of rapid air motion) grinding, abrasive blasting, tumbling, high speed wheel 2.5-10 m/s (500-2000 f/min.) generated dusts (released at high initial velocity into zone of very high rapid air motion).

Within each range the appropriate value depends on: Lower end of the range Upper end of the range 1: Room air currents minimal or favorable to capture 1: Disturbing room air currents

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2: Contaminants of low toxicity or of nuisance value only.

2: Contaminants of high toxicity

3: Intermittent, low production.

4: Large hood or large air mass in motion 1: Room air currents minimal or favorable to capture

3: High production, heavy use 4: Small hood-local control only 1: Disturbing room air currents

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Simple theory shows that air velocity falls rapidly with distance away from the opening of a simple extraction pipe. Velocity generally decreases with the square of distance from the extraction point (in simple cases). Therefore the air speed at the extraction point should be adjusted, accordingly, after reference to distance from the contaminating source. The air velocity at the extraction fan, for example, should be a minimum of 1-2 m/s (200-400 f/min) for extraction of solvents generated in a tank 2 meters distant from the extraction point. Other mechanical considerations, producing performance deficits within the extraction apparatus, make it essential that theoretical air velocities are multiplied by factors of 10 or more when extraction systems are installed or used.

8.2.2 Personal protection equipment 8.2.2.1 Eye / Face protection: · Chemical goggles. · Full face shield may be required for supplementary but never for primary protection of eyes · Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. · A written policy document, describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. · Lens should be removed at the first signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands thoroughly.

[CDC NIOSH Current Intelligence Bulletin 59] 8.2.2.2 Skin protection Hand protection  Wear chemical protective gloves, e.g. PVC.  Wear safety footwear or safety gumboots, e.g. Rubber Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include: such as:  frequency and duration of contact,  chemical resistance of glove material,  glove thickness and  dexterity Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739).  When prolonged or frequently repeated contact may occur, a glove with a protection class of 5 or higher (breakthrough time greater than 240 minutes according to EN 374) is recommended.  When only brief contact is expected, a glove with a protection class of 3 or higher

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(breakthrough time greater than 60 minutes according to EN 374) is recommended.  Contaminated gloves should be replaced.

Gloves must only be worn on clean hands. After using gloves, hands should be washed and dried thoroughly. Application of a non-perfumed moisturiser is recommended.  DO NOT wear cotton or cotton-backed gloves.  DO NOT wear leather gloves.  Promptly hose all spills off leather shoes or boots or ensure that such footwear is protected with PVC over-shoes.

Body protection  Overalls. · P.V.C. apron. · PVC protective suit may be required if exposure severe.

Other protection · Eyewash unit. · Ensure there is ready access to a safety shower. · Some plastic personal protective equipment (PPE) (e.g. gloves, aprons, overshoes) is not recommended as they may produce static electricity. · For large scale or continuous use wear tight-weave non-static clothing (no metallic fasteners, cuffs or pockets), non-sparking safety footwear. · Wash hands before breaks and at the end of workday. · Wash thoroughly after using product. · Wash contaminated clothing. · Wash hands before eating or drinking. · Use Barrier cream. · Use Skin cleansing cream. · Use Eye wash unit.

8.2.2.3 Respiratory protection  Respirators may be necessary when engineering and administrative controls do not adequately prevent exposures.  The decision to use respiratory protection should be based on professional judgment that takes into account toxicity information, exposure measurement data, and frequency and likelihood of the worker's exposure - ensure users are not subject to high thermal loads which may result in heat stress or distress due to personal protective equipment (powered, positive flow, full face apparatus may be an option).  Published occupational exposure limits, where they exist, will assist in determining the adequacy of the selected respiratory. These may be government mandated or vendor recommended.  Certified respirators will be useful for protecting workers from inhalation of particulates when properly selected and fit tested as part of a complete respiratory protection program.  Use approved positive flow mask if significant quantities of dust becomes airborne.

Try to avoid creating dust conditions.

8.2.3 Environmental exposure controls · Legislation for the protection of the environment must be met in full.

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9. PHYSICAL AND CHEMICAL PROPERTIES 9.1 Important health, safety and environmental information 9.2 Appearance Solid - Powder Form/Physical state White Color No odor Odorless 9.3 Safety relevant basic data Value pH (1% Solution) (25 °C) Meting Range (°C) Boiling point/range (°C)101,3 kPa Decomposition Temperature (°C) Flash Point (°C)closed cup Ignition temperature (°C) Vapour pressure hPa at …(°C) Vapour density (air=1) Bulk Density (kg7m3) (Powder Material) Solubility in water Solubility in other media Partition Coefficient n-octanol/water (log Po/w) Viscosity, dynamic )mPa.s) Lower Explosion Limit (as volume and in air) Upper Explosion Limit (as volume and in air) Molecular Weight Specific Gravity (Water=1) Oxidation Property

pH of water soluble part3 : 7 pH of the solid after use4 : 8 None No data available No data available No data available No data available None None 1000±50 Partially soluble in water Insoluble in oils and other solvents No data available No data available No data available Not applicable Not applicable 60,08 2,635-2,660 No data available

9.4 Physical Hazards Explosivity

Flammability

Self-Ignition Property

Oxidative Property

Effect of Electricity

No explosive property An impact of 38,5 N was ineffective. No explosive effect was observed. The material was compressed by 5000 psi (320 atm) and no observable change has been recorded.

Nonflammable at room temperature and higher temperatures.

The material is not flammable in open flame for short times. However, it gives an exothermic reaction with a bright light at around 450-500 °C. It burns with a fast cracking sound in a very short time No self-ignition property It has no oxidative effect in its solid state. It I,s fairly a strong oxidant in humid and aqueous media for most metals.

In humid and aqueous media it oxidizes and rusts the metals (chromium, nickel, copper and iron etc.) because of its ingredients.

No change was observed by application of city voltage

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and current.

No change, - like burning explosion – was observed upon applying 220 volts city potential and 10 amperes current.

9.5 Other Safety Information Hygroscopic Properties

Shelf Life

Gases evolved after use

Solid material has capacity to absorb water and water vapor. The material must be stored dry.

The solid cakes in 100 % humid medium in 72 hr. and dries very slowly at room temperature. This caking causes the loss of easy flow solid powder.

The minimum shelf life is three (3) years, in plastic bags, dry medium (60% or less relative humidity) Shelf life can extend to 5 or more years if it is kept well dry.

Carbon dioxide, water vapor, nitrogen and chlorine Chlorine gas released during use was absorbed by the solid medium rocks.

Note : The above features was determined according to prescribed methods at the Classification, Packaging and Labeling of Hazardous Substances Regulation Section A-3 or a method comparable to the other.

10. STABILITY AND REACTIVITY 10.1 Reactivity : See section 7.2 10.2 Chemical stability  Presence of incompatible materials.  Product is considered stable under normal handling conditions.  Prolonged exposure to heat.  Hazardous polymerisation will not occur.  Presence of elevated temperatures.  Presence of incompatible materials.

10.3 Possibility of hazardous reactions · See section 7 10.4 Conditions to avoid: · No data availbale 10.5 Incompatible materials: · Strong reducing agents, Powdered metals, Strong acids, Alcohols, Organic materials 10.6 Hazardous decomposition products: · Hazardous decomposition products formed under fire conditions. - Hydrogen chloride gas, Potassium oxides 10.7 Hazardous polymerization: · Has not been reported.

11. TOXICOLOGICAL INFORMATION 11.1 General Information · No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label.

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Potassium chlorate [CAS#3811-04-9]  LD50 Oral - rat - 1.870 mg/kg  LD50 Dermal - rabbit - > 2.000 mg/kg Ammonium oxalate monohydrate [CAS#6009-70-7]  No Data Available Boric anhydride [CAS#1303-86-2]  LD50 Oral - mouse - 3.163 mg/kg Boron Decahydrate [CAS#1303-96-4]  LD50 Oral - rat - 4.500 - 5.000 mg/kg  LD50 Dermal - rabbit - 10.000 mg/kg Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur following exposure to high levels of highly irritating compound. Key criteria for the diagnosis of RADS include the absence of preceding respiratory disease, in a non-atopic individual, with abrupt onset of persistent asthma-like symptoms within minutes to hours of a documented exposure to the irritant. A reversible airflow pattern, on spirometry, with the presence of moderate to severe bronchial hyper reactivity on methacholine challenge testing and the lack of minimal lymphocytic inflammation, without eosinophilia, have also been included in the criteria for diagnosis of RADS. RADS (or asthma) following an irritating inhalation is an infrequent disorder with rates related to the concentration of and duration of exposure to the irritating substance. Industrial bronchitis, on the other hand, is a disorder that occurs as result of exposure due to high concentrations of irritating substance (often particulate in nature) and is completely reversible after exposure ceases. The disorder is characterised by dyspnea, cough and mucus production. Oral (rat) LD50: 4500-5000 mg/kg Eyes (rabbit) (-) Mild [Orica BORAX-Europe]Reproductive effector in rats Mutagenic towards bacteria 11.3 Skin corrosion/irritation and Eye damage/irritation: Potassium chlorate [CAS#3811-04-9]  Skin corrosion/irritation : Skin - rabbit - Mild skin irritation  Serious eye damage/eye irritation : Eyes - rabbit - Mild eye irritation Ammonium oxalate monohydrate [CAS#6009-70-7]  No Data Available Boric anhydride [CAS#1303-86-2]  No Data Available Boron Decahydrate [CAS#1303-96-4]  No Data Available 11.4 CMR effects (Carcinogenity) : Quartz ACGIH: A2 - Suspected Human Carcinogen California: carcinogen, initial date 10/1/88 (airborne particles of re NTP5: Known carcinogen (listed as Silica, crystalline (general f IARC6: Group 1 CARCINOGENIC TO HUMANS  The International Agency for Research on Cancer (IARC) has classified occupational exposures to respirable (<5 um) crystalline silica as being carcinogenic to humans .  This classification is based on what IARC considered sufficient evidence from

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epidemiological studies of humans for the carcinogenicity of inhaled silica in the forms of quartz and cristobalite.

Crystalline silica is also known to cause silicosis, a non-cancerous lung disease

Other: See actual entry in RTECS for complete information.

11.5 CMR7 effects (Mutagenicity and Toxicity for reproduction) : ď&#x192;&#x2014;

Not reported as mutagenic or toxic for reproduction

11.6 Other Toxicological Effects: Allergic Effects Not known Repeated or prolonged exposure to corrosives may result in the erosion of teeth, inflammatory and ulcerative changes in the mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial pneumonia may ensue.

Gastrointestinal disturbances may also occur.

Chronic exposures may result in dermatitis and/or conjunctivitis.

Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health effects involving organs or biochemical systems.

Chronic and/or sub-lethal exposure to inorganic chlorate may have deleterious effects on human health, such as redness of the eyes and skin (including dermatitis), sore throat, abdominal pain, blue lips or skin, diarrhea, nausea, vomiting, shortness of breath, and unconsciousness.

Sodium chlorate may damage the liver, kidneys, and blood cells of humans.

Subchronic chlorate exposure was associated with smaller body and organ weights, blood abnormalities and pituitary and thyroid Effects on Repeated Doses abnormalities in one study using Sprague-Dawley rats. Chlorate is a thyroid toxicant producing thyroid gland follicular cell hypertrophy in rats and mice following chronic exposures, and may produce follicular cell tumors in rats.

The lack of mutagenicity indicates that the thyroid tumors are induced by a non-mutagenic mechanism and are therefore not likely to be carcinogenic.

The effects may be attributed to changes in levels of thyroid hormones seen after administration of high doses of sodium chlorate. In female mice there was equivocal and marginal evidence of increased pancreatic islet carcinoma. Sodium chlorate was negative in most bacterial gene mutation assays and in several cytogenetics tests, including a hypoxanthineguanine phosphoribosyl-transferase (HGPRT) assay in Chinese hamster ovaries and a micronucleus assay.

Intramuscular administration of potassium chlorate to pregnant rats resulted in a prolonged gestation period in most cases, and reduced neonatal weight relative to the controls. According to the author, newborn rats also showed a "marked" increase of haematopoietic residue and lipid deposit over controls, and occasionally, exposure

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Sensitization

Developmental Toxicity (Teratogenicity)

Fertility

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resulted in the appearance of hyaline droplets and casts in newborn kidneys .

The number of animals per treatment group/number affected, duration of exposure, and information on dose levels was not available.

African green monkeys (five males and seven females) were used to study the thyroid effects of sodium chlorate when administered for 3060 days as chlorate at Concentrations of 4, 7.5, 15, 30 or 58.4 mg/kg bw per day.

Chlorate did not induce thyroid depression.

Chlorate did not induce a dose-dependent oxidative stress, as was observed in the case of chlorite.

Female rats were exposed to 1 or 10 mg chlorate/L in their drinking water for ten weeks. Fetuses were taken on the 20th day of gestation and examined for external, visceral and skeletal malformations. No significant adverse findings were reported.

No chromosomal abnormalities were seen in either the micronucleus test or a cytogenetic assay in mouse bone marrow cells following gavage dosing with chlorate.

Chronic exposure to oxalates may result in circulatory failure or nervous system irregularities may follow prolonged calcium metabolism due to oxalation. Prolonged and severe exposure can cause chronic cough, albuminuria, vomiting, pain in the back and gradual emaciation and weakness. Prolonged or repeated overexposure may result in delayed liver and/or kidney damage.

Certain rare individuals are subject to oxalosis (deposition of oxalates in the kidneys) and are unusually reactive to any exposure. Rats administered oxalic acid at 2.5 and 5% in the diet for 70 days developed depressed thyroid function and weight loss. A study of railroad car cleaners in Norway who were heavily exposed to oxalic acid solutions and vapors revealed a 53% prevalence of urolithiasis (the formation of urinary stones), compared to a rate of 12% among unexposed workers from the same company. In a multi generation study in mice, toxic effects in pups were seen only at maternally toxic doses. Oxalic acid is negative for genotoxicity in reverse mutation assays.

None.

May cause harm to the unborn child.

There is sufficient evidence to provide a strong presumption that human exposure to the material may result in developmental toxicity, generally on the basis of: - clear results in appropriate animal studies where effects have been observed in the absence of marked maternal toxicity, or at around the same dose levels as other toxic effects but which are not secondary non-specific consequences of the other toxic effects.

May impair fertility.

There is sufficient evidence to provide a strong presumption that

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human exposure to the material may result in impaired fertility on the basis of: - clear evidence in animal studies of impaired fertility in the absence of toxic effects, or evidence of impaired fertility occurring at around the same dose levels as other toxic effects but which is not a secondary non-specific consequence of other toxic effects.

Aspiration hazard None 8 11.7 STOT -single/repeated exposures: STOT-single exposure None Prolonged exposure to dust containing respirable quartz may cause STOT-repeated exposure silicosis or pneumoconiosis.

11.8 Symptoms related to the physical, chemical and toxicological characteristics: Persons with impaired respiratory function, airway diseases and conditions such as emphysema or chronic bronchitis, may incur further disability if excessive concentrations of particulate are inhaled.

If prior damage to the circulatory or nervous systems has occurred or if kidney damage has been sustained, proper screenings should be conducted on individuals who may be exposed to further risk if handling and use of the material result in excessive exposures.

In case of inhalation Inhalation of dusts, generated by the material, during the course of normal handling, may be harmful. Limited evidence or practical experience suggests that the material may produce irritation of the respiratory system, in a significant number of individuals, following inhalation. In contrast to most organs, the lung is able to respond to a chemical insult by first removing or neutralising the irritant and then repairing the damage.

The material can produce chemical burns following direct contact with the skin. Open cuts, abraded or irritated skin should not be exposed to this material. Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external damage is suitably protected. Limited evidence exists, or practical experience predicts, that the material In case of skin contact either produces inflammation of the skin in a substantial number of individuals following direct contact, and/or produces significant inflammation when applied to the healthy intact skin of animals, for up to four hours, such inflammation being present twenty-four hours or more after the end of the exposure period. Skin irritation may also be present after prolonged or repeated exposure; this may Result in a form of contact dermatitis (non-allergic).

When applied to the eye(s) of animals, the material produces severe In case of eye contact ocular lesions which are present twenty-four hours or more after instillation.

Accidental ingestion of the material may be harmful; animal experiments indicate that ingestion of less than 150 gram may be fatal In case of ingestion or may produce serious damage to the health of the individual.

The material can produce chemical burns within the oral cavity and www.tafteed.com

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gastrointestinal tract following ingestion.

Overexposure to chlorates may result in methaemoglobinaemia (lack of oxygen in blood) and cyanosis (bluish discoloration of skin and mucous membranes).

Effects may be delayed.

11.9 Additional Toxicological Information:  Toxicological classifications are based on available knowledge and information  EEC classification : T-Toxic  RTECS 9 Numbers of the product ingredients - Potassium chlorate [CAS#3811-04-9]: FO0350000 - Ammonium oxalate monohydrate [CAS#6009-70-7] : No Data Available - Boric anhydride [CAS#1303-86-2]: No Data Available - Boron Decahydrate [CAS#1303-96-4]: VZ2275000  The special effects to health are considered by taking into account the information in section 3.

12. ECOLOGICAL INFORMATION 12.1 Eco toxicity: Potassium Chlorate [CAS#3811-04-9] Toxicity to fish  LC50 - Oncorhynchus mykiss (rainbow trout) - 1,750 mg/l - 96,0 h Toxicity to daphnia and other aquatic Invertebrates  EC50 - Daphnia magna (Water flea) - 1.093 mg/l - 24 h Ammonium Oxalate Monohydrate [CAS#6009-70-7]  No Data Available Boric Anhydride [CAS#1303-86-2] Toxicity to fish  LC50 - Carassius auratus (goldfish) - 570 mg/l - 72 h Toxicity to daphnia and other aquatic Invertebrates  EC50 - Daphnia magna (Water flea) - 370 - 490 mg/l - 48 h Boron Decahydrate [CAS#1303-96-4] Toxicity to fish  LC50 - Carassius auratus (goldfish) - 178 mg/l - 72 h Toxicity to daphnia and other aquatic Invertebrates  EC50 - Daphnia magna (Water flea) - 1.085 - 1.402 mg/l - 48 h Toxicity to algae  IC50 - Desmodesmus subspicatus (green algae) - 158 mg/l - 96 h 12.2 Persistence And Degradability Decomposition Potential of the products No data available The half-life of degradation No data available Potential degradation of product content in the evaluation No data available of wastewater treatment plants

12.3 Bioaccumulation Potential Biological environment (biota) accumulation potential

No data available

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Potential - nutrients pass through Reference Values - Log Kow , Sw and BCF10

12.4 Mobility in Soil  No data available.

Water threat class Clean Water Impact Known or predicted environmental distribution

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No data available No data available

No data available No data available No data available.

12.5 Photo Degradation No data available 12.6 Results of PBT11 and vPvB12 assessment No data available 12.7 Additional Information  Toxic to aquatic life  Do not allow to be released into the environment  See the sections 6, 7, 13, 14 and 15.

13. DISPOSAL CONSIDERATIONS 13.1 Waste Water Treatment Method Waste Treatment Containers and appropriate methods Physical/chemical properties that may affect waste treatment

Sewage disposal

Special Precautions

Treatment should involve: Mixing or slurrying in water; Neutralisation followed by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical wastes or Incineration in a licensed apparatus (after admixture with suitable combustible material) Product has inhibitory effects on the activities of micro-organisms, whether the information is not related, the likely impact on waste water treatment plants is unknown.

DO NOT allow wash water from cleaning or process equipment to enter drains.

In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.

Where in doubt contact the responsible authority.

DO NOT allow wash water from cleaning or process equipment to enter drains. It may be necessary to collect all wash water for treatment before disposal. Recycle wherever possible. Consult manufacturer for recycling options or consult local or regional waste management authority for disposal if no suitable treatment or disposal facility can be identified. Treat and neutralise at an approved treatment plant.

13.2 Product / Packaging disposal  Containers may still present a chemical hazard/ danger when empty.  Return to supplier for reuse/ recycling if possible.

Otherwise:  If container cannot be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to store the same product, and then puncture containers, to prevent re-use, and bury at an authorised landfill. www.tafteed.com

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

Where possible retain label warnings and MSDS and observe all notices pertaining to the product.

FOR DISPOSAL OF SMALL QUANTITIES:  Cautiously acidify a 3% solution or a suspension of the material to pH 2 with sulfuric acid.  Gradually add a 50% excess of aqueous sodium bisulfite with stirring at room temperature.

(Other reducers such as thiosulfate or ferrous salts may substitute; do NOT use carbon, sulfur or other strong reducing agents).  An increase in temperature indicates reaction is taking place.  If no reaction is observed on the addition of about 10% of the sodium bisulfite solution, initiate it by cautiously adding more acid.  If manganese, chromium or molybdenum are present adjust the pH of the solution to 7 and treat with sulfide to precipitate for burial as a hazardous waste.  Destroy excess sulfide, neutralise and flush the solution down the drain (subject to State and Local Regulation).

13.3 Contaminated packaging  Recycle following cleaning or dispose of at an authorized site.  Decontaminate empty containers. Observe all label safeguards until containers are cleaned and destroyed.

13.4 Disposal Methods  Dispose of chemicals waste or in accordance with local regulations.  Follow all applicable local laws, rules and regulations regarding the proper disposal of this material. If this product has been altered or contaminated with other hazardous materials, appropriate waste analysis may be necessary to determine proper method for disposal. A qualified environmental professional should determine waste characterization, disposal and treatment methods for this material in accordance with applicable local regulations and requirements.

13.5 European Waste Catalogue  01 04 10 Dusty and powdery waste other than those mentioned in 01 04 07 14. TRANSPORT INFORMATION 14.1

Transport in Land, Inland Waterways, Sea and Air

UN3085 OXIDIZING SOLID, CORROSIVE, N.O.S, CLASS 5,1 II,(Potassium Chlorate, Oxalic Acid Ammonium Salt Monohydrate)

TRANSPORTATION PROPER SHIPPING NAME UN/ID No. CLASS PACKAGING GROUP

ADR13/RID14 ADNR15 IMDG16 ICAO17/IATA18 Road River Marine Airways OXIDIZING SOLID, CORROSIVE, N.O.S, CLASS 5,1 II,(Potassium Chlorate, Oxalic Acid Ammonium Salt Monohydrate) 3085 3085 3085 3085 5,1 5,1 5,1 5,1 II II II II

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Page No: 26/30

Safety Data Sheet According To Regulation (EC) No 1907/2006 (REACH)

TAFTEED Version: Form No:

1.0 122001

LABELLING NO CLASSIFICATION CODE HAZARD NO (HIN NO) LIMITED QUANTITY Equipment Required Special Provisions EmS MARINE Pollutant

Print Date: Revision Date:

5,1+8 OC2 58 LQ11

5,1+8 OC2

5,1+8 OC2

LQ0 PP

1 Kg

04.06.2011 04.06.2011

5,1 OC2

274 F-A-S-Q NO

Road Transport Notes: This product is not regulated as a hazardous material. The above regulatory prescriptions are those valid on the date of publication of this sheet. Given the possible evolution of transport regulations for hazardous materials, in case the present sheet is dating back to more than 12 months ago, it would be advisable to check their validity with your commercial agency

14.2

Transport in bulk according to Annex II of MARPOL 73 / 78 and the IBC code  No data available 15. REGULATORY INFORMATION 15.1 Safety, health and environmental regulations / legislation specific for the substance or mixture Potassium Chlorate (CAS: 3811-04-9) is found on the following regulatory lists;  "European Chemicals Agency (ECHA) List of substances identified for registration in 2010",  "European Customs Inventory of Chemical Substances (English)",  "European Union – European Inventory of Existing Commercial Chemical Substances (EINECS) (English)",  "European Union (EU) Annex I to Directive 67/548/EEC on Classification and Labelling of Dangerous Substances - updated by ATP: 31",  "European Union (EU) Control of Major Accident Hazards Involving Dangerous Substances - Seveso Category",  "European Union (EU) Inventory of Ingredients used in Cosmetic Products",  "European Union (EU) Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures - Annex VI","OECD Representative List of High Production Volume (HPV) Chemicals" Ammonium Oxalate (CAS: 1113-38-8,6009-70-7) is found on the following regulatory lists;  "European Customs Inventory of Chemical Substances (English)",  "European Union - European Inventory of Existing Commercial Chemical Substances (EINECS) (English)" Boron Oxide (CAS: 1303-86-2) is found on the following regulatory lists;  "European Chemicals Agency (ECHA) List of substances identified for registration in 2010",  "European Customs Inventory of Chemical Substances (English)",  "European Union – European Inventory of Existing Commercial Chemical Substances (EINECS) (English)",  "European Union (EU) Annex I to Directive 67/548/EEC on Classification and Labelling of Dangerous Substances - updated by ATP: 31",  "European Union (EU) Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures - Annex VI",  "Ireland Occupational Exposure Limits",  "OECD Representative List of High Production Volume (HPV) Chemicals"

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Page No: 27/30

Safety Data Sheet According To Regulation (EC) No 1907/2006 (REACH)

TAFTEED Version: Form No:

1.0 122001

Print Date: Revision Date:

04.06.2011 04.06.2011

Sodium Borate, Decahydrate (CAS: 1303-96-4) is found on the following regulatory lists;  "European Customs Inventory of Chemical Substances (English)",  "European Union (EU) Annex I to Directive 67/548/EEC on Classification and Labelling of Dangerous Substances – updated by ATP: 31",  "European Union (EU) Inventory of Ingredients used in Cosmetic Products",  "European Union (EU) Regulation (EC) No 1272/2008 on Classification, Labelling and Packaging of Substances and Mixtures - Annex VI",  "OECD Representative List of High Production Volume (HPV) Chemicals" This safety data sheet is in compliance with the following EU legislation and its adaptations – as far as applicable - : 67/548/EEC, 1999/45/EC, 76/769/EEC, 98/24/EC, 92/85/EEC, 94/33/EC, 91/689/EEC, 1999/13/EC, as well as the following British legislation: • The Control of Substances Hazardous to Health Regulations (COSHH) 2002 • COSHH Essentials The Management of Health and Safety at Work Regulations 1999 15.2 Chemical safety assessment 15.1.1 HAZARD CLP classification according to Annex VI of CLP (Regulation (EC) No 1272/2008)  Oxidising solids, Category 2,  Corrosive to metals, Category 1,  Acute toxicity (inhalation), Category 4,  Acute toxicity (oral), Category 4,  Reproductive toxicity FD, Category 1B,  Hazardous to the aquatic environment: Chronic hazard, Category 2, 15.1.2 RISK Risk Codes:  Harmful by inhalation and if swallowed.  Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.  May impair fertility and may cause harm to the unborn child.

15.2 Label Elements  This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006 and ISO 11014:2009. This product is classified according to EU Directive 67/548/EC and GHS/CLP.  System of specific information relating to Dangerous Preparations: 2001/58/EC as amended by Directive 93/112/EC, 2001/58/EC and 2006/8/EC. 16. OTHER INFORMATION 16.1 Other information  For additional information regarding TAFTEED LIMITED. Products please contact the TAFTEED



LIMITED. Technical Services Department (+ 90 312 496 48 24 ) The above information complies with the 199/45/EC and 1907/2006 Directives and their amendments. In all cases of potential poisoning supportive therapy is of the utmost importance.

If medical professionals require advice regarding first aid treatment, all TAFTEED LIMITED. products are registered with the Turkish National Poisons Unit (UZEM), UZEM local telephone no : 114 www.tafteed.com

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Page No: 28/30

Safety Data Sheet According To Regulation (EC) No 1907/2006 (REACH)

TAFTEED Version: Form No:

1.0 122001

Print Date: Revision Date:

04.06.2011 04.06.2011

16.2 Related Person   

Mr. Vasfi OZALP- TAFTEED LIMITED Prepared by :Doruk Chemical Management Systems Co Ltd. www.msdsmarket.com Competent Person Accreditation no: TSE GBF-0348 25/5/2009-TR

-

Analysis report for TAFTEED – Prepared by Middle East Technical University Department of Chemistry, April 12th ,2011,Project Code No:11-01-03-502 Safety Data Sheets for the product ingredients supplied by the manufacturers.

ACTOR - U.S. EPA Aggregated Computational Toxicology Resource AGRITOX - Base de données sur les substances actives phytopharmaceutiques CCR - Canadian Categorization Results CESAR - Canada’s Existing Substances Assessment Repository CHRIP - Information on Biodegradation and Bio concentration of the Existing Chemical Substances in the Chemical Risk information platform

 info@msdsmarket.com (contact for further information if needed) 16.3 Revision Date, Version and SDS no  Date : June 04th , 2011  Version : 1.0/EN  MSDS No : 122001 16.4 Reason of re-issue  First issue 16.5 Relevant R-, H- and EUH-phrases (number and full text): May cause fire or explosion; strong oxidizer H271 Harmful if swallowed H302 Harmful in contact with skin H312 Harmful if inhaled H332 May damage fertility or the unborn child H360FD Toxic to aquatic life with long lasting effects H411 Explosive when mixed with combustible material R9 Harmful by inhalation and if swallowed R20/22 Harmful in contact with skin and if swallowed R21/22 Toxic to aquatic organisms, may cause long-term adverse effects in the R51/53 aquatic environment May impair fertility R60 May cause harm to the unborn child R61 16.6 Classification For Mixtures And Used Evaluation Method According To EC/1207/2008 [CLP] Classification According To Classification Procedure EC/1207/2008 [CLP] Oxidising solids, Category 2, H272 On Basis of Test Data Corrosive to metals, Category 1, H290 Calculation Method Acute toxicity (inhalation), Category 4, H332 Calculation Method Acute toxicity (oral), Category 4, H302 Calculation Method Reproductive toxicity FD, Category 1B, H360FD Calculation Method 16.7 Key literature references and sources data -

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Safety Data Sheet According To Regulation (EC) No 1907/2006 (REACH)

TAFTEED Version: Form No:

1.0 122001

-

-

Print Date: Revision Date:

04.06.2011 04.06.2011

ECHA CHEM - European Chemicals Agency’s Dissemination portal with information on chemical substances registered under REACH ENVICHEM - Data Bank of Environmental Properties of Chemicals ESIS - European Chemical Substances Information System ) GHS-J - The Result of the GHS Classification by the Japanese Government HPVIS - High Production Volume Information System (HPVIS) HSDB - Hazardous Substance Data Bank HSNO CCID - New Zealand Hazardous Substances and New Organisms Chemical Classification Information Database INCHEM - Chemical Safety Information from Intergovernmental Organizations J-CHECK - Japan Chemicals Collaborative Knowledge database JECDB - Japan Existing Chemical Data Base NICNAS PEC - Australian National Industrial Chemicals Notification and Assessment Scheme (NICNAS) Priority Existing Chemical Assessment Reports OECD HPV - Organisation for Economic Cooperation and Development (OECD) Existing Chemicals Database OECD SIDS IUCLID - OECD Existing Chemicals Screening Information Data Sets (SIDS) Database SIDS UNEP - OECD Initial Assessment Reports for HPV Chemicals including Screening Information Data Sets (SIDS) as maintained by United Nations Environment Programme (UNEP) Chemicals UK CCRMP Outputs - UK Coordinated Chemicals Risk Management Programme Publications US EPA IRIS - United States Environmental Protection Agency Integrated Risk Information System US EPA SRS - United States Environmental Protection Agency Substance Registry Services

16.8 Legal disclaimer  The purpose of the above information is to describe the products only in terms of health and safety requirements.  The information given should not, therefore, be construed as guaranteeing specific properties or as specification.  Customers should satisfy themselves as to the suitability and completeness of such information for their own particular use.  The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.

The information given is designed only as guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification.  The above information relates only to the specific material(s) designated herein and may not be valid for such material(s) used in combination with any other materials or in any process or if the material is altered or processed, unless specified in the text.

1

CLP: Classification Labelling and Packaging GHS: Global Harmonised System 3 pH was determined in water soluble part the solid powder left in water for 24 hr.

4 pH of aqueous solution of the remained part after reaction ceramic crucible 5 NTP: National Toxicology Program (NIEHS) 6 IARC: International Agency for Research on Cancer (World Health Organization) 7 CMR: Carcinogenic, Mutagenic or Toxic to Reproduction (chemical safety classification) 8 STOT: Specific Target Organ Toxicity 9 RTECS : Registry of Toxic Effects of Chemical Substances 2

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Safety Data Sheet According To Regulation (EC) No 1907/2006 (REACH)

TAFTEED Version: Form No:

1.0 122001

Print Date: Revision Date:

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10

BCF: Bio concentration Factor PBT: Persistent Bioaccumulative Toxic 12 VPVB: Very Persistent, Very Bioaccumulative 13 ADR: Accord Dangereux Routier (European regulations concerning the international transport of dangerous goods by road) 14 RID: Regulations Concerning the International Transport of Dangerous Goods by Rail (European law) 15 ADNR: Regulation for the Carriage of Dangerous Substances on the Rhine (EU) 16 IMDG: International Maritime Dangerous Goods (United Nations) 17 ICAO: International Civil Aviation Organization 18 IATA: International Air Transport Association 11

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