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Novel sources of uranium
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Rising from the ashes
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Coal ash, fertiliser and even seawater may provide nuclear fuel Apr 8th 2010 | From the print edition
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ONE of the factoids trotted out from time to time by proponents of nuclear power is that conventional coal-burning power stations release more radioactivity into the environment than nuclear stations do. The reason is that the ash left over when coal is burned contains radioactive elements, notably uranium and thorium. Turn that logic on its head and it suggests that such ash is worth investigating as a source of nuclear fuel. And that is exactly what Sparton Resources, a firm based in Toronto, is doing. It has signed a deal with the China National Nuclear Corporation (CNNC), the authority that runs the country's nuclear-power stations, to recover uranium from coal ash at a site in Lincang, in Yunnan province. Uranium is usually extracted from ore that contains 1,000 or more parts per million (ppm) of the element. The Lincang coal ash holds much less, about 300ppm. That said, it does not need to be mined—which brings costs down. Sparton says it can extract a kilogram of uranium for $77 or less. Uranium's spot price is now near $90 a kilo. That is not a huge margin, but it is a profit nonetheless. To extract the uranium, Sparton adds sulphuric and hydrochloric acids to the ash, along with water, to make a
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acids dissolve the uranium, and various other things,
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leaching them from the ash. The trick is to get the dissolved
Rising from the ashes
uranium out of the resulting solution.
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slurry. With some sorts of ash, nitric acid is also used. The
Sparton's process uses a charcoal filter made from burned coconut husks to trap floating particles and eliminate organic
remove uranium ions while leaving the others behind— extracting about two-thirds of the uranium in the ash,
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according to the company. The uranium is then dissolved
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from the beads using a solution of ammonium carbonate
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compounds. The filtered solution is then passed through small beads of an ion-exchange resin. These selectively
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Novel sources of uranium: Rising from the ashes | The Economist
and precipitated as “yellow cake”, a mixture of uranium
5/18/13 11:17 AM
Nuclear energy
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oxides.
Democracy in America - May 17th, 21:50
China is developing ash-mining for reasons of energy security more than economics, according to Wang Hongfang, a marketing manager at CNNC. The country wants to get uranium from “every possible channel”, Mr Wang says. These include stripping it out of
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the tailings from gold and copper mines, and also from phosphoric acid produced during
Free exchange - May 17th, 19:19
the manufacture of fertiliser. Nor is CNNC alone in this aspiration. NUKEM, a GermanAmerican company that enriches and sells nuclear fuel, hopes soon to begin “mining”
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fertiliser in Florida.
Babbage - May 17th, 17:04
Some people are even turning to seawater as a source of uranium, in an eerie Arab television: Politician idol
recapitulation of Fritz Haber's attempt to pay off Germany's first-world-war debts by
Pomegranate - May 17th, 16:23
extracting gold from the ocean. Though seawater contains only three parts per billion of uranium, mostly in the form of uranyl tricarbonate, the element can be sucked out of it by ion exchange.
Syria's rivalrous rebels: Top dog Pomegranate - May 17th, 16:09
Several organisations, including Japan's Atomic Energy Agency and the Bhabha Atomic Research Centre in India, are attempting to do so. Their methods include the use of strips of ion-exchanging plastic, braided with polystyrene to toughen them up. These are placed in wire cages and anchored in a current of seawater. After a month or two, the plastic is
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removed and soaked in acid to dissolve the uranyl tricarbonate. The solution is then
Democracy in America - May 17th, 15:00
treated to precipitate uranium oxide.
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At the moment, this process costs more than ten times as much as conventional mining, but some countries might regard that as a small price to pay for security of supply. Perish the thought that the supply is for anything other than providing fuel for civilian nuclearpower stations.
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