E 0399 philips saeco milkclean en

SAFETY DATA SHEET According to EC 1907/2006 (REACH)

Date last verification Revision date Publication date

: 2016-06-02 : 2015-06-09 : 2012-08-07

Version number : 6.3

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1.

Product identifier

SDS Product code 12nc Supplier

: 28155 : 1322 538 18201 : GRUPPO LGM S.R.L. Via Pola 32 20096 Pioltello Italy TEL:02.9267205 - 92161349 FAX:02.9267205

Tradename

1.2.

: CA6705 PHILIPS SAECO MILK CIRCUIT CLEANER, MIXTURE

Relevant identified uses of the substance or mixture and uses advised against

General description Use Uses advised against

1.3.

: CLEANER : Various : Data not available.

Details of the supplier of the safety data sheet

Supplier safety data sheet Responsible department

1.4.

: Philips Electronics Nederland B.V., P.O. Box 218, 5600 MD Eindhoven, Tel. +31 (0)40 2747588 : dangerous.goods@philips.com

Emergency telephone number

Emergency telephone number

: +31 (0)497-598315

SECTION 2: Hazards identification 2.1.

Classification of the substance or mixture

GHS: (EC) No 1272/2008 Skin irritation Serious eye irritation Specific target organ toxicity — single exposure

Category 2 Category 2 Category 3

H315 H319 H335

EC: (EC) No 67/548 or 1999/45 Irritating to eyes, respiratory system and skin.

2.2.

Label elements

GHS: (EC) No 1272/2008 Hazard pictogram(s)

Signal word : Warning Hazard statements H315

Date of request : 2016-11-16

Causes skin irritation.

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H319 H335

Causes serious eye irritation.

May cause respiratory irritation.

Precautionary statements P101 If medical advice is needed, have product container or label at hand.

P102 Keep out of reach of children.

P103 Read label before use.

P261.6 Avoid breathing dust.

P264 Wash hands/skin thoroughly after handling.

P271 Use only outdoors or in a well-ventilated area.

P280.7 Wear protective gloves/eye protection/face protection.

P302+P352 IF ON SKIN: Wash with plenty of soap and water.

P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.

Continue rinsing.

P312 Call a POISON CENTER or doctor/physician if you feel unwell.

P321 Specific treatment.

P332+P313 If skin irritation occurs: Get medical advice/attention.

P337+P313 If eye irritation persists: Get medical advice/attention.

P362+P364 Take off contaminated clothing and wash it before reuse.

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/container to a hazardous or special waste collection point.

Hazardous component(s)

POTASSIUM CARBONATE

Remarks on GHS-labelling

Based on revised toxicity values H302 (Harmful is swallowed.) is no longer applicable.

EC: (EC) No 67/548 or 1999/45 Hazard pictogram(s)

IRRITANT R-phrases 36/37/38

Irritating to eyes, respiratory system and skin.

S-phrases 2 26 37

Keep out of the reach of children.

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

Wear suitable gloves.

Hazardous component(s) : not applicable Remarks on EC-labelling

2.3.

Based on revised toxicity values, R22 (Harmful is swallowed) is no longer applicable.

Other hazards

If applicable: see section 6.1 and section 7.1.

SECTION 3: Composition/information on ingredients Component POTASSIUM CARBONATE

POTASSIUM DIPHOSPHATE

NON IONIC SURFACE ACTIVE AGENTS

CAS-no.

EC-no.

Index No. Registration no.

584-08-7 209-529-3

01-2119532646-36

7320-34-5 230-785-7

01-2119489369-18

Percentage(%)

GHS-Label EC-Label

>50.0 - <54.0

GHS07 H315 Skin irrit. 2 H319 Eye irrit. 2 H335 STOT SE 3 Xi;R: 36/37/38

>14.0 - <19.0

GHS07 H319 Eye irrit. 2 Xi;R: 36

<5.0

For the full text of the H-sentences, hazard statements and R-sentences mentioned in this section, see section 16.

SECTION 4: First aid measures Date of request : 2016-11-16

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4.1.

Description of first aid measures

Skin

:

Ingestion

:

Inhalation

:

Eyes

:

4.2.

Remove contaminated clothes as soon as possible. Remove residue substance as soon as possible (e.g. rinse with plenty of water). In case of a serious exposure call for a doctor.

If victim is conscious let him rinse the mouth with water. Do NOT let him drink. In case of general disorders bring victim into the hospital, otherwise call for a doctor.

Bring victim into the fresh air as soon as possible and let rest. In case of severe exposure call for a doctor. In case of breathing problems, loose squeezing clothes and if victim is conscious bring victim in high sitting position. In case of stagnation of breathing give IMMEDIATELY oxygen and transport to hospital as soon as possible.

Rinse for a long time with plenty of water. In case of eye-sight disturbances bring victim immediately into the hospital, in other cases call for a doctor

Most important symptoms and effects, both acute and delayed

Skin Ingestion Inhalation Eyes

local general local general local general local

Remarks symptoms

4.3.

: : : : : : :

The substance is irritating: redness, pain.

Probably no absorbtion worth mentioning.

The substance is irritating: sore throat, abdominal pain.

The substance may be absorbed after ingestion.

The substance is with atomising irritating: sore throat, coughing.

Probably no absorbtion worth mentioning.

The substance is irritating: redness, pain.

:

The substance has an effect on: the blood.

Indication of any immediate medical attention and special treatment needed

For advice on further treatment contact a (national) poison center.

SECTION 5: Firefighting measures 5.1.

Extinguishing media

Suitable fire-extinguisher determined by surrounding Unsuitable fire-extinguisher not traceable

5.2.

Special hazards arising from the substance or mixture

Hazardous decomposition products in fire

5.3.

:

carbon monoxide, potassium oxide, phosphorus oxide, phosphine

Advice for firefighters

In the event of fire, wear protective clothing and use breathing apparatus that is independent of the ambient air.

SECTION 6: Accidental release measures 6.1.

Personal precautions, protective equipment and emergency procedures

Precautions Use protective equipment. See section 8.

Read label before use.

Emergency procedure Is not to be expected.

6.2.

Environmental precautions

Remainder material or uncleaned empty packagings have to be incinerated in a proper installation or dumped on an approved landfill, in accordance with local and national legislation.

6.3.

Methods and material for containment and cleaning up

Spillage procedure Where necessary, cover the spilt material with dry sand or dry earth in order to prevent displacement by wind or draught, sweep or shovel into plastic bags and remove to the central depot for hazardous waste.

6.4.

Reference to other sections

See section 8 for appropriate personal protection.

See section 13 for additional information on waste treatment.

SECTION 7: Handling and storage 7.1.

Precautions for safe handling

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Observe label precautions.

Do not eat, drink or smoke in work areas. Remove contaminated clothing and protective equipment. Wash hands after leaving the work area.

Local exhausting

:

Storage code (on behalf of PGS : 15)

7.2.

none

Conditions for safe storage, including any incompatibilities

Storage conditions

7.3.

Depends on processing circumstances, but at least good room ventilation.

:

See also any precautionary statements and S-phrases in section 2.2.

Store product away from ignition sources or heatsources, in a well ventilated area, in a closed, original container, protected from the sun.

Specific end use(s)

Data not available.

SECTION 8: Exposure controls/personal protection 8.1.

Control parameters

Exposure limits : applicable to: The Netherlands No TWA has been laid down.

No TWA has been laid down.

No TWA has been laid down.

POTASSIUM CARBONATE POTASSIUM DIPHOSPHATE NON IONIC SURFACE ACTIVE AGENTS

C=Ceiling; S=Skin Remarks exposure limits : Avoid breathing dust. Observe the TWA-value for irritant inhalable dust (10 mg/m3) and respirable dust (5 mg/m3) if the values for components are not available.

DNEL (Derived No Effect Level) Worker - Inhalation - Long term exposure - Local effects: 10 mg/m3 Worker - Inhalation - Long term exposure - Systemic effects: 10 mg/m3 Consumer - Inhalation - Long term exposure - Local effects: 10 mg/m3 Consumer - Inhalation - Long term exposure - Systemic effects: 10 mg/m3 Worker - Inhalation - Long term exposure - Systemic effects: 44 mg/m3 PNEC (Predicted No Effect Concentration) Fresh water: 0.05 mg/l Marine water: 0.005 mg/l Intermittent releases: 0.5 mg/l

8.2.

POTASSIUM CARBONATE Source : Supplier POTASSIUM CARBONATE Source : Supplier POTASSIUM CARBONATE Source : Supplier POTASSIUM CARBONATE Source : Supplier POTASSIUM DIPHOSPHATE Source : Chemicalcards

POTASSIUM DIPHOSPHATE

Source

:

Chemicalcards

POTASSIUM DIPHOSPHATE

Source

:

Chemicalcards

POTASSIUM DIPHOSPHATE

Source

:

Chemicalcards

Exposure controls

Advised personal protection : Hands Breakthrough time Eyes Inhalation Skin

: : : : :

neoprene gloves For information: consult the supplier of the gloves. dust goggles dust mask P2 protective clothing (such as: apron, coverall, boots)

SECTION 9: Physical and chemical properties 9.1.

Information on basic physical and chemical properties

Physical state Colour Odour Odour threshold (20ºC; 1013 mbar) pH Melting point/range Boiling point/range Flash point/range Vapor rate/range Flammability (solid, gas) Explosive limits Vapour pressure Relative density Solubility in water Log Po/w Autoignition temperature

Date of request : 2016-11-16

: : : : : : : : : : : : : : : :

powder white specific not traceable 11 (10 g/l) not traceable not traceable not applicable not applicable data not available not applicable not applicable ≥0.575 - ≤0.585 (water=1) (20 ºC) complete not traceable not applicable

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Decomposition temperature Viscosity Dust explosions possible in air Oxidising properties

9.2.

: : : :

not traceable not applicable no no

Other information

Solubility in fat Electrostatic chargement

: :

not traceable no

SECTION 10: Stability and reactivity 10.1.

Reactivity

See section 10.2 - 10.6.

10.2.

Chemical stability

The substance or mixture is stable under normal conditions. See also section 10.4.

10.3.

Possibility of hazardous reactions

Reactions with water

:

no

Other hazardous conditions

:

Data not available.

:

acids, alkaline earth metal powders, chloro trifluoride, oxidizing substances, halogens, silicon, carbon, calcium hydroxide, aluminium alloys, aluminium, by reaction with light metals releases hydrogen

10.4.

Conditions to avoid

Data not available.

10.5.

Incompatible materials

Hazardous reactions with

10.6.

Hazardous decomposition products

Hazardous decomposition products at heating :

none

SECTION 11: Toxicological information 11.1.

Information on toxicological effects

Acute oral toxicity LD-50: >2 g/kg (ORL-RAT) LD-50: 2.98 g/kg (ORL-RAT)

POTASSIUM DIPHOSPHATE

Source Source

: Supplier : Supplier

Acute dermal toxicity LD-50: >4.64 g/kg (SKN-RBT)

POTASSIUM DIPHOSPHATE

Source

: Supplier

Acute inhalation toxicity LC-50: >1.10 mg/l/4H (IHL-RAT)

POTASSIUM DIPHOSPHATE

Source

: Supplier

Ames test negative

POTASSIUM CARBONATE

Source

: ChemDat (Merck)

POTASSIUM CARBONATE

Skin corrosion/irritation Causes skin irritation.

Serious eye damage/irritation Causes serious eye irritation.

Respiratory or skin sensitisation The substance or mixture is not classified for respiratory or skin sensitisation.

Germ cell mutagenicity The substance or mixture is not classified for germ cell mutagenicity.

Carcinogenicity The substance or mixture is not classified for carcinogenicity.

Additional information regarding carcinogenicity (NTP, IARC, OSHA) NTP: no IARC: no OSHA: no NTP: no IARC: no OSHA: no

POTASSIUM CARBONATE POTASSIUM DIPHOSPHATE

Reproductive toxicity The substance or mixture is not classified for reproductive toxicity.

Specific target organ toxicity-single exposure May cause respiratory irritation.

Date of request : 2016-11-16

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Specific target organ toxicity-repeated exposure The substance or mixture is not classified for specific target organ toxicity-repeated exposure.

Aspiration hazard The substance or mixture is not classified for aspiration hazard.

Symptoms Skin

local general local general local general local

Ingestion Inhalation Eyes Remarks symptoms

: : : : : : :

The substance is irritating: redness, pain.

Probably no absorbtion worth mentioning.

The substance is irritating: sore throat, abdominal pain.

The substance may be absorbed after ingestion.

The substance is with atomising irritating: sore throat, coughing.

Probably no absorbtion worth mentioning.

The substance is irritating: redness, pain.

:

The substance has an effect on: the blood.

SECTION 12: Ecological information 12.1.

Toxicity

Ecotoxicity EC-50: 650 mg/l/48H (Daphnia) LC-50: >100 mg/l/96H (Fish) EC-50: >100 mg/l/48H (Daphnia)

12.2.

Source

: Easi View

: not traceable

: not traceable : not traceable

Mobility in soil

Henry Constant

12.5.

POTASSIUM CARBONATE

: not traceable : not traceable : not traceable

Bioaccumulative potential

Bioconcentration factor (BCF) Log Po/w

12.4.

: Easi View : Supplier : Supplier

POTASSIUM DIPHOSPHATE

Persistence and degradability

Biological oxygen demand Chemical oxygen demand Biological/chemical oxygen demand ratio Degradability

12.3.

POTASSIUM DIPHOSPHATE

Source Source Source

POTASSIUM CARBONATE

: 8.95E-14 atm m3/mol

Results of PBT and vPvB assessment

Data not available.

12.6.

Other adverse effects

Remarks on ecotoxicity

: none

SECTION 13: Disposal considerations 13.1.

Waste treatment methods

Remainder material or uncleaned empty packagings have to be incinerated in a proper installation or dumped on an approved landfill, in accordance with local and national legislation.

SECTION 14: Transport information 14.1.

UN number

Not subject to Transport-regulation Dangerous Substances

14.2.

UN proper shipping name

Not subject to Transport-regulation Dangerous Substances

14.3.

Transport hazard class(es)

Not subject to Transport-regulation Dangerous Substances

14.4.

Packing group

Not subject to Transport-regulation Dangerous Substances

Date of request : 2016-11-16

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14.5.

Environmental hazards

Marine pollutant : no

14.6.

Special precautions for user

Not subject to Transport-regulation Dangerous Substances

14.7.

Transport in bulk according to Annex II of Marpol and the IBC Code

Data not available.

SECTION 15: Regulatory information 15.1.

-

Water Hazard Class (WGK) = 1

15.2.

-

Safety, health and environmental regulations/legislation specific for the substance or mixture Chemical safety assessment

Data not available.

SECTION 16: Other information Remarks on SDS

: none

Overview relevant H-sentences from all components in section 3 H315 H319 H335

Causes skin irritation.

Causes serious eye irritation.

May cause respiratory irritation.

Overview relevant hazard statements from all components in section 3 Xi

IRRITANT

Overview relevant R-sentences from all components in section 3 36 36/37/38

Irritating to eyes.

Irritating to eyes, respiratory system and skin.

Training advice Provide adequate information, instruction and training for operators.

A key or legend to abbreviations and acronyms used in the safety data sheet REACH GHS CAS TGG = TWA LEL UEL NTP KHC RAHC IARC OSHA ADR RID UN IMDG IMO IATA ICAO EmS

Registration, Evaluation and Authorisation of CHemicals Globally Harmonised System of Classification and Labelling of Chemicals Chemical Abstracts Service Time Weighted Average Lower Explosive Limit Upper Explosive Limit National Toxicology Program Known Human Carcinogen Reasonably Anticipated Human Carcinogen International Agency for Research on Cancer Occupational Safety & Health Administration Accord europÊen relatif au transport international des marchandises Dangereuses par Route Règlement concernant le transport international ferroviaire des marchandises dangereuses United Nations International Maritime Dangerous Goods International Maritime Organization International Air Transport Association International Civil Aviation Organization Emergency Schedule

* Point to alterations with regard to the previous version.

The information provided in this Safety Data Sheet is believed to be correct as of the date issued. Philips Electronics Nederland B.V. makes no warranty as to its contents, nor as to its fitness for any particular purpose or use.

Date of request : 2016-11-16

SDS 28155 - Page 7 / 7