Lhch2ap

Page 1

ifjf'k"V ifjf'k"V I oqQN mi;ksxh lkjf.k;k¡ lkj.kh 1 & ewy HkkSfrd fLFkjkad izrhd

eku

xq#Rokd"kZ.k dk Roj.k ijek.kq nzO;eku ek=kd vkoksxknzks fLFkjkad cksYV~leku fu;rkad bysDVªkWu dk vkos'k iQSjkMs&fLFkjkad xSl&fLFkjkad ^fgekad* rki ekud rki vkSj nkc ij vkn'kZ xSl dk eksyj nzO;eku fuokZr dk ijkoS|qrkad

g

9.81 ms–2

amu

1.66053 × 10 –27 Kg

NA

6.02217 × 10 23 mol–1

K

1.38062 × 10 –23 J K–1

e

1.602192 × 10–19 C

F

9.64867 × 104 C mol–1

R

8.314 J K–1 mol –1

he

d

HkkSfrd fLFkjkad

273.150 K

2.24136 × 10–2 m3 mol–1

E0

8.854185 × 10 –12

is

Tice Vm

Kg –1 m –3s4 A 2 h

6.62620 × 10–34 J s

Rw

1.973731 × 10 7 m–1

bl

Iykad&fu;rkad fjM~cxZ fLFkjkad ekud nkc (ok;qeaMy) ty dk f=kd fcanq fuokZr esa izdk'k dh xfr

101325 N m–2

p

273016 K

2.997925 × 108 m s –1

© no N C tt E o R be T re pu

c

lkj.kh 2 & oqQN dkcZfud ;kSfxdksa osQ lkekU; xq.k/eZ

;kSfxd

xyukad

°C

DoFkukad °C ?kuRo/Kg m–3 (298 K)

viorZukad (nD) (293 K)

104 ×

';kurk/ –2

N s m

(298

,slhfVd vEy ,slhVsfuykbM ,slhVksu p-,sehuks,s”kkscsUthu (,sfuyhu ;syks) ,sfuyhu csU”kksbd vEy dkcZu VsVªkDyksjkbM DyksjkscsU”khu DyksjksiQkWeZ lkbDyksgsDlsu MkbcsU”ky ,slhVksu Mkb,fFkybZFkj ,fFky,slhVsV ,FksukWy fXyljkWy gsDlsu esFksukWy uSÝ- FkSyhu p-ukbVªks,slhVsfuykbV iQhukWy isQfuy&,s”kks&β-uSÝ- FkkWy (,s”kks jatd) VkywbuZ

K)

103 ×

ruko/N

i`"B m–1

(293 K)

16.7

117.9

1044.0

1.3716

11.55

114.0

-

-

-

-

27.8 -

–94.7

56.1

785.0

1.3588

3.16

23.7

125.0

-

-

-

-

42.9

–6.3

184.1

1022.0 (293)

1.5863

3.71

122.4

249.0

1266.0 (288)

1.504 (405)

-

-

–22.9

76.5

1584.0

1.4601

8.8

26.95

–45.2

132.0

1106.0

1.5241

7.97

33.56

–63.5

61.7

1480.0

1.4459

5.42

27.14

6.6

80.7

774.0

1.42662

9.8

25.5

112.0

-

-

-

-

-

–116.2

34.51

714.0

1.3526

2.22

17.01

–82.4

77.1

900.0 (293)

1.3723

4.41

23.9

–114.1

78.3

785.0

1.3611

10.6

22.75

18.07

290.0

1264.4

1.4746

942.0

63.4

–95.3

68.7

655.0

1.37506

2.94

18.43

–97.7

64.5

787.0

1.3288

5.47

22.61

80.3

218.0

1180.0

1.4003 (297)

-

-

214.0

-

-

-

-

-

40.9

181.8

1132.0

1.5509

-

-

113.0

-

-

-

-

-

–95.1

110.6

862.0

1.4961

5.50

28.5

131


iz;ks'kkyk iqfLrdk] jlk;u lkj.kh 3 & lkekU; vdkcZfud ;kSfxdksa dh ty esa foys;rk de foys; ;kSfxd cukrs gSa (0.1 M ls de foy;srk )

izrhd

ukbVªsV

NO3

vf/drj /uk;u

dksbZ Hkh ugha

,slhVsV

CH3COO–

vf/drj /uk;u

Ag+

DyksjkbM

Cl

vf/drj /uk;u

Ag+, Pb2+, Hg2

czksekbM

Br

vf/drj /uk;u

Ag+, Pb2+, Hg2

vk;ksMkbM

I

vf/drj /uk;u

Ag+, Pb2+, Hg2

lYisQV

SO4

ozQksesV

CrO4

vf/drj /uk;u

lYiQkbM

S2–

NH 4]

2–

he 2+

2+

is

2–

2+

vf/drj /uk;u

Br2+, Sr 2+, Pb 2+, Ag + Br2+, Sr 2+, Pb 2+, Ag +

bl

+

{kkjh; /krq ,oa {kkjh; e`nk /krq /uk;u

vf/drj vU; /uk;u

© no N C tt E o R be T re pu gkbMªkWDlkbM

OH

2–

dkcksZusV

CO 3

+ LI+ksQV IkQkW

PO4

132

3–

+

{kkjh; /krq ,oa {kkjh; e`nk /krq /uk;u rFkk Ba2+ vkSj

NH 4]

+

NH 4 Li+

vkSj {kkjh; /krq /uk;u

osQ vfrfjDr

d

;s vk;u fuEufyf[kr /uk;uksa osQ lkFk ?kqyu'khy ;kSfxd cukrs gSa (0.1 M ls vf/d foy;srk )

½.kk;u dk uke

vf/drj vU; /uk;u

Sr 2+

vf/drj vU; /uk;u


ifjf'k"V II rÙo] mudh ijek.kq&la[;k vkSj eksyj nzO;eku laosQr

ijek.kq Øekad

eksyj nzO;eku

rÙo

laosQr

ijek.kq Øekad

eSaMsyhfo;e eD;wZjh ekWfyCMsue uh;ksfM;e fu;kWu uSIVwfu;e fuoSQy fu;ksfc;e ukbVªkt s u ukscsfy;e vkslfe;e vkWDlhtu iSysfM;e I+kQkLI+kQksjl IySfVue IywVksfu;e iksyksfu;e iksVSf'k;e izSft;ksfMfe;e izksesfFk;e izksVSfDVfu;e jsfM;e jsMkWu jhfu;e jksfM;e :fcfM;e #Fkhfu;e jnjiQks£M;e lSesfj;e LoSQfUM;e lhcksZfx;e flyhfu;e flfydu flYoj lksfM;e LVªkWfU'k;e lYiQj VSUVsye VsDuhf'k;e Vsywfj;e VfcZve FkSfy;e Fkksfj;e Fkwfy;e fVu VkbVsfu;e VaxLVu vuvufc;e vuvufufy;e vuvuvuh;e ;wjsfu;e oSusfM;e ftukWu bVfcZ;e bfVª;e ¯”kd

Md Hg Mo Nd Ne Np Ni Nb N No Os O Pd P Pt Pu Po K Pr Pm Pa Ra Rn Re Rh Rb Ru Rf Sm Sc Sg Se Si Ag Na Sr S Ta Tc Te Tb Tl Th Tm Sn Ti W Uub Uun Uuu U V Xe Yb Y Zn

101 80 42 60 10 93 28 41 7 102 76 8 46 15 78 94 84 19 59 61 91 88 86 75 45 37 44 104 62 21 106 34 14 47 11 38 16 73 43 52 65 81 90 69 50 22 74 112 110 111 92 23 54 70 39 30

(g

9.01 208.98 (264) 10.81 79.91 112.40 132.91 40.08 251.08 12.01 140.12 35.45 52.00 58.93 63.54 247.07 (263) 162.50 (252) 167.26 151.96 (257.10) 19.00 (223) 157.25 69.72 72.61 196.97 178.49 (269) 4.00 164.93 1.0079 114.82 126.90 192.2 55.85 83.80 138.91 (262.1) 207.19 6.94 174.96 24.31 54.94 (268)

Zr

40

91.22

(247)

is

227.03 26.98 (243) 121.75 39.95 74.92 210 137.34

© no N C tt E o R be T re pu

fcLeFk cksgfj;e cksjkWu czksehu oSQMfe;e lhf”k;e oSQfYl;e osQfyiQksfuZ;e dkcZu lhfj;e Dyksjhu Øksfe;e dksckYV dkWij D;wfj;e M~;wcfu;e fMlLizksfl;e vkbULVhfu;e vfcZ;e ;wjksfi;e iQfeZ;e Ýyqvksjhu izsaQfl;e xSMksfyfu;e xSfy;e tesZfu;e xksYM gSiQfu;e gSfl;e ghfy;e gksfYe;e gkbMªkt s u baMh;e vk;ksMhu bjhfM;e vk;ju fØIVkWu ySUFksue ykWjsfU'k;e ysM yhfFk;e Y;wVhf'k;e eSXuhf'k;e eSaxuht feVSfu;e

89 13 95 51 18 33 85 56 97 4 83 107 5 35 48 55 20 98 6 58 17 24 27 29 96 105 66 99 68 63 100 9 87 64 31 32 79 72 108 2 67 1 49 53 77 26 36 57 103 82 3 71 12 25 109

bl

cosQZ fy;e csfjfy;e

Ac Al Am Sb Ar As At Ba Bk Be Bi Bh B Br Cd Cs Ca Cf C Ce Cl Cr Co Cu Cm Db Dy Es Er Eu Fm F Fr Gd Ga Ge Au Hf Hs He Ho H In I Ir Fe Kr La Lr Pb Li Lu Mg Mn Mt

tdksZfu;e

mol–1)

258.10 200.59 95.94 144.24 20.18 (237.05) 58.71 92.91 14.0067 (259) 190.2 16.00 106.4 30.97 195.09 (244) 210 39.10 140.91 (145) 231.04 (226) (222) 186.2 102.91 85.47 101.07 (261) 150.35 44.96 (266) 78.96 28.08 107.87 22.99 87.62 32.06 180.95 (98.91) 127.60 158.92 204.37 232.04 168.93 118.69 47.88 183.85 (277) (269) (272) 238.03 50.94 131.30 173.04 88.91 65.37

he

(g mol–1) ,sDVhfu;e ,syqfefu;e ,sesfjfl;e ,sUVheuh vkWxuZ vkWlsZfud ,slVSfVu cs f j;e

eksyj nzO;eku

d

rÙo

dks"Bd esa fn;k x;k eku vf/dre Kkr v/kZ;q okys leLFkkfud dk eksyj nzO;eku gSA

133


ifjf'k"V III oqQN ykHkizn :ikarj.k&xq.kkad æO;eku vkSj Hkkj osQ lkekU; ek=kd 1 ikSaM = 453.59 xzke

yackbZ dk lkekU; ek=kd 1

ikSaM = 453.59 xzke = 0.45359 fdyksxzke 1 fdyksxzke = 1000 xzke = 2.205 ikSaM 1 xzke = 10 Mslhxzke = 100 lsaVhxzke = 1000 feyhxzke 1 xzke = 6.022 × 1023 ijek.kq nzO;eku ek=kd 1 ijek.kq nzO;eku = 1.6606 × 10–24 xzke 1 ehfVªjd Vu = 1000 fdyksxzke = 2205 ikSaM 1

bap

= 2.54

lsaVhehVj (lfVd)

ehy = 5280 iQhV = 1.609 fdyksehVj 1 xt = 36 bap = 0.9144 ehVj 1 ehVj = 100 lsaVhehVj = 39.37 bap = 3.281 iQhV = 1.094 xt 1 fdyksehVj = 1000 ehVj = 1094 xt = 0.6215 ehy –8 1 ,axLVªkWe = 1.0 × 10 lsaVhehVj = 0.10 uSuksehVj = 1.0 × 10–10 ehVj = 3.937 × 10–9 bap

is

he

d

1

bl

vk;ru dk lkekU; ek=kd 1 DokV~”kZ = 0.9463 fyVj 1 fyVj = 1.056 DokV~”kZ fyVj = 1 ?ku MslhehVj = 1000 ?ku lsaVhehVj = 0.001 ?kuehVj 1 feyhfyVj = 1 ?ku lsaVhehVj = 0.001 fyVj 1

© no N C tt E o R be T re pu

cy* vkSj nkc osQ lkekU; ek=kd

= 1.056 × 10-3

1

DokV~t+Z

?kuiQqV = 28.316 fyVj = 29.902 DokV~t+Z = 7.475 xSyu

ÅtkZ dk lkekU; ek=kd twy = 1 × 107 ergs

1 1

Å"e jklk;fud osQyksjh**=

4.184 twy = 4.184 × 107 ergs = 4.129 ×10–2 fyVj ok;qeaMy

bysDVªkWu cksYV –7 –8 1 ergs = 1 × 10 twy = 2.3901 × 10 osQyksjh 1 bysDVªkWu oksYV = 1.6022 × 10–19 twy = 2.612 × 1019

1

1

*

** †

fyVj&ok;qeaMy

fczfV'k Å"ek

= 1.6022 × 10–12 erg = 96.487 kJ/mol† = 24.217 osQyksjh

feyhehVj ejdjh dk = 1.013 × 105 ikLdy = 14.70 ikSaM izfr oxZbap 5 1 ckj = 10 ikLdy 1 Vkj = 1 feyhehVj ejdjh dk 1 ikLdy = 1 kg/ms2 = 1 N/m2 1

ok;qeaMy

= 760

rki SI vk/kfjr ek=kd osQfYou (K)

K = -273.15°C K = °C + 273.15 °F = 1.8(°C) + 32

°C =

°F − 32 1.8

= 101.32 twy = 1.0132 ×109 ergs dk ek=kd = 1055.06 twy = 1.05506 ×1010 ergs = 252.2 osQyksjh

cyµ 1 U;wVu (N) = 1 kg m/s2, 1 U;wVu og cy gS] tks ,d lsdaM yxkus ij 1 fdyksxzke nzO;eku dks 1 ehVj izfr lsdaM dk osx iznku djrk gSA Å"ek dh og ek=kk] tks 1 xzke ty dk rki 14.50C ls 15.50C rd c<+kus osQ fy, vko';d gksrh gSA è;ku jgs fd vU; ek=kd izfrd.k gSa] ftUgsa 6.022 ×1023 ls xq.kk djuk gksxk] rkfd lgh&lgh rqyuk gks losQA

134


ifjf'k"V IV oS|qr~ jklk;fud ozQe esa 298 K ij ekud foHko vip;u v/Z vfHkfØ;k H4XeO6 + 2H+ + 2e– → XeO3 + 3H2O

E⊖ /V +3.0

vip;u v/Z vfHkfØ;k

E⊖ /V

Pu4+ + e– → Pu3+

+0.97

+2.87

NO–3 + 4H+ + 3e– → NO + 2H2O

+0.96

O3 + 2H+ + 2e– → O2 + H2O

+2.07

2Hg2+ + 2e– → Hg 2+ 2

+0.92

S2O8 + 2e– → 2SO4

+2.05

ClO– + H2O + 2e– → Cl– + 2OH–

+0.89

Ag+ + e– → Ag+

+1.98

Hg2+ + 2e– → Hg

+0.86

Co3+ + e– → Co2+

+1.81

NO–3 + 2H+ + e– → NO2 + H2O

+0.80

H2O2 + 2H+ + 2e– → 2H2O

+1.78

Ag+ + e– → Ag

+0.80

Au+ + e– → Au

+1.69

– Hg 2+ 2 +2e → 2Hg

+0.79

Pb4+ + 2e– → Pb2+

+1.67

Fe3+ + e– → Fe2+

+0.77

2HClO + 2H+ + 2e– → Cl2 + 2H2O

+1.63

BrO– + H2O + 2e– → Br– + 2OH–

+0.76

Ce4+ + e– → Ce3+

+1.61

Hg2SO4 +2e– → 2Hg + SO42–

+0.62

2HBrO + 2H+ + 2e– → Br2 + 2H2O

+1.60

MnO42– + 2H2O + 2e– → MnO2 + 4OH–

+0.60

MnO4 + 8H+ + 5e– → Mn2+ + 4H2O

+1.51

MnO–4 + e– → MnO42–

+0.56

Mn3+ + e– → Mn2+

+1.51

I2 + 2e– → 2I–

+0.54

Au3+ + 3e– → Au

+1.40

I3 + 2e– → 3I–

+0.53

Cl2 + 2e– → 2Cl–

+1.36

Cu+ + e– → Cu

+0.52

Cr2O 7 + 14H+ + 6e– → 2Cr3+ + 7H2O

+1.33

NiOOH + H2O + e– → Ni(OH)2 + OH–

+0.49

O3 + H2O + 2e– → O2 + 2OH–

+1.24

Ag2CrO4 + 2e– → 2Ag + CrO42–

+0.45

O2 + 4H+ + 4e– → 2H2O

+1.23

O2 + 2H2O + 4e– → 4OH–

+0.40

ClO–4 + 2H+ +2e– → ClO–3 + 2H2O

+1.23

ClO–4 + H2O + 2e– → ClO–3 + 2OH–

+0.36

MnO2 + 4H+ + 2e– → Mn2+ + 2H2O

+1.23

[Fe(CN)6]3– + e– → [Fe(CN)6]4–

+0.36

Pt2+ + 2e– → Pt

+1.20

Cu2+ + 2e– → Cu

+0.34

Br2 + 2e– → 2Br–

+1.09

Hg2Cl2 + 2e– → 2Hg + 2Cl–

+0.27

2–

he

is

bl

2–

© no N C tt E o R be T re pu

2–

d

F2 + 2e– → 2F–

135


iz;ks'kkyk iqfLrdk] jlk;u +0.27

S + 2e– → S2–

–0.48

Bi3+ + 3e– → Bi

+0.20

In3+ + e– → In2+

–0.49

SO42 + 4H+ + 2e– → H2SO3 + H2O

+0.17

U4+ + e– → U3+

–0.61

Cu2+ + e– → Cu+

+0.16

Cr3+ + 3e– → Cr

–0.74

Sn4+ + 2e– → Sn2+

+0.15

Zn2+ + 2e– → Zn

–0.76

AgBr + e– → Ag + Br–

+0.07

Cd(OH)2 + 2e– → Cd + 2OH–

–0.81

he

d

AgCl + e– → Ag + Cl–

2H2O + 2e– → H2 + 2OH–

–0.83

Cr2+ + 2e– → Cr

–0.91

0.00

2H+ + 2e– → H2

(ifjHkk"kkuqlkj) 0.0

Fe3+ + 3e– → Fe

–0.04

Mn2+ + 2e– → Mn

O2 + H2O + 2e– → HO–2 + OH–

–0.08

V2+ + 2e– → V

Pb2+ + 2e– → Pb

–0.13

Ti2+ + 2e– → Ti

–1.63

In+ + e– → In

–0.14

Al3+ + 3e– → Al

–1.66

Sn2+ + 2e– → Sn

–0.14

U3+ + 3e– → U

–1.79

AgI + e– → Ag + I–

–0.15

Sc3+ + 3e– → Sc

–2.09

Ni2+ + 2e– → Ni

–0.23

Mg2+ + 2e– → Mg

–2.36

V3+ + e– → V2+

–0.26

Ce3+ + 3e– → Ce

–2.48

Co2+ + 2e– → Co

–0.28

La3+ + 3e– → La

–2.52

In3+ + 3e– → In

–0.34

Na+ + e– → Na

–2.71

Tl+ + e– → Tl

–0.34

Ca2+ + 2e– → Ca

–2.87

PbSO4 + 2e– → Pb + SO2– 4

–0.36

Sr2+ + 2e– → Sr

–2.89

Ti3+ + e– → Ti2+

–0.37

Ba2+ + 2e– → Ba

–2.91

Cd2+ + 2e– → Cd

–0.40

Ra2+ + 2e– → Ra

–2.92

In2+ + e– → In+

–0.40

Cs+ + e– → Cs

–2.92

Cr3+ + e– → Cr2+

–0.41

Rb+ + e– → Rb

–2.93

Fe2+ + 2e– → Fe

–0.44

K+ +e– → K

–2.93

In3+ + 2e– → In+

–0.44

Li+ + e– → Li

–3.05

© no N C tt E o R be T re pu

bl

is

Ti4+ + e– → Ti3+

136

–1.18

–1.19


y?kqx.kd lkj.kh 1 3

4

0086

0128

0170

11

0414 0453

0492

0531

0569

5 0212

12 13 14 15 16 17 18

1139 1173 1461 1492 1761 1790 2041 2068 2304 2330 2553 2577 2788 2810

0864 1206 1523 1818 2095 2355 2601 2833

0899 1239 1553 1847 2122 2380 2625 2856

7

8

0253 0294 0334

9

1

2

3

4

5

7

8

9

0374

5 4

13 12

17 16

21 26 2O 24

30 28

34 38 32 36

8 7

12 11

16 15

20 18

23 22

27 26

31 35 29 33

8

6

9

0607

0645 0682 0719

0755

4 4

0969

1004 1038 1072 1106

3 3

7 7

11 10

14 14

18 17

21 20

25 24

28 32 27 31

1303

1335 1367 1399

1430

3 3

6 7

10 10

13 13

16 16

19 19

23 22

26 29 25 29

1614

1644 1673 1703

1732

3 3

6 6

9 9

12 12

15 14

19 17

22 20

25 28 23 26

1903

1931 1959 1987

2014

3 3

6 6

9 8

2175

2201 2227 2253

2279

3 3

6 5

8 8

2430

2455 2480 2504

2529

3 3

2672

2695 2718 2742

2765

2 2

0934 1271 1584 1875 2148 2405 2648 2878

2900

2923 2945 2967

2989

2 2

11 11

14 14

11 10

14 16 13 16

17 17

20 19

23 26 22 25

19 18

22 24 21 23

5 5

8 8

10 10

13 12

15 15

18 17

20 23 20 22

5 4

7 7

9 9

12 14 11 14

17 16

19 21 18 21

4 4

7 6

9 8

11 11

13 13

16 15

18 20 17 19

© no N C tt E o R be T re pu

19

0792 0828

6

d

1

he

2

0000 0043

is

0

10

bl

N

20

3010 3032

3054

3075

3096

3118

3139 3160 3181

3201

2

4

6

8

11

13

15

17 19

21 22

3222 3243 3424 3444

3263 3464

3284 3483

3304 3502

3324 3522

3345 3365 3385 3541 3560 3579

3404 3598

2 2

4 4

6 6

8 8

10 10

12 12

14 14

16 18 15 17

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