ifjf'k"V ifjf'k"V I oqQN mi;ksxh lkjf.k;k¡ lkj.kh 1 & ewy HkkSfrd fLFkjkad izrhd
eku
xq#Rokd"kZ.k dk Roj.k ijek.kq nzO;eku ek=kd vkoksxknzks fLFkjkad cksYV~leku fu;rkad bysDVªkWu dk vkos'k iQSjkMs&fLFkjkad xSl&fLFkjkad ^fgekad* rki ekud rki vkSj nkc ij vkn'kZ xSl dk eksyj nzO;eku fuokZr dk ijkoS|qrkad
g
9.81 ms–2
amu
1.66053 × 10 –27 Kg
NA
6.02217 × 10 23 mol–1
K
1.38062 × 10 –23 J K–1
e
1.602192 × 10–19 C
F
9.64867 × 104 C mol–1
R
8.314 J K–1 mol –1
he
d
HkkSfrd fLFkjkad
273.150 K
2.24136 × 10–2 m3 mol–1
E0
8.854185 × 10 –12
is
Tice Vm
Kg –1 m –3s4 A 2 h
6.62620 × 10–34 J s
Rw
1.973731 × 10 7 m–1
bl
Iykad&fu;rkad fjM~cxZ fLFkjkad ekud nkc (ok;qeaMy) ty dk f=kd fcanq fuokZr esa izdk'k dh xfr
101325 N m–2
p
273016 K
2.997925 × 108 m s –1
© no N C tt E o R be T re pu
c
lkj.kh 2 & oqQN dkcZfud ;kSfxdksa osQ lkekU; xq.k/eZ
;kSfxd
xyukad
°C
DoFkukad °C ?kuRo/Kg m–3 (298 K)
viorZukad (nD) (293 K)
104 ×
';kurk/ –2
N s m
(298
,slhfVd vEy ,slhVsfuykbM ,slhVksu p-,sehuks,s”kkscsUthu (,sfuyhu ;syks) ,sfuyhu csU”kksbd vEy dkcZu VsVªkDyksjkbM DyksjkscsU”khu DyksjksiQkWeZ lkbDyksgsDlsu MkbcsU”ky ,slhVksu Mkb,fFkybZFkj ,fFky,slhVsV ,FksukWy fXyljkWy gsDlsu esFksukWy uSÝ- FkSyhu p-ukbVªks,slhVsfuykbV iQhukWy isQfuy&,s”kks&β-uSÝ- FkkWy (,s”kks jatd) VkywbuZ
K)
103 ×
ruko/N
i`"B m–1
(293 K)
16.7
117.9
1044.0
1.3716
11.55
114.0
-
-
-
-
27.8 -
–94.7
56.1
785.0
1.3588
3.16
23.7
125.0
-
-
-
-
42.9
–6.3
184.1
1022.0 (293)
1.5863
3.71
122.4
249.0
1266.0 (288)
1.504 (405)
-
-
–22.9
76.5
1584.0
1.4601
8.8
26.95
–45.2
132.0
1106.0
1.5241
7.97
33.56
–63.5
61.7
1480.0
1.4459
5.42
27.14
6.6
80.7
774.0
1.42662
9.8
25.5
112.0
-
-
-
-
-
–116.2
34.51
714.0
1.3526
2.22
17.01
–82.4
77.1
900.0 (293)
1.3723
4.41
23.9
–114.1
78.3
785.0
1.3611
10.6
22.75
18.07
290.0
1264.4
1.4746
942.0
63.4
–95.3
68.7
655.0
1.37506
2.94
18.43
–97.7
64.5
787.0
1.3288
5.47
22.61
80.3
218.0
1180.0
1.4003 (297)
-
-
214.0
-
-
-
-
-
40.9
181.8
1132.0
1.5509
-
-
113.0
-
-
-
-
-
–95.1
110.6
862.0
1.4961
5.50
28.5
131
iz;ks'kkyk iqfLrdk] jlk;u lkj.kh 3 & lkekU; vdkcZfud ;kSfxdksa dh ty esa foys;rk de foys; ;kSfxd cukrs gSa (0.1 M ls de foy;srk )
izrhd
ukbVªsV
NO3
vf/drj /uk;u
dksbZ Hkh ugha
,slhVsV
CH3COO–
vf/drj /uk;u
Ag+
DyksjkbM
Cl
–
vf/drj /uk;u
Ag+, Pb2+, Hg2
czksekbM
Br
–
vf/drj /uk;u
Ag+, Pb2+, Hg2
vk;ksMkbM
I
–
vf/drj /uk;u
Ag+, Pb2+, Hg2
lYisQV
SO4
ozQksesV
CrO4
vf/drj /uk;u
lYiQkbM
S2–
NH 4]
2–
he 2+
2+
is
2–
2+
vf/drj /uk;u
Br2+, Sr 2+, Pb 2+, Ag + Br2+, Sr 2+, Pb 2+, Ag +
bl
–
+
{kkjh; /krq ,oa {kkjh; e`nk /krq /uk;u
vf/drj vU; /uk;u
© no N C tt E o R be T re pu gkbMªkWDlkbM
–
OH
2–
dkcksZusV
CO 3
+ LI+ksQV IkQkW
PO4
132
3–
+
{kkjh; /krq ,oa {kkjh; e`nk /krq /uk;u rFkk Ba2+ vkSj
NH 4]
+
NH 4 Li+
vkSj {kkjh; /krq /uk;u
osQ vfrfjDr
d
;s vk;u fuEufyf[kr /uk;uksa osQ lkFk ?kqyu'khy ;kSfxd cukrs gSa (0.1 M ls vf/d foy;srk )
½.kk;u dk uke
vf/drj vU; /uk;u
Sr 2+
vf/drj vU; /uk;u
ifjf'k"V II rÙo] mudh ijek.kq&la[;k vkSj eksyj nzO;eku laosQr
ijek.kq Øekad
eksyj nzO;eku
rÙo
laosQr
ijek.kq Øekad
eSaMsyhfo;e eD;wZjh ekWfyCMsue uh;ksfM;e fu;kWu uSIVwfu;e fuoSQy fu;ksfc;e ukbVªkt s u ukscsfy;e vkslfe;e vkWDlhtu iSysfM;e I+kQkLI+kQksjl IySfVue IywVksfu;e iksyksfu;e iksVSf'k;e izSft;ksfMfe;e izksesfFk;e izksVSfDVfu;e jsfM;e jsMkWu jhfu;e jksfM;e :fcfM;e #Fkhfu;e jnjiQks£M;e lSesfj;e LoSQfUM;e lhcksZfx;e flyhfu;e flfydu flYoj lksfM;e LVªkWfU'k;e lYiQj VSUVsye VsDuhf'k;e Vsywfj;e VfcZve FkSfy;e Fkksfj;e Fkwfy;e fVu VkbVsfu;e VaxLVu vuvufc;e vuvufufy;e vuvuvuh;e ;wjsfu;e oSusfM;e ftukWu bVfcZ;e bfVª;e ¯”kd
Md Hg Mo Nd Ne Np Ni Nb N No Os O Pd P Pt Pu Po K Pr Pm Pa Ra Rn Re Rh Rb Ru Rf Sm Sc Sg Se Si Ag Na Sr S Ta Tc Te Tb Tl Th Tm Sn Ti W Uub Uun Uuu U V Xe Yb Y Zn
101 80 42 60 10 93 28 41 7 102 76 8 46 15 78 94 84 19 59 61 91 88 86 75 45 37 44 104 62 21 106 34 14 47 11 38 16 73 43 52 65 81 90 69 50 22 74 112 110 111 92 23 54 70 39 30
(g
9.01 208.98 (264) 10.81 79.91 112.40 132.91 40.08 251.08 12.01 140.12 35.45 52.00 58.93 63.54 247.07 (263) 162.50 (252) 167.26 151.96 (257.10) 19.00 (223) 157.25 69.72 72.61 196.97 178.49 (269) 4.00 164.93 1.0079 114.82 126.90 192.2 55.85 83.80 138.91 (262.1) 207.19 6.94 174.96 24.31 54.94 (268)
Zr
40
91.22
(247)
is
227.03 26.98 (243) 121.75 39.95 74.92 210 137.34
© no N C tt E o R be T re pu
fcLeFk cksgfj;e cksjkWu czksehu oSQMfe;e lhf”k;e oSQfYl;e osQfyiQksfuZ;e dkcZu lhfj;e Dyksjhu Øksfe;e dksckYV dkWij D;wfj;e M~;wcfu;e fMlLizksfl;e vkbULVhfu;e vfcZ;e ;wjksfi;e iQfeZ;e Ýyqvksjhu izsaQfl;e xSMksfyfu;e xSfy;e tesZfu;e xksYM gSiQfu;e gSfl;e ghfy;e gksfYe;e gkbMªkt s u baMh;e vk;ksMhu bjhfM;e vk;ju fØIVkWu ySUFksue ykWjsfU'k;e ysM yhfFk;e Y;wVhf'k;e eSXuhf'k;e eSaxuht feVSfu;e
89 13 95 51 18 33 85 56 97 4 83 107 5 35 48 55 20 98 6 58 17 24 27 29 96 105 66 99 68 63 100 9 87 64 31 32 79 72 108 2 67 1 49 53 77 26 36 57 103 82 3 71 12 25 109
bl
cosQZ fy;e csfjfy;e
Ac Al Am Sb Ar As At Ba Bk Be Bi Bh B Br Cd Cs Ca Cf C Ce Cl Cr Co Cu Cm Db Dy Es Er Eu Fm F Fr Gd Ga Ge Au Hf Hs He Ho H In I Ir Fe Kr La Lr Pb Li Lu Mg Mn Mt
tdksZfu;e
mol–1)
258.10 200.59 95.94 144.24 20.18 (237.05) 58.71 92.91 14.0067 (259) 190.2 16.00 106.4 30.97 195.09 (244) 210 39.10 140.91 (145) 231.04 (226) (222) 186.2 102.91 85.47 101.07 (261) 150.35 44.96 (266) 78.96 28.08 107.87 22.99 87.62 32.06 180.95 (98.91) 127.60 158.92 204.37 232.04 168.93 118.69 47.88 183.85 (277) (269) (272) 238.03 50.94 131.30 173.04 88.91 65.37
he
(g mol–1) ,sDVhfu;e ,syqfefu;e ,sesfjfl;e ,sUVheuh vkWxuZ vkWlsZfud ,slVSfVu cs f j;e
eksyj nzO;eku
d
rÙo
dks"Bd esa fn;k x;k eku vf/dre Kkr v/kZ;q okys leLFkkfud dk eksyj nzO;eku gSA
133
ifjf'k"V III oqQN ykHkizn :ikarj.k&xq.kkad æO;eku vkSj Hkkj osQ lkekU; ek=kd 1 ikSaM = 453.59 xzke
yackbZ dk lkekU; ek=kd 1
ikSaM = 453.59 xzke = 0.45359 fdyksxzke 1 fdyksxzke = 1000 xzke = 2.205 ikSaM 1 xzke = 10 Mslhxzke = 100 lsaVhxzke = 1000 feyhxzke 1 xzke = 6.022 × 1023 ijek.kq nzO;eku ek=kd 1 ijek.kq nzO;eku = 1.6606 × 10–24 xzke 1 ehfVªjd Vu = 1000 fdyksxzke = 2205 ikSaM 1
bap
= 2.54
lsaVhehVj (lfVd)
ehy = 5280 iQhV = 1.609 fdyksehVj 1 xt = 36 bap = 0.9144 ehVj 1 ehVj = 100 lsaVhehVj = 39.37 bap = 3.281 iQhV = 1.094 xt 1 fdyksehVj = 1000 ehVj = 1094 xt = 0.6215 ehy –8 1 ,axLVªkWe = 1.0 × 10 lsaVhehVj = 0.10 uSuksehVj = 1.0 × 10–10 ehVj = 3.937 × 10–9 bap
is
he
d
1
bl
vk;ru dk lkekU; ek=kd 1 DokV~”kZ = 0.9463 fyVj 1 fyVj = 1.056 DokV~”kZ fyVj = 1 ?ku MslhehVj = 1000 ?ku lsaVhehVj = 0.001 ?kuehVj 1 feyhfyVj = 1 ?ku lsaVhehVj = 0.001 fyVj 1
© no N C tt E o R be T re pu
cy* vkSj nkc osQ lkekU; ek=kd
= 1.056 × 10-3
1
DokV~t+Z
?kuiQqV = 28.316 fyVj = 29.902 DokV~t+Z = 7.475 xSyu
ÅtkZ dk lkekU; ek=kd twy = 1 × 107 ergs
1 1
Å"e jklk;fud osQyksjh**=
4.184 twy = 4.184 × 107 ergs = 4.129 ×10–2 fyVj ok;qeaMy
bysDVªkWu cksYV –7 –8 1 ergs = 1 × 10 twy = 2.3901 × 10 osQyksjh 1 bysDVªkWu oksYV = 1.6022 × 10–19 twy = 2.612 × 1019
1
1
*
** †
fyVj&ok;qeaMy
fczfV'k Å"ek
= 1.6022 × 10–12 erg = 96.487 kJ/mol† = 24.217 osQyksjh
feyhehVj ejdjh dk = 1.013 × 105 ikLdy = 14.70 ikSaM izfr oxZbap 5 1 ckj = 10 ikLdy 1 Vkj = 1 feyhehVj ejdjh dk 1 ikLdy = 1 kg/ms2 = 1 N/m2 1
ok;qeaMy
= 760
rki SI vk/kfjr ek=kd osQfYou (K)
K = -273.15°C K = °C + 273.15 °F = 1.8(°C) + 32
°C =
°F − 32 1.8
= 101.32 twy = 1.0132 ×109 ergs dk ek=kd = 1055.06 twy = 1.05506 ×1010 ergs = 252.2 osQyksjh
cyµ 1 U;wVu (N) = 1 kg m/s2, 1 U;wVu og cy gS] tks ,d lsdaM yxkus ij 1 fdyksxzke nzO;eku dks 1 ehVj izfr lsdaM dk osx iznku djrk gSA Å"ek dh og ek=kk] tks 1 xzke ty dk rki 14.50C ls 15.50C rd c<+kus osQ fy, vko';d gksrh gSA è;ku jgs fd vU; ek=kd izfrd.k gSa] ftUgsa 6.022 ×1023 ls xq.kk djuk gksxk] rkfd lgh&lgh rqyuk gks losQA
134
ifjf'k"V IV oS|qr~ jklk;fud ozQe esa 298 K ij ekud foHko vip;u v/Z vfHkfØ;k H4XeO6 + 2H+ + 2e– → XeO3 + 3H2O
E⊖ /V +3.0
vip;u v/Z vfHkfØ;k
E⊖ /V
Pu4+ + e– → Pu3+
+0.97
+2.87
NO–3 + 4H+ + 3e– → NO + 2H2O
+0.96
O3 + 2H+ + 2e– → O2 + H2O
+2.07
2Hg2+ + 2e– → Hg 2+ 2
+0.92
S2O8 + 2e– → 2SO4
+2.05
ClO– + H2O + 2e– → Cl– + 2OH–
+0.89
Ag+ + e– → Ag+
+1.98
Hg2+ + 2e– → Hg
+0.86
Co3+ + e– → Co2+
+1.81
NO–3 + 2H+ + e– → NO2 + H2O
+0.80
H2O2 + 2H+ + 2e– → 2H2O
+1.78
Ag+ + e– → Ag
+0.80
Au+ + e– → Au
+1.69
– Hg 2+ 2 +2e → 2Hg
+0.79
Pb4+ + 2e– → Pb2+
+1.67
Fe3+ + e– → Fe2+
+0.77
2HClO + 2H+ + 2e– → Cl2 + 2H2O
+1.63
BrO– + H2O + 2e– → Br– + 2OH–
+0.76
Ce4+ + e– → Ce3+
+1.61
Hg2SO4 +2e– → 2Hg + SO42–
+0.62
2HBrO + 2H+ + 2e– → Br2 + 2H2O
+1.60
MnO42– + 2H2O + 2e– → MnO2 + 4OH–
+0.60
MnO4 + 8H+ + 5e– → Mn2+ + 4H2O
+1.51
MnO–4 + e– → MnO42–
+0.56
Mn3+ + e– → Mn2+
+1.51
I2 + 2e– → 2I–
+0.54
Au3+ + 3e– → Au
+1.40
I3 + 2e– → 3I–
+0.53
Cl2 + 2e– → 2Cl–
+1.36
Cu+ + e– → Cu
+0.52
Cr2O 7 + 14H+ + 6e– → 2Cr3+ + 7H2O
+1.33
NiOOH + H2O + e– → Ni(OH)2 + OH–
+0.49
O3 + H2O + 2e– → O2 + 2OH–
+1.24
Ag2CrO4 + 2e– → 2Ag + CrO42–
+0.45
O2 + 4H+ + 4e– → 2H2O
+1.23
O2 + 2H2O + 4e– → 4OH–
+0.40
ClO–4 + 2H+ +2e– → ClO–3 + 2H2O
+1.23
ClO–4 + H2O + 2e– → ClO–3 + 2OH–
+0.36
MnO2 + 4H+ + 2e– → Mn2+ + 2H2O
+1.23
[Fe(CN)6]3– + e– → [Fe(CN)6]4–
+0.36
Pt2+ + 2e– → Pt
+1.20
Cu2+ + 2e– → Cu
+0.34
Br2 + 2e– → 2Br–
+1.09
Hg2Cl2 + 2e– → 2Hg + 2Cl–
+0.27
–
2–
he
is
bl
2–
© no N C tt E o R be T re pu
2–
d
F2 + 2e– → 2F–
–
135
iz;ks'kkyk iqfLrdk] jlk;u +0.27
S + 2e– → S2–
–0.48
Bi3+ + 3e– → Bi
+0.20
In3+ + e– → In2+
–0.49
SO42 + 4H+ + 2e– → H2SO3 + H2O
+0.17
U4+ + e– → U3+
–0.61
Cu2+ + e– → Cu+
+0.16
Cr3+ + 3e– → Cr
–0.74
Sn4+ + 2e– → Sn2+
+0.15
Zn2+ + 2e– → Zn
–0.76
AgBr + e– → Ag + Br–
+0.07
Cd(OH)2 + 2e– → Cd + 2OH–
–0.81
he
–
d
AgCl + e– → Ag + Cl–
2H2O + 2e– → H2 + 2OH–
–0.83
Cr2+ + 2e– → Cr
–0.91
0.00
2H+ + 2e– → H2
(ifjHkk"kkuqlkj) 0.0
Fe3+ + 3e– → Fe
–0.04
Mn2+ + 2e– → Mn
O2 + H2O + 2e– → HO–2 + OH–
–0.08
V2+ + 2e– → V
Pb2+ + 2e– → Pb
–0.13
Ti2+ + 2e– → Ti
–1.63
In+ + e– → In
–0.14
Al3+ + 3e– → Al
–1.66
Sn2+ + 2e– → Sn
–0.14
U3+ + 3e– → U
–1.79
AgI + e– → Ag + I–
–0.15
Sc3+ + 3e– → Sc
–2.09
Ni2+ + 2e– → Ni
–0.23
Mg2+ + 2e– → Mg
–2.36
V3+ + e– → V2+
–0.26
Ce3+ + 3e– → Ce
–2.48
Co2+ + 2e– → Co
–0.28
La3+ + 3e– → La
–2.52
In3+ + 3e– → In
–0.34
Na+ + e– → Na
–2.71
Tl+ + e– → Tl
–0.34
Ca2+ + 2e– → Ca
–2.87
PbSO4 + 2e– → Pb + SO2– 4
–0.36
Sr2+ + 2e– → Sr
–2.89
Ti3+ + e– → Ti2+
–0.37
Ba2+ + 2e– → Ba
–2.91
Cd2+ + 2e– → Cd
–0.40
Ra2+ + 2e– → Ra
–2.92
In2+ + e– → In+
–0.40
Cs+ + e– → Cs
–2.92
Cr3+ + e– → Cr2+
–0.41
Rb+ + e– → Rb
–2.93
Fe2+ + 2e– → Fe
–0.44
K+ +e– → K
–2.93
In3+ + 2e– → In+
–0.44
Li+ + e– → Li
–3.05
© no N C tt E o R be T re pu
bl
is
Ti4+ + e– → Ti3+
136
–1.18
–1.19
y?kqx.kd lkj.kh 1 3
4
0086
0128
0170
11
0414 0453
0492
0531
0569
5 0212
12 13 14 15 16 17 18
1139 1173 1461 1492 1761 1790 2041 2068 2304 2330 2553 2577 2788 2810
0864 1206 1523 1818 2095 2355 2601 2833
0899 1239 1553 1847 2122 2380 2625 2856
7
8
0253 0294 0334
9
1
2
3
4
5
7
8
9
0374
5 4
13 12
17 16
21 26 2O 24
30 28
34 38 32 36
8 7
12 11
16 15
20 18
23 22
27 26
31 35 29 33
8
6
9
0607
0645 0682 0719
0755
4 4
0969
1004 1038 1072 1106
3 3
7 7
11 10
14 14
18 17
21 20
25 24
28 32 27 31
1303
1335 1367 1399
1430
3 3
6 7
10 10
13 13
16 16
19 19
23 22
26 29 25 29
1614
1644 1673 1703
1732
3 3
6 6
9 9
12 12
15 14
19 17
22 20
25 28 23 26
1903
1931 1959 1987
2014
3 3
6 6
9 8
2175
2201 2227 2253
2279
3 3
6 5
8 8
2430
2455 2480 2504
2529
3 3
2672
2695 2718 2742
2765
2 2
0934 1271 1584 1875 2148 2405 2648 2878
2900
2923 2945 2967
2989
2 2
11 11
14 14
11 10
14 16 13 16
17 17
20 19
23 26 22 25
19 18
22 24 21 23
5 5
8 8
10 10
13 12
15 15
18 17
20 23 20 22
5 4
7 7
9 9
12 14 11 14
17 16
19 21 18 21
4 4
7 6
9 8
11 11
13 13
16 15
18 20 17 19
© no N C tt E o R be T re pu
19
0792 0828
6
d
1
he
2
0000 0043
is
0
10
bl
N
20
3010 3032
3054
3075
3096
3118
3139 3160 3181
3201
2
4
6
8
11
13
15
17 19
21 22
3222 3243 3424 3444
3263 3464
3284 3483
3304 3502
3324 3522
3345 3365 3385 3541 3560 3579
3404 3598
2 2
4 4
6 6
8 8
10 10
12 12
14 14
16 18 15 17
23 24
3617 3636 3802 3820
3655 3838
3674 3856
3692 3874
3711 3892
3729 3747 3766 3909 3927 3945
3784 3962
2 2
4 4
6 5
7 7
9 9
11 11
13 12
15 17 14 16
25 26
3979 3997 4150 4166
4014 4183
4031 4200
4048 4216
4065 4232
4082 4099 4116 4249 4265 4281
4133 4298
2 2
3 3
5 5
7 7
9 8
10 10
12 11
14 15 13 15
27 28
4314 4330 4472 4487
4346 4502
4362 4518
4378 4533
4393 4548
4409 4425 4440 4564 4579 4594
4456 4609
2 2
3 3
5 5
6 6
8 8
9 9
11 11
13 14 12 14
29
4624 4639
4654
4669
4683
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2018 2065 2113 2163 2213 2265 2317 2371 2427 2483
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