Structural and Dielectric Properties of Mg(1-x)CaxTiO3 (x=0.7, 0.8) Ceramic Materials

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Mechanics, Materials Science & Engineering, March 2017

ISSN 2412-5954

Structural and Dielectric Properties of Mg (1-x)CaxTiO3 (x=0.7, 0.8) Ceramic Materials4 V. Sharon Samyuktha 1, T. Subba Rao 2, R. Padma Suvarna1 1

JNTUA, Anantapuram, Andhra Pradesh, India-515001

2

Sri Krishna Devaraya University, Andhra Pradesh, India-515003 DOI 10.2412/mmse.30.345.847 provided by Seo4U.link

Keywords: calcium magnesium titanate, solid state reaction method, dielectric response, XRD.

ABSTRACT. Calcium Magnesium titanate ceramic materials with the molar formula Mg(1-x) CaxTiO3 in which the x varies from 0.7 to 0.8 were synthesized by conventional Solid State Reaction method. The XRD pattern revealed that the samples exhibit Orthorhombic structure. The microstructure and surface morphology for the samples was studied by SEM. The elemental composition was studied by EDAX. The dielectric response of both samples was measured by HIOKI 3532-50 LCR HiTESTER in the frequency range of 1KHz-1MHz from room temperature to 350 0C. These samples find applications in capacitors, microwave antennas, stainless steel electrodes and data storage devices.

Introduction. Over more than 200 years, Ceramic materials are known for technical applications. To overcome the limitations of other conventional materials, various special tailored ceramics are developed with novel chemical, electrical, biological and mechanical properties. In the last three decades there has been a phenomenal transformation in microwave communication systems such as mobile telecommunication systems, satellite communication and broadcasting systems, and global positioning systems. The rapid development in microwave communication systems was made possible with the use of dielectric ceramics as enabling materials for resonators, filters and other key components in microwave components. For these applications the ceramic materials are required to have a high relative permittivity ( r), low dielectric loss, and near zero temperature coefficient of resonant frequency ( f). The combination of these requirements greatly restricts the ceramic dielectrics available for applications in microwave systems [1]. Magnesium titanate ceramics play an important role in microwave technologies such as global positioning system operating at microwave frequencies, resonators, filters, antennas for communication system and multilayer capacitors [2-5]. It is a multifaceted material of low dielectric loss with high quality factor (Q above 20000 at 8GHz) and intermediate dielectric constant ( r=17) [6]. Calcium titanate is a popular ceramic material which has a wide range of applications in industry and technology. The Calcium titanate ceramic material has high dielectric constant ( r=170) Qxf 0 C [7] and modest dielectric losses which makes it a f suitable candidate for microwave applications. In the present work, the magnesium calcium titanate ceramic materials of different compositions such as Mg(1-x)CaxTiO3 (x=0.7-0.8) were synthesized by conventional Solid State diffusion method and the phase, crystallite size, microstructure and dielectric properties were investigated. Experimental Procedure. MCT CaxMg(1-x)TiO3 (x=0.7&0.8) was synthesized using Solid- state reaction method. High purity materials such as CaO (99.6% purity, Sigma Aldrich), TiO2 (99.4% purity, Sigma Aldrich), and MgO (99.6% purity, Sigma Aldrich) were used as precursor materials. These materials were weighed, taken according to the composition and mixed uniformly. The mixed 4

Magnolithe GmbH. This is an open access article under the CC BY-NC-ND license http://creativecommons.org/licenses/by-nc-nd/4.0/

MMSE Journal. Open Access www.mmse.xyz

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