Mechanics, Materials Science & Engineering, July 2017 – ISSN 2412-5954
Novel and Proficient Organic-Inorganic Lead Bromide Perovskite for SolidState Solar Cells 1
B. Praveen1, Tenzin Tenkyong1, W. Jothi Jeyarani1, J. Sahaya Selva Mary1, V.Chandrakala1, Neena Bachan1, J. Merline Shyla1,a 1 – Department of Physics, Energy NanoTechnology Centre (ENTeC), Loyola Institute of Frontier Energy (LIFE), Loyola College, Chennai, India a – jmshyla@gmail.com DOI 10.2412/mmse.24.90.160 provided by Seo4U.link
Keywords: perovskite, spin coating, photoconductivity, solid-state solar cells.
ABSTRACT. Efficient solar cells based on organic/inorganic lead halide perovskite absorbers which are emerging recently, assure the renovation in the fields of dye sensitized, organic and thin film solar cells, whose performance are reported to have exceeded ~ 24% power conversion efficiency. Here, we report the synthesis and fabrication of a novel and proficient perovskite material prepared by spin coating technique using methyl ammonium lead bromide (CH3NH3PbBr3). Several characterization techniques such as Ultraviolet–Visible Diffuse Reflectance Spectroscopy (UVDRS), Fourier Transformer Infra-Red (FTIR) analysis, X-Ray Diffraction (XRD) analysis and Field dependent dark and photoconductivity are to be done to analyze the behavior of the perovskite material. The X-ray diffraction pattern reveals the composition of the materials present in the sample. UV-visible analysis showed an enhanced absorption of the perovskite material and the photoconductivity techniques revealed the ohmic nature of the samples with a linear increase in both dark and photocurrent with corresponding increase in the applied field. Thus, these novel and proficient perovskite materials could overcome the limitations of existing perovskites and lead to higher performance in solid-state solar cells.
Introduction. Efficient and economical energy harvesting by solar cells is a great challenge for the 21st century in the field of key technology for sustainable energy supply. Most recently, inorganic– organic hybrid perovskite materials have been widely fabricated and rapidly demonstrated in the most promising emerging photovoltaic devices with respect to increase in efficiency[1-2]. Perovskite is a material with a specific crystal structure named after the Russian mineralogist L. A. Perovski [3]. Inorganic-organic perovskite materials taking the form ABX3 (A = CH3NH3+; B = Pb+; and X=Cl–, I–, Br–) has with in the past 4 years been used to fabricate high-performance hybrid solar cells, with reported power conversion efficiencies (ƞ) >25 % [4]. An organo-lead halide perovskite based solar cell which requires charge separation (electrons and holes) and less recombination in a light absorbing material to transmit electricity for photovoltaic applications [5]. In the present work, the CH3NH3PbBr3 perovskite material has been synthesized and fabricated by using the spin coating method. The perovskite sensitizer has high light absorption coefficient [6], [7] which would aid in increasing the light harvesting ability of the sensitized material. Experimental Section Perovskite (CH3NH3PbBr3) synthesis. The perovskite solution was synthesised as described in the Fig 1. Initially Methylammonium Bromide (CH3NH3Br) precursor solution was synthesized by reacting 30 mL of hydrobromide acid and 23 mL of methylamine at 0oC for 2 h with continuous stirring. The precipitate was recovered by evaporating at 50°C for 1 h. The product is washed (using funnel and filter paper) three times with di-ethyl ether or one time with ethanol and finally dried at 60°C for 24 h. An amount of 0.369g of prepared CH3NH3Br solution was added to 1.157g of PbBr2 1
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