Mechanics, Materials Science & Engineering, July 2017 – ISSN 2412-5954
Conductivity, Morphology and Thermal Studies of Polyvinyl Chloride (PVC)Lithium Nitrate with Cadmium Oxide (CdO) 1
P. Karthika1, a, R. Gomathy2, P.S. Devi Prasadh 3, b 1 – Department of Physics, SNS College of Engineering, Coimbaore, India 2 – Department of Physics, Dr. Mahalingam College of Engineering & Technology, Pollachi, Coimbatore, India 3 – School of Advanced Sciences, VIT University, Vellore, Tamilnadu, India a – pkarthikaa@gmail.com b – psdprasadh@gmail.com DOI 10.2412/mmse.31.97.961 provided by Seo4U.link
Keywords: PVC, LiNO3, CdO, conductivity, SEM, TGA.
ABSTRACT. High ionic conductivity of polymeric system is important in polymer research. Solvent cast technique is used to formulate the polyvinyl Chloride (PVC) – Lithium Nitrate (LiNO3) – Cadmium Oxide (CdO) system. Nature of complexation and concentration of various ionic species are important to understand the conductance mechanism. Conductivity studies provided with the help of ac impedance analyser. Morphology behaviours of polymer electrolytes have been studied using SEM. The thermal properties of polyvinyl chloride(PVC) – Lithium Nitrate (LiNO3) – Cadmium Oxide (CdO) by Thermo Gravimetric Analysis (TGA) gives rise the information on the thermal stability of polymer electrolytes.
Introduction. Now a days, researchers have very much interested in studying the ionic conductivity at ambient temperature due to their unique performance in high power rechargeable lithium battery, which can be used in laptops and even electric vehicles and other portable electronic equipment. The preparation of polymer electrolytes with high conductivity, good mechanical strength and thermal stabilities are interest due to the role of polymer electrolytes in lithium batteries, electro – chromic windows, sensors and fuel cells etc. [1]. In our everyday life, polymers are widely used due to their fascinating and extraordinary characteristics. To replace the conventional materials in terms of strength, stability and toughness they are found. Since the beginning of plastic industry, it is observed that blending yields materials with superior features of the individual components. Blending of polymers provide new materials which combine the useful property of all constituents. Technological interest of polymer electrolytes are due to their possible application as solid electrolytes in various electrochemical devices such as energy conversion units, electro-chromic display devices, photo chemical solar cells and sensors. The polymer electrolytes in lithium batteries are most widely studied among the various applications, A polymer electrolyte will function as a separator as well as an electrolyte in a secondary battery. Studies on polymer electrolytes have great intention to explain the enhancement mechanism of conductivity. Various ionic species’ concentration are important to understand the overall mechanism of conductivity, The structural and morphological behaviours of polymer electrolytes have been studied by SEM. In this work, polymer electrolytes are prepared by solution casting technique which contained polyvinyl chloride (PVC) as a host polymer and lithium nitrate(LiNO3) as a salt. The nano filler CdO added with various proportion to these polymer electrolytes to get nanocomposite polymer electrolytes (NCPE). Then,
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