Exploring the Properties of NiO Nanoparticles Prepared by Reflux Method10

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Mechanics, Materials Science & Engineering, May 2017

ISSN 2412-5954

Exploring the Properties of NiO Nanoparticles Prepared by Reflux Method10 A. Dhayal Raj1,a, A. Albert Irudayaraj1, A. Reenaarul Vani1 1

Department of Physics, Sacred Heart College, Tirupattur, India

a

dhayalraj03@gmail.com DOI 10.2412/mmse.25.82.979 provided by Seo4U.link

Keywords: NiO nanostructures, pH, SEM, XRD, reflux method.

ABSTRACT. Admirable nanoparticles of nickel oxide have been synthesized by Reflux method. Required amount of nickel nitrate was dissolved in 200ml of Ethylene Glycol (EG).To the above solution 50ml of PEG was added and stirred well. The pH of the solution was adjusted as 8, 10 and 12 using HCl in order to investigate the effect of pH on the properties of the prepared NiO nanoparticles. The precipitate was collected, washed several times and was calcinated at 500oC for 1 hr. The samples were subjected to various characterizations such asXRD, SEM, UV and FTIR, inorder to study its structure, morphology, optical properties and functional group. The results show that pH plays a key role in the synthesis of NiO nanostructures. The morphology of the prepared samples holds substantial promise for applying NiO as a potential gas sensing material.

Introduction. Nickel oxide (NiO) nanoparticles have been received considerable attention due to their wide range of applications in various fields included the fabrication of catalysis [1-4], electro chromic films [4-6], fuel cell electrode and gas sensors [6-9], battery cathodes [10-11], magnetic materials [12-13], photovoltaic devices and electrochemical super capacitors, smart windows and dye-sensitized photocathodes [14]. Therefore, NiO became one of the most important transition metal oxides. However, most of these applications require particles with a small size and a narrow size distribution. The reduction in size leads to the volume effect, the quantum size effect and the surface effect which in turn improves the properties of NiO nanoparticles. One of the major challenges, the world recently facing is energy consumption and demand. To meet the energy requirements of this modern generation, an ideal energy storage device is needed at present to provide high energy in short time. Especially, the device should store more power and deliver high energy output for various applications. Among all energy storage devices, electrochemical capacitors exhibit high power density than other electrochemical devices, such as batteries, photo-voltaic devices, etc. and high energy density than conventional capacitors because of unique charge storage mechanisms. Transition metal oxides have been studied to obtain high specific capacitance and high charge/discharge ability in electro-chemical capacitors. Among the transitional metal oxides available, nickel oxide is an attractive material in electrochemical devices. In this research work, nanocrystalline nickel oxide nanoparticles have been prepared by reflux method. The prepared samples are found to have uniform particle size distribution and excellent morphological characteristics. The obtained results were discussed and presented in this research article. Experimental. Required amount of nickel nitrate was added to 200ml of ethylene glycol. To the above solution 50 ml of PEG was added and stirred well. The pH of the resultant solution was altered to the required value (10 and 12) using dilute HCL. The final solution was refluxed for 5 hours under constant stirring. The precipitate was collected, washed several times with double distilled water and ethanol. Then it was 10

-NC-ND license http://creativecommons.org/licenses/by-nc-nd/4.0/

MMSE Journal. Open Access www.mmse.xyz

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