Vercet Polyols

Page 1

POLYOLS 1 // NATUREWORKS PERFORMANCE CHEMICALS | POLYOLS


CREATING PERFORMANCE THROUGH CHEMISTRY Building upon decades spent advancing materials chemistry innovation, NatureWorks offers solutions based on lactides and lactide intermediates that help innovators within the coatings, adhesives, sealants, and elastomers (C.A.S.E.), toner and surfactant industries realize:

Significant, measurable product performance benefits

Move through the R&D process more efficiently and with minimal risk

Decrease systems costs via an optimized supply chain

VERSATILE VERCET LACTIDE CHEMISTRY O x

O O

R

+ HO

O

O OH

O

LACTIDE

H

O

O

O

R

O

O

x/2

O

O O

LACTIDE POLYOLS

Reacts readily with alcohols, amines, glycols

Tg ranges ~ 0-60°C

100% solids

Hydroxyl values 12-112 mg-KOH/g

No water loss

Secondary hydroxyl functionality

Sustainably sourced

Readily reacts with isocyanates Readily soluble in esters and ketones Renewably-sourced biobased polyols and resins

2 // NATUREWORKS PERFORMANCE CHEMICALS | POLYOLS

x/2

H


LACTIDES — POLYOLS — RESINS

We achieve this by coupling tunable Vercet™ lactidebased chemistries with the knowledge of scientists and engineers who understand how to dial in the full capabilities of this versatile product line.

POLYOLS FOR POLYURETHANES

CUSTOM SOLUTIONS FOR COATINGS & ADHESIVES Using Vercet polyester polyols for polyurethanes enables unique properties including excellent grease and oil resistance for both adhesive and coating applications.

COATINGS

ADHESIVES

SUBSTRATES

MARKETS

SUBSTRATES

MARKETS

Wood Metal Cements Ceramics

Furniture Flooring Architecture Decorative

Wood Wood laminates Metal Mixed substrates

Furniture Flooring Nonwovens / hygiene Foams Electronics Packaging- rigid & flexible

PERFORMANCE BENEFITS

PERFORMANCE BENEFITS

Excellent oil, grease, and solvent resistance

Tailored open times and work-life

High hardness polyurethanes

Excellent solvent resistance

Controlled functionality

Solvent-borne & hot melt adhesives

Controlled viscosity (hydroxyl values 12-112 mg-KOH/g)

Renewably-sourced building block

Low haze Solvent-borne & hot melt coatings

VERCET.NATUREWORKSLLC.COM // 3


POLYOLS FOR URETHANE ADHESIVES Vercet polyols show compatibility with a variety of polyols such as 2000 molecular weight adipate-based polyols. Vercet Grade

f

Tg (˚C)

Viscosity @100˚C (Pa*s)

OHV1 [mg-KOH/g]

P1025X

1

15

1.3

25

P2025X

2

40

11.3

25

P2056X

2

25

2.1

56

P20112X

2

5

<1.0

112

P2225X

2

35

13

25

Performance Features Chain stopper

High modulus & hardness. Oil & grease resistance.

High modulus & hardness. Oil & grease resistance.

P2256X

2

21

2

56

P22112X

2

-1

<1.0

112

Improves flexibility & toughness.

P3025X

3

40

19.1

25

Crosslinker

1. OHV-Hydroxyl Value as determined by ASTM E1899

PROPERTIES

POLYURETHANES FORMULATED WITH VERCET POLYOLS Control

Polyurethane with Polyol

Vercet P2025X

(Based on AA-HDO)8

Wt% - Polyol / MDI6 /1,2 PDO7

85.3/12.5/0.8

86.6/11.6/0.8

Polyol OHV1 [mg-KOH/g]

30

29

Gel Time [sec] 120°C

158

60

Hardness2 [Shore A / D]

84/71

70/33

Tg/Tm3

Tg 51-55˚C

Tm peak 55˚C

Resiliency4

17

23

Water Pickup55

0.9%

0.6%

1. OHV – Hydroxyl Value as determined by ASTM E1899 2. Hardness as determined by ASTM 2240, 4 weeks 3. DSC mid-point, 20°C/min, 2nd heat 4. Resiliency as determined by ASTM D2632

5. Immersion testing, 8 days at 25°C 6. 4,4' - Methylene diphenyl diisocyanate 7. 1,2 - Propanediol 8. 1,6 - Hexanediol adipate

4 // NATUREWORKS PERFORMANCE CHEMICALS | POLYOLS


POLYURETHANE PERFORMANCE

HIGHER MODULUS CREATES HIGHER STRENGTH OVER EXTENDED TEMPERATURE RANGE 1E+10

10X

1E+09

100X

1E+08

Storage Modulus (Pa)

1E+07

1E+06

Temp (°C)

1E+05 20

25

30

35

Tg (°C, DSC)

CONTROL TPU

40

Tg (°C, DMA)

41-44 Tm (onset)

VERCET P2025X

49-52

56

45

50

55

60

E' (MPa, 30°C)

E' (MPa, 35°C)

E' (MPa, 45°C)

E' (MPa, 50°C)

24

21

8.8

3.0

347

331

321

315

ASTM Method D790. 3 point bend fixture heated 3°C per minute.

POLYURETHANE PERFORMANCE

EXCELLENT HARDNESS AT LOW MDI CONTENT USES LESS ISOCYANATE 71 CONTROL 34

 18%

84 VERCET P2025X

 109%

71

Shore A

Shore D

0

10

20

30

40

50

60

70

80

90

ASTM Method 2240. Measured after 4 weeks.

VERCET.NATUREWORKSLLC.COM // 5


HOT OIL SWELL SHOWS EXCELLENT OIL RESISTANCE WT% CANOLA OIL PICK-UP 68˚C

4

Wt% Change

Wt% Pick-up

WT% IRM 903 OIL PICK-UP 68˚C

8

3

6

2

4

1

2

0

0 Time (Days)

Time (Days)

-1 0

2

4

6

8

-2

10

0

1.5

3

4.5 Vercet P2025X

MEASURABLE PERFORMANCE

6

7.5 Control

VERCET-BASED POLYURETHANE SOLVENT RESISTANCE: 10 DAY SWELL VALUES WT% SOLVENT PICK-UP

16% 14% 12% 10% 8% Not equilibrated after 10 days

6% 4% 2% 0% -2% IRM 903 OIL

CANOLA OIL

N-HEXANE

ETHANOL

WATER

CONTROL

10.00%

4.50%

1.50%

8.10%

0.60%

VERCET P2025X

-0.20%

0.20%

0.60%

13.90%

0.90%

Wt% data collected 68˚C 6 // NATUREWORKS PERFORMANCE CHEMICALS | POLYOLS


POLYOLS FOR POLYURETHANES IN REACTIVE HOT MELT ADHESIVES

Polyol

Vercet P2025X

Control, (HDO-Adipate)

%NCO

2.0

2.5

Viscosity (mPa*s, 120˚C)

+100,000

14,000

DSC Transition (˚C)

PREPOLYMER FORMULATION • • • •

ADHESIVE FORMULATION • • • •

53

51

85% Vercet-based polyol 15% 4,4' MDI Isocynate index 1.05 Reaction time 2-3 hours

88 Wt% Vercet-based prepolymer 10 Wt% DEG-adipate prepolymer 1.0 Wt% Epoxy silane adhesion promoter 1.0 Wt% DMDEE catalyst

REACTIVE HOT MELT ADHESIVES PERFORMANCE

STABLE NCO PREPOLYMER ENSURES STORAGE AND POTLIFE STABILITY %NCO OF PREPOLYMERS OVER TIME 3.0 AT 120˚C HDO-Adipate Control

2.5 Vercet P2025X

2.0

1.5

1.0

0.5 Time (Hours) 0

1

2

3

4

5

6

VERCET.NATUREWORKSLLC.COM // 7


VERCET POLYOLS IN SOLVENTBORNE URETHANE COATINGS Excellent gloss, adhesion and hardness in urethane coatings.

Sample

60° Gloss

Cross-hatch Adhesion

¨ Konig Hardness

Pencil Hardness

Weight % Solvent Swell Canola Oil @ 68°C

Vercet P2025X

95

5B (<5% removed)

73

2B

0.05

PU Control

40

1B (35-65% removed)

45

<8B

5.0

Uncoated Metal

83

220

NA

NA

NA

1. Solvent borne TPU coated on metal Q panels 2. Ethyl acetate ~20% solids, bar coated DFT ~30 um thick

3. RT dried, no crosslinking reagent

VERCET POLYOL THERMAL STABILITY No significant change to hydroxyl value after thermal aging.

120 Vercet P20112X

OHV (mg-KOH/g)

100

80

Vercet P2056X

60 Vercet P2025X

40 Control

20 Time (Days)

0 0

7

14

21

28

40°C, ~40-50% RH Evaluated by Titration Method ASTM E1899

8 // NATUREWORKS PERFORMANCE CHEMICALS | POLYOLS


BENIGN BY DESIGN

REDUCING VOLATILITY IN PRICING THROUGH ALTERNATIVE FEEDSTOCKS Renewably-sourced Vercet lactide-based products bring sensible, elegant, and cost-effective solutions based squarely on the principles of green chemistry to supply chains that, until now, were coupled with traditional fossil-petroleum solutions and their inherent price volatility.

250

200

150

50 Prices re-based to 100

0 2006

Petrochemical Feedstocks

2018

Vercet Feedstock

VERCET.NATUREWORKSLLC.COM // 9


HOW CAN WE HELP YOU?

BRIAN GLASBRENNER COMMERCIAL MANAGER

+1 (952) 562.3391 brian_glasbrenner@natureworksllc.com

To learn more about Vercet custom solutions, please contact a member of our Performance Chemicals team.

BILL COGGIO

APPLICATION AND TECHNOLOGY MANAGER

+1 (952) 562.3308 bill_coggio@natureworksllc.com

vercet.natureworksllc.com | vercet@natureworksllc.com | @natureworks Vercet and the Vercet logo are trademarks or registered trademarks of NatureWorks LLC in the USA and other countries. © 2018 NatureWorks LLC. All rights reserved.

10 // NATUREWORKS PERFORMANCE CHEMICALS | POLYOLS


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