analysis applications of nanomaterials 1st Edition Chaudhery Mustansar Hussain
Visit to download the full and correct content document: https://textbookfull.com/product/advanced-environmental-analysis-applications-of-nan omaterials-1st-edition-chaudhery-mustansar-hussain-2/
More products digital (pdf, epub, mobi) instant download maybe you interests ...
Advanced environmental analysis applications of nanomaterials 1st Edition Chaudhery Mustansar Hussain
https://textbookfull.com/product/advanced-environmental-analysisapplications-of-nanomaterials-1st-edition-chaudhery-mustansarhussain-2/
Handbook of Functionalized Nanomaterials for Industrial Applications 1st Edition Chaudhery Mustansar Hussain (Editor)
https://textbookfull.com/product/handbook-of-functionalizednanomaterials-for-industrial-applications-1st-edition-chaudherymustansar-hussain-editor/
Handbook on Miniaturization in Analytical Chemistry: Application of Nanotechnology 1st Edition Chaudhery Mustansar Hussain
https://textbookfull.com/product/handbook-on-miniaturization-inanalytical-chemistry-application-of-nanotechnology-1st-editionchaudhery-mustansar-hussain/
Green Synthesis of Nanomaterials: Biological and Environmental Applications 1st Edition Chakravarty
https://textbookfull.com/product/green-synthesis-ofnanomaterials-biological-and-environmental-applications-1stedition-chakravarty/
Nanomaterials in energy and environmental applications 1st Edition He
https://textbookfull.com/product/nanomaterials-in-energy-andenvironmental-applications-1st-edition-he/
Nanomaterials for Advanced Biological Applications Moones Rahmandoust
https://textbookfull.com/product/nanomaterials-for-advancedbiological-applications-moones-rahmandoust/
Environmental Toxicity of Nanomaterials First Edition Dasgupta
https://textbookfull.com/product/environmental-toxicity-ofnanomaterials-first-edition-dasgupta/
Chemistry of Advanced Environmental Purification Processes of Water Fundamentals and Applications 1st Edition Erik Sogaard
https://textbookfull.com/product/chemistry-of-advancedenvironmental-purification-processes-of-water-fundamentals-andapplications-1st-edition-erik-sogaard/
Artificially Intelligent Nanomaterials For Environmental Engineering Chang
https://textbookfull.com/product/artificially-intelligentnanomaterials-for-environmental-engineering-chang/
on 08 November 2016 on
RSC Detection Science Series
Editor-in-Chief
Professor Michael Thompson, University of Toronto, Canada
Series Editors:
Dr Sub Reddy, University of Central Lancashire, Preston, UK
Professor Damien Arrigan, Curtin University, Perth, Australia
Titles in the Series:
1: Sensor Technology in Neuroscience
2: Detection Challenges in Clinical Diagnostics
3: Advanced Synthetic Materials in Detection Science
4: Principles and Practice of Analytical Techniques in Geosciences
5: Microfluidics in Detection Science: Lab-on-a-chip Technologies
6: Electrochemical Strategies in Detection Science
7: Peroxynitrite Detection in Biological Media: Challenges and Advances
8: Biological Fluid-Surface Interactions in Detection and Medical Devices
9: Advanced Environmental Analysis: Applications of Nanomaterials, Volume 1
10: Advanced Environmental Analysis: Applications of Nanomaterials, Volume 2
How to obtain future titles on publication: A standing order plan is available for this series. A standing order will bring delivery of each new volume immediately on publication.
For further information please contact:
Book Sales Department, Royal Society of Chemistry, Thomas Graham House, Science Park, Milton Road, Cambridge, CB4 0WF, UK
Telephone: +44 (0)1223 420066, Fax: +44 (0)1223 420247
Email: booksales@rsc.org
Visit our website at www.rsc.org/books
Advanced Environmental Analysis Applications of Nanomaterials, Volume 2
Edited by
Chaudhery Mustansar Hussain
New Jersey Institute of Technology, Newark, NJ, USA
Email: chaudhery.m.hussain@njit.edu and Boris Kharisov
Universidad Autonoma de Nuevo Leon, Monterrey, Mexico
Email: bkhariss@hotmail.com
RSC Detection Science Series No. 10
Print ISBN: 978-1-78262-906-1
Two volume set print ISBN: 978-1-78262-907-8
PDF eISBN: 978-1-78262-913-9
EPUB eISBN: 978-1-78262-914-6
ISSN: 2052-3068
A catalogue record for this book is available from the British Library
© The Royal Society of Chemistry 2017
All rights reserved
Apart from fair dealing for the purposes of research for non-commercial purposes or for private study, criticism or review, as permitted under the Copyright, Designs and Patents Act 1988 and the Copyright and Related Rights Regulations 2003, this publication may not be reproduced, stored or transmitted, in any form or by any means, without the prior permission in writing of The Royal Society of Chemistry or the copyright owner, or in the case of reproduction in accordance with the terms of licences issued by the Copyright Licensing Agency in the UK, or in accordance with the terms of the licences issued by the appropriate Reproduction Rights Organization outside the UK. Enquiries concerning reproduction outside the terms stated here should be sent to The Royal Society of Chemistry at the address printed on this page.
The RSC is not responsible for individual opinions expressed in this work.
The authors have sought to locate owners of all reproduced material not in their own possession and trust that no copyrights have been inadvertently infringed.
Published by The Royal Society of Chemistry, Thomas Graham House, Science Park, Milton Road, Cambridge CB4 0WF, UK
Registered Charity Number 207890
For further information see our website at www.rsc.org
Printed in the United Kingdom by CPI Group (UK) Ltd, Croydon, CR0 4YY, UK
Preface
Environmental analysis has become a topic of considerable importance these days. It is not only significant to environmentalists but also to regulators, decision makers, surveillance agencies and the organizations assessing the impact of pollutants on the environment, and it has evolved as a true discipline throughout the world. In recent years, there has been a rapid union of nanotechnology and analytical sciences. This convergence, although highly interdisciplinary in nature, has been brought about by new technologies that have led to application-specific devices, for example lab-on-a chip. The high demand for advanced comprehensive understanding and awareness of more accurate and precise measurement tools for pollutants and their characterization dictate the terms and conditions for this convergence. The reduction in size from bulk to micro- and nano-scale promises high sensitivity, high speed, increased selectivity and increased device lifetime for new devices. Instruments with more sensitivity are required today to analyze ultra-trace levels of environmental pollutants, pathogens in water, and low vapor pressure energetic materials in air.
The objective of this book is to provide an overview of new developments for a variety of environmental analytical techniques. Every effort has been made to include the state-of-the-art to show improvements in environmental analytical techniques and processes due to nanomaterials in the book. Additionally, special attention is paid to those approaches that are green and reduce the cost of the analysis, process both in terms of chemicals and time consumption. In the end the legal, economical and toxicity aspects of nanomaterials are also presented in detail.
To put all of the shared knowledge into perspective, add a touch of reality to the concepts, and to cover extensive expansion of the applications of nanomaterials in the environmental analysis field, the book is divided into two volumes and each volume has subdivisions of several sections. Moreover, to
RSC Detection Science Series No. 10
Advanced Environmental Analysis: Applications of Nanomaterials, Volume 2
Edited
by
Chaudhery Mustansar Hussain and Boris Kharisov
© The Royal Society of Chemistry 2017
Published by the Royal Society of Chemistry, www.rsc.org
maintain coherence in the flow of knowledge, these sections are patterned in a continuous manner in both volumes. As a result, sections one to four are contained in the first volume, whereas sections five to ten are provided in the second volume.
In Volume One, the first section talks about the perspective of analytical sciences in relation to nanotechnology, synthetic techniques for nanomaterials, different unique properties of nanomaterials and a detailed description of the mechanisms of adsorption on nanomaterials. The second section encompasses the recent advances in sample preparation and extraction techniques for organic and inorganic pollutants with nanomaterials. The third section is all about new developments in separation techniques with a focus on applications of nanomaterials for chromatography and membrane technology. The fourth section incorporates spectroscopic techniques using nanomaterials, especially surface-enhanced Raman scattering (SERS), for detection of environmental pollutants.
In Volume Two, the fifth section describes new trends in environmental analysis, i.e., applications of magnetic nanomaterials, nano-sensors, composite materials and nano-bio sensors, like nanozymes. The sixth section talks about the applications of nanomaterials for water treatment and purification techniques. The effects of nanomaterials on the environment and the ecosystem in terms of their toxicity, safety regulations and economic issues are depicted in the seventh section. Section eight discusses the monitoring and analysis of nanomaterials, whereas section nine is about the future of environmental analysis in light of new developments in science and technology. In the last section, the editors provide concluding remarks about the application of nanomaterials for environmental analysis.
The selection of these sections in both volumes is based on the most recent research, teaching, the practical experience of editors and the philosophy that environmental analysis is moving towards its next generation. The contributing authors are selected from a wide cross-section around the world. The diversity of authors for each chapter and their disciplinary backgrounds reveal the interdisciplinary emphasis of this book. Thanks to the multidisciplinary nature of this book, the reader can enjoy a lot of knowledge in one place.
The anticipated audience is scientists, researchers, consultants, regulators and engineers. Moreover, graduate students will find this book to be very useful in their research and understanding of advances in environmental analysis techniques and beyond. The book is also intended to provide more experienced researchers with a condensed summary of the influence of nanotechnology on analytical techniques and excellent up-to-date references that will prove useful in their future endeavors. The editors and contributors are lead scientists and researchers in academia and industry in their subject areas. On behalf of the Royal Society of Chemistry, we are very thankful to all contributors for their special and hard work in the making of this book.
Chaudhery Mustansar Hussain and Boris Kharisov
Emilio Morán and Rainer
Chapter
Rani Bushra, Anees Ahmed and Mohammad Shahadat
5.1
5.3
5.2.3 Adsorption of Pollutants by Nanoparticles
5.2.4 Adsorption of Pollutants by CNTs
5.2.5 Adsorption of Pollutants by Dendritic
Rohama Gill, Quratulain Nadeem and Mohamed Bououdina
6.1
6.2 Carbonaceous Nanomaterials as Nanoadsorbents
6.2.2
6.3
6.4
6.5
6.6 Clays as Nanoadsorbents
6.6.1 Nanoclays
6.6.2
6.6.3
6.6.4
6.7.1
6.7.2
6.7.3
6.8
S. Azzaza, R. Thinesh Kumar, J. Judith Vijaya and M. Bououdina 7.1
7.3
Chapter 8 Adsorption Selectivity of
Designed
Levan Chkhartishvili, Lina Sartinska and Tsiuri Ramishvili 8.1
Chapter 9
Víctor Manuel Jiménez-Pérez, Oxana V. Kharissova and Blanca M. Muñoz Flores 9.1
Section II: Sample Preparation and
Mostafa Khajeh, Kamran Dastafkan, Mousa Bohlooli and Mansour Ghaffari-Moghaddam
Krystyna Pyrzynska
Elizabeth Guihen
Chapter 14 Advanced Environmental Engineering Separation Processes, Environmental Analysis and Application of Nanotechnology: A Far-Reaching Review
Sukanchan Palit 14.1 Introduction
14.2 Vision of the Present Treatise
14.2.1 Purpose and Aim of the Present Study
14.3 Global Ecological Balance, Provision of Clean Drinking Water and the Progress of Human Civilization
14.3.1 Environmental Engineering Science: A New Beginning and Future Perspective
14.3.2 Water Process Engineering, Environmental Separation Processes and the Vision of Tomorrow
14.4 A Review of Important and Relevant Technologies for Wastewater Treatment and Oxidation Technologies: A Vision for the Future
14.4.1 The Vision of Scientific Endeavour in the Field of Advanced Oxidation Processes: A Deep Introspection
14.4.2 Use and Immense Importance of Selected Advanced Oxidation Processes for Wastewater Treatment
14.4.3 Wastewater Treatment by a Visionary Combination of Advanced Oxidation Processes and Conventional Biological Systems
14.4.4 Ozonation: The Next Generation Environmental Engineering Technique
14.4.5 Contribution of Membrane Separation Processes in the Advancement of Science
14.5 Advanced Oxidation Processes: Vision, Current Status and Visionary Prospects
14.5.1 A Review of Photochemical Processes in Wastewater Treatment
14.5.2 An Introspection into Treatment of Textile Wastewater by Advanced Oxidation Processes: A Critical Overview
14.6 Recent Scientific Endeavour in the Field of Non-Conventional Environmental Engineering Separation Processes
14.6.1 Recent Scientific Pursuits in the Field of Membrane Separation Processes and Other Environmental Engineering Separation Processes
14.6.2 Recent Scientific Endeavour in the Field of Ozonation of Industrial Wastewater
14.7 Milestones in the Research of Advanced Oxidation Processes
14.7.1 Milestones and Unparalleled Achievements in Environmental Engineering Separation Processes
14.8 Global Drinking Water Crisis and Application of Membrane Separation Processes
14.8.1 Industrial Wastewater Treatment and the Application of Novel Separation Processes: A Definitive Vision for the Future
14.8.2 Doctrine of Environmental Engineering Separation Processes and the World of Indomitable Challenges
14.9 Scientific Cognizance, Visionary Future of Environmental Pollution Control and Environmental Analysis
14.9.1 Visionary Environmental Analysis and the Progress of Science Ahead
14.10 Application of Nanotechnology in Environmental Engineering and the Vision for the Future
14.10.1 Nanofiltration, Application of Membrane Separation Processes and the Visionary Domain of Environmental Analysis
14.11 Fouling: Difficulties and Plausible Solutions
14.13 Future Perspectives of Application of Novel Separation Processes and the Visionary Frontier Ahead
14.13.1 Challenges, Difficulties and Barriers to Environmental Sustainability and Ecological Balance
Environmental Sustainability and the Future of Science and Technology
14.13.3 Challenges, Barriers and Vision in the Application of Environmental Separation Processes
14.14 Environmental Analysis and Its Application to Relevant Environmental Separation Processes
14.15 Future Targets, Future Vision and the March of Science and Engineering
14.15.1 A Deep Introspection and the Road Towards the Future
14.15.2 Challenges in Advanced Oxidation Processes and Membrane Separation Processes
14.15.3
Runcy Wilson, Jithin Joy, Gejo George and V. Anuraj
Section IV: Spectroscopic Techniques with Nanomaterials
Monica
Potara, Cosmin Farcau, Ioan Botiz and Simion Astilean
M. Umadevi and A. Milton Franklin Benial
23.2
25.2
25.6
25.7
25.4.2
27.3.1
Section VI: Nanomaterials for Water Treatment and Purification
Chapter
David D. J. Antia
28.3.3
28.4.4
Section VII: Various Important Aspects About Nanomaterials (Toxicity,
Ivan Pacheco and Cristina Buzea
29.1
29.2.1
29.2.6
Water Solubility–Dispersability- or Hydrophobicity–Hydrophilicity-Mediated
29.5.3
30.1
29.5.6
Section VIII: Monitoring and Analysis of Nanomaterials
Chapter 32 Fire and Explosion Risk Analysis for Nanomaterials
Hong-Chun Wu
32.1 Introduction
32.2 Explosion Characteristics of Nanopowders
32.2.1 The Minimum Ignition Energy for Microand Nano-Particles
32.2.2 Minimum Explosive Concentration, Maximum Explosion Pressure, and Maximum Rate of Pressure Rise for Microand Nano-Aluminum
32.2.3 Maximum Explosion Pressure and Maximum Rate of Pressure Rise for Particles on NanoAluminum
32.2.4 Minimum Ignition Temperature (MIT) of Titanium
32.2.5 Data for Nano Zn, Nano Cu, Carbon Nanotubes, and Poly(methyl methacrylate) (PMMA)
32.3 Risk of Nanometals Conveyed by Air
32.3.1 Nano Ti, Fe, and Al Conveyed by Air in a 20 Liter Explosion Ball Experiment
32.3.2 Risk of Old Oxygen Facility and Cylinder
32.3.3 Nano Ti and Fe Conveyed by Air in a
32.3.4 Study of the Relationship Between Air Velocity and Charge of Nanoparticles
32.3.5 Hypothesis of Nano-Metal Fire Caused by High-Speed Air Transport
Section IX: Future of Environmental Analysis
Chapter 33 Consequences of the Use of Nanomaterials for Environmental Analysis: Fate,
Section V
New Trends in Environmental Analysis (Magnetic NMs,
Published on 08 November 2016 on
Chapter 19
Magnetic Nanomaterials for Environmental Analysis
Chaudhery Mustansar hussaina
adepartment of Chemistry and environmental science, new Jersey institute of technology, newark, nJ 07102, usa
*e-mail: chaudhery.m.hussain@njit.edu
19.1 Introduction
Magnetic nanomaterials (MnMs) have widespread applications in biotechnology, biomedical, material science, engineering, and environmental areas. therefore, considerable attention has been given to their synthesis methods. MnMs as sorbents have been extensively exploited as materials of choice to separate biological cells and isolate proteins, enzymes or peptides. separation techniques with magnetic nanomaterials are usually gentle and nondestructive to analytes, and even large complexes that tend to be broken up in the process of traditional column chromatography may remain active. Furthermore, magnetic separation can be easily and directly used for raw samples with several simple steps. recently, different kinds of magnetic nanomaterials have been rapidly and extensively developed, and widely used in analytical techniques. MnMs are superparamagnetic so can attract a magnetic field, but retain no residual magnetism after the field is removed. therefore, it is easy to isolate MnMs stuck to analytes from a sample solution or complicated matrices by simply applying an external magnetic field and this requires no filtration or centrifugation. in this chapter, factors
RSC Detection Science Series No. 10
Advanced Environmental Analysis: Applications of Nanomaterials, Volume 2
Edited by Chaudhery Mustansar Hussain and Boris Kharisov
© The Royal Society of Chemistry 2017
Published by the Royal Society of Chemistry, www.rsc.org
influencing contaminant removal by magnetic nanoparticles are reviewed and to reduce the treatment cost, the feasibility of the reuse and recovery of magnetic nanoparticles is also discussed.1,2
Compared with conventional separation techniques, there is no need for packing of the column with the sorbent, since the phase separation can be quickly and easily accomplished by applying an external magnetic field. there are a few problems associated with particles at the nano range, i.e., their intrinsic instability, which tends to lead to formation of agglomerates. Moreover, uncovered metallic nanomaterials are chemically highly active and are easily oxidized in air, which results in loss of magnetism and dispersibility. the critical part is to develop shield approaches to chemically stabilize the isolated magnetic nanomaterials. Grafting or coating with an inorganic layer, like silica or carbon, or coating with organics, like surfactants and polymers, are a few shield approaches that have been utilized. in most of these approaches, the shielding shells not only stabilize the nMs but can also offer opportunity for additional functionalization. in summary, magnetic nanomaterials in environmental analysis are able to facilitate or accelerate many extraction and purification procedures and efficiently combine with the majority of other procedures used in environmental analysis.3,4
19.2 Properties and Format of Magnetic Nanomaterials
the properties of magnetic materials were identified early in the sixth century BC, but the first patent was filed by William Fullarton relating to the separation of iron minerals with a magnet in 1792. application for the separation and analysis of various biologically active compounds and cells using magnetic materials was started in the 1970s. since then, an increasing number of studies have focused on magnetic separation and analysis of biological samples using magnetic materials. Figure 19.1 shows the data of published articles on magnetic separation of proteins/peptides, nucleic acids, cells, and bioactive compounds and immobilization of enzymes from 2003 to 2013.5 there are two main ways of performing magnetic separation of analytes. in the first circumstance, no special modification of the target is needed when dealing with those exhibiting sufficient intrinsic magnetic moments involving some paramagnetic or ferromagnetic biomolecules or cells, such as ferritin, hemoglobin and deoxygenated erythrocytes (in plasma). in the second case, when coping with diamagnetic molecules and supramolecular structures, suitable magnetic modifications should be performed in order to attach magnetic labels to targets or immobilize targets to magnetic carriers or adsorbents. the linkage of magnetic labels to the targets is often mediated by affinity ligands or other types of interactions.5,6 in general, there are two modes for magnetic separation, i.e., direct or indirect (Figure 19.2).5 in the direct mode, magnetic affinity particles that possess appropriate affinity ligands and exhibit affinity toward the target
Another random document with no related content on Scribd:
