Organiki

Page 1

,

,

. MSc-MEd


Fehling

– CuSO4.5H2O 100ml NaOH


Fehling

1.

7g CuSO4.5H2O

2.

10g aOH

3.

100ml

( )

3,5g

100ml H2O ( ) A

B


;

Cu(II) .

,

Cu(OH)2. Cu(II) -

. Fehling

.

Hermann von Fehling (1812 - 1885).

.


Fehling

– Fehling Fehling (9g C6

12

6

0,5 100ml

2

)


Fehling

1. 2. 3.

2ml Fehling A 4ml

0,5

2ml Fehling


Tollens – NaOH 2M NH3 ) AgNO3 0,1M (1,7g AgNO3 100ml 2 )


Tollens 1.

2ml

2.

AgNO3

4-5

3.

3

: (Ag3N)

.


llens

– (9g C6

12

6

ollens 0,5 100ml 2 )


Tollens 1. 2. 3.

2ml 2ml

Tollens 0,5


– 10ml (2)

. CH3COOH .H2SO4


CH3CH2OH + CH3COOH 1. 2. 3. 4. 5.

CH3COOCH2CH3 + H2O 2ml

1ml .

2SO4

90 C

2ml


– Na2CO3 100ml


2 CH3COOH + a2CO3

2CH3COONa + CO2 + H2O

1.

(2

2.

3.

CO2 ,

4.

CO2

.

) Na2CO3


KMnO4

– (COONa)2 0,1M nO4 0,01M : 2ml (COONa)2 2ml nO4 1ml 2SO4


KMnO4

nO4


– 100ml


CH3CH2OH + Na 1. 2. 3.

4.

CH3CH2ONa + ½ H2 (

3-4

)


– 400ml 6 NaCl


1. 2. 3.

200ml 150-200ml

6M


1.

.

,

,

2000 ,

2. 3.

,

BBING GAMMON,

1994

,

4.

,

5.

,

, , 2005

6.

,

,


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