Research Inventy: International Journal Of Engineering And Science Issn: 2278-4721, Vol. 2, Issue 2 (January 2013), Pp 45-50 Www.Researchinventy.Com
Dielectric and Ac Conductivity Studies of Vanadium Pentaoxide Doped Polyaniline Composites Parinitha.M1 and A.Venkateshlu,2 1
2
Department Of Physics, CMJ University, Shillong, Meghalaya, India Department Of Physics, Govt. First Grade College, Bangalore, Karnataka, India
Abstract: Polyaniline/ V2 O5 composites at different weight percentages were synthesized by in situ polymerization method. The composites have been synthesized with various compositions (5, 10, 15, 20, and 25 wt %) of vanadium pentaoxide in PANI. From the Fourier transform infrared spectroscopy (FTIR) studies on polyaniline/ V2 O5 composites, the peak at 1122 cm-1 is considered to be measure of the degree of electron delocalization, 1487 cm-1 is C=C stretching of benzonoid ring, 1558 is C=N quinonoid stretching mode of vibration. The surface morphology of these composites was studied with scanning electron micrograph (SEM). The ac conductivity has been studied in the frequency range of 50 Hz to 5 MHz and it is found that 15 wt% shows high conductivity compare to pure polyaniline and other composites. The results obtained for these composites are of scientific and technological interest.
Key Words: Polyaniline; Vanadium pentaoxide; Composites; AC conductivity, Tangent loss I.
Introduction
Intrinsically conductive polymers have aroused a great interest among the researchers due to high mobility of the charge carriers, which also can be the excellent hosts for the trapping of metals and semiconducting nanoparticles as stabilizers or surface capping agents [1-3]. A mongst conductive polymers, polyaniline (PANI) has been widely studied owing to relative ease in preparation, good environmental stability and tunable conductivity, and showed its promising applications in many technologic fields, such as s ensors, electro magnetic interference shielding, electrostatic discharge, conducting materials and corrosion inhib itors, etc [4-7]. Incorporation of inorganic co mpounds into PANI poly mers will facilitate the combination of different features of inorganic and organic species, and the inorganic fillers in the nano-form are expected to modify the properties of the conducting polymers leading to the development of mu ltifunctional devices [8, 9]. A mong the modified properties, the enhanced conductivity was displayed due to the change in morphology of the conductive PANI in the hybrids [10, 11]. Inorganic V2 O5 has been attracted much attention as cathodes in rechargeable ion bat-teries, selective gas sensors such as ammonia because of their high surface area and re dox activity [12, 13]. One of the important aspects of the V2 O5 is its layered lamellar structure. The layered V2 O5 structures show intercalated nano-spaces which can be used as a reaction space of guest organic mono mers [14, 15]. Mono mers are incorporated into the V2 O5 spaces and simultaneously polymerized into polymers by redox reaction with V2 O5 layers [16, 17]. Although many studies have been conducted to form V2 O5 /polymer composite structures, controlling internal mo r-phology has still remained a challenge.In this paper author reports synthesis, characterization and ac conductivity of polyaniline / V2 O5 composites of different weight percentages at room temperature. The FTIR spectra of V2 O5 doped in polyaniline shows the characteristic peaks indicates the formation of co mposites. SEM image shows that the change in morphology helps in transport properties of these composites. Among all 15 wt% shows high conductivity and low d ielectric constant.
II.
Materials And Method
All Chemicals used were analytical reagent (AR) grade. The mono mer aniline was doubly distilled prior to use. Ammoniu m persulphate (APS) ((NH4 )2 S2 O8 ), Hydrochloric acid (HCl), and Vanadiu m pentaoxide (V2 O5 ) were p rocured fro m sig ma and were used as received.
III.
Synthesis Of Polyaniline
The synthesis was based on mixing aqueous solutions of aniline hydrochloride and ammoniu m peroxydisulphate at room temperature, fo llowed by the separation of polyaniline hydrochloride precipitate by filtration and drying. Aniline hydrochloride (equi mo lar volu mes of aniline and hydrochloric acid) was dissolved in distilled water in a volumetric flask to 100 mL of solution. Ammoniu m pero xydisulfate (0.25M ) was dissolved in water also to 100 mL of solution. Both solutions were kept for 1 hour at room temperat ure (25째C), then mixed in a beaker, stirred with a mechanical stirrer, and left at rest to polymerize. Next day, the PA NI
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