Tan Print's Chemistry for NTA CUET (UG) 2022 by Taxmann

þśƓǗ !¯,© ϸ¯CϹ μκμμ Ǟâǒ

R E T I N L R E A D %N E %P OE D -N NIN O ONI I AT T A A Z CSI UAN D A %$G R F2O O Y(G R N T I S T T I S N N E E I T -MR E YPI O BL M DE E EVR HEP S$D I L E B E N ACI T R A S UT E S SOU S I E S !2L F 4 E .NS AD YMN C A NUT E(N G F A !O I L G E NYR R I F T T L S S E I E N S 4I LS A U NSO OA M I T O A NN .WO EOT HNU 4KA About NTA

CK GI E NM I E T ES C O UDT DAS NCT OAN CEE FH TD O U R YO T S T F I L Y OR IST B T 5YN I S TU N#I O NO PSUC SETE I R T E IO H R S T ERPS HEPS V O T O I HN R WC T 5OA I WLD A NS DR I T EN 5 W# T S E UEL R#G S T E E NI N T EHIS S T I L NL AR EA E EV ERD I BO IN SFV S A O5 T RL HS P A E R T LT !E L I 4C N WE .N A 4# YR %E CT H NN5T EE#F GE O !T Y GA N NU A D I T A N S R I E G 4R N LE I O A D S N NNO S O5 I I I S M T ES A D EA HS .T CUET – Common University Entrance Test

S N N T O O N I I S S AS S R II I P MM SD D A A EAR HRO 4OF F N E S I5 DT OE # L -L U S E 4"T I NI "O S #I R T E TAV S I MN E R 4O 5 DF L NA E) R S T A EN "H E T# RO E T TD U E RR PE I FS ME E ORD #YE S AHE NM I T FM D ETOM S T SA E C R UTEG DEMO NHMR OT 0 CRAE R O G EF T A BROU LARD L IEPA E WPT R PAG 'AUE R ODD 5T A E N R 4R G 5 I R %S E E 5ED H #DN T O EO5T HHON 4WT I Mode of Examination

S N O I T C E 3 G N I W O L L O F E H T F O T S I S N O C L L I W n ' 5 4 % 5 # Examination Structure for CUET (UG):

Section II

Section III

DS! EU4 S AB. A BL LNE T SYOI NS 1SE B #NV E IW -OG

S E T S U H NCC T NCI lE A I A I J C -EME B ROP U O$ 33 F

NRD AOE CFS S T AN D X EEBO T I S T TU 1S U E PE#U NB -1 )

CUET(UG) Domain Subject (Section II) Paper Pattern

S N O D I T E S T E F U PO M E 1B ET T U T OA O T

SES I SN H OI CT OA lRH I E ME C EDCOL B PNY$A SUA C S S M I E D L I NE P T E P I I RT A S E A A R MF F D EE I OO V I $ DFHN T G N NAOY5 I B C M E Y EB!UDT R I S MES R A T N IS I R C OX EE E R V TAEI JI D E C B HU EMSN 5 4S 3AA

Six (06)

I-5

Section II Domain

T S E 4 L A R E N E ' Section IB

S T C E J B U 3 C I F I C E P S N I A M O $

S E G A U G N A , Section IA

S E G A U G N A ,

! 8 % ' 5 4 % 5 # 4 5 / " !

I-6

Type of Questions in Domain Subject (Section II) Paper Pattern (analysed from Sample Paper provided by NTA)

S N O I T S E U 1 G N I N O S A E 2 N O I T R E S S ! I

S 1 #

S N O I T S E U 1 E N O L A D N A T 3

S N O I T S E U 1 D E S A B T N E M E T A T 3 I I

S 1 #

S N O I T S E U 1 D E S A B E L B A 4 I

S N O I T S E U 1 G N I W O L L O F E H T H C T A I I

S 1 #

S N O I T S E U 1 D E S A " E S A # I

H C A E S 1 # H T I W S 1

S N O I T S E U 1 D E S A " T X E 4 I I

200 F O T U O D E T P M E T T A E B O T S N O I T S E U 1

40 Total

Total Marks Number of MCQs Typology of MCQs

ƴŉŉâþƓǖ !¯,© ϸ¯CϹ μκμμ Note:

There will be one Question Paper which will have 50 questions out of which 40 questions need to be attempted.

CHEMISTRY - 306

GL TON S LR N W E I O ET CT K L A C C N T VI AIU N L OL PU D CE N L CL CO CT E I I C ICB N S ONTUL I U C I N A T RAUAE A F N E L DOIM U L CIT FR L S YYE O ER I L C O S O YT A NI TR C MTE OU N N EDUED S H F M N E R T O O CL E EN DI C R PN OE O S F I AM S T E GDAM"S L O LU NI T O S I E C A D E S P L I N T A FR Y E I T NCOE B I L RP S L TA E E OD N BR T C ES N I MPA R T YT E R C U A F I C L F T I LNE D DA D S N N NN DGA NA OI A OSI S SOMR V DUN O O EH EYDT S A A L PMCNU BRINAS D E LN I SOEC A I DME C I I F I A D L R F R O T HE N SST C A D G E FI D L S N L O E R NI O O SAK NC S T LCT C OI A A C I U L T NPE L D A A FN O T CE S E I I S DDO F N I I M C S ELTI O S N D M S M I A O NI L E NP # AD S I UNIT I: SOLID STATE

L LFCA I O O T M SGO R NMO EI HR S N T EO B SW DOTA N I L I S U EO E QV I I T IPR L T G E NA NP L I I SEZ O DRE R E I EP L HR O E STFV FSFT I O O E A N SI G T NR OL I I OE L I O PSC S T OE U RR L G O PPN SE EI DS FV O I U T 0 NA S OG" E I I S LF T L S A O A R COM T N N ESO CNIR T A O NI A L U V OT CUECR L L E O FO L T O SEO C NDWMA I OO AFF L I L F S F S SOO S E TN( S L R D U OT PI OI XU TN EQAAA N6 I2I SL NN MS OIE R R S S I E UT T A E SE U S M S L A DR E O SGR A FFPEL O R O U R UC SYUS T E E OS I L L PI P EO YB AR 4UV PM UNIT II: SOLUTIONS

DA DS VN LNF I L T AE AO C USCN& I CO DS I IYN NL T % OO A A CR VUD L TA QN RC A E'EA L L TE O E S G D M NN N R A DWAE H NA . S C L A,L SE L Y C A C G I H I F R I CCT E N C S I N T EU E Y T E PA L O SR S LOPB R SH T B EI NOC D' O E + L I O T E R N U T N L E C O O E L E SIL T L W E E CAC T R I E T DB T YR N Y L ERAN O CDDO RN NT T I C O A A A EC T ES L L E E HD I 2 L NT L I Y E I S R CL EWA L CYT AE NTN AIEFC V L T I MOA T C N UCE&CO I L DUE -MI ND S EO ONS%H R COI R CSRCO O Y O S F L T C T NO O A OS L RU N S I T L O T N C L C MIE E T O AI L C A U T E EA CE L CL R I FC IO PU XR OASAPF DAL DVW L ASE EYA EI TC TLL 2I

UNIT III: ELECTROCHEMISTRY

WD N N AA OL I T EO C ATR EAE R R Z R FN O O O F I SC T Y E L T A N A EO R R G E NAI F F I L T O C F EYA L F T F I H R A A D L SU N R OCA T E C L S AON F MI O T SDA UNU OAQ ERE NE E AD T T RA N AOR T D T S E S NY T I A LR DAG NTE A AC T N E I GET ARN U R T A E A T VR S AE N PO NMC OEE I TT T C A ANR EOC I R I T F A I AR C TE FN O EP ECS T ND A ON 2C A

UNIT IV: CHEMICAL KINETICS

I-7

L A C I T A M E H T A M O N A E D I Y R A T N E M E L E N YO R I OT EA HU T Q NE OS I U S I I L N L E O H CR FR O ! TY P EG CR NE ON CE N O SI NT OA I V T I C T AC E! R RT E N DE RM OT TA S E R R I F T FS SE E N MNOO S E A YPSS I E GZ SI L T U FNUR S E E O M P D E NY O OTNR I A N I V P T I O P T S I S RC T DD A OEI I L SLO O U DEL L LL G ASO O A GDCCO C NN R S A I A N T S L Y C O I U T I S EI T C F E V U F E I R L L T A O O O C H SM SA R P EOO O S U T RT R UR C C O T AE C AE F NML NE E E N EDT OGW NN I O T RTAE P REE M OTBRE A E SH NLV I U OC MDI O T E ENC M L HAN O C N I M S T A II DUST N NOIL D ANEUW O NEHMR G OOTI C" I B T ME P ROTOT C A H OHS T ES PF S I F N S S ILOEO A Y Y S I L S L HYDLA I L L CD 0A O U I L TL L I NM A O H YE CC P4 O F S SYS O DI S L I S DE L Y I O L S O P SA N L T L Y OO NA T I OCS C CR I E T Y P L P O O RC T C EM L E U NN OI I M T C U UL DA EF R O NN OI O I T T A C A DR I X T X OE NF OO I T S A E R L T P N I C EN CI NR OP CD N A E C N E R R U C C O G N I N I F E R N DO NR AI D DN OA H T C E N I MZ

S CFD NSI OI EROI I T S C T T I DA A R N E N DP O I DUX X ONO O OR APD EPAMN C I A O NNN C EOO I L R # T MS R A UR M0 MR CA CP A O L OE FF# C 0 NROI OPSP S I E T O E I A N RD T T R R I L UEEOA GGPLH L O I A O RR F T N S E I P ON UN I C DOH CS NRP E I AOS I N H T O OR NP RE H O S T P I OP C T F EOA HO R L E PR0S A E NLP I Y OAEL T C R I R N I T PO E C P UM EO DENR E R OHG UP RCO T T D DRCN N U T N I I RA L AN T A N S LF R O A E NCONI T I S E Y A ES L D GR 'YN N OAO H R P PUT EA I O R N NP E PD I I SMFS DOOU Y S NCE R OA ES D RT R ION E T X HE S O P SU M S E DO T DI E A L HE NC T AAP S

L SRFA O E I E R T S P T A Y DS O T L NU S RU N DO NPO NS ONP I I E O T M R D I A TO U I DA C T I C R C X A AU S OP C R I T EMR S NR RU OPO HR I F PU T N L A CU H EI R P UGPSL GYO U E R X I F T DS OO N I I F L OD LXO O C A I S S D D CE R I I I T C N URA R OE HUO H RP PP T X OLL C O U ERUS 3 L P S E FE LE A OS N NC OIOSU E I Z D S TMO N C E U A UH S D DCE S N ODI DA E I RN T X T R S AO N E E I L I F P A T LC O O R A R INEP R S P E O OE NYT I RR EHA PU 'PC I NF T NC I I O SS A I DST F A U A NL R EC N A R A P T S EM EER F CSP O NU EDR S R NUS R E HC UAP SL CE O CI UR OT SP

SAS E D PN T EU A R T S PO P NS ONM I EO T GC A ON DL I AE X OHG O FL NOA SH OD I R T NT E A R UN UOI G P I D F M I N C O OC A C C I CSR E I I O N T L R OE H RP C T O C OR ER D L PY E L H A NC D OI I MN T A C Y E UEN L DHI N OCR O RDO S N T L E N AHR I C L U LA FT A CO C R I S S U E E R NYS T EHU S 'PD S N I N N SAE DS G NI O E L ET A R RH T E EPF COO NRS EPI D R C N R UOA I O CT X CA OR O

S D N E R T E C N E R R U C C O N O I T A R U G I F N O C C I N O R T C E L E S NE OS I T U C US E DI OR T RE T N P I O LR A P R E L A NC EI 'M E H C D N A L A C I S Y H P N I

S C Y N NL I E T I L A AA R T L R R E T T E D P FEO P N O M O R A S PR C P Y I C S T T D I L I S T A N V I Y T R I A L T E E A C N T MA T A C O I E A C T N R R A O A L R R I A HT A U I C CS OP I DNLE M NAOR C E 0 R AT H I E C IN CWD O I S NOAT E ERRA T R TCM A R S I T UR R N S I CF OO F N CE I O Y OH I SO T NTEL A L T OFA A D O I I T T S X S A S S O R E E ND I UT C ON U N GE R N I T O I OE F A I P P U T N DM A Q OOI R E CRXO US CPOC G N I N L I O YA N I F C N OSPI T L I RD OS T T T CI NAS C H EETR CD E L R I N N T E T N N / O A LEI NA N R N N S ORO T I O TEIE- CT I T I E N T C + L A R C UEZ E E I A D DGN P R N OSO T OA RA L N R I T P O T N RC / C E I E I L T T MC D R I A E R O N A N # N E ORG + NI A A A EI THM F H 'S O C T

Lanthanoids -

' 5 4 % 5 # 3 5 " ! , , 9 3

I-8

UNIT V: SURFACE CHEMISTRY

Adsorption

UNIT VI: GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF ELEMENTS

Principles and methods of extraction

UNIT VII: p-BLOCK ELEMENTS

Group 15 elements:

Group 16 elements:

Group 17 elements:

Group 18 elements:

UNIT VIII: d AND f BLOCK ELEMENTS

' 5 4 % 5 # 3 5 " ! , , 9 3

L FA C S I DOC T E I EG NNC U O GO N L AP A O T I MM R B ROOD UCPN ONMA L I O O S I CT OA L AE RN RT E BIEE D T MRSM F UODO O N NC N NRAO L OAA I I E T R T L C A U C A T NU R C I T N D UX ROR E ONT S OO S C I M S M S Y S L DFI A NOR N AEEA GR M U I T L E O A V SI NL I C T ON A I T T E4L I C UM&A DO#U ON 4Q R# "N T N I !6 ) 0YS 5R D )ON EU SH E O T PS P A M HR SEO DNC NRN AEO I S7T E A I GN S T NI R M I E DE PDRT ONOS ROOY PBCS S E I T R E P O R P L A C I M E H C D N A L A C I S Y HN PO I T DA T NO OR BL A 8C I T #P F/ O S EN R O UI T T A C NA E ER R N UO T I T A L U C T I NT ES B MU OS .F O M S I N A H C E M

N E G O L A H F O E C N E U L F N I E V I T C E R I D S N O I T C A E R N O I T U T I T Y S L BN UO SS DD NN OU BO P 8M #O FC O D E ET R U UT T I A T S .B U S O N O M R O F O R O L H C A R T E T E N A H T E M O R O L H C I R T E N A H T E M O R O L H C I D F O 4 S$ T C E$ F F S E N LO A E T R N EF MM NR O OF RO I V D NO EI DE NN AA H ST E E S 5M

SS E L I O T R HL E OO PC N OL RAA PYH T LRE A A I CR TD I N MEA ETL HDO CNN A DAH NYT ARE A M LD A N O CO T I S C E Y EC HS N P E YR NRE F OAE M I T R IL A R R PI A A C PFE EOP R NS PO IH FT T O AI CW SI DF I S T ON E HE S T E DU MIN O YI EL T R N A UO R T D S A Y L L O C H NHE EOD CF ML OAO .YM R S A I N MA IH R PC FE O M S E I T R E P O R PS L LO A N CE I MH EP HF CO S DE NS AU LS A N CO I S I T Y C HA PE R NN OO I I T T A U R T A I T PS EB R U PS FC O I L I SH DP OO HR T T E C E ML E EL R O UN T E A H L C P NF EO ME OR U .T A N C I D I C A

F NO OY I T T I A V R I A T PC EA R E PR FE O SH DT ON O HI T T E I D MD PA UC I OI L RH G LP Y O NE L OC BU RN A CF FO O EM R S I UN T A A NH C EE R UMS T E A SS L E C U I NT R EE S E MP D OOY .RH P E LD A L CA I N MI EN HE CG DO NR AD LY A H CA I S H Y P HL PA

Carboxylic Acids:

T X E T N O C N I S E C A L P T N A V E L E R T A D E N O I T N E M E B L L I W

C I N A G R O C I T E H T N Y S N I E C N A T R O P M I D N A S N O I T C A E R L A C I M E H C N O I T A R A P E R 0

Y R T S I M E H C

S CE UD RR I F A DH NC AC EA S S OY L CO UP L G E ES DO I R T L A HA CM C AE S S OT O NC OA ML E S SO E R S OC T U E S K DS E ND E AI C R N SA E A S T HR OC O DC L AP A S M OI NG OL I I N T O E A G CNO I O F C I I S T Y S A L A G R L UE # G S I F O N L U OL CL E ,C $H C R EA S T O S T

Carbohydrates -

D N A L A C I S Y H P N O I T A R A P E R P F O S D O H T E M

D N AS E LN A CI I M S Y A HY PR A NT I OR I E T T A R D A PN EA R Y PR FA O D SN DO OC E HS T E Y MR A EM R I UR T P C UF RO T N S O I NT OA I C T I A F I CT I N F I E S D S I A L S C E S EU R US T A E L I T C R NE EP MO R OP .L A C I M E H C

Cyanides and Isocyanides -

E R U T A N C I D I C A

E R U T A L C S NE ES MU OS .E I T R E P O R P L A C I M E H C

Diazonium salts:

S E S U S E I T R E P O R P L A C I M E H C D N A L A C I S Y H P N O I T A R A P E R P F O S D O H T E M E R U T A L C N E M O . Ethers:

S D I O N A H T N A L H T I W N O S I R A P M O C D N A S E T A T S N O I T A D I X O N O I T A R U G I F N O C C I N O R T C E L % Actinoids -

I-9

UNIT IX: COORDINATION COMPOUNDS

Coordination compounds:

UNIT X: HALOALKANES AND HALOARENES

Haloalkanes:

Haloarenes:

UNIT XI: ALCOHOLS, PHENOLS, AND ETHERS

Alcohols:

Phenols:

UNIT XII: ALDEHYDES, KETONES, AND CARBOXYLIC ACIDS

Aldehydes and Ketones:

UNIT XIII: ORGANIC COMPOUNDS CONTAINING NITROGEN

Amines:

UNIT XIV: BIOMOLECULES

' 5 4 % 5 # 3 5 " ! , , 9 3

I-10

E SR NU I T E C T O U RR PS T SY E R DA I N T R P E ET PA YU L Q O PD DN NA OE R BU S E ETM DCY U I T RZ T P N ESE P Y R S A SI N I DT E I RT C E O AT R OEP NRF I U O T MC N AU O I RT AT A FSR O YU R T AA A ED N DN E I OD YC R EY S A L T N N EO ER A MUE T EC D L U I % R E T V S I T YA R T A I L MA IU R Q P Proteins -

Nucleic Acids:

! . 2 D N A ! . $ Vitamins -

S N O I T C N U F D N A N O I T A C I F I S S A L #

Hormones -Elementary idea (excluding structure).

AE N S S NER E E H DTM Y NL Y OO L CP O DEP NI KE L AL B NI CA OT D I EA T I H R D T G DN E AYD S O ND I ON B I T AN A ZLO A I R N R U E D T MA N YNA L E O S L PR B FEA O MD SYA DL R OOG HPE T TD E N O MAI T " R CO I R T PE E HMB T IB N EU YM R S DOT E N3L I A E LNK O A I A R T UA B T Z A I S R R .E E T MS YE L Y O L PO OP CN O NL OY I N T UNIT XV: POLYMERS

N A S T N A T C E F S N E I S N I I D M SA C T I S T I P H I ET S N I T A N AS D SC I R E A Z T I N L I A U QS C NI AT R O T I B ST I C N I S A E GS L G A U NR AD Y ST E I L NT I I R C I E D F I ET N MA NS I L SI A L A B CO I R MC I EM HI #T S T N E G A G N I N E T E E W S L A I C I F I T R A S E V I T A V R E S E R P

elementary idea

D O O F N I S L A C I M E H #

N O I T C A G N I S N A E L C S T N E G R E T E D D N A S P A O S S T N E G A G N I S N A E L # of antioxidants.

Classification -

UNIT XVI: CHEMISTRY IN EVERYDAY LIFE

!śŒƌĊŒƌǖ

% ' ! 0

About CUET (UG) 2022 Exam

I-5 Syllabus CUET (UG) 2022

I-7 1.1 S E D I L A ( L Y R ! S E D I L A ( L Y K L ! Chapter 1

2.1 R E H T % D N A L O N E H 0 L O H O C L ! Chapter 2

3.1 S E N O T E + D N A S E D Y H E D L ! Chapter 3

Chapter 5

D N U O P M O # G N I N I A T N O # N E G O R T I .

5.1

Chapter 6

S E L U C E L O M O I "

6.1

Chapter 7

Y R T S I M E H C O R T C E L %

7.1

Chapter 8

S D N U O P M O # N O I T A N I D R O O #

8.1

Chapter 9

E T A T 3 D I L O 3 E H 4

9.1

Chapter 10

N O I T U L O 3 D I U Q I , E H 4

10.1

Chapter 11

K C O L " F D N A D

11.1

I-11

4.1 S E V I T A V I R E $ S T I D N A D I C ! C I L Y X O B R A # Chapter 4

3 4 . % 4 . / #

I-12

% ' ! 0

S C I T E N I + L A C I M E H #

Chapter 12

12.1

S R E M Y L O 0

Chapter 13

13.1

S T N E M E L % K C O L " P

Chapter 14

14.1

Y R T S I M E H # E C A F R U 3

Chapter 15

15.1

Y G R U L L A T E E V I T C A R T X %

Chapter 16

16.1

Mock Test-1

M.1

Mock Test-2

M.7

Mock Test-3

M.13

Mock Test-4

M.19

Mock Test-5

M.26

Biomolecules

A QUICK REVIEW CARBOHYDRATE

(i) alcohol

Y B D E R A P E R P S I T I Y L L A I C R E M M O C E L I H W

E S O R C U S F O S I S Y L O R D Y H E H T H YC BR A DT ES R F A O PS EI R S PY L SO I R ED S OY CH UE L H 'T

D-(+) – Glucose

(ii) dil.HCl,50 C C12 H12 O11 → C6 H12 O6

Sucrose

heat for 2hrs.

Glucose (insoluble in alcohol)

C6 H12 O6 Fructose (soluble in alcohol)

dil.H → nC6 H12 O6 (C6 H10 O5 )n  heat +

Starch

Glucose

E C N A T S B U S E N I L L A T S Y R C E T I H W A S I E S O C U L ' E S O R T X E D D E L L A C O S L A E C N E H

E H T F O N O I T U L O S S U O E U Q A N I N O I T A T O R C I F I C E P S N I E G N A H C N O I T A T O R A T U MD SN WU OO HP SM O TC )

Y R O T A T O R O R T X E D S I T )

L O H O C L A N I E L B U L O S Y L G N I R A P S R E T A W N I E L B U L O 3

Chemical properties.

9 2 4 3 ) % ( #

6.2

COONa CHO COONH 4 | | | Fehling 's solution Tollens 'reagent Cu 2 O ↓ + ( CHOH )4 ← → ( CHOH )4  → ( CHOH )4 + 2Ag ↓ Cu ( OH )2 + NaOH  Ag ( NH3 )  OH 2  | | | CH 2 OH CH 2 OH CH 2 OH (+ ) − Glu cos e

Re d ppt.

Silver mirror

COOH COOH CHO | | | ( CHOH )4 CHOH CHOH ( )4 ( )4 Conc.HNO3 Br Water iii  → | ← | (mild oxidising agent ) | ( strong oxi.agent ) COOH CH 2 OH CH 2 OH Glucaric acid Gluconic acid (+ ) − Glu cos e (Saccharic acid) 2

CH 3 CH 2 OH CHO | | | (CH 2 )4 CHOH ( )4 ( CHOH )4 | NaBH 4 ,H 2 / Ni,or P / HI iv  → | ←  | CH 3 Na ( Hg ) + water heat CH 2 OH CH 2 OH n − Hexane Glucitol (+ ) − Glu cos e (indicates presence of (Sorbitol) a straight chain of C's)

HCOOH + 5HIO 4 4HCOOH ←  + CH 2 O

CHO CH = NNHC6 H 5 | | ( CHOH )4 CHOH )4 ( C6 H5 NHNH 2  → | | (1mole ) CH 2 OH CH 2 OH ( + ) − Glu cos e Glucose phenylhydrazone

Reaction of carbohydrates with phenylhydrazine. CHO CH = NNHC6 H 5 CH = NNHC6 H 5 | | | C6 H5 NHNH 2 C6 H5 NHNH 2 → CHOH  → CO + C6 H 5 NH 2 + NH 3 CHOH  #

(1st mole )

CH = NNHC6 H 5 | CO #

( 2nd mole )

 → C6 H5 NHNH 2

( 3rd mole )

# CH = NNHC6 H 5

→ | ( −2C6 H5 NHNH 2 )

CO # Osone

L Y N O B R A C I D M R O F O T D E V O M E R E B N A C E N O Z A S O F O S E U D I S E R S E EN NO I Z S AO R DS YA HN L W Y N EO HN PK S ED HN T U FO O P HM T O O "C

| C = NNHC6 H 5 # Osazone

CHO H+

3 % , 5 # % , / / ) "

Y L N O S E V L O V N I N O I T A M R O F E N O Z A S O S D N U O P M O C E N I L L A T S Y R C D E R U O L O C W O L L E Y E R A S E N O Z A S /

S AE FS O O X SE E H S OS T U E KH 4 N I E L U C E L O M E H T F O DT NS AE SR E E S H OT DF L O A N NO I I T A (R /U G (I F #N /O (C #E H T E G I N ST I MC OF E T F A A NT OU BO RH A T CI OW WD TN TU S O R P I F M EO HC T

P I C E R P D E R ! N O I T U L O S S G N I L H E & H T I W D E M R A W S I D EE S OM CR UO L F 'S I TE S D E I T X NO OS I U T O U L R O P SU SC G F NO I LE H T A ET &I

A S E V I G E N I Z A R D Y H L Y N E H P F O S S E C X E H T I W G N I T A E H N O ED S N OU CO UP L 'M O NC OE I N T I A L L MA T RS OY F ER NC OW ZO AL L S E /Y

D A R G NM OO I R T F A S T E O S RA CE I R F I C C EN PI SD SN T A I E S E O I C NU L OG I T A T F O RO A E T S U A MC SN WI O H S EO S OT E S C O U C L U G L F O MG NO OR F I F O T SE U E L S S O SAA SEC URN C I OE ED UY QL L AA O !UT

E R A H C I H W A L U M R O F N O I T C E J O R P H T R O W A ( Y B N W O H S O S L A E R A E S O C U L G $ F O S M RW OO F L OE WB TN E EV HI 4G

β -D-glucose glucose (β -D(+) glucopyranose)

α-D-glucose (α -D(+) glucopyranose)

H OH

CH2OH

E D

Same osazone 3C6 H5NHNH2 H OH OH

C I F I C E P S H T I W E S O C U L G N O I T A T DO NR AC I F C I SE MP RS OH F T I CW I R E E S MO OC SU I L O EG R E S T A S E OR WE TH NW I S T S I X E EN S O OT I CA UT L O 'R Structure of Glucose :

E S O C U L G G E E N O Z A S O E M A S M R O F L L I W

D E ES MO RC A U L WG SS I EM T R A I F R T N I O N C RS E L VA L L I S W LR A E CN I N N OI ME H MT AN DO NR AO R ER S OI CM R UE L G V L FS I O F EO R UE T C X N I A MR A !E P TP S E ! T RE OB RU R T I T MS E RT E VA L I N 3 I

C G I L N O I R H T O E C L L D O A EI E FT V T O AAA R R OT FD WNO Y TENH RCO O ONI B TR POA OCM A RN C DO RA !IOF T F U L EO S H E O E T S4C A N E E R DSES YOBE HCUR T U OL TP BG S E RFT E H A COET R,HS OMTM F FI R T O F S OSN E T E T O DC LDI A E S R DSD E I NDEU H EAT Q GI SGL I AL N O OO SH L I W A T SH T I YF H L O 4PL AUN TNFO E S I R T E A C F T SOCN U NDJ H E O CI DE S T I H D L U AT O L O T SA -S I Tests of glucose :

E i

iii

D N A

N O N O I T A R UE GS I O F T N C OU CR RF A D L N I MA IE S S GO NN I N V AA HM

H 2SO 4

Fructose Mannose Glucose

CH2 OH CH2 OH CH2 OH

CO HO H ; H H H OH OH HO HO H ; H OH H OH OH H HO H H

CH2 OH CHO CHO

C3 ,C4

6.3

CH 2 OHCO −

9 2 4 3 ) % ( #

6.4

S E D I R A H C C A S O N O M O W T S I S Y L O R D Y H N O D L E I Y S E D I R A H C C A S I D E H 4

Disaccharides:

H2O C12 H 22 O11  → C6 H12 O6 + C6 H12 O6 +

N O T A T O R A T T U N ME G WA OE HR SS TG O N NI SH L E OE D& TR U O BS YN R OL E T L A O T 4 O RE OC RU T X D EE DR ST I O T ) N S E O D /T I S (A R #A G RU A S GG UN SI EC NU AD CE RR ON O EN S O RA C S I UT 3) F O D E S O P M O C S I T )

E YS D BO N A RC OU T I L DG N I U C A E L S A O $ R C E F U NO L I G S ME E L H AU T C HE F T O I L WO GM # N L I A N L I U E O Q E BE W YF T BO E B EE S R E O U G RT A C X K UI N SM I L F A O C I S SE D I I S C S Y O U L O C D RO Y L DR G Y HP E ES HO 4R Y C BT U DI S EN R NU O I E O S E E J O S S T EC A O T R T R U A C E R U SF VR T NF I E I N H UT E F M$ EO S Y E ZD H NN 4# EA

H C12 H 22 O11 + H 2 O  → C6 H12 O6 + C6 H12 O6 Sucrose D − Glu cos e D − Fructose (This mixtureis laevorotatory)

T I N U E S O N A R U F O T C U R F $ A D N A T I N U E S O N A R Y P O C U L G $

Fructose Glucose

sucrose

H2O Lactose  → Glucose + Galactose + H

H2O Maltose  → Glucose + Glucose + H

D E

Inversion of cane-sugar

3 % , 5 # % , / / ) "

6.5

S EI HE T S DO NC T AU RR A GF U S F$ O D NS AA D EE S OM CA UN L G S I S A N O D I S E$R MFE O V RS E N E T I I T SI E I T H N T EA S S OUG RQN C I R R UA B SL T FOA O MH SLT I AE S U Y L QM O Y REZ DGN YNE I HV E FA O HH SE4 S R E U CT OX RI PM ED HE T S NY I LD SOE R UD L L HY A 4HC inversion

invert sugar.

invertase.

Reducing and non-reducing sugars : H C R A T 3 E S O R C U 3

Non-reducing sugars

E S O T C U R & $ E S O C U L ' $

Reducing sugars

E S O L U L L E # N E G O C Y L '

E S O T C A , E S O T L A -

A H T O B S N I A T N O C T A H T E L U C E L O M C I N A GP R U OO R LG A NE ON I I T C M N UA FN I A B S AA SL L I E DW I C S AA O N( I M/ A/ N# !P U O SR DG I C L AY X OO NB I MR !A C

Amino Acids

S EI HS T D OI T C TA N O EN CI AM J D AA M OE T H A T NF OO BE RR A U CT C EU HR T T S NL OA R DE EN T A E CG OE L H S4 I P U OM RO G T EA NN I O MB AR EA HC T DE I H C T A OPS NU A I OD MR E AGT LN Y E XS OE NB R AR P AE NC R )

− NH 2

Carboxyl group H R-C-COOH NH2 ← Amine group α-Carbon atom D

S D I C A O L A H n

F O N O I T A N I M !

Methods of Preparation of D–Amino Acids

Cl − CH 2 COOH + 2NH 3 → H 2 NCH 2 COOH + NH 4 Cl α − Chloro acetic acid Glycine

S I S E H T N Y S E D I M I L A H T H P L E I R B A '

CH 3CHCOOH + 2NH 3 → CH 3CHCOOH + NH 4 Cl | | Br NH 2 α − Bromo propionic acid α − Aminopropionic acid (Alanine) CO CO

NK + ClCH2COOC 2H5 Chloro ethyl acetate

Pot.phthalimide

COOH COOH Phthaclic Phthalic acid

-KCl

CO CO

NCH2COOC 2H5

+ CH2NH2COOH+C 2H5OH Glycine Glycine

2H2O HCl

9 2 4 3 ) % ( #

6.6

S I S E H T N Y S P O O N +

iii

NH3 H 2 / Pd → CH 3C − COOH  → CH 3 − CH − COOH CH 3COCOOH 

Pyruvic acid

or Na / C2 H5 OH

|| NH

S I S E H T N Y S R E K C E R T 3

| NH 2 Alanine

H H H H | | | | NH3 H2O HCN R − C = O  → R − C − OH  → R − C − NH 2  → R − C − NH 2 + Aldehyde S E I T R E P O R 0

| COOH α − Amino acid

E V I T C A Y L L A C I T P O E R A S D I C A O N I M A

| CN Aminonitrile

SN I O PI UR OE RT T G I (W /: /A #D E nL DL NA AC M CR I S O A F BC I SN I O PI UL OA RN G R E T (N .I N A EN HI T S T TI S N X I O E PT CIN I N R O OI T I C TR EU L A L E L OOO SSI P I L A D DR S NT AUA NEN N ON W I O RIN E C K T I T D I O I WC S L :A A

E H T L L A E N I C Y L G T P E C X %

| CN Cyanohydrin

R |

A H T O B S N I A T N O C D N A L A R T U E N Y L L A C I R T C E L E L L A R E V O T U B D E G R A HE CG R RA A H L C O PE I V D I T SA I G NE ON I RD E N T A T I E WV :T I I ES HO 4P

In water − CH − COO + H → H N − CH − COO H 2 NCHCOOH  → H2 N 3 Zwitter ion α − Amino acid (Dipolarion)

H O H O H O | || | || | || + H+ OH − → H 3 N − C − C − OH ← H 3 N − C − C − O −  H 2 N − C − C − O− − H2O | | | (Protonre moved) R R R +

Zwitter ion ( I) Neutralform

High pH (Basicsoln.) Negative form (III) (Anion)

SS DG RI N A H WT OE T E ER T H A T R G G I N MI LW L I O WL L O TF I DM L E U I F I D CE I R T M C EE L H E NT AF NO I D( EP CE AH L T P SN I O DG I C N AI D ON NE I MP AE F$ O E MD O RR OT F DC E L EE S I E N N T OS E I I P NOP APA NPH EOY HEA HM 7T

Low pH (Acidicso ln.) Positive form (II) (Cation)

S A T S I X E ; E D O H T A C S D R A W O T S E V O M N O I E V I T I S O P E H T

( P W O= L ) ) N E OR I T U U T L C O U SR T CS I D N I C O AT I A NC )

3 % , 5 # % , / / ) "

SS DI RD A L E WI OF T C I ER T T A C R E G L I E MN OA T YN CI ND EE C DA NL EP T ON NE SH WW O HM SI U DR I B C I AL I U OQ NE I ME AT H ES HT T S HI X CE I H D T WN N I TAO A SP (EC I PDR O T RC ET T E CL A I EE D L O EES MEI S HA RT E T FN N O I W EYO HN N 4AK C I R E M O N A E H T E S O T C U R F F O E R U T C U R T S G N I S RI EN HO T B NR ) A C

TP DF GR U EO I A F L N DRR ONO G CA L TTY ,SHX GO SI RT R OI RD RAY $E HSH DT AE EE H HT NH G F IWAO # # S L S NUY A O M L " $ R EP E RV AUOT I SGFC E NNE DD I OP I I S R TE N A C E ER HP J CE N A O O R D I P T # # S O N A NO R T E N H ! # OI TEE H T A -R IT SR I U& OA N O B R A C C I R T E M M Y S A T S O M P O T !

U M S T I N B O I B H R X A E C S C R I A R T G E U S M G M N N I Y R O W S E A B O R L T B A L S M C O O U F C E M N I R H M N E T O M F O B T ON O T R O N A HO B C A C I T I A H T " # $ 7 O R A T

Y H L Y N E H P E F S E O O S S O N S C N E U A C L X ' - E N , $ A H " $ I T W E S S E T O S C T O C A M T A C ER L R O U E A F R S ' F O OT $ $ CE UN L I ! # 'Z A R D

E S O T C U R F

" " $ S I R E A S G O U C S U L E G P A ! # R ! '

R E M I P E E # S E E E H S H T O T T S F I C U O G L R L N & A I W O " $ L L O F E H E E T S S FE O O O S C T O U C HC A L CU I ' , H L G ! # 7$ F O E S O T N E P O D L A E F E S O S O O T S T R C A C E L U A R M O ' & S SI I O S " $ E M R R E T O S F E F C S O I E O L RC S N E O I Y BC C B U A MG R L N ' ! UI N D EU ! # HL 4C X E

N E P O E H T N I S E E R S T O N S T EI C E A CS L L O A C R $ I U H C L G F FO O E RR E E S U O BT T MC L U A UR M NT S EN # HI 4A H C

S I S E D I R A H C C A S O N O M G N I W O E E E E L N N N N L A A A A O X X X X F E E E E E H H H H H O O O O T D D D D F O O O O OE I I I I HS CO I T H N ! " # $ E 7P A

11.

S I ! @ D N U O P M O C E H T

E N O Z A R D Y H L Y N E H P E S O C U L G

E N O S O C U L G

E N O Z A S O C U L G

E N O Z A R D Y H L Y N E H P E S O T C U R F

! " # $

S I K L I M E S O N T I L T A N E M S E R " $ P " E D I R A E H S C O C R A C S I U D S E ! # H ! 4

N O I T C A E R N E V I G E H T N )

glu cos e

Re dP/HI C6H12O6 → (A) + CH3 − (CH2 )4 − CH3 383K

10.

Carbohydrate

N O I R A L O P I D L A R T U E N ; S E D O R T C E L E E H T F O Y N A S D R A W O T T O N S E O D N O I = R) E T T E I R WU T :C EU R HT 4S

iii

N O I N A S A T S I X E ; E D O N A S D R A W O T S E V O M N O I E V I T A G E N E H T ( P H G I H N O= I T ) ) U ) L O E SR CU I T S C A U BR NS T )

6.7

MULTIPLE CHOICE QUESTIONS (MCQs)

E S O I B O L L E C

E S O T C A L #

9 2 4 3 ) % ( #

6.8

E S O B I 2

E S O C U L '

E D Y H E D L A R E C Y L '

N O I R E T T I W : S A S T S I X E G N I W S O L L S D O D N F N O E O B H E B D T F R I O T E H P H E T C P I E H # $ 7

T A P U O R G L Y X O R D Y H D N A P U O R G E D Y H E D L # A

P U O R G L Y X O R D Y H D N A # T A P U O R G E N O# T E T +A

S A S T S I X L E D O I N E C E E D A N N I H I I C C C P A M Y I L I A L O N C N L G I O A L I Y N H A M C P H I L ! L A U T ( P 3 3 % P T ! " # $ ! T A P U O R G L Y X O R D Y H D N A P U O R G E D Y H E D L # A "

C A E R F O E C N E U Q E S G N I W O L L O F E H T R E D I S N O #S N O I T

T U O B A S T N E M E T A T S G N I W O L E L U O F R ET T HO T F N O S EI NS OD I HC CA I H O N " # $ 7I M A

E S O C U L '

NH3 − CH2 − COO−

17.

D E Z I L I B A T S S I N I E T O R P F O E S R S D U D N T N O C O U B B R T N E S E D G L I A T O C P I R L E D E P Y H I D H E H 4 ! " Y B T A P U O R G L Y X O R D Y H D N A P U O R G E D Y H E D L # A !

NH3 − CH2 − COOH

24.

L O T I B R O S

! #

E S O N I B A R A

" $

E S O N N A M

NH2 − CH2 − COO−

E S O T C U R F

NH2 − CH2 − COOH

E B O T D E T C E P X E S I # T C U D O R P E H 4

H3O PhNHNH2 Zn/ AcOH  → A  → B  →C (excess) heat

23.

" # $

TE C S AO R N E A T R N Y I EP SO OT CG U D D L N G I N N F D A A O A SL E PL UA OE T RC " $ G A LI AM N O E T I H D D C C N N NI A A UL FC Y H CE C R I U HMT RC OU ! # 7F R OS T T

E S O E R H T !

EB HI T L I EU S Q OE CE UH L T G T $A R Y FEL E E OMV E S E E S I NOT S O S O O ONC N T O I AE N T I T C B N C P U A A L S L A U O E DR M R A R S A G F N E D D D D SA R N N N N U A A A A A O E N E U E S E S E S FO S I O O O O QOI T C C C C AED G U NA U L U L U L N L A G G G G O T N C NE ! " # $ )C M RU E I PR

21.

16.

Protein -

15.

22.

E S E S E E S S O O O T O T T C L L L U A A A L M M M G E E E S E S S S O O O O T T C L R C C U A U L U M S R G F S E E E I E S S S E S O O S O O R R C T O C C C D U U U U A L L R S S G F T E S E E E E S S L S L O O S A O T O T R C C C M C U U U S U R L R G S F F E H ! " # $ 4 O T N I N W O D S K E E A S E S R O O T R B C U C E R U S O & 3 T C A " $ L S I S Y E L S O O R E I S D B Y O O T L H C L A E N , # O P ! # 5

20.

14.

S S E N T E E W S F O R E D R O G N I W " $ O L L O F E H T F O HT CC I H E R R ! # 7O C S I

G N I C E E S U S D O O N E E T R I S O C B E N U S T R A O L O R F A T A N C M A A L S I $ $ G D D D N D I N N N N W A A A A O E S E E L E S L S O O O S O C C C O F U U U C E U L L L H ' ' ' L T ' F O H C $ $ $ $ I H R A ! " # $ 7G U S 13.

19.

E WL OO (M R /E )P (D FE O M SU S S E N CO XC EE HB T I L L WI DW E / T A ) E( R T F SO I R SA EE S OLG COU UMS L E YH 'N T AF MO M R O F S R A G U S F O S R I A E PV GT I NA I V WI R OE L L D O F E EN HO T Z FA O S HO L CA I H C I T 7N E D I

18.

12.

S N I E T O R P L L A F O S T N E U T I T S N O C E R A Y E H 4

(A)

21.

(B)

COOH

CH3structure of protein is stabilized by: TheOhelical

dipeptide bonds (B) O

27.At

C I R T C E L E O S I Y B D E Z I R E T C A R A H C

E V I G / . ( C N O C H T I W D ES T I A S EI HH N4 ER HU WO L SO NC I E T W O O RL L 0E Y A

Which exists as NHO of Hthe CHfollowing COOH (D)Zwitter ion? NH 2

peptide bo

6.9

COOH

acid O Sulphanilic CH H (D) O H3

pH =4, of glycine exists as: does represent the peptide chain? Which the following structure C

C H

COOHC

O Nether C bonds C C

Nbonds Nbonds C NH NH bondsbonds (C) (A) ether dipeptide (B) C hydrogen n bonds (C) (A) (D) peptide

22. (C)

(D)

O by: The H H helical structure of protein is stabilized NH3 CH2 COO (B) NH CH 3 2 (B)

E R A T YI N EO HP T

(A)

COOH

hydrogen bonds (C) CH3 etherObonds

23.

NHthe following exists as Zwitter Which of (D) ion? H2N H2N NH COOH p Amino phenol (B) Salicylic acid (C) O CH3

S D I C A O N I M A G N I R R N UO I CT CA OR U YG L I L F A N R O UC T A N$ TE S V OA -H

(A)

stabilized by: 21.

witter ion?

H2N

S D I L O S G N I T L E M H G I H L L A E R A Y E H 4

" #

22. (C)

3 % , 5 # % , / / ) "

(A)

H2N

CH2 O COO

N C (D)

Ethanolam

Cpeptide C

bonds

T A

S A S T S I X E D I C A O N I M A

N !

O N I M A E H 4 S I T N I S O A PT CI S I R X T E C L EI L L E OW S I S T I D N( AP T A D (I C PA

E EI D NT I P N E AP L I ! R T EE NH I T C F YO L 'E R SU A T C NU T ER S T T T E I S T T R S T T C S T E WC I T S E T E S E T O R E I R G R T S E O P S A N O DC B I I E Z T H E P I T D P D PH N E I I 4 X A O C P I O X ( ! R E TN I ! " # $ !C Y L S 'I

H H Salicylic O H(D) (B) Ethanolamine p Amino phenol acid (C) Ethanolamine O acid25. (C) (A) Sulphanilic acid H Sulphanilic acid (D) H 24. Which one of the following statements about amino acids is not true? stabilized by:(C) N C C N C C N C C C C 23. At pH =4, glycine exists as: (D) N C C N C C N C C of allbonds proteins en bonds (C) (A) ether They bondsare constituents (D) peptide H O O O The helical structure ofmelting protein stabilized (B) is (A) NH CH COO NH3 by:CH2 COOH NH3 ion? CH21. COOH They all solids witter 3 are 2 high 2(B) R (C) (A) dipeptide bonds (B) hydrogen bonds ether bonds (D) peptideRbonds c NH acid CH (C) (C) Sulphanilic acid (D) Ethanolamine | CH (C) Most naturally occurring aminoNH acids have D configuration NH CH COOH (D) COO + 2 2 2 28. 2D COO 2 2 22. Which of following as Zwitter ion? NH3 - CHCOOH at (pH=2) and its isoelectric point is| 6. The amino acid 28. Anthe D-amino acid exists exists as, (D) they are characterized by isoelectric point NH+3 - CH- COOH 24. Which one of the statements acids is acid not true? ents about amino acids is not true? at pH 10.97 will exist as: (A) p Amino phenol (B)following Salicylic acid about (C) amino Sulphanilic (D) Ethanolamine

25. Proteins when heated with conc. HNOR3 give a yellow colour. This Ris: (A) areglycine constituents of proteins R exists 23. AtThey pH =4, as:all 3 CH2 COOH 26. | test | | (A) oxidizing test (B) xanthoprotic (C) Hoppe’s test They are +all high melting (B) solids

nsNH

(A) - CH- COO NH COO (B) (B) NH NH (C) 3 - CHNH2 CH(A) COO NH CH 2CH COOH 2(C) 3 2 COO 2 R Most naturally occurring amino acids3 have D configuration ids have D configuration

(D)

NH2 - CH- COOH

(D)

26. A tripeptide is written as Glycine Alanine Glycine. The correct structure of the tripeptid R | ments about amino acids is not true? (D) they2 are characterized | CH ric point NH (D)isoelectric (C) NH2point CH2 COO NH+3 - CH- COO O CH3 CH−3 O CH3 by 2 COOH NH CHCOOH ns 2 25. colour. Proteins when heated with conc. HNO3 give a yellow colour. This is: yellow This is: HNO3 give a 24. Which one of the following statements about amino acidsRis not true? NH NH (B) (A) 29. Match the following H NH COOH H|2N Hoppe’s test (A) oxidizing test NH xanthoprotic testtest (C) (D) Acid base te rotic test Hoppe’s test(B)COOH Acid base 2N (C)They (A) are constituents of(D) all proteins − NH CHCOO 2 cids have D configuration O CH –I Column II 26. TheThey A tripeptide is written astripeptide Glycine Alanine Glycine. The correct O structure of the–tripeptide is Alanine Glycine. correct ofColumn the is (B) arestructure all 3high melting solids R tric point CH (a) First acid synthesized in lab acids have D configuration (i) CH OO O CHCH (C) CH Most naturally occurring 3 CH3 O 3 3 amino 3 amino O3 |Glycine yellow colour. This is: HNO3 give a (D) NH NH CHCOOH they are characterized by isoelectric point NH NH 2 (B) (A) (B) NH NHNH NH H2N COOH NH COOH H protic(C) test Hoppe’s test (D) (D)H2Ncolour. H22NN(C)Proteins HR2NThis is: COOH NHCOOH NH COOH a yellow 25. when heated with conc. Acid base HNO3 give test OO CH3 O | Alanine Glycine. The correct structure of the tripeptide is (A) oxidizing test xanthoprotic test (C) Hoppe’s Acid base test O CH3 (B) O test CH(D) NH2+ - CH- COOH CH3 structure O of the3tripeptide is O CHas CH 26. CH A 33 tripeptideO is written 3 Glycine Alanine Glycine. The correct

G N I W O L L O F E H T H C T A -

E N I T S Y #

iii

H C

C OC

E N I N I G R !

H H

H C C

E N I N O I H T E -

E N I C Y L '

(B) |

S E D O ! " # $ #

(D) Rd

C C O ON CH 3

O O does represent the peptide WhichOofHthe following chain? H OH structure H O

N CC C CO N C C C HN NN CCCCCCC NC C N NC CC CC N NO C H NH OC NH O

C NH CO N C C COOH

E V I T C A ND I I C Y LA L A O CN I I T P M /A

c (D)

27. H HH

H C CNH

P E R S E O D E R U T C U R T S G N I N I WA OH L LC O E F D EI HT T P FE O P HE CH I T H T 7N E S E R

(D)(B) H N N 2

O O

CH H 3

C I R T C FE O L E DO I C S AI T OE S T NH I N I MI GO !H P

NH COOH NH H NH N C C HNH C C CO N C CH C C C O COOH NH 3 O CHN3 C C N C C O C HC O 27. oes (C) represent theNpeptide chain?

G N I N I A T N O C R U H P L U 3

H O O NH

H H2N H H2NNN

B A DL I C N AI OD E NZ I I MS E AH TT S N R I Y & S

(D) (A) (B) (C)

) ) n N M U L O #

27. H H22N N

) n N M U L O #

Which of the following structure does the peptide NHO chain? NH 29.represent NHO CH CH3 CH (D) 3 H2N COOH NH NH3 COOH NH COOH H O H H NH NH (B) (A) O CH O CH H2N COOH NH O 3 3 NH H2N COOH (B) (A) N C C C C N C N O N C NH C NH CH 3 the of following structure does represent the peptide chain? oes represent27. the peptide chain? O CHWhich O a i 3 (C) (D) (B)

at (pH=2) and its isoelectric point is 6. An D-amino acid exists as, NH3 - CH- COOH O H O O R R H H | | at pH 10.97 will exist Has: H H O i O ii H iii iv H H C C N C C N C C C+ C An CHCOOH D-amino acid exists as,isNH - CH- (D) COOH28. atN(pH=2) and its isoelectric point 6. 3The amino acid at (pH=2) and its isoelectric point is 6. The amino R R R N C C N C C N C C C C (C) (D) N C N C C N C C iii ii iv i at pH 10.97 willCexist as: HC N C C C 28.

iii H iv (C) O RiiNH - CHi COOH O O +R NH (B) R 2 - CH- COO R (A) O NH 2 3 - CH- COOR R | | | | | R iv iii ii i | R + (A) - CHCOO NH2 - CH- COOH NHand - CHCOO (B) (C) (D) - CH- COO NH2 - CHCOOH | NH 2(D) 3(C) - NH CH-2 COOH at (pH=2) its isoelectric point is +6. The amino acid | 28. R An D-amino acid exists as, NH3 - CH- COOH at (pH=2) and its isoelectric point is 6. The amino acid NH2 - CH- COOH at pH 10.97 will exist | as: R NH2 - CHCOOH 29. R Match the following R R R | | | | | the following Match NH29. CHCOO NH CHCOOH (C) (D) + 2 2 –I Column(D) – II (A) NH2 - CH- COO NH2 - CH- COOH NH3 - CH- COOColumn (B) (C)

Column – I – II Column

Column – II

E S O C U L G $ S T L A S L A N R E T N I S A T S I X E S D I C AS ON NO I I R ME T !T I W Z L L A C

F O R E M Y L O P A S I E S O L U L L E #

Y BS N DO ER R T UC T E P L AE CF SO I R I (A P /E #N YO BL G NN EI VV I A G H P (U EO HR 4G ( . " # " " 14.

# $ $ #

7. " " " # !

! # $ " "

$ $ " # !

$ " ! " ! ! " # # "

N O I T C A E R N E V I G E H T N )

R I E H T

S E L U C E L O M L A R I H C E R A !O .T E $U DD NS AI Y !I T L .A 2I R H C

Re dP/HI C6H12O6 → (A) + CH3 − (CH2 )4 − CH3 383K

S I ! @ D N U O P M O C E H T

T N E N O P M O C R A G U S $

glu cos e

S E S A B L A R I H #

S I $ N I M A T I V F O M R O F E V I T C A Y L L A N O I T C N

L O R E F I C L A C E L O H C

GN NO I I V T I U G L O RS A G S UT SI C GD NE I N C UE D" EH R T

L O R E F I C L A C O G R E

L O R E T S E L O H C O R D Y H E D

L O I R T I C L A C

E E E E NI N N N N OW A A A A NT X X X X S E E E E AE H H H H ST O O O O I S D D D D EEN VA O I O SI O I O I I OTE RA C GM UE S ! " # $ 3 I NH

T N E N O P M O C R A G U S ,

U ! " # $ ! " # $ &

S T I N U R E T S E E T A H P S O H P L A R I H #

N A M U H Y B D E T S E G I D T O N S I E S O L U L L E # S G N I E B

E U R T S I 2 T U B E S L A F S I ! F )

E D Y H E DT L N A E NG AA E NR I A S T N N OL E CL O T4 O NS E SC E OU DD E ER S L OI L T T C S UT RU &B P U O R G

33. A. :

33. 32. 31. 29.

O N E L I H W E G A K NE I S L O LR A T C E U CS I N MI EE HR E AH ST A S HI E EG S OA T K L N A I -L H C U S

E S L A F S I 2 T U B E U R T S I ! F ) #

28. 27. 26. 25. 24. 22.

21. 20. 19. 18. 17. 15.

U S E L I H W R A G U S G N I C U D E R A S I E S O T L T A O -N S I E S O R C

32. A. : E H T T O N S I 2 T U B E! UF RO T N EO R I A T A 2N A DL NP AX E !T HC T E O R R BO FC )

E H T S I 2 D N A E U! RF T EO R N A O I T 2A N DA NL AP X !E T HC T E O R BR O FC ) !

R. :

13. 12. 11. 10. 8.

R. :

5. 4. 3. 1.

R. :

30. A. :

AE S SO E ON GN R A E DM ND UN EA S E OS T O C C UU RL F EG S M A R BO AF F FO O ET CN NE EM S E E G R N PA NR ) R A E R -

R.:

31. A. :

NEG EO R N T A I S A W A T U S E O O L O2Y L O WDSF TNN E FAOH I O T T !S T F EO S N I U S O Q NT E I OR EN CE S O E SSH S Y N! TN OS GA I T AN S IE D E S R UEE O T O QN W S H I SC GR E N S NP A I N O WHET O P OCL A I D L S H L E E E O R S R 7 F I T U R EN Q U HE2E O 4M RF

9 2 4 3 ) % ( #

6.10

ASSERTION AND REASON

ANSWER KEY:

QUIZ

3 % , 5 # % , / / ) "

O H2N O

H N H N H222N

O O O

(B)

CH3

NH NH NH

CH3

CH CH 33

CH3

NH NH NH

OH OH OH

(X) o Nylon 6 O

CH3

E C N E U Q E E S S E H N T O F T I O C E A N E O R . E H T $ N ) (X)

None of these

Which of the following hexoses will form the same osazone, when treated with' excess of phe

(X)  → Nylon 6 hydrazine?

is D-glucose, D-fructose D-galactose cyclohexanone (B) and caprolactum

E N O M N U A T X C E A L H O O R L P C Y A C C S ! " I 8

(X) (A) (A)

cyclohexanone (B) caprolactum 10. In the reaction sequence HO(CH Hexamethylene diisocyanate 540 K 2)6NH2 (D)

(X) o Nylon 6

540 7. K

C U R F D N A E S O C U L G N I S M O T ( A N # ( ( 0 O B . R ( . . $ A / n n n C ( ( ( L A R . . . I E R HA ! " # $ #E S O T

(A) 6. (C)

None of these NH H2N

(D)

O CH3

OOO

6. In the reaction sequence OH NH None these H2N of540 NH K

H2N

(D) (B)

TS E N S I I N OTD O A Z MH E A T S A E O H7RE E S T G L N O L FE N E C I O C N G U I EGS L A G NN T E L B OI F O SVUO I C I L E R E L EAL O U S F S ONOC I " $ DE E CIML ES E UN0O S S O LI O4 UT E G M T C H F ! TU C T N E F A R F OE EF O N O N G F AO E ORRO E N ITE M B T N E R O A V AMO . D I ET T R H I R A X OUF 4V N S # ! $ I P L E R L /M E HE D ITC

CH3

(A)

E E E E E S S S S N O O O O I E T T T T N D C C C C AI U U U U L T R R R R !P F F F F E F O F O F O F EP O I NR C I T F # # # # YO L O T O T O T O 'E T R D D D D SU E E E E AT K K K K C N N I N I N I N E U I R L L L L T T T S S S S S I I I I I E E E E RC T W S S S S O O O O E R C C C C SR U U U U IO L L L L EC G G G G D F O F O F O F T I E O H P E 4 # # # # PE I R N T I C ! " # $ Y !L '

6.11

E S O N N A D N A E S O T C U R F $ E S O T C A L A G $ D N A E S O N N A M $ E S O T C A L A G $ D N A E S O N N A M $

E S O T C U R F $

( P

N I T C E P O L Y M !

" $

14.

S I H C R A T S F O R E " $ M Y L O P

13.

N R E E S A G O E L O N Y C I Y L M L E ! ' H ! # 4 ! #

E N I N A L ! R O F T C E R R O C S I E R U T C U R T S H C I H None of these

12.

G N I R E S O N A R Y P N T I E E D L E R E O H I 2 6 T E R " $ A S M O T A Y W N N O W A L O M L R E 9 " W O ! # (

E S O T C A L A G $ D N A E S O T C U R F $

E S O C U L G $

(D)

E S O C U L G $

(C)

8.(B)

E S O C U L G $

! " # $ 7

(B) (A)

E E S S S O T O I T E C C S U U O R F R C F U L N N G I I F O D D E N N N A A O E Z E S S A O O S H H C C O C C U U F A A L L O G E E G R N N N N U I I I I O L O ! " # $ #

S MS RE OC F X LE L I H WT I E SW T E A S D N O E A XT Y EA C HE O R S GT I NN I I D E W E O H N L W E L E O ( Y L N F EI . H Z T E N A OR E H Z ( M TA D FS Y # A OOH / X L E E H Y ( ( C MN I E H AH # $ 7SP EF HO T

ctum (B) D-glucose, D-fructose Mannose (C) HO(CH (D) and Hexamethylene diisocyanate 2)6NH2 ethylene diisocyanate (C) D-glucose, D-mannose and D-galactose 7. Which of the following hexoses will form the same osazone, when treated with' excess of phenyl will form the(D) same osazone, treated and with'D-galactose excess of11. phenyl hydrazine? D-fructose,when D-mannose (A) D-glucose, D-fructose and D-galactose 8. Which structure is correct for Alanine? ctose (B) D-glucose, D-fructose and Mannose pH = 10 pH= 2 ose (C) D-glucose, D-mannose and D-galactose actose 7. (D) D-fructose, D-mannose and D-galactose (A) lactose 8. Which structure is correct for Alanine? nine? pH = 10 pH= 2

E S E H T F O E N O .

9. Oxidation of glucose is one of the most important reaction in a living cell. What is the number of A (C) molecules generated in cells fromone molecule of glucose ?

(A) 38 (B) 12 None of these (C) 18 (D) 28 9. Oxidation of glucose is one of the most important reaction in a living cell. What is the number of ATP 10. The reagent used for obtaining osazone derivative of fructose is molecules generated in cells fromone molecule of glucose ? (B) NHWhat (A) NH e most important reaction in a(B) living cell. 2 – NHis 2 the number of ATP (A) 38 2OH 12 (D)

9 2 4 3 ) % ( #

6.12

13.

7. 14.

" !

12.

" #

11.

# !

10.

" $

! #

$ !

" "

ANSWER KEY:

Tan Print's Chemistry for NTA CUET (UG) 2022 AUTHOR

: A. Mourya

DATE OF PUBLICATION : MAY 2022 EDITION ISBN NO NO. OF PAGES BINDING TYPE

: : : :

2022 9789394186699 246 PAPERBACK

Rs. : 325

| USD : 35

Description This book intends to cater to the principal needs of all the students preparing for the Common University Entrance Test (CUET) at the Undergraduate Level in the Chemistry Domain. This book contains the practice material in a highly student-friendly and thorough manner. The Present Publication is the Latest 2022 Edition, authored by A. Mourya, with the following noteworthy features:

[As per the Latest Syllabus] released by the National Testing Agency (NTA)

· ·

[Chapter-wise/Topic-wise MCQs] with hints and answers [Chapter-wise' Mind Maps/Quick Review'] for complete revision of concepts

· ·

[Tease your Brain] section for conceptual clarity [Mock Tests based on Oﬃcial Mock Test Pattern] are provided in the book to gauge the students' knowledge & understanding. It also enables the students to get acquainted with the pattern of examination before appearing for the ﬁnal exam

ORDER NOW