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SAFETY DATA SHEET

1. Product and company identification Product name

CIMPERIAL® 1070 METALWORKING FLUID

Manufacturer Company name Address Telelphone Emergency telephone number (Korea) Supplier Company name Address Telelphone (General Information) Emergency telephone number (24 hour access)

CIMCOOL® Korea Inc 255, Gongdan-ro, Onsan-eup, Ulju-gun,Ulsan, Korea +82-52-239-2333 +82-52-239-2331

TRADE TOOLS 23 Olive Road, Penrose Auckland 1642 +64 9 525 8882 03 4747 000 (New Zealand Poisons Information Centre)

Recommended use and Limitations on use Recommended use METALWORKING FLUID SDS number

Not applicable

2. Hazards identification GHS classification Physical hazards Health hazards

Environmental hazards

Not classified.

Acute toxicity, oral

Category 4 (75.95 % of the mixture consists of component(s) of unknown toxicity.)

Acute toxicity, dermal

Category 5 (81.77 % of the mixture consists of component(s) of unknown toxicity.)

Skin corrosion/irritation

Category 2

Serious eye damage/eye irritation

Category 2

Hazardous to the aquatic environment, acute hazard

Category 2 (70.77 % of the mixture consists of component(s) of unknown hazards to the aquatic environment.)

Hazardous to the aquatic environment, long-term hazard

Category 2 (71.44 % of the mixture consists of component(s) of unknown hazards to the aquatic environment.)

Label elements Symbols

Signal word

Warning

Hazard statement

Harmful if swallowed. May be harmful in contact with skin. Causes skin irritation. Causes serious eye irritation. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Precautionary statement Prevention

Do not handle until all safety precautions have been read and understood. Avoid breathing mist or vapour. Wash thoroughly after handling. Do not eat, drink or smoke when using this product.

Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. In case of inadequate ventilation wear respiratory protection.

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Response

IF ON SKIN: Wash with plenty of soap and water. If skin irritation or rash occurs: Get medical advice/attention. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Call a poison center/doctor if you feel unwell. IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor if you feel unwell. Take off contaminated clothing and wash it before reuse.

Storage

Keep container tightly closed. Protect from sunlight. Store in a well-ventilated place. Store away from incompatible materials. Store in accordance with local/regional/national/international regulations.

Disposal

Dispose of contents/container in accordance with local/regional/national/international regulations.

3. Composition/information on ingredients Substance or mixture

Mixture

Chemical property

CAS Number

Distillates (petroleum), hydrotreated heavy naphthenic DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTHENIC

64742-52-5

40 - < 50

PARAFFINS, CHLORINATED

63449-39-8

10 - < 20

141-43-5

3-<5

ALCOHOLS, C12-18, ETHOXYLATED PROPOXYLATED

69227-21-0

1-<3

HEXAHYDRO-1,3,5-TRIS (2-HYDROXYETHYL)-S- TRIAZINE

4719-04-4

1-<3

3-Iodo-2-propynyl butylcarbamate 3-IODO-2-PROPYNYL BUTYLCARBAMATE

55406-53-6

< 0.3

MONOETHANOLAMINE

Other components below reportable levels

Concentration (%)

20 - < 30

4. First aid measures Inhalation

If symptoms are experienced, remove source of contamination or move victim to fresh air. Call a physician if symptoms develop or persist. Under normal conditions of intended use, this material is not expected to be an inhalation hazard.

Skin contact

Immediately flush with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. If skin irritation occurs: Get medical advice/attention. Wash clothing separately before reuse.

Eye contact

Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses. Continue rinsing. Get medical attention immediately.

Ingestion

IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Rinse mouth. Drink 1 or 2 glasses of water. Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration.

Potential delayed effects

Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. Rash.

Dermatitis. Prolonged exposure may cause chronic effects.

Personal protection for first-aid responders

IF exposed or concerned: Get medical advice/attention. Show this safety data sheet to the doctor in attendance.

Notes to physician

Treat symptomatically. Symptoms may be delayed.

5. Fire-fighting measures Extinguishing media

Water fog. Foam. Dry chemical powder. Dry chemicals. Carbon dioxide (CO2). Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Extinguishing media to avoid

Do not use water jet as an extinguisher, as this will spread the fire.

HAZCHEM Code Number

None.

Specific hazards during fire fighting

During fire, gases hazardous to health may be formed.

Special fire fighting procedures

Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk.

Protection of fire-fighters

Wear suitable protective equipment.

Hazards from combustion products

Smoke, fumes, oxides of nitrogen, hydrogen chloride, and oxides of carbon

Specific methods

Use standard firefighting procedures and consider the hazards of other involved materials.

General fire hazards

No unusual fire or explosion hazards noted.

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6. Accidental release measures Personal precautions, protective equipment and emergency procedures

Keep unnecessary personnel away. Wear appropriate personal protective equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8.

Environmental precautions

Avoid discharge into drains, water courses or onto the ground. Use appropriate containment to avoid environmental contamination.

Spill cleanup methods

Local authorities should be advised if significant spillages cannot be contained. This product is miscible in water.

Large Spills: Stop the flow of material, if this is without risk. Absorb in vermiculite, dry sand or earth and place into containers. Prevent entry into waterways, sewer, basements or confined areas.

Clean up in accordance with all applicable regulations. Following product recovery, flush area with water.

Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination.

Never return spills to original containers for re-use. For waste disposal, see section 13. Do not flush spill to drain.

7. Handling and storage Handling Precautions

Keep away from open flames, hot surfaces and sources of ignition. Avoid contact with eyes. Avoid contact with skin. Avoid contact with clothing. Wear personal protective equipment. Do not taste or swallow. When using, do not eat, drink or smoke. Wash hands thoroughly after handling. Use care in handling/storage. Avoid release to the environment. Do not empty into drains.

Safe handling advice

Do not breathe vapour. Do not get this material in contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Use personal protection recommended in Section 8 of the SDS. Follow all SDS/label precautions even after container is emptied because they may retain product residues.

Prevention of fire and explosion

Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Follow all SDS/label precautions even after container is emptied because they may retain product residues. Use only with adequate ventilation.

Storage Suitable storage conditions

To maintain product quality, do not store in heat or direct sunlight. Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS).

Incompatible materials

Strong oxidising agents. Strong acids. For further information, please refer to section 10.

Safe packaging materials

Do not cut, weld, solder, drill, grind, or expose containers to heat, flame, sparks, or other sources of ignition. Keep in original container. Do not handle or store near an open flame, heat or other sources of ignition.

8. Exposure controls/personal protection Exposure limits New Zealand. WES. (Workplace Exposure Standards) Type MONOETHANOLAMINE (CAS 141-43-5)

Value

STEL

15 mg/m3

TWA

6 ppm 7.5 mg/m3 3 ppm

Type

Value

STEL

6 ppm

TWA

3 ppm

US. ACGIH Threshold Limit Values MONOETHANOLAMINE (CAS 141-43-5)

UK. EH40 Workplace Exposure Limits (WELs) Type MONOETHANOLAMINE (CAS 141-43-5)

Material name: CIMPERIALÂŽ 1070 Version No.: 01 Issue date: 12-March-2014

Value

STEL

7.6 mg/m3

TWA

3 ppm 2.5 mg/m3 1 ppm SDS New Zealand

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Australia. National Workplace OELs (Workplace Exposure Standards for Airborne Contaminants, Appendix A) Type Value MONOETHANOLAMINE (CAS 141-43-5)

STEL

15 mg/m3

6 ppm 7.5 mg/m3 3 ppm Australia. OELs. (Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment) Type Value TWA

MONOETHANOLAMINE (CAS 141-43-5)

STEL

15 mg/m3

TWA

6 ppm 7.5 mg/m3 3 ppm

Biological limit values

No biological exposure limits noted for the ingredient(s).

Engineering controls

Ensure compliance with applicable exposure limits. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash fountain and emergency showers are recommended.

Personal protective equipment Respiratory protection In case of insufficient ventilation, wear suitable respiratory equipment.

Skin protection

Wear appropriate chemical resistant clothing. Wear suitable protective clothing and gloves.

Eye/face protection

Wear safety glasses with side shields (or goggles). Avoid contact with eyes. Eye wash fountain is recommended.

Radioactive or thermal hazards

Follow standard monitoring procedures.

Hygiene measures

When using, do not eat, drink or smoke. Do not get in eyes, on skin, on clothing. Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants.

9. Physical and chemical properties Appearance Physical state

Liquid.

Form

Liquid.

Colour

Not available.

Odour

CHEMICAL

Odour threshold

Not available.

pH

Not applicable

Melting point/freezing point

0 °C (32 °F) estimated

Boiling point, initial boiling point, and boiling range

100 °C (212 °F) estimated

Flash point

170 °C (338 °F) Cleveland open cup

Auto-ignition temperature

Not available.

Flammability (solid, gas)

Not available.

Flammability limit - lower (%)

Not available.

Flammability limit - upper (%)

Not available.

Explosive limit - lower (%)

Not available.

Explosive limit – upper (%)

Not available.

Vapour pressure

Not available.

Vapour density

Not available.

Evaporation rate

Like water when diluted

Relative density

Not available.

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Density

Not available.

Solubility

100 % Water Miscible

Partition coefficient (n-octanol/water)

Not available.

Decomposition temperature

Not available.

Other data pH in aqueous solution

8.6 @ 5%

Specific gravity

1.01

10. Stability and reactivity Stability

Material is stable under normal conditions.

Conditions to avoid

Excessive heat. Contact with incompatible materials.

Incompatible materials

Strong acids. Strong oxidising agents. Avoid contact with oxidisers or reducing agents. Do not add sodium nitrite or other nitrosating agents which may form cancer causing nitrosamines.

Hazardous decomposition products

Smoke, fumes, oxides of nitrogen, hydrogen chloride, and oxides of carbon

Possibility of hazardous reactions

No dangerous reaction known under conditions of normal use. Hazardous polymerisation does not occur.

11. Toxicological information Acute toxicity Components

Harmful if swallowed. May be harmful in contact with skin.

Species

Test results

3-Iodo-2-propynyl butylcarbamate (CAS 55406-53-6) Acute

Dermal LD50

Rabbit

> 2000 mg/kg

Rat

1.1 g/kg

Oral LD50

ALCOHOLS, C12-18, ETHOXYLATED PROPOXYLATED (CAS 69227-21-0) Acute

Oral LD50

Rat

1225 mg/kg

MONOETHANOLAMINE (CAS 141-43-5) Acute

Dermal LD50

Rabbit

1025 mg/kg

Guinea pig

620 mg/kg

Mouse

700 mg/kg

Rat

10.2 g/kg

Mouse

50 mg/kg

Rat

67 mg/kg

Oral LD50

Other LD50

* Estimates for product may be based on additional component data not shown.

Routes of exposure

Inhalation. Ingestion. Skin contact. Eye contact.

Symptoms

Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May cause redness and pain.

Skin corrosion/irritation

Causes skin irritation.

Serious eye damage/eye irritation

Causes serious eye irritation.

Skin sensitiser

This product is not expected to cause skin sensitisation.

Germ cell mutagenicity

No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic.

Carcinogenicity

This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.

Toxic to reproduction

This product is not expected to cause reproductive or developmental effects.

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Specific target organ toxicity - single exposure

Not classified.

Specific target organ toxicity - repeated exposure

Not classified.

Aspiration hazard

May be harmful if swallowed and enters airways.

Chronic effects

Prolonged inhalation may be harmful. May be harmful if absorbed through skin.

Prolonged or repeated exposure may cause liver and kidney damage. These effects have not been observed in humans.

Relevant negative data

Not available.

12. Ecological information Ecotoxicological data Components

Species

Test results

3-Iodo-2-propynyl butylcarbamate (CAS 55406-53-6) Aquatic Fish

LC50

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

0.05 - 0.089 mg/l, 96 hours

ALCOHOLS, C12-18, ETHOXYLATED PROPOXYLATED (CAS 69227-21-0) Aquatic

Acute Fish

LC50

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

0.46 mg/l, 96 hours

Rainbow trout,donaldson trout (Oncorhynchus mykiss)

114 - 196 mg/l, 96 hours

Bluegill (Lepomis macrochirus)

> 0.1 mg/l, 96 hours

MONOETHANOLAMINE (CAS 141-43-5) Aquatic Fish

LC50

PARAFFINS, CHLORINATED (CAS 63449-39-8) Aquatic Fish

LC50

* Estimates for product may be based on additional component data not shown.

Ecotoxicity

Toxic to aquatic life with long lasting effects. Accumulation in aquatic organisms is expected.

Persistence and degradability

No data is available on the degradability of this product.

Bioaccumulation

No data available.

Partition coefficient n-octanol/water (log Kow) MONOETHANOLAMINE

-1.31

Bioconcentration factor (BCF)

Not available.

Mobility

This product is miscible in water.

Other hazardous effects

No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation potential, endocrine disruption, global warming potential) are expected from this component.

13. Disposal considerations Disposal methods/information

Consult authorities before disposal. Dispose of contents/container in accordance with local/regional/national/international regulations. Do not contaminate ponds, waterways or ditches with chemical or used container.

Special precautions

Dispose in accordance with all applicable regulations.

14. Transport information IATA UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards

UN3082 Environmentally hazardous substance, liquid, n.o.s. (PARAFFINS, CHLORINATED) 9 III No.

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ERG Code Special precautions for user Other information Passenger and cargo aircraft Cargo aircraft only IMDG UN number UN proper shipping name Transport hazard class(es) Class Subsidiary risk Packing group Environmental hazards Marine pollutant EmS Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code

9L Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Allowed.

Allowed.

UN3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (PARAFFINS, CHLORINATED), MARINE POLLUTANT 9 III Yes F-A, S-F Read safety instructions, SDS and emergency procedures before handling. Read safety instructions, SDS and emergency procedures before handling.

Not available.

IATA; IMDG

Marine pollutant

15. Regulatory information Applicable regulations New Zealand Inventory of Chemicals (NZIoC): Registration status 3-Iodo-2-propynyl butylcarbamate (CAS 55406-53-6) ALCOHOLS, C12-18, ETHOXYLATED PROPOXYLATED (CAS 69227-21-0) Distillates (petroleum), hydrotreated heavy naphthenic (CAS 64742-52-5) HEXAHYDRO-1,3,5-TRIS (2-HYDROXYETHYL)-STRIAZINE (CAS 4719-04-4) MONOETHANOLAMINE (CAS 141-43-5) PARAFFINS, CHLORINATED (CAS 63449-39-8)

HSNO Approved May be used as a single component chemical under an appropriate group standard May be used as a single component chemical under an appropriate group standard HSNO Approved HSNO Approved May be used as a single component chemical under an appropriate group standard

16. Other information References

Not available.

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Issued by Company name Address/Telephone

Prepared by Title

CIMCOOLÂŽ Industrial Products LLC 3000 Disney Street Cincinnati, OH 45209 United States 513-458-8199 Regulatory Affairs Department

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.

Issue date

12-March-2014

Material name: CIMPERIALÂŽ 1070 Version No.: 01 Issue date: 12-March-2014

SDS New Zealand

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