Safety Data Sheet According to Regulation (EC) No 1907/2006
Powergel VG1 Revision: 2012-10-08
Version 06
SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name: Powergel VG1
1.2 Relevant identified uses of the substance or mixture and uses advised against Identified uses: For industrial use only. AISE-P802 - Food process cleaner. Semi-closed cleaning process AISE-P806 - Foam cleaner. Semi-automatic with venting process AISE-P807 - Foam cleaner. Semi-automatic without venting process Uses advised against Uses other than those identified are not recommended 1.3 Details of the supplier of the safety data sheet Diversey Ltd Contact details Weston Favell Centre, Northampton NN3 8PD, United Kingdom Tel: 01604 405311, Fax: 01604 406809 Regulatory Email: MSDSinfoUK@sealedair.com 1.4 Emergency telephone number For medical or environmental emergency only: call 0800 052 0185
SECTION 2: Hazards identification 2.1 Classification of the substance or mixture The product has been classified and labelled in accordance with Directive 1999/45/EC and corresponding national legislation. Indication of danger C - Corrosive Risk phrases: R35 - Causes severe burns. 2.2 Label elements
C - Corrosive Contains sodium hydroxide Risk phrases: R35 - Causes severe burns. Safety phrases: S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S28a - After contact with skin, wash immediately with plenty of water. S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible). S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection.
2.3 Other hazards No other hazards known. The product does not meet the criteria for PBT or vPvB in accordance with Regulation (EC) No 1907/2006, Annex XIII.
SECTION 3: Composition/information on ingredients
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SAFETY DATA SHEET Powergel VG1 3.2 Mixtures Ingredient(s)
EC number
CAS number
REACH number
Classification
sodium hydroxide
215-185-5
1310-73-2
01-2119457892-27
C; R35
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
263-179-6
61791-46-6
No data available
Xi,N; R38-41-50
sodium alkylethersulphate
Polymer*
68585-34-2
01-2119488639-16
Xi; R38-41
propane-1,2-diol
200-338-0
57-55-6
01-2119456809-23
-
alkyl alcohol ethoxylate
Polymer*
68439-50-9
[4]
Xi,N; R41-50
Classification (EC) 1272/2008 Skin Corr. 1A (H314)
Notes
Weight percent 10-20
Eye Dam. 1 (H318) Aquatic Acute 1 (H400) Skin Irrit. 2 (H315) Eye Dam. 1 (H318) Skin Irrit. 2 (H315) -
3-10
Eye Dam. 1 (H318) Aquatic Acute 1 (H400)
0.1-1
3-10 3-10
* Polymer. For the full text of the R, H and EUH phrases mentioned in this Section, see Section 16. Workplace exposure limit(s), if available, are listed in subsection 8.1. [1] Exempted: ionic mixture. See Regulation (EC) No 1907/2006, Annex V, paragraph 3 and 4. This salt is potentially present, based on calculation, and included for classification and labelling purposes only. Each starting material of the ionic mixture is registered, as required. [2] Exempted: included in Annex IV of Regulation (EC) No 1907/2006. [3] Exempted: Annex V of Regulation (EC) No 1907/2006. [4] Exempted: polymer. See Article 2(9) of Regulation (EC) No 1907/2006.
SECTION 4: First aid measures 4.1 Description of first aid measures General Information Inhalation Skin contact Eye contact Ingestion Self-protection of first aider:
If unconscious place in recovery position and seek medical advice. Remove from source of exposure. Get medical attention immediately. Immediately wash off with plenty of water. Take off all contaminated clothing immediately. Get medical attention. Wash off immediately with plenty of water. Get medical attention immediately. Remove material from mouth. Immediately drink 1-2 glasses of water or milk. Get medical attention immediately. Consider personal protective equipment as indicated in subsection 8.2.
4.2 Most important symptoms and effects, both acute and delayed Severe irritant, may cause respiratory tract irritation. Inhalation Causes severe burns. Skin contact Causes severe or permanent damage. Eye contact Causes severe burns. Ingestion will lead to a strong caustic effect on mouth and throat and to the Ingestion danger of perforation of oesophagus and stomach. No known effects. Sensitisation 4.3 Indication of any immediate medical attention and special treatment needed No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found in section 11.
SECTION 5: Firefighting measures 5.1 Extinguishing media Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam. 5.2 Special hazards arising from the substance or mixture No special hazards known. 5.3 Advice for firefighters As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.
SECTION 6: Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Wear suitable protective clothing, gloves and eye/face protection. 6.2 Environmental precautions Do not allow to enter drainage system, surface or ground water. Dilute with plenty of water. 6.3 Methods and material for containment and cleaning up Use neutralising agent. Absorb onto dry sand or similar inert material. 6.4 Reference to other sections For personal protective equipment see subsection 8.2. For disposal considerations see section 13.
Page 2 / 12
SAFETY DATA SHEET Powergel VG1
SECTION 7: Handling and storage 7.1 Precautions for safe handling Advice on safe handling Handle in accordance with good industrial hygiene and safety practice. Do not mix with other products unless advised by Diversey. For advice on general occupational hygiene see subsection 8.2. For environmental exposure controls see subsection 8.2. For incompatible materials see subsection 10.5. Prevention of fire and explosion No special precautions required. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage rooms / facilities: In accordance with local and national regulations. Combined storage in storage rooms / facilities: In accordance with local and national regulations. For incompatible materials see subsection 10.5. Basic storage conditions Store in original container. Keep container tightly closed. For conditions to avoid see subsection 10.4. 7.3 Specific end use(s) No specific advice for end use available.
SECTION 8: Exposure controls/personal protection 8.1 Control parameters Workplace exposure limits Air limit values, if available: Ingredient(s)
UK - Long term value(s)
sodium hydroxide propane-1,2-diol
UK - Short term value(s) 2 mg/m3
150 ppm total 450 ppm total particulate and vapour particulate and vapour 3 474 mg/m total 1422 mg/m3 total particulate and vapour particulate and vapour 10 mg/m3 particulate 30 mg/m3 particulate
Biological limit values, if available: Recommended monitoring procedures, if available: Additional exposure limits under the conditions of use, if available:
DNEL/DMEL and PNEC values Human exposure DNEL oral exposure - Consumer (mg/kg bw) Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate DNEL dermal exposure - Worker Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate DNEL dermal exposure - Consumer Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate
Short term - Local effects No data available No data available No data available No data available No data available
Short term - Systemic effects No data available No data available No data available No data available No data available
Long term - Local effects No data available No data available No data available No data available No data available
Long term - Systemic effects No data available No data available No data available 85 No data available
Short term - Local effects 2% No data available No data available No data available No data available
Short term - Systemic effects (mg/kg bw) No data available No data available No data available No data available No data available
Long term - Local effects No data available No data available No data available No data available No data available
Long term - Systemic effects (mg/kg bw) No data available No data available No data available No data available No data available
Short term - Local effects 2% No data available No data available No data available No data available
Short term - Systemic effects (mg/kg bw) No data available No data available No data available No data available No data available
Long term - Local effects No data available No data available No data available No data available No data available
Long term - Systemic effects (mg/kg bw) No data available No data available No data available 213 No data available
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SAFETY DATA SHEET Powergel VG1
DNEL inhalatory exposure - Worker (mg/m3) Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate DNEL inhalatory exposure - Consumer (mg/m3) Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate
Short term - Local effects No data available No data available No data available No data available No data available
Short term - Systemic effects No data available No data available No data available No data available No data available
Long term - Local effects 1 No data available No data available 10 No data available
Long term - Systemic effects No data available No data available No data available 168 No data available
Short term - Local effects No data available No data available No data available No data available No data available
Short term - Systemic effects No data available No data available No data available No data available No data available
Long term - Local effects 1 No data available No data available 10 No data available
Long term - Systemic effects No data available No data available No data available 50 No data available
Surface water, fresh Surface water, marine (mg/l) (mg/l) No data available No data available No data available No data available No data available No data available 260 26 No data available No data available
Intermittent (mg/l) No data available No data available No data available 183 No data available
Sewage treatment plant (mg/l) No data available No data available No data available 20000 No data available
Soil (mg/kg)
Air (mg/m3)
No data available No data available No data available 50 No data available
No data available No data available No data available No data available No data available
Environmental exposure Environmental exposure - PNEC Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate Environmental exposure - PNEC, continued Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate
Sediment, freshwater (mg/kg) No data available No data available No data available 572 No data available
Sediment, marine (mg/kg) No data available No data available No data available 57.2 No data available
8.2 Exposure controls General health and safety measures Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Take off immediately all contaminated clothing. Wash hands before breaks and at the end of workday. Avoid contact with skin and eyes. The following information applies for the uses indicated in subsection 1.2. If available, please refer to the product information sheet for application and handling instructions. Normal use conditions are assumed for this section. Recommended safety measures for handling the undiluted product: Appropriate engineering controls:
Appropriate organisational controls: Personal protective equipment Eye / face protection: Hand protection:
If the product is diluted by using specific dosing systems with no risk of splashes or direct skin contact, the personal protection equipment as described in this section is not required. Where possible: use in automated/closed system and cover open containers. Transport over pipes. Filling with automatic systems. Use tools for manual handling of product. Avoid direct contact and/or splashes where possible. Train personnel.
Safety glasses or goggles (EN 166). Chemical-resistant protective gloves (EN 374) Verify instructions regarding permeability and breakthrough time, as provided by the gloves supplier Consider specific local use conditions, such as risk of splashes, cuts, contact time and temperature Suggested gloves for prolonged contact: Material: butyl rubber Penetration time: >= 480 min Material thickness: >= 0.7 mm Suggested gloves for protection against splashes: Material: nitrile rubber Penetration time: >= 30 min Material thickness: >= 0.4 mm
Body protection: Respiratory protection:
In consultation with the supplier of protective gloves a different type providing similar protection may be chosen Wear chemical-resistant clothing and boots in case direct dermal exposure and/or splashes may occur. No special requirements under normal use conditions Page 4 / 12
SAFETY DATA SHEET Powergel VG1
Environmental exposure controls:
Should not reach sewage water or drainage ditch undiluted or unneutralised.
Recommended safety measures for handling the diluted product: Recommended maximum concentration (%): 10 Appropriate engineering controls: Appropriate organisational controls: Personal protective equipment . Eye / face protection: Hand protection:
Ensure that foam equipment does not generate respirable particles. Avoid direct contact and/or splashes where possible. Train personnel.
Safety glasses or goggles (EN 166) are always recommended for foam applications. Chemical-resistant protective gloves (EN 374) are always recommended for foam applications Verify instructions regarding permeability and breakthrough time, as provided by the gloves supplier Consider specific local use conditions, such as risk of splashes, cuts, contact time and temperature Suggested gloves for prolonged contact: Material: butyl rubber Penetration time: >= 480 min Material thickness: >= 0.7 mm
Body protection: Respiratory protection:
In consultation with the supplier of protective gloves a different type providing similar protection may be chosen No special requirements under normal use conditions. No special requirements under normal use conditions
Environmental exposure controls:
No special requirements under normal use conditions.
SECTION 9: Physical and chemical properties 9.1 Information on basic physical and chemical properties Liquid Physical State: Clear Pale Brown Colour Product specific Odour > 12 (neat) pH: Not determined Boiling point/range (°C): Not applicable. Flash point (°C): Not flammable. Flammability 1.22 g/cm³ (20°C) Specific gravity: Solubility in / Miscibility with Water: Fully miscible Not explosive. Explosive properties Not oxidising. Oxidising properties: 9.2 Other information No other relevant information available
SECTION 10: Stability and reactivity 10.1 Reactivity No reactivity hazards known under normal storage and use conditions. 10.2 Chemical stability Stable under normal storage and use conditions. 10.3 Possibility of hazardous reactions No hazardous reactions known under normal storage and use conditions. 10.4 Conditions to avoid None known under normal storage and use conditions. 10.5 Incompatible materials Reacts with acids. 10.6 Hazardous decomposition products None known under normal storage and use conditions.
SECTION 11: Toxicological information 11.1 Information on toxicological effects Mixtures No test data is available on the mixture Page 5 / 12
SAFETY DATA SHEET Powergel VG1
Substance data, where relevant and available, are listed below. Acute toxicity Acute oral toxicity Ingredient(s)
Endpoint
sodium hydroxide
LD
50
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate
LD
propane-1,2-diol
LD
50 50
alkyl alcohol ethoxylate
Value (mg/kg) 1350
Species
Method
Exposure time (h)
Rat
Method not given
No data available > 2000
Rat
OECD 401 (EU B.1)
> 22000
Rat
Method not given
Species
Method
No data available
Acute dermal toxicity Ingredient(s)
Endpoint
sodium hydroxide
LD
50
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate
LD
propane-1,2-diol
LD
50 50
alkyl alcohol ethoxylate
Value (mg/kg) 1350
Exposure time (h)
Rabbit
Method not given
No data available > 2000
Rat
OECD 402 (EU B.3)
> 2000
Rabbit
Method not given
Species
Method
Mouse
Method not given
No data available
Acute inhalative toxicity Ingredient(s)
Endpoint
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
LC
50
sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate
Value (mg/l) 4800 No data available No data available No data available No data available
Exposure time (h) 1
Irritation and corrosivity Skin irritation and corrosivity Ingredient(s) sodium hydroxide
Result Corrosive
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
Irritant
Species Rabbit
Method Method not given
Exposure time
Method not given
sodium alkylethersulphate
Irritant
Rabbit
OECD 404 (EU B.4)
propane-1,2-diol
Not irritant
Rabbit
OECD 404 (EU B.4)
alkyl alcohol ethoxylate
No data available
Ingredient(s) sodium hydroxide
Result Corrosive
Species Rabbit
Method Method not given
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
Severe damage
sodium alkylethersulphate
Severe damage
Rabbit
OECD 405 (EU B.5)
propane-1,2-diol
Not corrosive or irritant No data available
Rabbit
OECD 405 (EU B.5)
Result No data available
Species
Method
Eye irritation and corrosivity
alkyl alcohol ethoxylate Respiratory tract irritation and corrosivity Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
No data available
sodium alkylethersulphate
No data available
propane-1,2-diol
No data available
alkyl alcohol ethoxylate
No data available
Exposure time
Exposure time
Sensitisation Sensitisation by skin contact Ingredient(s) sodium hydroxide
Result Not sensitising
Species
Method Exposure time (h) Human repeated patch test
Page 6 / 12
SAFETY DATA SHEET Powergel VG1 ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
No data available
sodium alkylethersulphate
Not sensitising
Guinea pig
propane-1,2-diol
Not sensitising
Guinea pig
alkyl alcohol ethoxylate
No data available
Ingredient(s) sodium hydroxide
Result No data available
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
No data available
sodium alkylethersulphate
No data available
propane-1,2-diol
No data available
alkyl alcohol ethoxylate
No data available
OECD 406 (EU B.6) / GPMT Read across OECD 406 (EU B.6) / GPMT
Sensitisation by inhalation Species
Method
Exposure time
Repeated dose toxicity Sub-acute or sub-chronic oral toxicity Ingredient(s)
Endpoint
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate
NOAEL
propane-1,2-diol
Sub-chronic dermal toxicity Ingredient(s)
Endpoint
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate
NOEL
propane-1,2-diol
Sub-chronic inhalation toxicity Ingredient(s)
Endpoint
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate
Endpoint
Method
Exposure Specific effects and organs time (days) affected
Method not given
Value (mg/kg bw/d) No data available No data available > 12.5
Species
Method
Exposure Specific effects and organs time (days) affected
Method not given
No data available No data available
alkyl alcohol ethoxylate
Exposure route
Species
No data available No data available
alkyl alcohol ethoxylate
Chronic toxicity Ingredient(s)
Value (mg/kg bw/d) No data available No data available 50
Value (mg/kg bw/d) No data available No data available
Value (mg/kg bw/d) No data available No data available No data available No data available No data available
Species
Method
Species
Exposure time
Method
Exposure Specific effects and organs time (days) affected
Specific effects and organs affected
Remark
No data available No data available No data available
CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)
Page 7 / 12
SAFETY DATA SHEET Powergel VG1 Mixture data: Based on available data, the classification criteria are not met. Substance data, where relevant and available Carcinogenicity Ingredient(s) sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate Mutagenicity Ingredient(s)
Effect No evidence for carcinogenicity, weight-of-evidence No data available
No evidence for carcinogenicity, negative test results No evidence for carcinogenicity, negative test results No data available
Method Result (in-vivo) (in-vitro) sodium hydroxide No evidence for mutagenicity, negative test results DNA repair test No evidence for mutagenicity, negative test results on rat hepatocytes OECD 473 ethanol, 2,2'-iminobis-, No data available No data available N-tallow alkyl derivs., N-oxides sodium No evidence for mutagenicity, negative test results OECD 476 No evidence for mutagenicity, negative test results alkylethersulphate (Chinese Hamster Ovary) propane-1,2-diol No evidence for mutagenicity, negative test results Method not No data available given alkyl alcohol ethoxylate No data available No data available
Toxicity for reproduction Ingredient(s)
Result (in-vitro)
Endpoint
Specific effect
sodium hydroxide
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate
Value (mg/kg bw/d) No data available
Species
Method
Exposure time
Rat
OECD 416, (EU B.35), oral
Method (in-vivo) OECD 474 (EU B.12) OECD 475 (EU B.11)
Remarks and other effects reported No evidence for developmental toxicity No evidence for reproductive toxicity
No data available NOAEL
Developmental toxicity
propane-1,2-diol
86.6
No data available No data available
alkyl alcohol ethoxylate
No known significant effects or critical hazards No evidence for reproductive toxicity
Potential adverse health effects and symptoms Effects and symptoms related to the product, if any, are listed in subsection 4.2.
SECTION 12: Ecological information 12.1 Toxicity Mixtures No test data is available on the mixture. Substance data, where relevant and available, are listed below Aquatic short-term toxicity Aquatic short-term toxicity - fish Ingredient(s)
Endpoint
sodium hydroxide
LC
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
LC
sodium alkylethersulphate
LC
propane-1,2-diol
LC
alkyl alcohol ethoxylate
50
50
50
50
Value (mg/l) 35 > 0.1 - 1 1 - 10 40613
Species
Method
Various Method not given species Brachydanio Method not given rerio Brachydanio OECD 203, semi-static rerio Oncorhynchus Method not given mykiss
Exposure time (h) 96 96 96 96
No data available
Aquatic short-term toxicity - crustacea
Page 8 / 12
SAFETY DATA SHEET Powergel VG1 Ingredient(s)
Endpoint
sodium hydroxide
EC
Value (mg/l) 40.4
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
EC
> 0.1 - 1
EC 50 EC
1 - 10 > 100 No data available
Endpoint
Value (mg/l) 22
50
50
sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate
50
Aquatic short-term toxicity - algae Ingredient(s) sodium hydroxide
EC
50
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol
No data available 7.5 24200
EC 50 EC 50
alkyl alcohol ethoxylate
Species
Method
Ceriodaphnia sp. Daphnia magna Straus Daphnia Daphnia
Method not given
Exposure time (h) 48
Method not given
48
OECD 202, static Method not given
48 48
Species
Method
Photobacteriu m phosphoreum
Method not given
Exposure time (h) 0.25
Not specified Desmodesmus subspicatus
DIN 38412, Part 9 OECD 201
72 72
No data available
Aquatic short-term toxicity - marine species Ingredient(s)
Endpoint
Value (mg/l) No data available No data available No data available No data available No data available
Species
Method
Exposure time (days)
Endpoint
Inoculum
Method
Exposure time
Method not given
0.5 hour(s)
Pseudomonas putida
Method not given
18 hour(s)
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol alkyl alcohol ethoxylate
Impact on sewage plants - toxicity to bacteria Ingredient(s)
sodium alkylethersulphate
EC
Value (mg/l) No data available No data available 300 - 500
propane-1,2-diol
EC
> 20000
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides 10 0
alkyl alcohol ethoxylate
No data available
Aquatic long-term toxicity Aquatic long-term toxicity - fish Ingredient(s)
Endpoint
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate
NOEC
propane-1,2-diol
Species
Method
Exposure time
Not specified
Method not given
365 day(s)
Species
Method
Exposure time
Daphnia sp.
Method not given Method not given
21 day(s)
Effects observed
No data available No data available
alkyl alcohol ethoxylate
Aquatic long-term toxicity - crustacea Ingredient(s)
Value (mg/l) No data available No data available 0.1 - 0.13
Endpoint
sodium alkylethersulphate
NOEC
Value (mg/l) No data available No data available 0.18 - 0.72
propane-1,2-diol
NOEC
13020
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
Ceriodaphnia dubia
Effects observed
7 day(s)
Page 9 / 12
SAFETY DATA SHEET Powergel VG1 alkyl alcohol ethoxylate
No data available
Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available: Ingredient(s) Endpoint Value Species (mg/kg dw sediment) sodium alkylethersulphate NOEC 0.72 - 0.9
Method
Exposure time (days)
Method not given
3
Effects observed
Terrestrial toxicity Terrestrial toxicity - soil invertebrates, including earthworms, if available: Terrestrial toxicity - plants, if available: Terrestrial toxicity - birds, if available: Terrestrial toxicity - beneficial insects, if available: Terrestrial toxicity - soil bacteria, if available:
12.2 Persistence and degradability Abiotic degradation Abiotic degradation - photodegradation in air, if available: Ingredient(s) Half-life time sodium hydroxide 13 second(s)
Method Method not given
Evaluation Rapidly photodegradable
Remark
Abiotic degradation - hydrolysis, if available: Abiotic degradation - other processes, if available:
Biodegradation Ready biodegradability - aerobic conditions Ingredient(s)
Inoculum
Analytical method
DT50
Method
sodium hydroxide ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides
Oxygen depletion
sodium alkylethersulphate propane-1,2-diol
Evaluation
> 60%
OECD 301D
Not applicable (inorganic substance) Readily biodegradable
> 60 % in 28 day(s) > 70 % in 28 day(s)
OECD 301B
Readily biodegradable
OECD 301A
Readily biodegradable
alkyl alcohol ethoxylate
No data available
Ready biodegradability - anaerobic and marine conditions, if available: Degradation in relevant environmental compartments, if available:
The surfactant(s) contained in this preparation complies(comply) with the biodegradability criteria as laid down in Regulation (EC) No. 648/2004 on detergents. Data to support this assertion are held at the disposal of the competent authorities of the Member States and will be made available to them, at their direct request or at the request of a detergent manufacturer. 12.3 Bioaccumulative potential Partition coefficient n-octanol/water (log Kow) Ingredient(s) Value sodium hydroxide No data available ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate
No data available
propane-1,2-diol
-1.07
alkyl alcohol ethoxylate
No data available
Method
0.95 - 3.9
Bioconcentration factor (BCF) Ingredient(s) Value sodium hydroxide No data available ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides sodium alkylethersulphate propane-1,2-diol
No data available
alkyl alcohol ethoxylate
No data available
Species
Evaluation Not relevant, does not bioaccumulate No bioaccumulation expected
Remark
Low potential for bioaccumulation Method not given
Method
No bioaccumulation expected
Evaluation
Remark
No data available No data available
Page 10 / 12
SAFETY DATA SHEET Powergel VG1
12.4 Mobility in soil Adsorption/Desorption to soil or sediment Ingredient(s)
sodium hydroxide
Adsorption coefficient Log Koc No data available
Desorption coefficient Log Koc(des)
Method
Soil/sediment type
Evaluation
Mobile in soil
ethanol, 2,2'-iminobis-, N-tallow alkyl derivs., N-oxides No data available sodium alkylethersulphate
No data available
propane-1,2-diol
No data available
alkyl alcohol ethoxylate
No data available
12.5 Results of PBT and vPvB assessment Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section 3. 12.6 Other adverse effects No other adverse effects known.
SECTION 13: Disposal considerations 13.1 Waste treatment methods Waste from residues / unused products Dispose of in compliance with all Federal, state, provincial, and local laws and regulations. 20 01 15* - alkalines. European Waste Catalogue: Empty packaging Recommendation: Suitable cleaning agents
Dispose of observing national or local regulations. Water, if necessary with cleaning agent.
SECTION 14: Transport information
ADR, RID, ADN, IMO/IMDG, ICAO/IATA 14.1 UN number: 1824 14.2 UN proper shipping name: Sodium hydroxide solution 14.3 Transport hazard class(es): Class:8 Label(s):8 14.4 Packing group: II 14.5 Environmental hazards: Environmentally hazardous:No Marine pollutant No 14.6 Special precautions for user: None known. 14.7 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code: The product is not transported in bulk tankers. Other relevant information: ADR Classification Code C5 Tunnel restriction code E Hazard identification number: 80 IMO/IMDG EmS F-A, S-B The product has been classified, labelled and packaged in accordance with the requirements of ADR and the provisions of the IMDG Code. Transport regulations include special provisions for certain classes of dangerous goods packed in limited quantities.
SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Ingredients according to EC Detergents Regulation 648/2004 anionic surfactants, non-ionic surfactants
< 5%
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SAFETY DATA SHEET Powergel VG1 15.2 Chemical safety assessment A chemical safety assessment has not been carried out on the mixture
SECTION 16: Other information The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product features and does not establish a legally binding contract MSDS code: MSDS1627
Version 06
Revision: 2012-10-08
Reason for revision: Overall design adjusted in accordance with Regulation (EC) No 1907/2006, Annex II Full text of the R, H and EUH phrases mentioned in section 3 •R35-Causessever ebur ns. •R50-Ver yt oxi ct oaquat i cor gani sms. •R41-Ri skofser i ousdamaget oey es. •R38-I r r i t at i ngt oski n. •H314-Causessever eski nbur nsandey edamage. •H315-Causesski ni r r i t at i on. •H318-Causesser i ousey edamage. •H400-Ver yt oxi ct oaquat i cl i f e.
Abbreviations and acronyms: •AI SE-Thei nt er nat i onalAssoci at i onf orSoaps,Det er gent sandMai nt enancePr oduct s •DNEL-Der i vedNoEf f ectLi mi t •EUH-CLPSpeci f i chazar dst at ement •PBT-Per si st ent ,Bi oaccumul at i veandToxi c •PNEC-Pr edi ct edNoEf f ectConcent r at i on •REACHnumber-REACHr egi st r at i onnumber ,wi t houtsuppl i erspeci f i cpar t •vPvB-ver yPer si st entandver yBi oaccumul at i ve
End of Safety Data Sheet
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