Signum

Safety data sheet Page: 1/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015

SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier

SIGNUM 1.2. Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: crop protection product, fungicide

1.3. Details of the supplier of the safety data sheet Company: BASF SE 67056 Ludwigshafen GERMANY

Telephone: +44 161 485-6222 E-mail address: product-safety-north@basf.com

1.4. Emergency telephone number International emergency number: Telephone: +49 180 2273-112

SECTION 2: Hazards Identification 2.1. Classification of the substance or mixture According to Regulation (EC) No 1272/2008 [CLP] Acute Tox. 4 (oral) Aquatic Acute 1 Aquatic Chronic 1

Contact address: BASF plc PO Box 4, Earl Road, Cheadle Hulme, Cheadle, Cheshire SK8 6QG, UNITED KINGDOM

Page: 2/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 For the classifications not written out in full in this section the full text can be found in section 16.

2.2. Label elements Globally Harmonized System (GHS) in accordance with UK regulations.

Pictogram:

Signal Word: Warning Hazard Statement: H302 H400 H410 EUH401

Harmful if swallowed.

Very toxic to aquatic life.

Very toxic to aquatic life with long lasting effects.

To avoid risks to human health and the environment, comply with the instructions for use.

Precautionary Statement: P264 Wash with plenty of water and soap thoroughly after handling.

P270 Do not eat, drink or smoke when using this product.

P301 + P312 IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

Precautionary Statements (Response): P330 Rinse mouth.

P391 Collect spillage.

Precautionary Statements (Disposal): P501 Dispose of contents/container to a licensed hazardous-waste disposal contractor or collection site except for empty clean containers which can be disposed of as non-hazardous waste.

2.3. Other hazards According to Regulation (EC) No 1272/2008 [CLP] See section 12 - Results of PBT and vPvB assessment.

If applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture.

Page: 3/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015

SECTION 3: Composition/Information on Ingredients 3.1. Substances Not applicable

3.2. Mixtures Chemical nature crop protection product, fungicide, water dispersible granules Hazardous ingredients (GHS) according to Regulation (EC) No. 1272/2008 3-Pyridinecarboxamide, 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)Content (W/W): 26.7 % Aquatic Chronic 2 CAS Number: 188425-85-6 H411

pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3-yloxymethyl]phenyl}(Nmethoxy)carbamate Content (W/W): 6.7 % Acute Tox. 3 (Inhalation - mist) CAS Number: 175013-18-0 Skin Corr./Irrit. 2 INDEX-Number: 613-272-00-6 STOT SE 3 (irr. to respiratory syst.)

Aquatic Acute 1 Aquatic Chronic 1 M-factor acute: 100 M-factor chronic: 100 H315, H331, H335, H400, H410

Sodium diisobutylnaphthalenesulphonate Content (W/W): < 5 % CAS Number: 27213-90-7 EC-Number: 248-326-4

Ammonium sulphate

Acute Tox. 4 (Inhalation - dust) Acute Tox. 4 (oral) Skin Corr./Irrit. 2 Eye Dam./Irrit. 1 STOT SE 3 (irr. to respiratory syst.)

Aquatic Chronic 3 H318, H315, H332, H302, H335, H412

Page: 4/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Content (W/W): < 15 % CAS Number: 7783-20-2 EC-Number: 231-984-1 REACH registration number: 012119455044-46

Silica gel, precipitated, crystalline free Content (W/W): < 10 % CAS Number: 112926-00-8 REACH registration number: 012119379499-16

Sodium sulphate Content (W/W): < 5 % CAS Number: 7757-82-6 EC-Number: 231-820-9 REACH registration number: 012119519226-43

For the classifications not written out in full in this section, including the hazard classes and the hazard statements, the full text is listed in section 16.

SECTION 4: First-Aid Measures 4.1. Description of first aid measures Show container, label and/or safety data sheet to physician.

If inhaled: Keep patient calm, remove to fresh air.

On skin contact: Wash thoroughly with soap and water.

On contact with eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open.

On ingestion: Rinse mouth and then drink plenty of water.

4.2. Most important symptoms and effects, both acute and delayed Symptoms: No significant reaction of the human body to the product known.

4.3. Indication of any immediate medical attention and special treatment needed Treatment: Symptomatic treatment (decontamination, vital functions).

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Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015

SECTION 5: Fire-Fighting Measures 5.1. Extinguishing media Suitable extinguishing media: dry powder, foam, water spray Unsuitable extinguishing media for safety reasons: carbon dioxide

5.2. Special hazards arising from the substance or mixture carbon monoxide, hydrogen chloride, Carbon dioxide, nitrogen oxides, organochloric compounds The substances/groups of substances mentioned can be released in case of fire.

5.3. Advice for fire-fighters Special protective equipment: Wear self-contained breathing apparatus and chemical-protective clothing.

Further information: Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Dispose of fire debris and contaminated extinguishing water in accordance with official regulations. In case of fire and/or explosion do not breathe fumes. Keep containers cool by spraying with water if exposed to fire.

SECTION 6: Accidental Release Measures 6.1. Personal precautions, protective equipment and emergency procedures Avoid dust formation. Use personal protective clothing. Avoid contact with the skin, eyes and clothing.

6.2. Environmental precautions Do not allow contamination of public drains or surface or ground waters. Inform local water plc if spillage enters drains and the Environment Agency (England & Wales), the Scottish Environmental Protection Agency (Scotland), or the Environment and Heritage Service (Northern Ireland) if it enters surface or ground waters. Keep people and animals away.

6.3. Methods and material for containment and cleaning up For small amounts: Contain with dust binding material and dispose of.

For large amounts: Sweep/shovel up.

Avoid raising dust. Dispose of absorbed material in accordance with regulations. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations.

6.4. Reference to other sections Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

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Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015

SECTION 7: Handling and Storage 7.1. Precautions for safe handling No special measures necessary if stored and handled correctly. Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion: Avoid dust formation. Dust can form an explosive mixture with air. Prevent electrostatic charge sources of ignition should be kept well clear - fire extinguishers should be kept handy.

7.2. Conditions for safe storage, including any incompatibilities Segregate from foods and animal feeds.

Further information on storage conditions: Keep away from heat. Protect against moisture. Protect from direct sunlight.

Protect from temperatures above: 40 째C Changes in the properties of the product may occur if substance/product is stored above indicated temperature for extended periods of time.

7.3. Specific end use(s) For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

SECTION 8: Exposure Controls/Personal Protection 8.1. Control parameters Components with occupational exposure limits none Refer to the current edition of HSE Guidance Note EH40 Occupational Exposure Limits (United Kingdom). For normal use and handling refer to the product label/leaflet. In all other cases the following apply.

8.2. Exposure controls Personal protective equipment Respiratory protection: Respiratory protection not required.

Hand protection: Suitable chemical resistant safety gloves (EN 374) also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374): E.g. nitrile rubber (0.4 mm), chloroprene rubber (0.5 mm), butyl rubber (0.7 mm) etc.

Eye protection: Safety glasses with side-shields (frame goggles) (e.g. EN 166)

Page: 7/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Body protection: Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures The statements on personal protective equipment in the instructions for use apply when handling crop-protection agents in final-consumer packing. Wearing of closed work clothing is recommended.

Store work clothing separately. Keep away from food, drink and animal feeding stuffs.

SECTION 9: Physical and Chemical Properties 9.1. Information on basic physical and chemical properties Form: Colour: Odour: Odour threshold:

pH value:

Melting temperature:

solid, granules brown smoky Not determined due to potential health hazard by inhalation. approx. 4 - 6 (1 %(m), 20 째C) (as suspension) approx. 142 - 144 째C The data given are those of the active ingredient.

(OECD Guideline 102)

Boiling point: The product is a non-volatile solid.

Flash point: not applicable Evaporation rate: Flammability:

not applicable No dangerous quantities of (Directive 92/69/EEC, A.12) flammable gases will be produced by contact with water.

Lower explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use.

Page: 8/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Upper explosion limit: As a result of our experience with this product and our knowledge of its composition we do not expect any hazard as long as the product is used appropriately and in accordance with the intended use.

Vapour pressure: The product has not been tested.

Density: approx. 1.57 g/cm3 (OECD Guideline 109) (20 째C) Relative vapour density (air): not applicable Solubility in water: dispersible Partitioning coefficient n-octanol/water (log Kow): not applicable Self ignition: Temperature: 246 째C (Method: Directive 92/69/EEC, No self ignition was observed up to A.16) the specified temperature.

Thermal decomposition: 150 째C, 130 kJ/kg, (DSC (OECD 113)) (onset temperature) 335 째C, 130 kJ/kg, (DSC (OECD 113)) (onset temperature) Viscosity, dynamic: not applicable, the product is a solid Explosion hazard: not explosive (Directive 92/69/EEC, A.14) Fire promoting properties: not fire-propagating (Directive 92/69/EEC, A.17)

9.2. Other information Bulk density:

656 - 754 kg/m3

SECTION 10: Stability and Reactivity 10.1. Reactivity No hazardous reactions if stored and handled as prescribed/indicated.

10.2. Chemical stability The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions No hazardous reactions if stored and handled as prescribed/indicated.

10.4. Conditions to avoid See MSDS section 7 - Handling and storage.

10.5. Incompatible materials

Page: 9/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Substances to avoid: strong acids, strong bases, strong oxidizing agents

10.6. Hazardous decomposition products Hazardous decomposition products: No hazardous decomposition products if stored and handled as prescribed/indicated.

SECTION 11: Toxicological Information 11.1. Information on toxicological effects Acute toxicity Assessment of acute toxicity: Virtually nontoxic after a single ingestion. Virtually nontoxic after a single skin contact. Virtually nontoxic by inhalation. The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

Experimental/calculated data: LD50 rat (oral): > 2,000 mg/kg LC50 rat (by inhalation): > 5.6 mg/l 4 h The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

LD50 rat (dermal): > 2,000 mg/kg The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

Irritation Assessment of irritating effects: Not irritating to the skin. Not irritating to the eyes.

Experimental/calculated data: Skin corrosion/irritation rabbit: non-irritant (OECD Guideline 404) Serious eye damage/irritation rabbit: non-irritant (OECD Guideline 405) Respiratory/Skin sensitization Assessment of sensitization: There is no evidence of a skin-sensitizing potential.

Experimental/calculated data: modified Buehler test guinea pig: Non-sensitizing.

Page: 10/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Germ cell mutagenicity Assessment of mutagenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Mutagenicity tests revealed no genotoxic potential.

Carcinogenicity Assessment of carcinogenicity: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: 3-Pyridinecarboxamide, 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)Assessment of carcinogenicity: In long-term studies in rats the substance induced thyroid tumors. The effect is caused by an animal specific mechanism that has no human counter part. In long-term studies in mice in which the substance was given by feed, a carcinogenic effect was not observed.

---------------------------------Reproductive toxicity Assessment of reproduction toxicity: The product has not been tested. The statement has been derived from the properties of the individual components. The results of animal studies gave no indication of a fertility impairing effect.

Developmental toxicity Assessment of teratogenicity: The product has not been tested. The statement has been derived from the properties of the individual components. Animal studies gave no indication of a developmental toxic effect at doses that were not toxic to the parental animals.

Specific target organ toxicity (single exposure) Assessment of STOT single: Based on the available information there is no specific target organ toxicity to be expected after a single exposure.

Remarks: The product has not been tested. The statement has been derived from the properties of the individual components.

Repeated dose toxicity and Specific target organ toxicity (repeated exposure) Assessment of repeated dose toxicity: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: 3-Pyridinecarboxamide, 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)Assessment of repeated dose toxicity: Adaptive effects were observed after repeated exposure in animal studies.

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Page: 11/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Aspiration hazard No aspiration hazard expected.

Other relevant toxicity information Misuse can be harmful to health.

SECTION 12: Ecological Information 12.1. Toxicity Assessment of aquatic toxicity: Very toxic to aquatic organisms. May cause long-term adverse effects in the aquatic environment.

The product has not been tested. The statement has been derived from substances/products of a similar structure or composition.

Toxicity to fish: LC50 (96 h) 0.088 mg/l, Oncorhynchus mykiss Aquatic invertebrates: EC50 (48 h) approx. 0.24 mg/l, Daphnia magna (OECD Guideline 202, part 1) Aquatic plants: EC50 (72 h) 8.43 mg/l, Agmenellum quadruplicatum

12.2. Persistence and degradability Assessment biodegradation and elimination (H2O): The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: 3-Pyridinecarboxamide, 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).

Information on: pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3yloxymethyl]phenyl}(N-methoxy)carbamate Assessment biodegradation and elimination (H2O): Not readily biodegradable (by OECD criteria).

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12.3. Bioaccumulative potential Assessment bioaccumulation potential: The product has not been tested. The statement has been derived from the properties of the individual components.

Page: 12/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Information on: 3-Pyridinecarboxamide, 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)Bioaccumulation potential: Bioconcentration factor: 57 - 70 (28 d), Oncorhynchus mykiss Does not accumulate in organisms.

Information on: pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3yloxymethyl]phenyl}(N-methoxy)carbamate Bioaccumulation potential: Bioconcentration factor: 379 - 507, Oncorhynchus mykiss (OECD-Guideline 305) Accumulation in organisms is not to be expected.

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12.4. Mobility in soil Assessment transport between environmental compartments: Volatility: The product has not been tested. The statement has been derived from the properties of the individual components.

Information on: 3-Pyridinecarboxamide, 2-chloro-N-(4'-chloro[1,1'-biphenyl]-2-yl)Assessment transport between environmental compartments: Adsorption in soil: Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.

Information on: pyraclostrobin (ISO); methyl N-{2-[1-(4-chlorophenyl)-1H-pyrazol-3yloxymethyl]phenyl}(N-methoxy)carbamate Assessment transport between environmental compartments: Adsorption in soil: Following exposure to soil, adsorption to solid soil particles is probable, therefore contamination of groundwater is not expected.

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12.5. Results of PBT and vPvB assessment The product does not contain a substance fulfilling the PBT (persistent/bioaccumulative/toxic) criteria or the vPvB (very persistent/very bioaccumulative) criteria.

12.6. Other adverse effects The product does not contain substances that are listed in Regulation (EC) 1005/2009 on substances that deplete the ozone layer.

12.7. Additional information Other ecotoxicological advice: Do not discharge product into the environment without control.

SECTION 13: Disposal Considerations 13.1. Waste treatment methods

Page: 13/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Must be disposed of or incinerated in accordance with local regulations.

The UK Environmental Protection (Duty of Care) Regulations (EP) and amendments should be noted (United Kingdom).

This product and any uncleaned containers must be disposed of as hazardous waste in accordance with the 2005 Hazardous Waste Regulations and amendments (United Kingdom)

Contaminated packaging: Contaminated packaging should be emptied as far as possible and disposed of in the same manner as the substance/product.

SECTION 14: Transport Information Land transport ADR UN number UN proper shipping name:

UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BOSCALID, PYRACLOSTROBIN) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for Tunnel code: E user: RID UN number UN proper shipping name:

UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BOSCALID, PYRACLOSTROBIN) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for None known user:

Inland waterway transport ADN UN number UN proper shipping name:

UN3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BOSCALID, PYRACLOSTROBIN) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for None known user:

Page: 14/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 Transport in inland Not evaluated waterway vessel:

Sea transport IMDG UN number: UN proper shipping name:

UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BOSCALID, PYRACLOSTROBIN) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Marine pollutant: YES Special precautions for None known user:

Air transport IATA/ICAO UN number: UN proper shipping name:

UN 3077 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (contains BOSCALID, PYRACLOSTROBIN) Transport hazard class(es): 9, EHSM Packing group: III Environmental hazards: yes Special precautions for None known user:

14.1. UN number See corresponding entries for “UN number” for the respective regulations in the tables above.

14.2. UN proper shipping name See corresponding entries for “UN proper shipping name” for the respective regulations in the tables above.

14.3. Transport hazard class(es) See corresponding entries for “Transport hazard class(es)” for the respective regulations in the tables above.

14.4. Packing group See corresponding entries for “Packing group” for the respective regulations in the tables above.

14.5. Environmental hazards

Page: 15/16 BASF Safety data sheet according to Regulation (EC) No. 1907/2006 as amended from time to time.

Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 See corresponding entries for “Environmental hazards” for the respective regulations in the tables above.

14.6. Special precautions for user See corresponding entries for “Special precautions for user” for the respective regulations in the tables above.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Regulation: Shipment approved: Pollution name: Pollution category: Ship Type:

Not evaluated Not evaluated Not evaluated Not evaluated Not evaluated

Further information This product is subject to the most recent edition of "The Carriage of Dangerous Goods and Use of Transportable Pressure Equipment Regulations" and their amendments (United Kingdom).

SECTION 15: Regulatory Information 15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture This product is classified under the European CLP Regulation.

The data should be considered when making any assessment under the Control of Substances Hazardous to Health Regulations (COSHH), and related guidance, for example, 'COSHH Essentials' (United Kingdom).

This product may be subject to the Control of Major Accident Hazards Regulations (COMAH), and amendments if specific threshold tonnages are exceeded (United Kingdom).

15.2. Chemical Safety Assessment Advice on product handling can be found in sections 7 and 8 of this safety data sheet.

SECTION 16: Other Information For proper and safe use of this product, please refer to the approval conditions laid down on the product label.

Full text of the classifications, including the hazard classes and the hazard statements, if mentioned in section 2 or 3: Acute Tox. Acute toxicity Aquatic Acute Hazardous to the aquatic environment - acute Aquatic Chronic Hazardous to the aquatic environment - chronic Skin Corr./Irrit.

Skin corrosion/irritation

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Date / Revised: 14.07.2015 Version: 6.0 Product: SIGNUM (ID no. 30266621/SDS_CPA_GB/EN) Date of print 15.07.2015 STOT SE Specific target organ toxicity â&#x20AC;&#x201D; single exposure Eye Dam./Irrit.

Serious eye damage/eye irritation H411 Toxic to aquatic life with long lasting effects.

H315 Causes skin irritation.

H331 Toxic if inhaled.

H335 May cause respiratory irritation.

H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects.

H318 Causes serious eye damage.

H332 Harmful if inhaled.

H302 Harmful if swallowed.

H412 Harmful to aquatic life with long lasting effects.

If you have any queries relating to this MSDS, it's contents or any other product safety related questions, please write to the following e-mail address: product-safety-north@basf.com The data contained in this safety data sheet are based on our current knowledge and experience and describe the product only with regard to safety requirements. The data do not describe the product's properties (product specification). Neither should any agreed property nor the suitability of the product for any specific purpose be deduced from the data contained in the safety data sheet. It is the responsibility of the recipient of the product to ensure any proprietary rights and existing laws and legislation are observed.

Vertical lines in the left hand margin indicate an amendment from the previous version.