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STORMWATER ANNUAL REPORT JULY 2013 – JUNE 2014 September 30, 2014
IMPORTANT NOTE: This annual report has been prepared by the City of Mesa (City) in response to the conditions established by the Arizona Department of Environmental Quality’s (ADEQ) Municipal Separate Storm Sewer System (MS4) permit issued to the City, effective August 30, 2010 (herein referred to as the 2010 MS4 Permit). This report is designed to meet all the requirements established under Appendix B as provided in the 2010 MS4 Permit and is required to be submitted to the ADEQ on or before September 30th of each year. This report incorporates the requirements under the 2010 MS4 Permit for the previous reporting year, which also coincides with the City’s fiscal year. This document can be found on the ESD Server at the following location: I:\STORMWATER\Annual Reports\2013-2014 Annual Report\Document Text\2014-09 Stormwater Annual Report - Final.docx
TABLE OF CONTENTS PAGE 1.0
GENERAL INFORMATION ............................................................................... 1-1
2.0
ANNUAL REPORT CERTIFICATION ............................................................... 2-1
3.0
NARRATIVE SUMMARY OF STORMWATER PROGRAM ACTIVITIES ......... 3-1 3.1 PUBLIC EDUCATION & OUTREACH ....................................................... 3-1 3.1.1 General Public ................................................................................ 3-2 3.1.2 Business Sectors ............................................................................ 3-3 3.1.3 Additional Education & Outreach Activities ..................................... 3-4 3.2 PUBLIC INVOLVEMENT ........................................................................... 3-4 3.2.1 Environmental Hotline ..................................................................... 3-4 3.2.2 Stormwater Website ....................................................................... 3-5 3.2.3 Household Hazardous Waste Program .......................................... 3-5 3.3 NON-STORMWATER FLOWS TO THE CITY’S STORM SEWER SYSTEM.................................................................................................... 3-7 3.3.1 Non-Stormwater Flow Prevention Activities .................................... 3-7 3.3.2 Training Dates and Topics .............................................................. 3-8 3.3.3 Investigations .................................................................................. 3-8 3.4 MUNICIPAL FACILITIES ......................................................................... 3-10 3.4.1 Description & Status of Inventory.................................................. 3-11 3.4.2 Overview of Findings .................................................................... 3-11 3.4.3 Response Actions ......................................................................... 3-11 3.4.4 Facilities Covered under the Multi-Sector General Permit ............ 3-11 3.5 INVENTORIES, MAPS, AND MAP STUDIES ......................................... 3-11 3.5.1 Inventories .................................................................................... 3-11 3.5.2 Maps ............................................................................................. 3-12 3.5.3 Map Studies .................................................................................. 3-13 3.6 INDUSTRIAL FACILITIES ....................................................................... 3-13 3.6.1 Identification and Inventory of Private Commercial and Industrial Facilities ........................................................................ 3-14 3.6.1.1 Commercial Facilities ...................................................... 3-14 3.6.1.2 Industrial Facilities ........................................................... 3-14 3.6.2 Overview of Inspection Findings and Significant Findings ............ 3-15 3.6.2.1 Commercial Facilities Inspection & Prioritization ............. 3-15 3.6.2.2 Industrial Facilities Inspection & Prioritization.................. 3-16 3.6.3 Summary of Corrective and Enforcement Actions ........................ 3-17 3.6.3.1 Commercial Facility Corrective & Enforcement Actions... 3-17 3.6.3.2 Industrial Facility Corrective & Enforcement Actions ....... 3-18
PAGE 3.7 CONSTRUCTION PROGRAM ACTIVITIES ............................................ 3-19 3.7.1 Status of Inventory and Plan Review of Construction Operations .................................................................................... 3-19 3.7.1.1 Private Construction Projects .......................................... 3-20 3.7.1.2 City Projects .................................................................... 3-20 3.7.2 Overview of Inspection Findings and Significant Findings ............ 3-20 3.7.2.1 Private Construction Projects .......................................... 3-21 3.7.2.2 City Projects .................................................................... 3-22 3.7.3 Summary of Corrective and Enforcement Actions ........................ 3-23 3.7.3.1 Private Construction Projects .......................................... 3-23 3.7.3.2 City Projects .................................................................... 3-24 3.8 POST-CONSTRUCTION PROGRAM ACTIVITIES ................................. 3-25 3.8.1 New or Revised Post-Construction Controls ................................. 3-25 3.8.2 Overview of Post-Construction Inspection Program ..................... 3-25 3.8.3 Summary of Corrective and Enforcement Actions ........................ 3-26 3.9 DRY-WEATHER SCREENING................................................................ 3-26 3.9.1 Staff Training ................................................................................ 3-26 3.9.2 Outfall and Field Screening Point Inventory .................................. 3-27 3.9.3 Inspection Tracking System .......................................................... 3-27 3.9.4 Inspection and Screening Procedures and Significant Findings ... 3-27 3.10 ORDINANCES, RULES, & POLICIES ..................................................... 3-28 3.11 FISCAL EXPENDITURES ....................................................................... 3-28 4.0
STORMWATER PROGRAM NUMERIC SUMMARY ........................................ 4-1
5.0
EVALUATION OF THE STORMWATER PROGRAM ...................................... 5-1 5.1 PROGRAM PROGRESS ........................................................................... 5-1 5.2 PROGRAM SUCCESSES ......................................................................... 5-2 5.3 REDUCTION OF POLLUTANTS TO THE CITY’S STORM SEWER SYSTEM.................................................................................................... 5-2 5.3.1 Public Education & Outreach .......................................................... 5-2 5.3.2 Public Reporting ............................................................................. 5-2 5.3.3 Household Hazardous Waste Events ............................................. 5-3 5.3.4 Commercial & Industrial Facility Inspections................................... 5-3 5.3.5 Construction Site Inspections ......................................................... 5-3 5.4 REDUCTION OF POLLUTANTS FROM THE CITY’S STORM SEWER SYSTEM.................................................................................................... 5-4 5.4.1 Storm Sewer Systerm Infrastructure Maintenance ......................... 5-4 5.4.1.1 Street Sweeping ................................................................ 5-4 5.4.1.2 Storm Sewer Components ................................................ 5-4 5.4.1.3 Detention/Retention Basins ............................................... 5-4
PAGE 5.4.2 Post-Construction Requirements .................................................... 5-5 6.0
STORMWATER MANAGEMENT PROGRAM MODIFICATIONS .................... 6-1 6.1 ADDITION OF NEW CONTROL MEASURES .......................................... 6-1 6.2 ADDITION OF TEMPORARY CONTROL MEASURES ............................ 6-1 6.3 INCREASE OF EXISTING CONTROL MEASURES ................................. 6-1 6.4 REPLACEMENT OF EXISTING CONTROL MEASURES ........................ 6-1 6.5 FOURTH YEAR ANNUAL REPORT ......................................................... 6-1
7.0
MONITORING LOCATIONS ............................................................................. 7-1 7.1 AS-US60 ................................................................................................... 7-2 7.2 SS-US60 ................................................................................................... 7-2 7.3 54-EMF...................................................................................................... 7-2 7.4 UN-EMF .................................................................................................... 7-3 7.5 FF-ACES ................................................................................................... 7-3
8.0
STORM EVENT RECORDS .............................................................................. 8-1
9.0
SUMMARY OF MONITORING DATA ............................................................... 9-1
10.0
ASSESSMENT OF MONITORING DATA ....................................................... 10-1 10.1 SURFACE WATER QUALITY STANDARDS .......................................... 10-1 10.2 EXCEEDANCES OF SURFACE WATER QUALITY STANDARDS ........ 10-1 10.3 STORMWATER QUALITY EVALUATION - BY LOCATION ................... 10-2 10.3.1 Station AS-US60........................................................................... 10-2 10.3.2 Station SS-US60........................................................................... 10-2 10.3.3 Station 54-EMF ............................................................................. 10-3 10.3.4 Station UN-EMF............................................................................ 10-3 10.3.5 Station FF-ACES .......................................................................... 10-4 10.4 SWQS EXCEEDANCE INVESTIGATIONS ............................................. 10-4
11.0
ESTIMATE OF POLLUTANT LOADING ........................................................ 11-1 11.1 POLLUTANT LOADING MODELING, DATA ANALYSIS, AND CALCULATIONS ..................................................................................... 11-1 11.1.1 Event Mean Concentration ........................................................... 11-2 11.1.2 Rainfall Data Evaluation ............................................................... 11-2 11.1.3 Drainage Area Runoff Volumes .................................................... 11-3 11.1.3.1 Drainage Area Evaluation................................................ 11-3 11.1.3.2 Weighted Average Runoff Coefficient ............................. 11-4 11.1.4 Annual Pollutant Loading Estimate ............................................... 11-4
PAGE 11.2 COMPARISON OF POLLUTANT LOADING ESTIMATES ...................... 11-5 12.0
ANNUAL EXPENDITURES............................................................................. 12-1
13.0
ATTACHMENTS ............................................................................................. 13-1 13.1 DRAINAGE SYSTEM MAPS ................................................................... 13-1 13.2 LISTING OF OUTFALLS & FIELD SCREENING POINTS ...................... 13-1 13.3 LIST OF CHANGES TO OUTFALL & FIELD SCREENING POINTS ...... 13-1 13.4 STORMWATER MONITORING ANALYTICAL LABORATORY REPORTS ............................................................................................... 13-2 13.5 NEW OR REVISED STORMWATER MANAGEMENT ORDINANCES ... 13-2 13.6 NEW OR REVISED PUBLIC EDUCATION & OUTREACH DOCUMENTS ......................................................................................... 13-2 13.7 HOUSEHOLD HAZARDOUS WASTE EVENT REPORTS ..................... 13-2 13.8 UPDATED CITY FACILITY INVENTORY................................................ 13-2 13.9 ANNUAL EXPENDITURE REPORTS ..................................................... 13-2
ADDENDUM NO. 1 – PERMIT RE-APPLICATION, SEPTEMBER 2014 ADDENDUM NO. 2 – STORM WATER MANAGEMENT PLAN, SEPTEMBER 2014
ACRONYMS AND ABBREVIATIONS 2010 MS4 Permit – City of Mesa MS4 Stormwater Permit, AZS000004-2010 ADEQ – Arizona Department of Environmental Quality APP – Aquifer Protection Permit AZPDES - Arizona Pollutant Discharge Elimination System BMP – Best Management Practice(s) City – City of Mesa CGP – Construction General Permit FCDMC – Flood Control District of Maricopa County FOG – Fats, Oils, and Greases GRD – Grease Removal Device HHW – Household Hazardous Waste IDDE – Illicit Discharge Detection & Elimination LID – Low-Impact Development MS4 – Municipal Separate Storm Sewer System MSGP – Multi-Sector General Permit NAICS - North American Industry Classification System NOI - Notice of Intent NOT – Notice to Terminate PSA – Public Service Announcement SARA – Superfund Amendments and Reauthorization Act SIC – Standard Industrial Code Stormwater Code - Title 8, Chapter 5, of the Mesa City Code STORM – STormwater Outreach for Regional Municipalities SWMP – Storm Water Management Plan
SWPPP – Storm Water Pollution Prevention Plan SWQS – Surface Water Quality Standard TRI - Toxic Release Inventory USEPA – United States Environmental Protection Agency
1.0
GENERAL INFORMATION
A.
Name of Permittee: City of Mesa
B.
Permit Number:
AZS000004-2010
C.
Reporting Period:
July 1,
D.
Program Contact:
Scott Bouchie
Title:
Deputy Director, Environmental & Sustainability Division
Mailing Address:
P.O. Box 146
City:
Zip:
Fax: E.
Mesa
480-644-4774
2013
through
85211-1466 Email Address:
Certifying Official:
Christopher J. Brady
Title:
City Manager
Mailing Address:
P.O. Box 1466
City:
Zip:
Fax:
Mesa
480-644-2175
85211-1466 Email Address:
City of Mesa, Storm Water Annual Report
June 30,
Phone:
2014
480-644-4366
Scott.bouchie@mesaaz.gov
Phone:
480-644-2066
Chris.Brady@mesaaz.gov
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3.0
NARRATIVE SUMMARY OF STORMWATER PROGRAM ACTIVITIES
The 2010 MS4 Permit requires the City of Mesa (City) to provide a narrative describing the implementation, progress, and challenges associated with the stormwater program activities as provided in the following subsections. The permit also requires the City to explain any significant developments or changes to the number or type of activities or the priorities or procedures for specific management practices. 3.1 PUBLIC EDUCATION & OUTREACH The 2010 MS4 Permit requires the City to report outreach events, topics, number of people reached, number and type of materials distributed and the target groups in this Annual Report as it pertains to the City’s stormwater public education and outreach program. The City’s stormwater public education and outreach method is managed through the STormwater Outreach for Regional Municipality (STORM) organization. STORM is comprised of Phase I and Phase II MS4 operators in the greater Phoenix Metropolitan Area. STORM was founded in 2002 largely in response to the Phase II stormwater regulations and was spearheaded by the Phase I MS4 operators as a method of assisting all regulated MS4 operators in the development of their public education programs, among other things. As such, the City played a key role in the early years of the development of the STORM organization and continues to be a major participant and proud supporter to this day. The traditional approach to public stormwater education and outreach is for individual communities to work independently. STORM encourages a new perspective at a regional level to improve public outreach and education. Members meet monthly to discuss ideas, gather information, and share results of stormwater management tools, techniques, programs, and initiatives. The City realizes a great economic benefit from their membership investment. For a relatively small contribution, the City receives a significant return in public outreach and education, much more than the City would have gained working independently. Membership in STORM also provides increased buying power that helps achieve bulk pricing on storm water pollution awareness promotional items. Additionally, the ability to City of Mesa, Storm Water Annual Report
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cooperatively apply for grants and other financial assistance helps further the common goal of public education to reduce stormwater pollutants and ultimately improve the regional water quality. STORM uses a multimedia approach targeting audiences through radio, television, special events, and providing permit information to the general public and the regulated community. These approaches include, but are not limited to, radio and television public service announcements (PSAs), developing brochures and other handouts, and attending public events. Additionally, STORM has created a comprehensive website that includes the copies of outreach materials and PSAs which can be accessed at www.azstorm.org. 3.1.1 General Public The 2010 MS4 Permit requires the City to target at least one of the following groups during each permit year (August 30 through August 29th): 1. 2. 3. 4. 5.
General Public Residential Community Home Owners Home Owners Associations Schools
The 2010 MS4 Permit requires that at least one of the following topics be addressed for these target groups: •
Post-construction ordinances and long-term maintenance requirements for permanent stormwater controls
•
Stormwater runoff issues and residential stormwater management practices
•
Potential water quality impacts of application of pesticides, herbicides and fertilizer and control measures to minimize runoff of pollutants in stormwater
•
Potential impacts of animal waste on water quality and the need to clean up and properly dispose of pet waste to minimize runoff of pollutants in stormwater
•
Illicit discharges and illegal dumping, proper management of non-stormwater discharges, and to provide information on reporting spills, dumping, and illicit discharges
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•
Spill prevention, proper handling and disposal of toxic and hazardous materials, and measures to contain and minimize discharges to the storm sewer system
•
Installation of catch basin markers or stenciling of storm sewer inlets to minimize illicit discharges and illegal dumping to the storm sewer system
•
Proper management and disposal of used oil
STORM developed and ran a movie theater campaign between November 22, 2013 and January 2, 2014 (6 weeks) to correspond with the winter rain season. A new 15 second video advertisement targeting the general public in the topics of illicit discharges and stormwater quality was designed and produced and ran for 15 seconds prior to the start of the movie. The video was shown at seven AMC Theaters locations throughout the Phoenix metropolitan area, on 131 movie screens, averaging 5 movies per day. That attributes to 655 movies per day, 4,585 movies per week, and 27,510 movies over the 6 week campaign. Based upon historical movie admission rates, it is estimated that the campaign was shown to approximately 850,000 people. STORM expended $8,025 for the movie theater campaign. 3.1.2 Business Sectors The 2010 MS4 Permit also requires the City to target at least one of the following business sector groups during each permit year: 1. 2. 3. 4.
Development Community Construction Site Operators Targeted Sources Types of Businesses (industrial or commercial)
The 2010 MS4 Permit requires that at least one of the following topics be addressed for these target groups: •
Planning ordinances, engineering standards and grading and drainage design standards for stormwater management in new developments and significant redevelopments
•
Municipal stormwater requirements and stormwater management practices for construction sites
•
Illicit discharges and proper management of non-stormwater discharges
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•
Spill prevention, proper handling of toxic and hazardous materials, and measures to contain and minimize discharges to the storm sewer system
•
Proper management and disposal of used oil and other hazardous or toxic materials, including practices to minimize exposure of materials/wastes to rainfall and minimize contamination of stormwater runoff
•
Stormwater management practices, pollution prevention plans, and facility maintenance procedures
STORM was a sponsor of the Construction General Permit seminar conducted on April 8, 2014. The purpose of the seminar was to provide education and outreach associated with the AZPDES Construction General Permit, including updates on the 2013 CGP, Stormwater Pollution Prevention Plans, BMPs, local municipal requirements and networking opportunities. The Arizona Department of Transportation provided the seminar room at no charge. STORM contributed $500 towards supporting costs associated with the seminar. Approximately 141 people were in attendance at the seminar. Seminar details and presentations are posted on the STORM website. 3.1.3 Additional Education & Outreach Activities More information regarding the STORM organization’s public education and outreach program activities for the current reporting year can be found in the STORM Annual Report, FY 2011 available at the following address: http://www.azstorm.org/annualreports. 3.2 PUBLIC INVOLVEMENT The 2010 MS4 Permit requires the City to identify activities, number of people involved, number and type of materials distributed, if applicable and to describe a system for public reporting of spills, dumping, discharges, and related stormwater issues in this Annual Report as it pertains to the City’s public involvement stormwater program. 3.2.1 Environmental Hotline The 2010 MS4 Permit requires the City to provide and publicize a reporting system to facilitate and track public reporting of spills, discharges or dumping to the storm sewer system (i.e., storm water hotline, web page, etc.) on a continuous basis. The City established an Environmental Hotline as a method to receive calls regarding stormwater as well as other environmental issues [air quality, hazardous material disposal, illegal
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dumping, and public nuisances (i.e. mosquitoes)]. During normal business hours, calls are answered by personnel trained to understand the nature of the types of calls they receive and can address questions that are informational in nature. Where a complaint is filed, the record is turned over to appropriate personnel trained in code enforcement procedures for inspection. All complaints are logged into the City’s Tidemark® database system for tracking purposes. During off-business hours, callers are provided an opportunity to leave a message which is retrieved and processed the following business day. 3.2.2 Stormwater Website The City maintains a website specifically for stormwater. That website has information specific to the City’s stormwater program. The 2010 MS4 Permit requires the City to post the Storm Water Management Plan (SWMP) and latest annual report on the City’s web site within one (1) year from the effective date of the permit. The draft version of the SWMP was posted on the City’s website within ten (10) business day of the end of the first permit term (August 30, 2011). The final version of the SWMP, after being approved of by the ADEQ, was uploaded to the website within ten (10) business days after the receipt of the ADEQ approval (date April 12, 2012). The City will also provide a link to this Annual Report within ten (10) business days of submittal of this document to the ADEQ. These documents are accessible through City’s Environmental & Sustainability Division website at http://www.mesaaz.gov/environ/. 3.2.3 Household Hazardous Waste Program The 2010 MS4 Permit requires the City to incorporate at least one of the following as fundamental support to its storm water program: •
An opportunity to involve the public in the City’s stormwater program and encourage public participation in monitoring and reporting spills, discharges, or dumping within their communities (such as facilitation of neighborhood watch groups) once per year.
•
An opportunity to participate in the City’s stormwater program, such as voluntary litter control activities (e.g., facilitation of Adopt-A-Wash, Adopt-A-Park, and Adopt-A-Street litter control activities) or voluntary erosion control projects as a regular ongoing activity.
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•
A household hazardous waste (HHW) program to facilitate proper disposal of used oil, antifreeze, pesticides, herbicides, paints, and other hazardous and toxic materials by city residents (such as scheduled household hazardous waste collection events or operation of full-time disposal facilities) a minimum of two (2) times per year for the first two (2) years of the permit, three (3) times per year for years three (3) and four (4) of the permit, and every year thereafter.
The City has selected to incorporate the HHW program into their stormwater program since the City has been conducting these types of events as part of meeting the requirements of their previous MS4 permit. The City’s HHW program facilitates proper disposal of used oil, antifreeze, pesticides, herbicides, paints, and other hazardous and toxic materials as well as electronics, tires, and prescription medicine generated by city residents. During this reporting period, the City provided four opportunities to residents to dispose of HHW. By providing a proper disposal option to the City’s residents, the City has kept this material from potentially being illegally dumped into the City’s storm sewer system, spilled onto City streets, or improperly disposed of into solid waste receptacles. The City’s HHW collection events are held at two different locations, one on the east side of the City, the other on the west. The events alternate between locations to ensure that all residents have adequate access to these events. Information, including the number of residents attending, amount and type of material received, is included as an attachment to this Annual Report (see Section 13.7 and Attachment B). At these events, the City distributes packets to residents as they enter. Based on the timing of each event, this information would have included some or all of the following: •
HHW Collection Event Date Flier
•
Additional Electronics Recycling Opportunities
•
Christmas tree recycling information
•
Environmental & Sustainability Information
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3.3 NON-STORMWATER FLOWS TO THE CITY’S STORM SEWER SYSTEM The City’s 2010 MS4 Permit requires the City to summarize their program activities related to non-stormwater flows. This includes: 1. Prevention activities associated with the release of non-stormwater flows to the MS4; 2. Training dates and topics of City personnel addressing non-stormwater flow complaints; and, 3. Overview of identified sources resulting from industrial facility inspections, illicit releases, types of illicit connections identified, and significant corrective or enforcement actions. For the overview of industrial facility inspections, see Section 3.6.2. 3.3.1 Non-Stormwater Flow Prevention Activities The City does not operate as a permitting agency for stormwater or non-stormwater flows. However, the City has identified the following non-stormwater releases to target through the development of fact sheets to reduce the pollutants from these sources to the maximum extent practicable. Targeted Release Flood Irrigation Water
Targeted Pollutant(s) Sediment
Individual Car Washing
Sediment Solvents
Street Wash Water
Sediment Oils
Swimming Pools & Hot Tub Water (generally not allowed)
Chlorine Bromine Sediment Bacteria
City of Mesa, Storm Water Annual Report
Targeted Areas Irrigation over areas that are exposed to bare soils. Washing heavily soiled trucks. Washing undercarriage or engine compartments. Washing paved surfaces impacted with dirt. Washing standing liquid oil spills from paved surfaces. Flows must remain on site (irrigation usage) go to sanitary sewer, or be pumped and hauled away for disposal.
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During this reporting period, the City finalized these documents which are accessible through City’s Environmental & Sustainability Division website at http://www.mesaaz.gov/environ/. 3.3.2 Training Dates and Topics The City developed an Environmental Program Training Standard Operating Procedures manual (dated February 2012) to meet the training requirements of the 2010 MS4 Permit and other environmental program areas. The City has developed a training module targeting inspectors/staff with no direct stormwater responsibilities (general awareness training). Topics included what types of discharges are allowed under the Title 8, Chapter 5 of the Mesa City Code (Stormwater Code) and the procedure for reporting suspected illicit discharges. The City has also developed a training module targeting stormwater inspectors/field staff (enforcement training). Topics include identifying illicit discharges, tracking illicit discharges, allowable stormwater discharges, and enforcement actions. 3.3.3 Investigations For stormwater complaints publically reported to the City, the 2010 MS4 Permit requires the City to: 1. Investigate reported releases to identify the source(s) of the release; 2. Respond to 90% of all reports of releases made to the City (i.e. called into the Environmental Hotline, or other form of reporting) or other detection methods (i.e. pro-active inspections); and, 3. Initiate investigation of 80% of releases reported to the City within three (3) business days of the date of report. The City has established an Environmental Hotline as a method to receive calls regarding stormwater as well as other environmental issues (see Section 3.2.1). It has been the City’s experience that non-stormwater releases reported to the Environmental Hotline are identified at locations prior to entering the subsurface portions of the City’s storm sewer system (primarily flowing down the curb and gutter system). Most connections that are reported to the Environmental Hotline are in the form of a pipe (usually PVC) installed through a block wall or a pump hose that is placed in the yard,
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through a fence, or directly in the street or alleyway; and are associated with swimming pool discharges. These surface flows and connections are generally easy to track down to the source through a drainage area investigative approach. In general, the City can utilize a corrective or enforcement action to obtain compliance with the Mesa City Code. “Corrective actions” are generally those taken by the responsible party to remove pollutants or reduce the potential of pollutants from entering the City’s storm sewer system. “Enforcement actions” are those taken by the City to address any hazards associated with the violation, generally where a voluntary compliance option has failed to be an effective tool in gaining compliance, and includes reporting violations to other City departments or regulatory agencies having ultimate authority regarding the nature of the violation. During this reporting period, the majority of the complaints received through public reporting involved draining and/or backwashing of swimming pools to the City’s storm sewer system. Other noted complaints involved sediment and debris in streets and/or storm sewer system, oil dumped on the ground, raw sewage discharges, track-out issues, broken sprinkler head and excessive irrigation runoff, and stagnant water in retention basins. Section 8-5-5 of the City’s Stormwater Code (Commencement of Action) provides for formal enforcement actions by issuing a notice of abatement under this Chapter or a citation for civil sanctions under this Chapter, or both. However, the code provides that City employees may seek voluntary compliance “through notices of violation, warnings, or other informal devices designed to achieve compliance in the most efficient and effective manner under the circumstances.” The City’s code enforcement procedure provides the option of voluntary compliance to responsible parties to implement corrective actions by issuing a courtesy notice. Where voluntary compliance is not obtained within a reasonable timeframe, the City has the ability to issue a civil violation and citation, issue a notice to abate, or suspend any
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license issued by the City. Additionally, the City may impose criminal violations for responsible parties identified as habitual offenders. Most cases were closed with the issuance of a courtesy notice during this reporting period. 3.4 MUNICIPAL FACILITIES The 2010 MS4 Permit requires the City to report the following in the annual report as it relates to City facilities: 1. 2.
Description of the status of identification and inventory of these facilities. Overview of inspection findings (i.e., number inspected, number with follow-up actions needed, significant findings).
3.
Description of activities needed and performed in response to inspections (control measures implemented). Description of the identification and tracking of municipally-owned and operated facilities subject to permitting under the Multi-Sector General Permit (MSGP).
4.
In general, this program includes City facilities that meet the following conditions: •
City parks, golf courses, and other recreational facilities (where landscape maintenance, herbicide, pesticide, and fertilizer application, and waste management are implemented);
•
Public swimming pools (pool maintenance/repair and chemical storage);
•
Water treatment plants;
•
Public septic systems (sanitary waste handling);
•
Fire stations and other city fleet maintenance facilities (vehicle washing and maintenance, chemical handling, waste storage);
•
Publically-owned treatment works and sludge handling areas;
•
Material and waste storage and processing facilities, including oil collection facilities; or,
•
Those facilities that handle, store, or otherwise use hazardous materials where any single container exceeds five (5) gallons and where such materials are exposed or have the potential to be exposed to stormwater
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3.4.1 Description & Status of Inventory A current version of the City facility inventory is included in the City’s updated SWMP dated September 2014 which is included as an addendum to this annual report. 3.4.2 Overview of Findings No additional facility assessments were conducted during this reporting period. A site specific spill plan was developed and implemented at one facility during this reporting period. No other City facilities have been identified as requiring this type of plan. 3.4.3 Response Actions No response actions were required at facilities required to have a site specific spill plan during this reporting period. 3.4.4 Facilities Covered under the Multi-Sector General Permit The City has one facility (i.e. Falcon Field Airport) that is covered under the Multi-Sector General Permit. 3.5 INVENTORIES, MAPS, AND MAP STUDIES The 2010 MS4 Permit requires the City to report the status of all inventories, maps, and map studies required by the permit to be developed including completion dates. 3.5.1 Inventories The 2010 MS4 Permit requires to City to develop “inventories” or other methods of identification of the following: 1. An inventory or map of all major outfalls, and of other field screening points (FSPs) if applicable, identified by Mesa as priority for illicit discharges or other non-stormwater flows (see Section 13.2); 2. An inventory, list, database or map of facilities owned and operated by Mesa (excluding office and administration buildings) that have the potential to discharge pollutants to waters of the United States (see Section 13.8); 3. An inventory, list, or database of private commercial and industrial facilities that have the potential to discharge pollutants to the city’s storm sewer system (see Section 3.6.1); and,
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4. An inventory, list, database, or map of construction activities that result in land disturbance of one (1) or more acres and that have the potential to discharge to the city’s storm sewer system (see Section 3.7.1). 3.5.2 Maps Appendix A of the 2010 MS4 Permit requires the City to prepare and routinely update maps of the City’s storm sewer system that incorporates mapping of all of the following: 1. Linear Drainage Structures - Line layer showing the location of the City’s MS4 storm drain pipes and the direction of stormwater flow. 2. Storm Drain Inlets and Catch Basins - Point layer showing the locations of the City’s MS4 storm drain inlets and catch basins. 3. Major Outfalls, Field Screening Points, and Monitoring Locations a. Point layer showing the location of the City’s stormwater monitoring locations, field screening points, and major outfalls (pipes or culverts). b. Layer showing the drainage area associated with each monitoring location identified in the 2010 MS4 Permit. 4. Detention/Retention Basins - Point or polygon layer showing the locations of all City-owned retention and detention basins that are connected to the municipal stormwater conveyance system (i.e., that receive drainage from or discharge to a stormwater conveyance). 5. Jurisdictional MS4 Boundary - Line or polygon layer showing the jurisdictional boundaries of the City’s MS4, including any new land annexations during the permit term. The City is required to incorporate mapping of the above by the due date of the fourth (4th) year annual report (i.e. September 30, 2014). The City maintains Land and Utilities maps that are continually updated for use by City employees. The application provides the ability to view and print Land, Water, Gas, Sewer, or Storm Drain maps for each quarter section of the City. The City also maintains this information in ArcGIS software which is available for use by select City personnel. As of the date of the Annual Report, the City’s current mapping system includes all the information that is required under the 2010 MS4 Permit.
City of Mesa, Storm Water Annual Report
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3.5.3 Map Studies Appendix A of the 2010 MS4 Permit requires the City to complete a study that evaluates the cost, method, and time it will take to complete the following: 1. Linear Drainage Structures a. Line layer showing the location of all streets used for stormwater conveyance and the direction of stormwater flow. b. Line layer showing other linear stormwater conveyance structures (channels, floodways, etc.) and the direction of stormwater flow. 2. Land Uses - Layer showing the land uses. 3. Detention/Retention Basins a. Point or polygon layer showing the location of all privately-owned retention and detention basins that are connected to the municipal stormwater conveyance system (i.e., that receive drainage from or discharge to a stormwater conveyance). b. Line layers showing the drainage infrastructure associated with each retention/detention basin. 4. Locations of Discharges to Waters of the United States - Line or polygon layer showing the location (and name) of all waters of the United States that may receive stormwater discharges from the MS4 and to clearly identify any listed Outstanding Arizona Water or Impaired Water. The City is required to complete studies associated with the above mapping requirements by the due date of the fourth (4th) year annual report (i.e. September 30, 2014). As of the date of the Annual Report, the City’s stormwater mapping system includes all of the information identified in the 2010 MS4 Permit mapping studies requirements. Please note, the City does not discharge to waters of the United States that are considered to be an Outstanding Arizona Water or Impaired Water. 3.6 INDUSTRIAL FACILITIES The 2010 MS4 Permit requires the City to report the following in the Annual Report as it pertains to the inspection of private commercial and industrial facilities: 1. Status of identification and inventory of these facilities. 2. An overview of inspection findings and note significant findings.
City of Mesa, Storm Water Annual Report
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3. Corrective and enforcement actions needed and taken in response to inspections. 3.6.1 Identification and Inventory of Private Commercial and Industrial Facilities The 2010 MS4 Permit requires the City to: 1. Develop and maintain an inventory, list, or database of commercial and industrial facilities that have the potential to discharge pollutants to the City’s MS4. 2. Maintain a system to collect and update this information on a routine basis. 3.6.1.1 Commercial Facilities The City inspects commercial facilities that require a grease removal device (GRD) as part of the City’s industrial pre-treatment fats, oils, and greases (FOG) program. These types of facilities are required to submit an industrial pretreatment survey to the City to determine the type of business (i.e. industrial, commercial, manufacturing, restaurant etc.) and the nature of the facilities discharges to the City’s sanitary sewer. This survey assists the City in determining what, if any, pretreatment devices are required. These facilities are entered into a database and tracked for inspection purposes. During these inspections, City inspectors also conduct a stormwater assessment associated with the operations of these facilities. 3.6.1.2 Industrial Facilities In December 2009, the City received information from InfoUSA, a private customer listing group commonly used by other regulated Phase I MS4 operators (i.e. City of Phoenix, City of Tempe), related to provide facilities subject to the MSGP based on standard industrial classification (SIC) codes. Additionally, the City conducts a review of the United State Environmental Protection Agency Toxic Release Inventory (TRI) database annually. The City operates an Industrial (Private) database that includes the information supplied by InfoUSA and incorporates the most recent listing of TRI facilities. As of June 30, 2014, the City’s industrial facility inventory included approximately 800 facilities, of which approximately 680 were active facilities, and of those approximately 480 facilities are currently listed as MSGP facilities (i.e. those having a SIC code identified in the 2011 MSGP).
City of Mesa, Storm Water Annual Report
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3.6.2 Overview of Inspection Findings and Significant Findings The 2010 MS4 Permit requires the City to: 1. Develop an inspection and prioritization program. 2. Inspect at least 50 industrial facilities [Superfund Amendments and Reauthorization Act (SARA) Title III and MSGP facilities] each year during the permit term. 3. Inspect other commercial and industrial sources (or category of sources) which the City determines to be a significant source of pollutants. 4. Verify implementation and maintenance of stormwater management practices in compliance with the City’s Stormwater Code. 5. Identify and eliminate potential discharges of pollutants to the system. 6. Confirm permit coverage to discharge stormwater associated with industrial activity, as applicable. 7. Conduct follow-up inspections as necessary. 3.6.2.1 Commercial Facilities Inspection & Prioritization Inspections of commercial facilities are based on a geographical distributional approach. Commercial inspections are also conducted in response to complaints from other City staff and the general public. Priority is given to complaint responses, which are investigated without regard to the geographical distribution approach. Commercial inspections are conducted by City inspectors trained to identify stormwater compliance issues related to these types of facilities. Though all commercial facilities inspected under the FOG program are assessed for stormwater compliance, those that pose a higher risk include, but are not limited to: •
Auto Repair Shops;
•
Gasoline Stations;
•
Grocery Stores;
•
Restaurants;
•
Car Washes; and,
•
Movie Theaters
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Stormwater issues that were identified as a result of follow-up inspections at commercial facilities during this reporting period included: •
Raw sewage flowing to stormwater collection system/drywells; and,
• Used oil exposed to stormwater 3.6.2.2 Industrial Facilities Inspection & Prioritization The following criteria are used to determine categories and establishing a prioritization for conducting industrial inspections. 1. Complaints. 2. Newly identified TRI listed facilities that have not been previously inspected. 3. Current TRI listed facilities that were not previously inspected within the last 5 years. 4. Industrial facility sectors, SICs or North American Industry Classification System (NAICS) groups that have a reasonable potential to conduct dust generating operations and that may require permit coverage for such operations (i.e. unlikely to be no-exposure facilities). 5. Other industrial facility sectors, SICs or NAICS groups that the City determines may be a significant source of pollutants. During this reporting period, the City concentrated on industrial facilities involved in the following operations (also provided are the industrial subsector code): •
Fabricated Metal Products, Except Machinery and Transportation Equipment, and Coating, Engraving, and Allied Services. (AA1)
•
Transportation Equipment Except Ship and Boat Building and Repairing (AB1)
•
Computer and Office Equipment (AC1)
•
Motor Freight Transportation and Warehousing (P1)
•
Fabricated Rubber Products, Not Elsewhere Classified (Y1)
Many of the industrial facilities in the City’s database that were inspected during this reporting period did not perform operations consistent with the SIC codes that were assigned to them from the information provided by InfoUSA. When contacted, the facilities operator was asked what types of operations took place there and assisted them with identifying the appropriate SIC. The City conducted an inspection to ensure City of Mesa, Storm Water Annual Report
Page 3-16
that these facilities did not require MSGP coverage and that their operations were being performed in compliance with the City’s Stormwater Code. The City’s industrial inspection database was updated for revised SIC codes. Issues at industrial facilities noted as part of the inspection process during this reporting period included: •
Open containers of oil/water exposed to stormwater;
•
General housekeeping issues;
•
Process water and trash discharged to drywell;
•
Private industries subject to MSGP but do nothing to comply
3.6.3 Summary of Corrective and Enforcement Actions The 2010 MS4 Permit requires the City to: 1. Establish an effective compliance and enforcement program that incorporates escalating actions for violations of the City’s Stormwater Code that provides timeframes and escalation for corrective actions; and, 2. Focus the escalated enforcement protocol on having the highest level of enforcement action resolved within one (1) year of the initial inspection/violation. 3.6.3.1 Commercial Facility Corrective & Enforcement Actions Corrective actions needed and taken at commercial facilities during this reporting period included: •
City of Mesa cleaned up stormwater collection system and reported to Maricopa County / Arizona Department of Environmental Quality
•
The operator removed used oil stored in an area exposed to stormwater
Section 8-5-5 (Commencement of Action) of the City’s Stormwater Code provides for formal enforcement actions by issuing a notice of abatement or a citation for civil sanctions, or both. However, the code provides that City employees may seek voluntary compliance through notices of violation, warnings, or other informal devices designed to achieve compliance in the most efficient and effective manner under the circumstances. City of Mesa, Storm Water Annual Report
Page 3-17
The City’s commercial and industrial facility enforcement procedure provides the option of voluntary compliance to responsible parties to implement corrective actions by issuing a courtesy notice. Where voluntary compliance is not obtained within a reasonable timeframe, the City has the ability to issue a civil violation and citation, issue a notice to abate, or suspend any license issued by the City. Additionally, the City may impose criminal violations for responsible parties identified as habitual offenders. Most cases were closed with the issuance of a courtesy notice during this reporting period. During this reporting period, no formal enforcement actions were needed or taken as a result of stormwater inspections conducted by the City of private commercial facilities. Some cases were closed without a violation being confirmed. The remaining cases were closed when the issue had been addressed or upon the issuance of a courtesy notice. 3.6.3.2 Industrial Facility Corrective & Enforcement Actions Corrective actions needed and taken at industrial facilities during this reporting period included: •
Open containers of oil and oil/water were removed
•
Reported drywell violations to ADEQ Aquifer Protection Permit (APP) Program personnel
•
Report to ADEQ the private industries that are subject to the multi sector general permit (MSGP) as non-filers
Section 8-5-5 of the City’s Stormwater Code provides for formal enforcement actions by issuing a notice of abatement or a citation for civil sanctions under the code, or both. However, the code provides that City employees may seek voluntary compliance through notices of violation, warnings, or other informal devices designed to achieve compliance in the most efficient and effective manner under the circumstances. The City’s commercial and industrial facility enforcement procedure provides the option of voluntary compliance to responsible parties to implement corrective actions by issuing a courtesy notice. Where voluntary compliance is not obtained within a reasonable timeframe, the City has the ability to issue a civil violation and citation, issue
City of Mesa, Storm Water Annual Report
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a notice to abate, or suspend any license issued by the City. Additionally, the City may impose criminal violations for responsible parties identified as habitual offenders. During this reporting period, no formal enforcement actions were needed or taken as a result of stormwater inspections conducted by the City of private industrial facilities. Some cases were closed without a violation being confirmed. The remaining cases were closed when the issue had been addressed or upon the issuance of a courtesy notice. 3.7 CONSTRUCTION PROGRAM ACTIVITIES The 2010 MS4 Permit requires the City to report the following in the Annual Report as it pertains to the review of plans and inspections of construction operations: 1. Status of inventory/plan review of these facilities. 2. An overview of inspection findings and significant findings. 3. Corrective and enforcement actions needed and taken in response to inspections. 3.7.1 Status of Inventory and Plan Review of Construction Operations The 2010 MS4 Permit requires the City to: 1. Develop an inventory, list, or database, or map of construction activities that result in land disturbance of one (1) or more acres and that have the potential to discharge to the City’s storm sewer system within one (1) year of permit issuance (August 30, 2011) and to be updated at least annually; 2. Review at least 80% of plans for new development and redevelopment (such as grading and drainage plans) to verify conformance with the City requirements for stormwater, including erosion and sediment control, prior to issuing construction approvals or authorizations; and, 3. Require a copy of the ADEQ’s Authorization Certificate for non-municipal construction projects (as required by municipal stormwater requirements or ordinances or state stormwater requirements) be submitted prior to issuing construction approval or authorization.
City of Mesa, Storm Water Annual Report
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3.7.1.1 Private Construction Projects When plans are submitted to the City, information on the construction project is entered into a database providing a detailed record of the construction operations from the point of plan submittal through inspection and approval (i.e. issuance of a Certificate of Completion or Certificate of Occupancy). The City reviews all construction plans for compliance with all aspects of the City’s Engineering and Design Standards Manual and the City Mesa Code. Stormwater drainage and infrastructure are generally detailed in grading and drainage plans. Approval of these plans is required before a building permit is issued by the City. A copy of the contractor’s ADEQ Authorization Certificate is also required before a building permit is issued by the City of Mesa for projects involving land disturbance of one or more acres. The City places a “hold” that prevents the issuance of a building permit where an ADEQ Authorization Certificate is required until it has been submitted. 3.7.1.2 City Projects For City projects, the City is deeply involved in the project through all phases of development (i.e. conception, planning, construction, and completion). Grading and drainage plans are required for most engineering projects, certainly any project that disturbs one or more acres of land. The City maintains a separate database for City construction projects that disturb more than 0.1 acres. This is the threshold disturbance limit where a dust control permit would be required from the Maricopa County Air Quality Department. The general contractor is required to submit a copy of their SWPPP for review and approval along with a copy of their ADEQ Authorization Certificate before the contractor is authorized to conduct any land disturbance activities for City projects that disturb one or more acres of land. The City files as a co-permittee under the ADEQ’s Construction General Permit (CGP) and is issued a separate Authorization Certificate. 3.7.2 Overview of Inspection Findings and Significant Findings The 2010 MS4 Permit requires the City to:
City of Mesa, Storm Water Annual Report
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1. Establish a prioritization schedule for inspecting construction sites with a higher frequency of inspections for those sites that have a higher potential to discharge to the storm sewer system; 2. Routinely inspect construction projects to determine whether effective erosion and sediment controls are in place, and verify conformance with local stormwater requirements and approved construction plans; 3. Inspect higher priority sites, based on the prioritization schedule, a minimum of one (1) time every three (3) months and all other sites at least once every six (6) months until final stabilization is established; and, 4. Conduct follow-up inspection of construction sites within 30 days to ensure stormwater deficiencies/concerns/non-compliance identified as a result of a routine inspection were corrected 3.7.2.1 Private Construction Projects The City will generally first inspect a private construction operation within three (3) weeks of the issuance of any permit for projects that involve a surface/land disturbance of one (1) acre or more. During this visit, the City will review the operator’s plans to identify active areas and stormwater best management practices (BMPs), and inspects all active areas of the project to ensure that BMPs and other environmental ordinance issues identified on the operator’s plans are in place and maintained, and to ensure there are no illicit discharges to the City’s storm sewer system. These projects are inspected thereafter a minimum of one (1) time every three (3) months where construction activities are still active. Where deficiencies are noted and a re-inspection is required, the City will conduct this follow-up inspection within 30 calendar days. Inspection findings for private construction projects during this reporting period included: 1. Improper BMP Installation or Use: Wattles not staked around stockpiles 2. Inadequate BMP Maintenance: Poorly maintained track-out devices Poorly maintained silt fence 3. Lack of BMPs: No perimeter control
City of Mesa, Storm Water Annual Report
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Unprotected catch basins No track-out control devices No erosion control BMPs around stockpiles 4. Non-Stormwater Discharges: Fugitive dust control issues Track-out onto City streets Sediment discharges to streets, sidewalks, and curb and gutter systems 5. Paperwork Issues: Authorization Certificate not available at the site 3.7.2.2 City Projects The City generally conducts a compliance audit within two (2) weeks of the issuance of approval by the City to the general contractor (i.e. issuance of a Notice to Proceed) and where the disturbance of land associated with the project has begun. These projects are inspected thereafter a minimum of one (1) time every three (3) months. Where deficiencies are noted and a re-inspection is required, the City will conduct this follow-up inspection within 30 calendar days. Inspection findings for City construction projects during this reporting period included: 1. Improper BMP Installation or Use: Wattles not staked around stockpiles 2. Inadequate BMP Maintenance: Poorly maintained track-out devices Poorly maintained silt fence 3. Lack of BMPs: No perimeter control Unprotected catch basins No track-out control devices No erosion control BMPs around stockpiles 4. Non-Stormwater Discharges: Track-out onto City streets Sediment discharges to streets, sidewalks, and curb and gutter systems 5. Paperwork Issues: Lack of updated SWPPP site inspection records SWPPP waiver not available at the site SWPPP not updated to show current BMPs
City of Mesa, Storm Water Annual Report
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3.7.3 Summary of Corrective and Enforcement Actions The 2010 MS4 Permit requires the City to: 1. Establish an effective compliance and enforcement program that incorporates escalating actions for violations of the City’s Stormwater Code that provides timeframes and escalation for corrective actions; and, 2. Focus the escalated enforcement protocol on having the highest level of enforcement action resolved within one (1) year of the initial inspection/violation. 3.7.3.1 Private Construction Projects Corrective actions needed and taken at private construction projects during this reporting period included: 1. Improper BMP Installation or Use: Proper installation and usage of wattles was established 2. Inadequate BMP Maintenance: Track-out control device became properly maintained Silt fences became properly maintained 3. Lack of BMPs: Perimeter control was established Catch basin BMPs were installed Erosion control BMPs installed around stockpiles 4. Non-Stormwater Discharges: Fugitive dust control issues were addressed Track-out was cleaned up Sediment was removed from streets, sidewalks, and curb and gutter systems 5. Paperwork Issues: Authorization Certificate became available at the site Section 8-5-5 of the City’s Stormwater Code provides for formal enforcement actions by issuing a notice of abatement or a citation for civil sanctions under this Chapter, or both. However, the code provides that City employees may seek voluntary compliance through notices of violation, warnings, or other informal devices designed to achieve compliance in the most efficient and effective manner under the circumstances.
City of Mesa, Storm Water Annual Report
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The City’s private construction enforcement procedure provides an option of obtaining voluntary compliance by allowing a reasonable timeframe for obtaining compliance and taking actions equivalent to issuing a stop work order (i.e. not approving site improvements until such time the issues have been adequately addressed) where necessary. Where voluntary compliance is not obtained within a reasonable timeframe, the City has the ability to take formal enforcement actions by issuing a civil violation and citation, issue a notice to abate, or suspend any license issued by the City. Additionally, the City may impose criminal violations for responsible parties identified as habitual offenders. 3.7.3.2 City Projects Corrective actions needed and taken at City construction projects during this reporting period included: 1. Improper BMP Installation or Use: Proper installation and usage of wattles was established 2. Inadequate BMP Maintenance: Track-out control device became properly maintained Silt fences became properly maintained 3. Lack of BMPs: Perimeter control was established Catch basin BMPs were installed Erosion control BMPs installed around stockpiles 4. Non-Stormwater Discharges: Track-out was cleaned up Sediment was removed from streets, sidewalks, and curb and gutter systems 5. Paperwork Issues: Updated SWPPP site inspection records were available SWPPP waiver became available at the site SWPPP was updated Section 8-5-5 of the City’s Stormwater Code provides for formal enforcement actions by issuing a notice of abatement or a citation for civil sanctions under this Chapter, or both. However, the code provides that City employees may seek voluntary compliance
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through notices of violation, warnings, or other informal devices designed to achieve compliance in the most efficient and effective manner under the circumstances. The City construction enforcement procedure provides for an option of obtaining voluntary compliance by allowing a reasonable timeframe for obtaining compliance and confirming during a follow-up inspection(s), and where compliance issues remain unresolved, initiating the stop work order process until such time the issues have been adequately addressed. 3.8 POST-CONSTRUCTION PROGRAM ACTIVITIES The 2010 MS4 Permit requires the City to report the following in the Annual Report as it pertains to the post-construction requirements associated with construction operations: 1. Summary of any new or revised post-construction controls for City projects or post-construction requirements related to permits the City issues. 2. An overview of the city’s post-construction inspection program. 3. Corrective and enforcement actions needed and taken in response to postconstruction inspections. 3.8.1 New or Revised Post-Construction Controls During this reporting period, no changes were made to the Engineering & Design Standards (2012) which incorporates the City’s stormwater drainage and retention standards. A copy of that document is available at the following link: http://www.mesaaz.gov/engineering/MesaStandardandSpecs.aspx 3.8.2 Overview of Post-Construction Inspection Program For private construction projects, the City requires developers to obtain a third party inspection of post-construction stormwater controls to determine effectiveness of these controls. These third party inspection are submitted to the City. For City projects, the City conducts a final stability inspection for projects involving land disturbance of one or more acres ensure the site has achieved permanent stabilization. An inspection of this nature is necessary in order to file a Notice of Termination (NOT) to end coverage under the CGP.
City of Mesa, Storm Water Annual Report
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3.8.3 Summary of Corrective and Enforcement Actions For private construction projects, a certificate of occupancy will not be issued until such a time that the developer provides a third party inspection of post-construction stormwater controls for projects requiring such an inspection. For City construction projects, the City files a NOT to end coverage under the CGP for each project that disturbed one or more acres of land based on the results of the final stability inspection. Where final stabilization has not been achieved, coverage under the CGP is maintained. This may occur in instances where one general contractor’s scope of work did not include final stabilization (e.g. application of ground cover) but that this would be achieved under another project phase, either by City personnel or another general contractor. 3.9 DRY-WEATHER SCREENING The 2010 MS4 Permit requires the City to report the status of the following in the Annual Report as it pertains to the dry-weather screening requirements: 1. 2. 3. 4.
Staff training. Outfall and field screening point inventory. Inspection tracking system. Inspection and screening procedures and significant findings.
3.9.1 Staff Training The 2010 MS4 Permit requires the existing employees directly involved with stormwater management activities, including dry-weather screening and associated investigations, be trained at least once every two (2) years and to provide an opportunity for new employee training at least one (1) time per year. As such, all City staff who conduct these types of operations must meet the following requirements: •
Review the procedures detailed in the Environmental Code Violation Standard Operating Procedures;
•
Have knowledge of:
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Ordinances, rules, and regulations governing stormwater discharges, particulate pollution, and hazardous materials; Principles and practices for field monitoring protocols, sample collection, preservation, analysis, and documentation requirements; Occupational and safety precautions at industrial and construction work sites (position requirement; and, •
Have a basic knowledge of chemicals on human and ecological systems (position requirement).
Dry weather screening inspections involve two personnel for health and safety reasons among others. Dry-weather screening inspections conducted during this reporting period involved personnel that were hired during the reporting year. Training was provided to these personnel prior to conducting dry-weather screening activities. 3.9.2 Outfall and Field Screening Point Inventory Two newly installed FSPs were added to the City’s inventory during this reporting period. 3.9.3 Inspection Tracking System Dry-weather screening and associated investigations are documented on the DryWeather Screening Report Form specific for each location. The City has developed a database with the functionality to retrieve data and generating reports required for the annual report and to better track results at these locations. 3.9.4 Inspection and Screening Procedures and Significant Findings During this reporting period, the City completed the dry-weather screening process by inspecting all outfall and FSP locations that had not been inspected during the first three years reporting periods of the 2010 MS4 Permit. The push to complete dry-weather screening during the fourth year of the 2010 MS4 Permit term was conducted for the purpose of updating the City’s SWMP and for the preparation of the City’s 2010 MS4 Permit re-application (both included as addendums to this annual report). During this reporting period, dry-weather flows were detected at two FSP locations. One location was not flowing when re-inspected within 24 hours and therefore, no
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inspection was required. The flow at other FSP location was determined to be resulting from a permitted de minimis source. 3.10 ORDINANCES, RULES, & POLICIES No changes to the City’s Stormwater Code were made during this reporting period. The most current version of the City’s Stormwater Code included in the City’s updated Storm Water Management Plan which is included as an addendum to the annual report. 3.11 FISCAL EXPENDITURES See Section 12.0.
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4.0
STORMWATER PROGRAM NUMERIC SUMMARY
The 2010 MS4 Permit requires the City to provide a summary of management practices and activities performed each year and to report that summary in a table as provided in that permit. Attached in this section is the table summarizing activities conducted under the City’s 2010 MS4 Permit.
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(This page intentionally left blank)
City of Mesa, Storm Water Annual Report
Page 4-2
NUMERIC SUMMARY OF STORMWATER MANAGEMENT PROGRAM ACTIVITIES STORMWATER MANAGEMENT PRACTICE OR ACTIVITY
ANNUAL REPORTING YEAR (July 1 – June 30)
2010 - 2011 2011 - 2012 Illicit Discharge Detection & Elimination Program 1. Municipal Employee Training Number of training sessions (on non-stormwater discharges and the IDDE program) Number of employees attending training 2. Spill Prevention Number of municipal facilities identified with hazardous materials Number of spills at municipal facilities with hazardous materials, that occurred in outside areas Number of facility assessments completed (identify any issues found requiring follow-up in narrative and summarize new practices to minimize exposure) Date of last review of site-specific materials handling and spill response procedures (identify participant(s) with stormwater expertise in narrative) 3. Outfall and Field Screening Point Inspections Total number inspected (attach or forward electronic copy of inventory or map of major outfalls and field screening points and priority outfalls and field screening points) Number of ‘priority outfalls’ and field screening points identified to date (summarize findings and follow-up actions in narrative) Number of ‘priority outfalls’ and field screening points inspected (summarize findings and follow-up actions in narrative) Number of dry weather flows detected Number of dry weather flows investigated Number of outfalls and field screening points sampled Number of illicit discharges identified Number of illicit discharges eliminated Amount of storm drain inspected (length) Number of storm drain cross connection investigations Number of illicit connections detected Number of illicit connections eliminated Number of corrective or enforcement actions initiated within 60 days of identification Percent of cases resolved within one (1) calendar year of original enforcement action Number of illicit discharge reports received from public Percent of illicit discharge reports responded to Percent of responses initiated within three (3) business days of receipt
City of Mesa, Storm Water Annual Report
2012 - 2013
2013 - 2014
22
0
13
6
NA
358
59
531
0 NA
0 0
2 0
1 0
NA
230
55
0
NA
NA
NA
05/06/14
41
30
44
56
0
0
0
0(4)
NA
NA
NA
NA
0 NA NA 12 12 NA 0 2 2 12
0 NA NA 9 5 NA 0 0 0 13
0 NA NA 25 22 NA 0 0 0 27
2
35,444 0 0 0 37
100
100
100
100
28 100 100
16 100 100
32 100 81
43 94 81
2014 - 2015
(1)(2)
(3)
(4)
(5)
1 (6) 0 34 32 (7)
Numeric Summary of Stormwater Management Program Activities Page 1 of 3
STORMWATER MANAGEMENT PRACTICE OR ACTIVITY
ANNUAL REPORTING YEAR (July 1 – June 30) 2010 - 2011
2011 - 2012
2012 - 2013
2013 - 2014
0 NA
7 165
4 36
207(1)
96 NA NA
286 NA NA
285 01/30/13 07/22/13
286 NA NA
NA NA 0 NA
NA NA 0 NA
NA NA 2 1
NA 3.2%(9) 0 NA
30,976
52,026
51,648
52,280
1,769
3,235
3,330
3,356(10)
8,508 19,146 17,050
10,042 21,586 11,420
9,951 22,862 5,318
17,340 2,309(12)
2014 - 2015
Municipal Facilities 1. Employee Training Number of training events (dates and topics to be included in narrative) Number of staff trained 2. Inventory, Map, or Database of MS4 Owned & Operated Facilities Total number of facilities on inventory Date identification of ‘higher risk’ facilities completed Date prioritization of municipal facilities completed 3. Inspections Miles of MS4 drainage system prioritized for inspection Miles visually inspected Number of ‘higher risk’ municipal facilities inspected Number of ‘higher risk’ municipal facilities found needing improved stormwater controls 4. Infrastructure Maintenance Linear miles of drainage system cleaned each year (city to maintain records documenting specific street cleaning events) Record amount of waste collected from street and lot sweeping (reported in pounds, gallons, etc.) Total number of catch basins Number of retention/detention basins cleaned Number of catch basins cleaned
Industrial and Commercial Sites Not Owned by the MS4 Number of training events for MS4 staff 0 1 Number of municipal staff trained NA 4 Number of industrial facilities inventory inspected (see Appendix A, Part V.B) 1,117 1,146 Number of corrective or enforcement actions initiated on industrial facilities 9 28 Percent of cases resolved within one (1) calendar year of original enforcement NA action Construction Program Activities Number of training events for MS4 staff (include topics in narrative summary) 0 Number of municipal staff trained NA Number of construction/grading plans submitted for review 80 Number of construction/grading plans reviewed 88 Number of construction sites inspected 113 Number of corrective or enforcement actions initiated on construction facilities 56 (identify the type of actions in narrative summary)
City of Mesa, Storm Water Annual Report
10
(8)
10,084 (11)
1 4 1,169 5
2 10 828(13) 8
100
100
100
10 121 89 122 58 57
2 19 121 134 73 12
(1)
7 122(1) 176 99 103(13) 28
Numeric Summary of Stormwater Management Program Activities Page 2 of 3
STORMWATER MANAGEMENT PRACTICE OR ACTIVITY
ANNUAL REPORTING YEAR (July 1 – June 30) 2010 - 2011
2011 - 2012
Post Construction Program Activities Number of post-construction inspections completed 18 Number of corrective or enforcement actions initiated for post-construction 0 activities (identify the type of actions in narrative summary)
23 0
2012 - 2013
2013 - 2014
4 0
39 0
2014 - 2015
Notes for current reporting period: NA- Not Applicable (1) Previous training numbers reported have been modified due to a database error. For some training, more than one module is presented. In these cases the number reported is the total number of employees trained for each module. (2) The increase in the number of people trained during this reporting period was the result of incorporating other departments into the training program following the results of the City facility assessments conducted during reporting period 2012-2013.
(3) Hazardous materials over in quantities greater than 5 gallons were identified in 23 facilities. These materials were exposed to stormwater at only 2 of those facilities. One facility required a spill plan. The hazardous material storage at the other facility was addressed through a revised waste disposal protocal. (4) To date, the City has not identified any conditions at outfall or field screening point locations that meet the definition of a "priority outfall" as provided in the 2010 MS4 Permit. (5) Dryweather flows were detected at two FSP locations. One location was not flowing when reinspected within 24 hours and therefore, no inspection was required. The flow at other FSP location was determined to be resulting from a permitted de minimis source. (6) Flow was from a permitted source. No samples for analytical analysis were collected. (7) Measured in linear feet. (8) The City does not measure linear miles of drainage system prioritized for inspection. Rather, these areas are provded in the SWMP. (9) Reported as a percentage of the linear miles of drainage system cleaned. (10) Quantity reported in tons. Waste generated from access roadways and lot sweeping is estimated by adding 10% to the waste generated as part of the City's street sweeping program. (11) The City has 174 basins in its inventory. Some basins are cleaned more frequently than others. Reported value is the total number of times City owned and operated basins were cleaned. (12) Between summer 2008 and summer 2012 the City conducted a concentrated effort to target the cleaning of every City owned catch basin. The recent drop in numbers is attributed to the City returning to a regular preventative maintenance schedule. (13) Number of inspections include follow-up inspections and is not indicative of the number of sites inspected.
City of Mesa, Storm Water Annual Report
Numeric Summary of Stormwater Management Program Activities Page 3 of 3
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5.0
EVALUATION OF THE STORMWATER PROGRAM
The 2010 MS4 Permit requires the City to provide an evaluation of the progress and success of the City’s stormwater management program, including an assessment of the effectiveness of stormwater management practices in reducing the discharge of pollutants to and from the City’s storm sewer system in the Annual Report. 5.1 PROGRAM PROGRESS The City has drafted the following standard operating procedures addressing the requirements provided in the 2010 MS4 Permit. The most current date of these procedures is also provided. •
Commercial & Industrial Facility Inspection Standard Operating Procedures (September 2011)
•
Environmental Code Violation Standard Operating Procedures (September 2011)
•
Environmental Program Training Standard Operating Procedures (February 2012)
•
Standard Operating Procedures for City Facility Compliance Assessments (February 2012)
•
Standard Operating Procedures for City Field Operations Activities (September 2011)
•
Standard Operating Procedures for City Stormwater Infrastructure Operations Activities (August 2014)
•
Standard Operating Procedures for Construction Activities of City Projects (March 2014)
•
Standard Operating Procedures for Construction Activities of Private Projects (February 2014)
•
Standard Operating Procedures for Stormwater Monitoring (October 2012)
•
Wet-Weather Stormwater Sampling & Analysis Plan (April 2011)
Many of these procedures incorporate other City requirements established under the Mesa City Code that are not specific to the City’s stormwater program.
City of Mesa, Storm Water Annual Report
Page 5-1
5.2 PROGRAM SUCCESSES During this fiscal year, the following successes to the City’s stormwater program include: •
The STORM organization conducted a movie theater campaign that reached an estimated 850,000 people over the Greater Phoenix Metropolitan Area.
•
STORM sponsored the Construction General Permit Seminar that attracted approximately 141 attendees.
5.3 REDUCTION OF POLLUTANTS TO THE CITY’S STORM SEWER SYSTEM Elements of the City’s stormwater program that the City identifies as having significantly reduced the release of pollutants to their storm sewer system include: 1. 2. 3. 4. 5.
Public Education & Outreach Public Reporting (i.e. Environmental Hotline) Household Hazardous Waste Events Commercial & Industrial Facility Inspections Construction Site Inspections
5.3.1 Public Education & Outreach The STORM organization’s movie theater campaign was a major benefit to the City’s stormwater program by providing information pertaining to illicit discharges and stormwater quality. The Construction General Permit seminar was a major benefit to the City’s stormwater program by providing information regarding stormwater requirements directly to construction site operators. This seminar helps to reduce the amount of pollutants discharged to the City’s storm sewer system by providing industrial site operators with increased knowledge of what is required on their facilities. 5.3.2 Public Reporting By providing a public reporting method for complaints regarding stormwater issues, the City is able to identify and take timely action against persons who are responsible for releasing pollutants to the City’s storm sewer system. Additionally, this information can
City of Mesa, Storm Water Annual Report
Page 5-2
be used to determine what topics need to be further addressed though the STORM organization’s public education and outreach program. 5.3.3 Household Hazardous Waste Events The City’s HHW events collected over 57,000 gallons of waste. It is not possible to quantify the amount of HHW that could be released into the storm sewer system if the HHW events were not held. However, since material collected at the events is disposed of properly, these events ultimately result in significantly reducing releases of these types of pollutants to the City’s storm sewer system. 5.3.4 Commercial & Industrial Facility Inspections City inspectors conduct inspections on a daily basis of commercial facilities that require permitting under the City’s FOG program. These inspectors are trained to identify violations of the City’s Stormwater Code and to report such violations to appropriate City personnel. The inspections of industrial facilities by qualified personnel to identify violations of the City’s Stormwater Code are also an effective method for reducing the release of pollutants to the City’s storm sewer system. Through the issuance of a courtesy notice requiring corrective actions, the City is able to have the source of pollutants removed by the responsible party while at the same time providing a public education opportunity to prevent future discharges and encourage public reporting. Where necessary, the City does have the authority to pursue civil and criminal actions against responsible parties if they refuse to take action, take action then recommit the offense, or commit offences in a manner that they are considered habitual offenders. These enforcement actions, or the threat of them, can be an effective tool in accelerating corrective actions by the responsible party. 5.3.5 Construction Site Inspections City inspectors conduct inspections of private construction projects to ensure they are operating in compliance with the City’s Stormwater Code. Where issues are identified, the City has the authority to issue a “Stop Work Order” or otherwise not approve contractor improvements (similar to a Stop Work Order) as a mean of obtaining compliance until such time that the issues have been adequately addressed.
City of Mesa, Storm Water Annual Report
Page 5-3
Where necessary, the City does have the authority to pursue civil and criminal actions by establishing a code compliance case against responsible parties if the construction site operator refuses to take action, takes action but then recommits the offense, or commits offences in a manner that they are considered repeat offenders. These enforcement actions, or the threat of them, can be an effective tool in accelerating corrective actions by the responsible party. 5.4 REDUCTION OF POLLUTANTS FROM THE CITY’S STORM SEWER SYSTEM Elements of the City’s stormwater program that the City identifies as having significantly reduced the discharge of pollutants from their storm sewer system to waters of the United States include: 1. Storm Sewer System Infrastructure Maintenance 2. Post-Construction Requirements 5.4.1 Storm Sewer Systerm Infrastructure Maintenance Maintenance of the City’s storm sewer system results in the direct removal of pollutants from the system, thus keeping them from being discharged into a water of the United States. 5.4.1.1 Street Sweeping Sediment and debris that collects on paved streets owned and operated by the City is removed through the City’s street sweeping program. The estimated amount of pollutants removed from the City’s street sweeping program is provided in the Numeric Summary of Stormwater Management Program Activities table in Section 4.0. 5.4.1.2 Storm Sewer Components The City has a program to clean catch basins, storm pipes, open channels, headwalls and culverts that are owned and operated by the City. Removal of trash, debris and sediment from these structures prevents this material from being discharged to a water of the United States. 5.4.1.3 Detention/Retention Basins The City owns and operates several detention and retention basins installed throughout the City. Much of the City’s streets and storm pipes drain to a detention or retention
City of Mesa, Storm Water Annual Report
Page 5-4
basin at some point before potentially draining to another regulated MS4 or a water of the United States. The City removes debris, trash, and sediment from detention basins to keep pollutants from discharging further into the City’s storm sewer systerm. The removal of these pollutants from retention basins keeps these basins operational and allows for the infiltration of stormwater. 5.4.2 Post-Construction Requirements The City has developed an Engineering and Design Standards Manual that provides specific direction and guidelines to the design professionals preparing construction documents for private land development projects. That manual adopts the Uniform Drainage Policies and Standards for Maricopa County as published by the Flood Control District of Maricopa County with modifications as specified within that manual. City regulations requiring the retention of the 50-year, 24-hour run-off volume were adopted in 1997 and were based on three (3) inches of precipitation. Retention standards requiring the 100-year 2-hour volume were adopted in the late 1980’s. The current design storm is based on the 100 year frequency, 2-hour duration storm event which is equivalent to 2.2 inches of rainfall, except in the Mesa Town Center where the retention standard only requires 2/3 of the 100 year, 2 hour rainfall depth, or 1.5 inches. The City’s retention standard results in the reduction of pollutants discharged from the City’s storm sewer system to a water of the United States.
City of Mesa, Storm Water Annual Report
Page 5-5
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City of Mesa, Storm Water Annual Report
Page 5-6
6.0
STORMWATER MANAGEMENT PROGRAM MODIFICATIONS
The 2010 MS4 Permit requires the City to provide a description of the modifications to the City’s SWMP for the areas described in the following subsections. No other changes to the City’s SWMP are allowed without permit modification. However, Section 8.1.4 of the 2010 MS4 Permit requires the 4th year annual report (this report) submittal to include an updated SWMP. 6.1 ADDITION OF NEW CONTROL MEASURES No additional control measures apart from those required in under the 2010 MS4 Permit were implemented during this reporting period. 6.2 ADDITION OF TEMPORARY CONTROL MEASURES No temporary control measures were implemented during this reporting period. 6.3 INCREASE OF EXISTING CONTROL MEASURES No increases to existing control measures were implemented during this reporting period. 6.4 REPLACEMENT OF EXISTING CONTROL MEASURES No existing controls were deemed to be ineffective and replaced with an alternate control measure that will continue to achieve an equivalent or increased reduction in pollutants during this reporting period. 6.5 FOURTH YEAR ANNUAL REPORT The first SWMP developed under the 2010 MS4 Permit was dated September 2011. The updated SWMP dated September 2014 is included as an addendum to this annual report.
City of Mesa, Storm Water Annual Report
Page 6-1
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City of Mesa, Storm Water Annual Report
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7.0
MONITORING LOCATIONS
The 2010 MS4 Permit requires the City to provide a brief description of the City’s wetweather stormwater monitoring locations in the first annual report. Subsequent annual reports need only advise of any changes or updates that were required. The information required includes the following: 1. Name and description of water of the United States receiving discharges from the monitoring location; 2. Monitoring location identification number (see subsection titles); 3. Address or physical location of the monitoring locations; 4. Latitude and longitude of monitoring locations; 5. Size (acres) of drainage area associated with each monitoring location; 6. Estimated acreage of individual land uses with each drainage area; and, 7. Type of monitoring equipment The City provided information regarding items 1, 2, 3, 4, and 7 in the Annual Report dated September 2011. Engineering & Environmental Consultants, Inc. (EEC) was contracted by the City under the request for proposal process for stormwater program development to conduct a study that would update the City’s pollutant loading model. The study included delineating drainage areas for each outfall and FPS location, estimating the total acreage of each drainage area, and estimating the acreage of each land use within each drainage area that results in a discharge to a water of the United States (see Section 11.0). EEC evaluated each outfall and FSP for the following land uses: streets, residential, commercial, industrial, lawns/parks, hillside/mountain, desert, and agricultural. Please note that the streets land use did not include streets incorporated in commercial and residential areas. This information was incorporated into the City’s Standard Operating Procedures for Stormwater Montioring manual. The following sections provide information for each sampling sampling location.
City of Mesa, Storm Water Annual Report
Page 7-1
7.1 AS-US60 The total drainage area for this location is approximately 149.3 acres and is broken down as follows: •
Residential – 128.5
•
Agricultural – 0.0
•
Commercial – 20.8
•
Industrial – 0.0
•
Lawns/Parks – 0.0
•
Desert – 0.0
•
Hillside/Mountain – 0.0
•
City Streets – 0.0
7.2 SS-US60 The total drainage area for this location is approximately 6.5 acres and is broken down as follows: •
Residential – 0.0
•
Agricultural – 0.0
•
Commercial – 0.0
•
Industrial – 0.0
•
Lawns/Parks – 0.0
•
Desert – 0.0
•
Hillside/Mountain – 0.0
•
City Streets – 6.5
7.3 54-EMF The total drainage area for this location is approximately 29.3 acres and is broken down as follows: •
Residential – 29.3
•
Agricultural – 0.0
•
Commercial – 0.0
•
Industrial – 0.0
City of Mesa, Storm Water Annual Report
Page 7-2
•
Lawns/Parks – 0.0
•
Desert – 0.0
•
Hillside/Mountain – 0.0
•
City Streets – 0.0
7.4 UN-EMF The total drainage area for this location is approximately 352.4 acres and is broken down as follows: •
Residential – 352.4
•
Agricultural – 0.0
•
Commercial – 0.0
•
Industrial – 0.0
•
Lawns/Parks – 0.0
•
Desert – 0.0
•
Hillside/Mountain – 0.0
•
City Streets – 0.0
7.5 FF-ACES The total drainage area for this location is approximately 73.78 acres. Land use data was not evaluated for this location since this sampling location did not meet the definition of an “outfall” or “FSP” as provided in the scope of work for the EEC study. However, this sampling location is interior to the Falcon Field Airport which is a regulated industry under the ADEQ’s Multi-Sector General Permit. As such, all this area is known to be industrial use.
City of Mesa, Storm Water Annual Report
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City of Mesa, Storm Water Annual Report
Page 7-4
8.0
STORM EVENT RECORDS
The 2010 MS4 Permit requires the City to summarize all measurable storm events (0.10 inches or greater) at each monitoring location until such a time that stormwater samples have been collected at that particular monitoring location during that particular season. The information is to include the following: •
Date of each event;
•
Amount of precipitation of each event;
•
Indication of whether or not a sample was collected as part of the event;
•
Information on conditions that prevented the collection of a sample.
Attached in this section is a table summarizing storm event records obtained under the 2010 MS4 Permit.
City of Mesa, Storm Water Annual Report
Page 8-1
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City of Mesa, Storm Water Annual Report
Page 8-2
8/6/13 10:07 8/18/13 0:29 8/24/13 0:43 8/30/13 20:43
11/21/13 23:24 12/4/13 13:24 12/20/13 6:20 7/12/13 14:47 7/16/13 19:22 7/19/13 0:19 7/21/13 0:11
11/4/13 21:31 11/22/13 0:54 7/12/13 14:50 7/15/13 18:10 7/16/13 0:18 7/19/13 0:54 7/21/13 14:37
7/27/13 0:32 8/6/13 10:25 8/18/13 0:17 9/6/13 16:35 9/7/13 8:52 9/8/13 12:23 11/4/13 21:40
11/22/13 14:12
8/6/13 5:29 8/18/13 0:16 8/24/13 0:43 8/30/13 17:09
11/21/13 20:22 12/4/13 11:59 12/20/13 2:18 7/12/13 14:47 7/16/13 19:17 7/19/13 0:19 7/20/13 20:31
11/4/13 21:31 11/21/13 21:19 7/12/13 14:38 7/15/13 18:10 7/16/13 0:16 7/19/13 0:54 7/20/13 20:17
7/27/13 0:20 8/6/13 7:28 8/17/13 22:32 9/6/13 15:47 9/7/13 7:34 9/8/13 7:42 11/4/13 21:32
11/21/13 21:17
0:12 2:57 1:45 0:48 1:18 4:41 0:08 16:55
0:00 3:35 0:12 0:00 0:02 0:00 18:20
3:02 1:25 4:02 0:00 0:05 0:00 3:40
4:38 0:13 0:00 3:34
1:47 0:34 0:32 2:48 0:12 2:33
11/21/13 22:24 7/11/13 10:24 7/15/13 18:19 7/16/13 22:07 7/19/13 0:22 7/20/13 23:00
11/21/13 20:37 7/11/13 9:50 7/15/13 17:47 7/16/13 19:19 7/19/13 0:10 7/20/13 20:27
Storm Event Records
FF-ACES
UN-EMF
54-EMF
0:05 6:25 0:37
7/16/13 3:57 7/16/13 14:40 7/19/13 6:34 7/27/13 0:49
0:07 12:17 0:20 10:19
1:26
Duration
7/16/13 14:35 7/19/13 0:09 7/27/13 0:12
11/4/13 21:29 11/22/13 8:22 7/12/13 15:01
11/4/13 21:22 11/21/13 20:05 7/12/13 14:41 7/15/13 17:38
SS-US60
7/15/13 19:02
7/15/13 17:36
AS-US60
Storm Event Stop Date/Time
Storm Start Date/Time
Storm Monitoring Station
S S S S S S W W
S W S S S S S
W W W S S S S
S S S S
W S S S S S
S S S
W W S S
S
Season(1) (S/W)
0.08 0.09 0.07 0.05 0.03 0.40 0.02 1.62
0.01 0.34 0.02 0.01 0.02 0.01 0.41
0.27 0.04 0.79 0.01 0.03 0.01 0.20
0.06 0.02 0.01 0.90
0.18 0.02 0.03 0.09 0.07 0.16
0.02 0.07 0.51
0.08 1.17 0.02 0.82
Event Rainfall (inches) 0.16
N N N N N N N N
N N N N N N N
N N N N N N N
N N N N
N N N N N N
N N N
N N N N
Flood Event(2) (Y/N) N
Y Y Y Y Y Y Y Y
Y Y Y Y Y Y Y
Y Y Y Y Y Y Y
Y Y Y Y
Y Y Y Y Y Y
Y Y Y
Y Y Y Y
Normal Storm(3) (Y/N) Y
Storm Information
STORM EVENT RECORDS - REPORTING PERIOD 2013-2014
Y Y Y Y Y N Y N
Y N Y Y Y Y N
N Y N Y Y Y N
Y Y Y N
N Y Y Y Y N
Y Y N
Y N Y N
Insufficient Rainfall(4) (Y/N) N
Composite Sample Information
SC
SC
SC
SC
SC
SC
EM
SC
SC
EM
SC
Winter season composite sampling complete
Summer season composite sampling complete
Winter season composite sampling complete
Summer season composite samplig complete
Winter season composite sampling complete
Summer season composite sampling complete
Sampler collected sample on 7/19/13 form nonqualifying event.
Winter season composite sampling complete
Summer season composite sampling complete
Sampler intake block by debris
Winter season composite sampling complete
Sample Collection Notes Result(5) Summer season composite samplig complete SC
Discrete Sample Information
SC
SC
IF
SC
SC
SC
IF
SC
SC
SC
HE
SC
Winter season discrete sampling complete
Page 1 of 2
Summer season discrete sampling complete
Winter season discrete sampling complete
Summer season discrete sampling complete
Winter season discrete sampling complete
Summer season discrete sampling complete
Winter season discrete sampling complete
Summer season discrete sampling complete
Sampling crew did not realize that they could collect discrete samples if a composite sample was not or could not be collected. Crew was retrained in this requirement.
Winter season discrete sampling complete
Sample Collection Notes Result(5) SC Summer season discrete sampling complete
(1) (2) (3) (4) (5)
Seasons: Summer (S): June 1st through October 30th (highlighted yellow). Winter (W): November 1st through May 31st (highlighted blue). Flood Event: Storm intensity exceeding the 100 Year, 2-Hour storm event (i.e. >2.2 inches in two hours). Normal Storm: Storm intensity up to and including the 100-year 2-hour duration storm event (i.e. < 2.2 inches in two hours). Insufficient Rainfall: Rainfall intensity below design storm requirments (i.e. less than 0.10 inches per hour for the summer events and less than 0.10 inches over a three hour period for the winter events). Where sufficient rainfall did occur, indicate one of the following results and/or describe in the "Notes" section: DS (Dangerous Storm): Adverse climatic conditions existed that created a dangerous condition for stormwater monitoring staff (e.g. local flooding, high winds, lightening, etc.). Generally for discrete sampling only. DWF (Dry-Weather Flow): Dry-weather flows were identified prior to event that may contain quantities and concentrations of pollutants that would significantly alter stormwater samples. EM (Equipment Malfunction): Equipment failed to enable to collect a composite sample or failed to notify stormwater monitoring personnel that a representative storm had occurred. HE (Human Error): Sampling was not conducted due to human error. HT (Hold Time): Permit requires sampling events for each location to be at least 72 hours since the last storm event discharge (i.e. flow in response to rainfall). IF (Insufficient Flow): Storm did not result in a level reading of two or more inches at the monitoring location or flow was insuffient to collect a sample. IM (Insufficient Manpower); Storm occurred during off-hours where a less than 20% chance of rain was forecasted and/or appropriate stormwater monitoring personnel were unavailable to respond. IS (Insufficient Sample): Did not collect enough aliquots to qualify as a flow proportional composite sample. NR (Not Required): Samples have been collected for all analyses for current season. SC (Sample Collected): Sample was collected during this storm event.
Storm Event Records
Notes:
Page 2 of 2
9.0
SUMMARY OF MONITORING DATA
The 2010 MS4 Permit requires the City to provide a summary of monitoring data (by location) using a table format as provided in Appendix B of that permit. Instructions stated that the City was to use a separate table for each monitoring location, to enter the analytical results for the stormwater samples collected for each season of the reporting period for each year, to enter subsequent monitoring data for each location on the same form, and to include, as an attachment, the laboratory reports for stormwater samples. The information in the table provided was to include the following: •
The monitoring location identification number;
•
The receiving water;
•
Designated uses; and,
•
The lowest surface water quality standards applicable to the receiving water.
Attached in this section are tables summarizing stormwater monitoring data obtained under the 2010 MS4 Permit. The laboratory analytical reports are included as an attachment to this Annual Report (see Section 13.4 and Attachment A). The 2010 MS4 Permit requires the City to collect samples for a full set of analyses (includes volatile organic compounds, semi-volatile organic compounds, and pesticides) once each wet season every other year and the remaining parameters once each wet season every year beginning in Winter 2010. Due to the time needed to relocate the four of the sampling locations and re-equipping the remaining location and the lack of rainfall once they did become active, the first set of samples were not collected until the summer 2011 sampling period. Also, due programming and trouble-shooting issues during the 2011 sampling period, the City was unable to collect the “full set” from most locations. Therefore, the first “full set” of analyses for all stations was collected during the winter 2011-2012 sampling season. The City will therefore be collecting samples for the full set of analyses during the following seasons:
City of Mesa, Storm Water Annual Report
Page 9-1
•
Winter 2011-12
•
Summer 2012
•
Winter 2013-14
•
Summer 2014
City of Mesa, Storm Water Annual Report
Page 9-2
Degrees Celsius
mg/L
mg/L
mg/L
mg/L
mg/L
MPN
Temperature
Hardness
Total Dissolved Solids (TDS)
Total Suspended Solids (TSS)
Biochemical Oxygen Demand (BOD)
Chemical Oxygen Demand (COD)
Microbiological Escherichia coli (E. coli)
ug/L
ug/L
ug/L
ug/L
Arsenic
Barium
Beryllium
Cadmium
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Nutrients Nitrate plus Nitrite as N
Ammonia as N
Total Kjeldahl Nitrogen (TKN) as N
Total Phosphorus
Orthophosphate (Total)
Organic Toxic Pollutants Total Petroleum Hydrocarbons (TPH)
Total Oil and Grease
Summary of Monitoring Data - Monitoring Station AS-US60
ug/L
Chromium Copper
ug/L
ug/L
Antimony
(8)
ug/L
Cyanide, total (6) Total Metals
Inorganics
Standard Units
gpm
Units(1)
Average Flow Rate(3) pH
Conventional Parameters
Parameter
28.9
NA(5) NA
2
4,667(7) 75
NA
NA
NA
NA
5
5
0.350
1.27
7.10
1.50 1.99
NA
247
36.1(9) NA
280,000
(7)
7 2
28,000(7) 4,667 2
12 0.2
62
15(7) 2.4
1,300
(7)
15
2
700(7) NA
1,867
112 2
2
7
20
1299.7
294
47.1
114
342
98,000
280
747
41
575
NA
NA
NA
NA
7.7 96.5
2097
9.0/6.5(4)
Summer 2011
NA
SWQS Salt(2)
5
10
0.260
0.55
2.70
1.90
0.79
135
1
2
7 2
10 0.2
34
13
2
78 2
2
4
8
1732.9
148
27.8
135
136
48.0
13.5
7.3
2286
Winter 2011-12
5
10
1.10
0.98
9.40
4.11
2.84
440
1
1
17 2
13 0.2
100
7
1
150 1
4
12
50
>2419
501
111
228
580
163
30.3
7.5
1643
Summer 2012
SUMMARY OF MONITORING DATA - MONITORING STATION AS-US60
5
10
0.31
0.68
5.61
2.35
2.00
297
1
1
9 1
17 0.20
66
6
1
88 1
2
6
20
1120.0
254
41.4
168
176
70.0
17.0
7.9
1686
Winter 2012-13
5.0
5.70
0.62
1.03
10.6
3.84
2.72
222
5
4
17 5
9 0.20
47
6
4
102 5
5
5
20
1300.0
534
86.0
196
564
116
33.0
7.2
1178
Summer 2013
9.4
11
0.29
0.45
3.30
1.37
0.807
159
1
1
8 1
8 0.20
35
5
1
56 1
2
5
20
14600.0
170
30.4
80.0
158
51.0
19.0
7.7
781
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 1 of 20
1,200
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Bromoform
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
2-chloroethylvinyl ether
Chloroform
Dichlorobromomethane (Bromodichloromethane) 1,2-dichlorobenzene
1,3-dichlorobenzene
1,4-dichlorobenzene
1,1-dichloroethane
1,2-dichloroethane
1,1-dichloroethylene
1,2-dichloropropane
1,3-dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-tetrachloroethane
Tetrachloroethylene
Toluene
1,2-trans-dichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Trichloroethylene
Trimethylbenzene
Vinyl chloride
Xylene (11)
ug/L
ug/L
ug/L
ug/L
ug/L
2,4-dichlorophenol
2,4-dimethylphenol
4,6-dinitro-o-cresol
2,4-dinitrophenol
2-nitrophenol
ug/L
ug/L
ug/L
Pentachlorophenol
Phenol
2,4,6-trichlorophenol
Summary of Monitoring Data - Monitoring Station AS-US60
15
ug/L
130
9.070 7,300
(9)
4,100
ug/L
NA
110
310
1,000
1,000
2,200
186,667
2,800
NA
280
3,733
2,600
18,667
8,700
6,500
4,700
NA
NA
NA
23,000
NA
26,000
15,000
59,000
NA
2,000
2,500
9,333
180,000
NA
NA
3,800
1,307
15,000
3,733
4-nitrophenol p-chloro-m-cresol
(12)
ug/L
Semi-Volatile Acid Compounds 2-chlorophenol
(10)
18,667
ug/L
Benzene
34
ug/L
3,800
ug/L
SWQS Salt(2)
Acrylonitrile
Units(1)
Volatile Organic Compounds (VOCs)(10) Acrolein
Parameter
40
40
200
40
100
60
200
200
40
40
40
3
1
2
1
0.5
0.5
0.5
0.5
0.5
0.5
5
1
1
0.5
1.5
0.5
0.5
0.5
0.5
1
1
1
0.5
0.5
5
2.5
0.5
0.5
0.5
1
0.5
1
50
Summer 2011
40
40
200
40
100
60
200
200
40
40
40
10
100
20
20
20
20
20
20
20
20
20
50
50
20
40
20
50
20
50
20
20
20
50
20
5
20
50
20
20
25
20
10
50
Winter 2011-12
20
20
100
20
50
30
20
100
20
20
20
10
2
2
2
2
2
2
2
2
5
5
5
2
2
2
2
5
2
2
2
2
2
2
2
1
5
2
2
2.5
5
2
17
15
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
44
44
220
44
110
67
220
220
44
44
44
1.5
0.5
2.0
0.5
0.5
0.5
0.5
0.5
0.5
0.5
5.0
1.0
1.0
0.5
0.5
0.5
0.5
0.5
0.5
1.0
1.0
1.0
0.5
0.5
1.00
1.0
0.5
0.5
0.5
1.0
0.5
1
30
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 2 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Acenaphthylene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenzo(a,h)anthracene
3,3-dichlorobenzidine
Diethyl phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-dinitrotoluene
2,6-dinitrotoluene
Di-n-octyl phthalate
1,2-diphenylhydrazine (as azobenzene)
Fluroranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodimethylamine
N-nitrosodi-n-propylamine
N-nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-trichlorobenzene
Summary of Monitoring Data - Monitoring Station AS-US60
ug/L
Semi-Volatile Base/Neutrals(10) Acenaphthene
Parameter
Units(1)
1,700
28,000
60
NA
88,667
0.03
467
3,200
59,000
1.9
490
3.5
45
6
37,333
2,000
1.8
373,333
3,733
1,867
NA
17,000
26,000
3
1.9
19
1.9
NA
NA
0.2
0.2
280,000
NA
850
SWQS Salt(2)
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
60 80
40
40
40
40
40
40
40
40
40
40
40
Summer 2011
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
40
80
40
40
40
40
40
20
40
40
40
40
40
40
Winter 2011-12
20
20
20
20
20
20
20
20
20
0.1
20
20
20
20
20
20
20
20
20
20
20
40
20
20
0.1
0.1
0.05
0.1
0.1
0.05
0.2
20
20
20
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
44
44
44
44
44
44
44
44
0.11 44
44
44
44
44
44
44
44
44
44
44
44
89
44
44
0.23 0.11
0.170
0.33 0.11
0.100
0.22
44
44
44
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 3 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Alpha-BHC
Beta-BHC
Gamma-BHC (Lindane)
Delta-BHC
Chlordane
4,4’-DDT
4,4’-DDE
4,4’-DDD
Dieldrin
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1242 (AROCLOR 1242)
PCB-1254 (AROCLOR 1254)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1248 (AROCLOR 1248)
PCB-1260 (AROCLOR 1260)
PCB-1016 (AROCLOR 1016)
Toxaphene
Units(1)
0.5
1 1 1 1 1 1
2(14) (14)
2(14) (14)
(14)
2(14) 0.7
2
2
2
10
1
(14)
2
0.5
0.5
0.5
0.5
0.6
0.6
0.09
0.09
0.05
0.2(13) 0.2
0.2
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Summer 2011
(13)
0.2
1.1
1.1
1.1
2.4
NA
NA
NA
NA
3
SWQS Salt(2)
10
1
1
1
1
1
1
1
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Winter 2011-12
20
20
20
20
20
20
20
20
1
1
1
1
1
1
1
1
1
1
1
10
1
1
1
1
1
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
22.0
3.70
3.30
4.00
7.70
4.40
6.30
10.0
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Summary of Monitoring Data - Monitoring Station AS-US60
14) SWQSs reported as PCBs
13) SWQSs report as total endosulfan.
12) Also known as p-nitrophenol.
11) SWQSs reported for total xylenes.
10) Methods: These parameters may be run using the following methods: VOCs, 624 or 8260; SVOCs, 625 or 8270; and PCB / Pesticides, 608/625 or 8081/8082 if the laboratory can pass QA with the method.
9) Depends on pH. Reported values are for pH of 7.0. Where field parameters (i.e. discrete samples) are not collected during the same storm event, the SWQS associated with a pH 7.0 will be used.
7) SWQS for total metals is provided and based on partial body contact. The SWQS for disolved metal concentration for effluent dependent water is dependant on the hardness value for each sample and will in most cases be below the SWQS for partial body contact. 8) Based on total chromium.
6) Based on free-cyanide.
5) Comparison of temperature at point of discharge is upgradient from the nearest stream segment having established SWQSs and is thus not relevant at proposed sampling locations.
4) pH range (maximum/minimum).
3) Average flow rate for the sampling period (no more than 6 hours).
Shaded Cells (results columns): Red - Detected above SWQS; Orange - Not detected, but reported above EDW SWQS; Green - Not detected, but reported above PBC SWQS.
2) Surface Water Quality Standards (SWQSs) established for Salt River segment extending from City of Mesa NW WRF outfall at 33°26'45"/111°56'35" to Tempe Town Lake at 33°26'01"/111°54'55". Partial Body Contact (PBC, shaded in brown) and Aquatic and Wildlife Effluent Dependent Water (A&Wedw, shaded in pink).
1) Analytical results shall be reported in the units specified for each category or parameter.
See attached laboratory analytical reports for flagged data.
Bold values were reported at levels above the laboratory method reporting limit (MRL). Non-bold values are the MRL. Shaded results were detected above the SWQS.
Notes:
ug/L
Pesticides Aldrin
Parameter
Page 4 of 20
Degrees Celsius
mg/L
mg/L
mg/L
mg/L
mg/L
MPN
Hardness
Total Dissolved Solids (TDS)
Total Suspended Solids (TSS)
Biochemical Oxygen Demand (BOD)
Chemical Oxygen Demand (COD)
Microbiological Escherichia coli (E. coli)
(4)
NA NA NA
1,300(7) 15(7) 5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Beryllium
Cadmium
Chromium Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Nutrients Nitrate plus Nitrite as N
Ammonia as N
Total Kjeldahl Nitrogen (TKN) as N
Total Phosphorus
Orthophosphate (Total)
Organic Toxic Pollutants Total Petroleum Hydrocarbons (TPH)
Total Oil and Grease
Summary of Monitoring Data - Monitoring Station SS-US60
ug/L
700 NA
ug/L
(8)
ug/L
Barium
280
NA
NA
NA
NA
NA
NA
NA
5
10
NA
NA
NA
NA
NA
NA NA
280,000(7)
NA
NA
NA
4,667(7) 75
28,000(7) 33
NA
NA
NA
(7)
NA
NA
1,867
98,000
NA
Arsenic
747
ug/L
Antimony
20
8820.0
NA
NA
NA
NA
26.5 NA
7.8
NA
Summer 2011
ug/L
84
575
NA
NA
NA
NA
NA(5) NA
9.0/6.5
NA
SWQS EMF(2)
Cyanide, total (6) Total Metals
Inorganics
Standard Units
Temperature
gpm
Units1
Average Flow Rate(3) pH
Conventional Parameters
Parameter
5
10
0.28 0.2
1.60
1.01
0.4
88
2
2
3 2
4 0.2
24
9
2
35 2
2
2
8
1986.3
56
9.20
53.0
62.0
28.0
13.0
7.2
666
Winter 2011-12
5
10
0.33 0.2
1.40
1.17
0.49
110
1
1
4 2
5 0.2
40
4
1
42 1
2
3
20
2419.2
96
11.0
59.0
79.0
17.0
30.0
7.2
1207
Summer 2012
SUMMARY OF MONITORING DATA - MONITORING STATION SS-US60
5
10
0.23
0.45
4.10
1.86
2.00
131
1
1
6 1
6 0.20
31
5
1
56 1
2 1
20
613
196
30.6
110
97.0
42.0
19.0
7.4
448
Winter 2012-13
5
10
0.35 0.20
2.30
1.56
0.826
66
5
1
5
5
0.20
28 5
5
1
21 5
5
5
20
1990.0
50
9.20
120
25.0
12.0
28.2
7.3
1603
Summer 2013
5
11
0.37
0.37
4.40
1.88
1.06
208
1
1
6 1
4 0.20
63
3
1
37 1
1
4
8
218.0
220
23.4
64.0
169
47.0
21
7.2
226
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 5 of 20
5,900
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Bromoform
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
2-chloroethylvinyl ether
Chloroform
Dichlorobromomethane (Bromodichloromethane) 1,2-dichlorobenzene
1,3-dichlorobenzene
1,4-dichlorobenzene
1,1-dichloroethane
1,2-dichloroethane
1,1-dichloroethylene
1,2-dichloropropane
1,3-dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-tetrachloroethane
Tetrachloroethylene
Toluene
1,2-trans-dichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Trichloroethylene
Trimethylbenzene
Vinyl chloride
Xylene (11)
ug/L
ug/L
ug/L
ug/L
ug/L
2,4-dichlorophenol
2,4-dimethylphenol
4,6-dinitro-o-cresol
2,4-dinitrophenol
2-nitrophenol
ug/L
ug/L
ug/L
Pentachlorophenol
Phenol
2,4,6-trichlorophenol
Summary of Monitoring Data - Monitoring Station SS-US60
ug/L
130
36.760 180,000
(9)
NA 48,000
ug/L
NA
1,867
3,733
18,667
2,800
4,667
186,667
2,800
NA
280
3,733
1,866,667
18,667
373,333
9,333
93,333
NA
NA
NA
93,333
NA
84,000
46,667
186,667
NA
6,500
NA
9,333
NA
NA
NA
18,677
1,307
18,667
3,733
4-nitrophenol p-chloro-m-cresol
(12)
ug/L
Semi-Volatile Acid Compounds 2-chlorophenol
(10)
18,667
ug/L
Benzene
467
ug/L
37,333
ug/L
SWQS EMF(2)
Acrylonitrile
Units1
Volatile Organic Compounds (VOCs)(10) Acrolein
Parameter
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
5
5
2
2
2.5
5
2
10
50
Summer 2011
10
10
50
10
25
15
50
20
10
10
10
100
20
20
20
20
20
20
20
20
20
50
50
20
20
40
20
50
20
50
20
20
20
20
20
1
50
20
20
25
50
20
10
50
Winter 2011-12
10
10
50
10
25
15
50
50
10
50
10
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
5
5
2
2
2.5
5
2
50
50
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
22
22
110
22
54
33
110
110
22
22
22
1.5
0.5
2.0
0.5
0.5
0.5
0.5
0.5
0.5
0.5
5.0
1.0
1.0
0.5
0.5
0.5
0.5
0.5
0.5
1.0
1.0
1.0
0.5
0.5
5.00
1.0
0.5
0.5
0.5
1.0
0.5
10
50
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 6 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Acenaphthylene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenzo(a,h)anthracene
3,3-dichlorobenzidine
Diethyl phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-dinitrotoluene
2,6-dinitrotoluene
Di-n-octyl phthalate
1,2-diphenylhydrazine (as azobenzene)
Fluroranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodimethylamine
N-nitrosodi-n-propylamine
N-nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-trichlorobenzene
Summary of Monitoring Data - Monitoring Station SS-US60
ug/L
Semi-Volatile Base/Neutrals(10) Acenaphthene
Parameter
Units1
9,333
28,000
NA
NA
88,667
0.03
467
18,667
186,667
1.9
850
11,200
187
747
37,333
37,333
1.8
373,333
3,733
1,867
NA
NA
746,667
3
1.9
19
1.9
NA
NA
0.2
0.2
280,000
NA
56,000
SWQS EMF(2)
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Summer 2011
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
10
Winter 2011-12
10
10
10
10
10
10
10
10
10
0.1
10
10
10
10
10
10
2.2
10
10
10
10
20
10
2.9
0.1
0.1
0.05
0.1
0.1
0.05
0.2
10
10
10
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
22
22
22
22
22
22
22
22
0.32 22
22
22
22
22
22
22
22
22
22
22
22
43
22
22
0.78 0.11
0.41
0.89 0.11
0.330
0.23
22
22
22
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 7 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Alpha-BHC
Beta-BHC
Gamma-BHC (Lindane)
Delta-BHC
Chlordane
4,4’-DDT
4,4’-DDE
4,4’-DDD
Dieldrin
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1242 (AROCLOR 1242)
PCB-1254 (AROCLOR 1254)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1248 (AROCLOR 1248)
PCB-1260 (AROCLOR 1260)
PCB-1016 (AROCLOR 1016)
Toxaphene
Units1
NA NA NA NA NA
(14)
11(14) 11(14) (14)
(14)
11 11
11
11
NA
NA
11(14)
11
NA
NA
NA
NA
(14)
0.9
0.9
0.7
NA
NA
NA
3(13) 3 0.7
NA
(13)
3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Summer 2011
4
1.1
1.1
1.1
3.2
NA
NA
NA
NA
4.5
SWQS EMF(2)
10
10
10
10
10
10
10
10
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Winter 2011-12
1.6
3.3
2.9
3.5
6.8
4
5.6
9
0.13
0.28
0.18
0.14
1
1
1
1
1
1
1
1
1
1
1
1
1
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
21.0
21.0
21.0
21.0
21.0
21.0
21.0
21.0
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
11.0
1.10
1.10
1.10
1.10
1.10
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Summary of Monitoring Data - Monitoring Station SS-US60
14) SWQSs reported as PCBs
13) SWQSs report as total endosulfan.
12) Also known as p-nitrophenol.
11) SWQSs reported for total xylenes.
10) Methods: These parameters may be run using the following methods: VOCs, 624 or 8260; SVOCs, 625 or 8270; and PCB / Pesticides, 608/625 or 8081/8082 if the laboratory can pass QA with the method.
9) Depends on pH. Reported values are for pH of 7.0. Where field parameters (i.e. discrete samples) are not collected during the same storm event, the SWQS associated with a pH 7.0 will be used.
7) SWQS for total metals is provided and based on partial body contact. The SWQS for disolved metal concentration for ephemeral water is dependant on the hardness value for each sample and will in most cases be below the SWQS for partial body contact. 8) Based on total chromium.
6) Based on free-cyanide.
5) No surface water quality standard established for maximum allowable increase in ambient water temperature for ephemeral waters.
4) pH range (maximum/minimum).
3) Average flow rate for the sampling period (no more than 6 hours).
Shaded Cells (results columns): Red - Detected above SWQS; Orange - Not detected, but reported above Ephemeral SWQS; Green - Not detected, but reported above PBC SWQS.
2) Surface Water Quality Standards (SWQSs) for EMF are based on that provided in A.A.C. R18-11-105(1) per 2010 MS4 Permit ADEQ Response to Comments. Partial Body Contact (PBC, shaded in brown) and Aquatic & Wildlife Ephemeral (A&We, shaded in blue).
1) Analytical results shall be reported in the units specified for each category or parameter.
See attached laboratory analytical reports for flagged data.
Bold values were reported at levels above the laboratory method reporting limit (MRL). Non-bold values are the MRL. Shaded results were detected above the SWQS.
Notes:
ug/L
Pesticides Aldrin
Parameter
Page 8 of 20
Degrees Celsius
mg/L
mg/L
mg/L
mg/L
mg/L
MPN
Temperature
Hardness
Total Dissolved Solids (TDS)
Total Suspended Solids (TSS)
Biochemical Oxygen Demand (BOD)
Chemical Oxygen Demand (COD)
Microbiological Escherichia coli (E. coli)
ug/L
ug/L
ug/L
ug/L
Arsenic
Barium
Beryllium
Cadmium
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Nutrients Nitrate plus Nitrite as N
Ammonia as N
Total Kjeldahl Nitrogen (TKN) as N
Total Phosphorus
Orthophosphate (Total)
Organic Toxic Pollutants Total Petroleum Hydrocarbons (TPH)
Total Oil and Grease
Summary of Monitoring Data - Monitoring Station 54-EMF
ug/L
Chromium Copper
ug/L
ug/L
Antimony
(8)
ug/L
Cyanide, total (6) Total Metals
Inorganics
Standard Units
gpm
Units1
Average Flow Rate(3) pH
Conventional Parameters
Parameter
28.5
NA(5) NA
1
1
4,667(7) 75
NA
NA
NA
NA
NA
NA
NA
280,000
(7)
41 1
28,000(7) 33
5
5
0.62 NA
4.70 NA
0.95
263
1
10.0 0.2
33
15(7) 5
1,300
(7)
16.0
700(7) NA
1,867
124 1
4
10
20
613.1
291
252 NA
336
98,000
280
747
84
575
NA
NA
NA
NA
7.6 151
194
NA
Summer 2011
9.0/6.5(4)
SWQS EMF(2)
5
10
0.240
0.73
2.70
1.23
1.19
102
1
1
6 1
4 0.2
28
7
1
47 1
1
2
8
816.4
160
17.2
156
72.0
44.8
12.0
7.4
289
Winter 2011-12
5
10
0.36
1.71
1.80
1.82
0.87
150
1
1
12 2
17 0.2
39
9
1
120 1
3
3
20
1553.1
232
14.0
219
93.0
25.0
29.5
7.0
3106
Summer 2012
SUMMARY OF MONITORING DATA - MONITORING STATION 54-EMF
5
10
0.23
0.58
2.90
1.00
2.00
88
1
1
5 1
7 0.20
19
4
1
47 1
1
1
20
2400.0
105
20.1
118
53.0
30.0
14
7.4
82
Winter 2012-13
5
10
0.22
0.44
2.80
1.42
1.14
68
5
1
6 5
7 0.20
15
5
5
48 5
5
5
20
7980.0
86
13.2
62.0
122
28.0
30.0
7.6
211
Summer 2013
5
11
0.36
1.30
3.20
1.00
1.02
178
1
1
9 1
12 0.20
28
7
1
94 1
3
2
8
1990.0
140
17.6
248
118
42.0
12.0
7.4
54
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 9 of 20
5,900
NA 48,000
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Bromoform
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
2-chloroethylvinyl ether
Chloroform
Dichlorobromomethane (Bromodichloromethane) 1,2-dichlorobenzene
1,3-dichlorobenzene
1,4-dichlorobenzene
1,1-dichloroethane
1,2-dichloroethane
1,1-dichloroethylene
1,2-dichloropropane
1,3-dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-tetrachloroethane
Tetrachloroethylene
Toluene
1,2-trans-dichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Trichloroethylene
Trimethylbenzene
Vinyl chloride
Xylene (11)
Semi-Volatile Acid Compounds(10) 2-chlorophenol
2,4-dichlorophenol
2,4-dimethylphenol
4,6-dinitro-o-cresol
2,4-dinitrophenol
2-nitrophenol
4-nitrophenol(12) p-chloro-m-cresol
Pentachlorophenol
Phenol
2,4,6-trichlorophenol
Summary of Monitoring Data - Monitoring Station 54-EMF
18,667
ug/L
Benzene
467
ug/L
(9)
130
36.760 180,000
NA
1,867
3,733
18,667
2,800
4,667
186,667
2,800
NA
280
3,733
1,866,667
18,667
373,333
9,333
93,333
NA
NA
NA
93,333
NA
84,000
46,667
186,667
NA
6,500
NA
9,333
NA
NA
NA
18,677
1,307
18,667
3,733
37,333
ug/L
SWQS EMF(2)
Acrylonitrile
Units1
Volatile Organic Compounds (VOCs)(10) Acrolein
Parameter
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
3
1
2
1
0.5
0.5
0.5
0.5
0.5
0.5
5
1
1
0.5
1.5
0.5
0.5
0.5
0.5
1
1
1
0.5
0.5
5
2.5
0.5
0.5
0.5
1
0.5
1
50
Summer 2011
23
23
110
23
57
34
23
110
23
23
23
100
20
20
20
20
20
20
20
20
20
50
50
50
20
40
20
50
20
20
20
20
20
20
20
5
50
20
20
25
50
20
10
50
Winter 2011-12
10
10
50
10
25
15
50
50
10
10
10
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
1
5
2
2
2.5
5
2
50
4
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
21
21
110
21
53
32
21
21
21
21
21
1.5
0.5
2.0
0.5
0.5
0.5
0.5
0.5
0.5
0.5
5.0
1.0
1.0
0.5
0.5
0.5
0.5
0.5
1.0
1.0
1.0
0.5
0.5
0.5
5.00
1.0
0.5
0.5
0.5
1.0
0.5
10
50
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 10 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Acenaphthylene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenzo(a,h)anthracene
3,3-dichlorobenzidine
Diethyl phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-dinitrotoluene
2,6-dinitrotoluene
Di-n-octyl phthalate
1,2-diphenylhydrazine (as azobenzene)
Fluroranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodimethylamine
N-nitrosodi-n-propylamine
N-nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-trichlorobenzene
Summary of Monitoring Data - Monitoring Station 54-EMF
ug/L
Semi-Volatile Base/Neutrals(10) Acenaphthene
Parameter
Units1
9,333
28,000
NA
NA
88,667
0.03
467
18,667
186,667
1.9
850
11,200
187
747
37,333
37,333
1.8
373,333
3,733
1,867
NA
NA
746,667
3
1.9
19
1.9
NA
NA
0.2
0.2
280,000
NA
56,000
SWQS EMF(2)
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Summer 2011
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
23
Winter 2011-12
10
10
10
10
10
10
10
10
10
0.1
10
10
10
10
10
10
2.2
10
10
10
10
20
10
2.9
0.1
0.1
0.05
0.1
0.1
0.05
0.2
10
10
10
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
21
21
21
21
21
21
21
21
21
0.10
21
21
21
21
21
21
21
21
21
110
21
43
21
21
0.10
0.10
0.052
0.10
0.10
0.052
0.21
21
21
21
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 11 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Alpha-BHC
Beta-BHC
Gamma-BHC (Lindane)
Delta-BHC
Chlordane
4,4’-DDT
4,4’-DDE
4,4’-DDD
Dieldrin
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1242 (AROCLOR 1242)
PCB-1254 (AROCLOR 1254)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1248 (AROCLOR 1248)
PCB-1260 (AROCLOR 1260)
PCB-1016 (AROCLOR 1016)
Toxaphene
Units1
NA NA NA NA NA
11(14) (14)
11(14) (14)
11(14) 11
11
11
NA
NA
11(14)
11
NA
NA
NA
NA
NA
(14)
0.9
0.9
0.7
0.7
NA
3(13) 3 NA
NA
(13)
3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Summer 2011
4
1.1
1.1
1.1
3.2
NA
NA
NA
NA
4.5
SWQS EMF(2)
10
10
10
10
10
10
10
10
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
0.5
Winter 2011-12
1.6
3.3
2.9
3.5
6.8
4
5.6
9
0.13
0.28
0.18
0.14
1
1
1
1
1
1
1
1
1
1
1
1
1
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
1.10
3.70
3.30
22.0
7.70
4.40
4.00
10.0
1.10
1.10
1.10
1.10
0.500
1.10
1.10
1.10
1.10
1.10
1.10
1.80
1.10
0.500
0.500
0.500
1.10
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Summary of Monitoring Data - Monitoring Station 54-EMF
14) SWQSs reported as PCBs
13) SWQSs report as total endosulfan.
12) Also known as p-nitrophenol.
11) SWQSs reported for total xylenes.
10) Methods: These parameters may be run using the following methods: VOCs, 624 or 8260; SVOCs, 625 or 8270; and PCB / Pesticides, 608/625 or 8081/8082 if the laboratory can pass QA with the method.
9) Depends on pH. Reported values are for pH of 7.0. Where field parameters (i.e. discrete samples) are not collected during the same storm event, the SWQS associated with a pH 7.0 will be used.
7) SWQS for total metals is provided and based on partial body contact. The SWQS for disolved metal concentration for ephemeral water is dependant on the hardness value for each sample and will in most cases be below the SWQS for partial body contact. 8) Based on total chromium.
6) Based on free-cyanide.
5) No surface water quality standard established for maximum allowable increase in ambient water temperature for ephemeral waters.
4) pH range (maximum/minimum).
3) Average flow rate for the sampling period (no more than 6 hours).
Shaded Cells (results columns): Red - Detected above SWQS; Orange - Not detected, but reported above Ephemeral SWQS; Green - Not detected, but reported above PBC SWQS.
2) Surface Water Quality Standards (SWQSs) for EMF are based on that provided in A.A.C. R18-11-105(1) per 2010 MS4 Permit ADEQ Response to Comments. Partial Body Contact (PBC, shaded in brown) and Aquatic & Wildlife Ephemeral (A&We, shaded in blue).
1) Analytical results shall be reported in the units specified for each category or parameter.
See attached laboratory analytical reports for flagged data.
Bold values were reported at levels above the laboratory method reporting limit (MRL). Non-bold values are the MRL. Shaded results were detected above the SWQS.
Notes:
ug/L
Pesticides Aldrin
Parameter
Page 12 of 20
Degrees Celsius
mg/L
mg/L
mg/L
mg/L
mg/L
MPN
Hardness
Total Dissolved Solids (TDS)
Total Suspended Solids (TSS)
Biochemical Oxygen Demand (BOD)
Chemical Oxygen Demand (COD)
Microbiological Escherichia coli (E. coli)
(4)
NA NA NA
1,300(7) 15(7) 5
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Beryllium
Cadmium
Chromium Copper
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Nutrients Nitrate plus Nitrite as N
Ammonia as N
Total Kjeldahl Nitrogen (TKN) as N
Total Phosphorus
Orthophosphate (Total)
Organic Toxic Pollutants Total Petroleum Hydrocarbons (TPH)
Total Oil and Grease
Summary of Monitoring Data - Monitoring Location UN-EMF
ug/L
700 NA
ug/L
(8)
ug/L
Barium
280
NA
NA
NA
NA
NA
NA
NA
5
10
NA
NA
NA
NA
NA
NA NA
280,000(7)
NA
NA
NA
4,667(7) 75
28,000(7) 33
NA
NA
NA
(7)
NA
NA
1,867
98,000
NA
Arsenic
747
ug/L
Antimony
20
1,986.30
NA
NA
NA
NA
24.0 NA
11.3
NA
Summer 2011
ug/L
84
575
NA
NA
NA
NA
NA(5) NA
9.0/6.5
NA
SWQS EMF(2)
Cyanide, total (6) Total Metals
Inorganics
Standard Units
Temperature
gmp
Units1
Average Flow Rate(3) pH
Conventional Parameters
Parameter
5
10
0.28
0.44
3.00
1.48
2
97
1
1
4 2
5 0.2
31
5
1
45 1
1
3
20
12,303.30
198
20.0
120
102
33.5
14.5
7.5
690
Winter 2011-12
19.1
10
0.22
0.51
1.30
1.26
0.69
160
1
1
9 2
16 0.2
33
7
1
89 1
3
3
20
1732.9
105
11.0
201
69.0
32.0
31.0
7.6
35,748
Summer 2012
SUMMARY OF MONITORING DATA - MONITORING STATION UN-EMF
5
10
0.23
0.39
2.95
1.48
2.00
139
1
1
6 1
6 0.20
30
5
1
55 1
2 1
20
1410.0
131
15.4
106
101
41.0
16.5
7.3
591
Winter 2012-13
5.0
11.0
0.22
0.71
6.27
2.75
0.400
215
5
1
16 5
10 0.20
44
7
1
101 5
5
5
20
2260.0
267
41.0
180
152
87.0
29.5
7.1
387
Summer 2013
5
11
0.47 0.20
4.70
1.57
1.04
169
1
1
6 1
8 0.20
31
4
1
75 1
2
2
20
2420.0
180
22.2
88.0
220
77.0
19.5
7.3
1412
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 13 of 20
5,900
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Bromoform
Carbon tetrachloride
Chlorobenzene
Chlorodibromomethane
Chloroethane
2-chloroethylvinyl ether
Chloroform
Dichlorobromomethane (Bromodichloromethane) 1,2-dichlorobenzene
1,3-dichlorobenzene
1,4-dichlorobenzene
1,1-dichloroethane
1,2-dichloroethane
1,1-dichloroethylene
1,2-dichloropropane
1,3-dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-tetrachloroethane
Tetrachloroethylene
Toluene
1,2-trans-dichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Trichloroethylene
Trimethylbenzene
Vinyl chloride
Xylene (11)
ug/L
ug/L
ug/L
ug/L
ug/L
2,4-dichlorophenol
2,4-dimethylphenol
4,6-dinitro-o-cresol
2,4-dinitrophenol
2-nitrophenol
ug/L
ug/L
ug/L
Pentachlorophenol
Phenol
2,4,6-trichlorophenol
Summary of Monitoring Data - Monitoring Location UN-EMF
ug/L
130
36.760 180,000
(9)
NA 48,000
ug/L
NA
1,867
3,733
18,667
2,800
4,667
186,667
2,800
NA
280
3,733
1,866,667
18,667
373,333
9,333
93,333
NA
NA
NA
93,333
NA
84,000
46,667
186,667
NA
6,500
NA
9,333
NA
NA
NA
18,677
1,307
18,667
3,733
4-nitrophenol p-chloro-m-cresol
(12)
ug/L
Semi-Volatile Acid Compounds 2-chlorophenol
(10)
18,667
ug/L
Benzene
467
ug/L
37,333
ug/L
SWQS EMF(2)
Acrylonitrile
Units1
Volatile Organic Compounds (VOCs)(10) Acrolein
Parameter
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
5
5
2
2
2.5
5
2
10
50
Summer 2011
10
10
50
10
25
15
50
50
10
10
10
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
1
5
2
2
2.5
5
2
1
30
Winter 2011-12
20
20
100
20
50
30
100
100
20
20
20
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
5
5
2
2
2.5
5
2
50
50
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
44
24
220
44
110
67
220
220
44
44
44
1.5
0.5
2.0
0.5
0.5
0.5
0.5
0.5
0.5
0.5
5.0
1.0
1.0
0.5
0.5
0.5
0.5
0.5
1.0
1.0
1.0
0.5
0.5
0.5
1.00
1.0
0.5
0.5
0.5
1.0
0.5
10
50
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 14 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Acenaphthylene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenzo(a,h)anthracene
3,3-dichlorobenzidine
Diethyl phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-dinitrotoluene
2,6-dinitrotoluene
Di-n-octyl phthalate
1,2-diphenylhydrazine (as azobenzene)
Fluroranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodimethylamine
N-nitrosodi-n-propylamine
N-nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-trichlorobenzene
Summary of Monitoring Data - Monitoring Location UN-EMF
ug/L
Semi-Volatile Base/Neutrals(10) Acenaphthene
Parameter
Units1
9,333
28,000
NA
NA
88,667
0.03
467
18,667
186,667
1.9
850
11,200
187
747
37,333
37,333
1.8
373,333
3,733
1,867
NA
NA
746,667
3
1.9
19
1.9
NA
NA
0.2
0.2
280,000
NA
56,000
SWQS EMF(2)
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Summer 2011
10
10
10
10
10
10
10
10
10
0.1
10
10
10
10
10
10
10
10
10
10
10
20
10
10
0.1
0.1
0.05
0.1
0.1
0.05
0.2
10
10
10
Winter 2011-12
20
20
20
20
20
20
20
20
20
0.1
20
20
20
20
20
20
2.2
20
20
20
20
40
20
2.9
0.1
0.1
0.05
0.1
0.1
0.05
0.2
20
20
20
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
44
24
44
44
44
44
44
44
44
0.1
44
44
44
220
44
44
44
44
44
44
44
44
220
44
0.12 0.10
0.093
0.21
0.19
0.051
0.2
44
44
44
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 15 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Alpha-BHC
Beta-BHC
Gamma-BHC (Lindane)
Delta-BHC
Chlordane
4,4’-DDT
4,4’-DDE
4,4’-DDD
Dieldrin
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1242 (AROCLOR 1242)
PCB-1254 (AROCLOR 1254)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1248 (AROCLOR 1248)
PCB-1260 (AROCLOR 1260)
PCB-1016 (AROCLOR 1016)
Toxaphene
Units1
NA NA NA NA NA
(14)
11(14) (14)
(14)
(14)
11 11
11
11
11
NA
NA
11(14)
11
NA
NA
NA
NA
(14)
0.9
0.9
0.7
NA
NA
NA
3(13) 3 0.7
NA
(13)
3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Summer 2011
4
1.1
1.1
1.1
3.2
NA
NA
NA
NA
4.5
SWQS EMF(2)
1
1
1
1
1
1
1
1
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
0.05
Winter 2011-12
1.6
3.3
2.9
3.5
6.8
4
5.6
9
0.13
0.28
0.18
0.14
1
1
1
1
1
1
1
1
1
1
1
1
1
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
21.0
3.40
3.00
3.70
7.00
4.10
5.80
9.30
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
1.10
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Summary of Monitoring Data - Monitoring Location UN-EMF
14) SWQSs reported as PCBs
13) SWQSs report as total endosulfan.
12) Also known as p-nitrophenol.
11) SWQSs reported for total xylenes.
10) Methods: These parameters may be run using the following methods: VOCs, 624 or 8260; SVOCs, 625 or 8270; and PCB / Pesticides, 608/625 or 8081/8082 if the laboratory can pass QA with the method.
9) Depends on pH. Reported values are for pH of 7.0. Where field parameters (i.e. discrete samples) are not collected during the same storm event, the SWQS associated with a pH 7.0 will be used.
7) SWQS for total metals is provided and based on partial body contact. The SWQS for disolved metal concentration for ephemeral water is dependant on the hardness value for each sample and will in most cases be below the SWQS for partial body contact. 8) Based on total chromium.
6) Based on free-cyanide.
5) No surface water quality standard established for maximum allowable increase in ambient water temperature for ephemeral waters.
4) pH range (maximum/minimum).
3) Average flow rate for the sampling period (no more than 6 hours).
Shaded Cells (results columns): Red - Detected above SWQS; Orange - Not detected, but reported above Ephemeral SWQS; Green - Not detected, but reported above PBC SWQS.
2) Surface Water Quality Standards (SWQSs) for EMF are based on that provided in A.A.C. R18-11-105(1) per 2010 MS4 Permit ADEQ Response to Comments. Partial Body Contact (PBC, shaded in brown) and Aquatic & Wildlife Ephemeral (A&We, shaded in blue).
1) Analytical results shall be reported in the units specified for each category or parameter.
See attached laboratory analytical reports for flagged data.
Bold values were reported at levels above the laboratory method reporting limit (MRL). Non-bold values are the MRL. Shaded results were detected above the SWQS.
Notes:
ug/L
Pesticides Aldrin
Parameter
Page 16 of 20
Degrees Celsius
mg/L
mg/L
mg/L
mg/L
mg/L
MPN
Hardness
Total Dissolved Solids (TDS)
Total Suspended Solids (TSS)
Biochemical Oxygen Demand (BOD)
Chemical Oxygen Demand (COD)
Microbiological Escherichia coli (E. coli)
ug/L
ug/L
ug/L
ug/L
Arsenic
Barium
Beryllium
Cadmium
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
mg/L
Lead
Mercury
Nickel
Selenium
Silver
Thallium
Zinc
Nutrients Nitrate plus Nitrite as N
Ammonia as N
Total Kjeldahl Nitrogen (TKN) as N
Total Phosphorus
Orthophosphate (Total)
Organic Toxic Pollutants Total Petroleum Hydrocarbons (TPH)
Total Oil and Grease
Summary of Monitoring Data - Monitoring Station FF-ACES
ug/L
Chromium Copper
ug/L
ug/L
Antimony
(8)
ug/L
Cyanide, total (6) Total Metals
Inorganics
Standard Units
Temperature
gpm
Units1
Average Flow Rate(3) pH
Conventional Parameters
Parameter
(4)
NA
NA
NA
NA
NA
NA
NA
280,000
(7)
4,667(7) 75
28,000(7) 33
15 5
(7)
1,300
5
10
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
700(7) NA (7)
NA
NA
NA
NA
20
146.7
NA
NA
NA
NA
24.0 NA
11.2
NA
Summer 2011
1,867
98,000
280
747
84
575
NA
NA
NA
NA
NA NA
(5)
9.0/6.5
NA
SWQS EMF(2)
5
10
0.35 0.2
2.40
1.16
2
246
1
1
6 1
16 0.2
20
10
1
41 1
1
1
20
44.8
97
19.7
24.0
72.0
24.2
15.0
7.6
896
Winter 2011-12
5
10
0.41 0.2
1.30
1.28
0.42
190
1
1
9 2
23 0.2
23
8
2
76 1
2
3
20
334.8
120
7.00
204
50.0
24.0
28.5
8.5
6392
Summer 2012
SUMMARY OF MONITORING DATA - MONITORING STATION FF-ACES
5
10
0.21 0.20
1.23
0.46
2.00
111
1
1
4 1
8 0.20
9
8
1
27 1
1
1
20
345.0
50
3.70
76.0
14.0 20.0
14.0
8.6
698
Winter 2012-13
5
11
0.22
0.15
2.09
1.56
2.00
123
5
1
5
5
12 0.20
10
12
1
30 5
5
5
20
51.2
56
7.00
58.0
192
18.0
25.6
7.3
4048
Summer 2013
5
11
0.24 0.20
1.10
0.29
0.500
60
1
1
5 1
8 0.20
8
4
1
47 1
1
1
20
178.0
38
2.10
140
49.0
21.0
17.0
7.4
7822
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 17 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Chlorodibromomethane
Chloroethane
2-chloroethylvinyl ether
Chloroform
Dichlorobromomethane (Bromodichloromethane) 1,2-dichlorobenzene
1,3-dichlorobenzene
1,4-dichlorobenzene
1,1-dichloroethane
1,2-dichloroethane
1,1-dichloroethylene
1,2-dichloropropane
1,3-dichloropropylene
Ethylbenzene
Methyl bromide
Methyl chloride
Methylene chloride
1,1,2,2-tetrachloroethane
Tetrachloroethylene
Toluene
1,2-trans-dichloroethylene
1,1,1-trichloroethane
1,1,2-trichloroethane
Trichloroethylene
Trimethylbenzene
Vinyl chloride
48,000
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
2,4-dimethylphenol
4,6-dinitro-o-cresol
2,4-dinitrophenol
2-nitrophenol
4-nitrophenol(12) p-chloro-m-cresol
Pentachlorophenol
Phenol
2,4,6-trichlorophenol
Summary of Monitoring Data - Monitoring Station FF-ACES
NA
ug/L
(9)
130
36.760 180,000
NA
1,867
3,733
18,667
2,800
ug/L
2,4-dichlorophenol
4,667
186,667
2,800
NA
280
3,733
1,866,667
18,667
373,333
9,333
93,333
NA
NA
NA
93,333
NA
84,000
46,667
186,667
NA
6,500
NA
9,333
NA
NA
NA
18,677
1,307
18,667
3,733
Semi-Volatile Acid Compounds 2-chlorophenol
ug/L
ug/L
Chlorobenzene
(10)
ug/L
Carbon tetrachloride
Xylene
5,900
ug/L
Bromoform
(11)
18,667
ug/L
Benzene
37,333
ug/L
Acrylonitrile
467
SWQS EMF(2)
ug/L
Units1
Volatile Organic Compounds (VOCs)(10) Acrolein
Parameter
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
5
5
2
2
2.5
5
2
10
50
Summer 2011
20
20
100
20
50
30
100
100
20
20
20
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
1
5
2
2
2.5
5
2
1
30
Winter 2011-12
20
20
100
20
50
30
100
100
20
20
20
10
2
2
2
2
2
2
2
2
2
5
5
2
2
2
2
5
2
2
2
2
2
2
2
5
5
2
2
2.5
5
2
50
50
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
24
24
120
24
59
35
24
120
24
24
24
1.5
0.5
2.0
0.5
0.5
0.5
0.5
0.5
0.5
0.5
5.0
1.0
1.0
0.5
0.5
0.5
0.5
0.5
1.0
1.0
1.0
0.5
0.5
0.5
5.00
1.0
0.5
0.5
0.5
1.0
0.5
10
50
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 18 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Acenaphthylene
Anthracene
Benz(a)anthracene
Benzo(a)pyrene
Benzo(b)fluoranthene
Benzo(g,h,i)perylene
Benzo(k)fluoranthene
Chrysene
Dibenzo(a,h)anthracene
3,3-dichlorobenzidine
Diethyl phthalate
Dimethyl phthalate
Di-n-butyl phthalate
2,4-dinitrotoluene
2,6-dinitrotoluene
Di-n-octyl phthalate
1,2-diphenylhydrazine (as azobenzene)
Fluroranthene
Fluorene
Hexachlorobenzene
Hexachlorobutadiene
Hexachlorocyclopentadiene
Hexachloroethane
Indeno(1,2,3-cd)pyrene
Isophorone
Naphthalene
Nitrobenzene
N-nitrosodimethylamine
N-nitrosodi-n-propylamine
N-nitrosodiphenylamine
Phenanthrene
Pyrene
1,2,4-trichlorobenzene
Summary of Monitoring Data - Monitoring Station FF-ACES
ug/L
Semi-Volatile Base/Neutrals(10) Acenaphthene
Parameter
Units1
9,333
28,000
NA
NA
88,667
0.03
467
18,667
186,667
1.9
850
11,200
187
747
37,333
37,333
1.8
373,333
3,733
1,867
NA
NA
746,667
3
1.9
19
1.9
NA
NA
0.2
0.2
280,000
NA
56,000
SWQS EMF(2)
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Summer 2011
20
20
20
20
20
20
20
20
20
0.1
20
20
20
20
20
20
20
20
20
20
20
40
20
20
0.1
0.1
0.05
0.1
0.1
0.05
0.2
20
20
20
Winter 2011-12
20
20
20
20
20
20
20
20
20
0.1
20
20
20
20
20
20
2.2
20
20
20
20
40
20
2.9
0.1
0.1
0.05
0.1
0.1
0.05
0.2
20
20
20
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
24
24
24
24
24
24
24
24
24
0.11
24
24
24
24
24
24
24
24
24
120
24
47
24
24
0.11
0.11
0.053
0.11
0.11
0.053
0.21
24
24
24
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Page 19 of 20
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
ug/L
Alpha-BHC
Beta-BHC
Gamma-BHC (Lindane)
Delta-BHC
Chlordane
4,4’-DDT
4,4’-DDE
4,4’-DDD
Dieldrin
Alpha-endosulfan
Beta-endosulfan
Endosulfan sulfate
Endrin
Endrin aldehyde
Heptachlor
Heptachlor epoxide
PCB-1242 (AROCLOR 1242)
PCB-1254 (AROCLOR 1254)
PCB-1221 (AROCLOR 1221)
PCB-1232 (AROCLOR 1232)
PCB-1248 (AROCLOR 1248)
PCB-1260 (AROCLOR 1260)
PCB-1016 (AROCLOR 1016)
Toxaphene
Units1
NA NA NA NA NA NA
(14) (14) (14)
11(14) (14)
11 11
11
11
11
11
NA
NA
11 (14)
NA
NA
NA
NA
(14)
0.9
0.9
0.7
0.7
NA
3(13) 3 NA
NA
(13)
3
NA
NA
NA
NA
NA
NA
NA
NA
NA
NA
Summer 2011
4
1.1
1.1
1.1
3.2
NA
NA
NA
NA
4.5
SWQS EMF(2)
0.5
0.17
0.15
0.18
0.34
0.2
0.28
0.45
0.00670
0.0140
0.00890
0.00720
0.0410
0.00650
0.00830
0.0290
0.0490
0.00650
0.00650
0.08
0.0160
0.00650
0.00740
0.0110
0.007
Winter 2011-12
1.6
3.3
2.9
3.5
6.8
4
5.6
9
0.13
0.28
0.18
0.14
1
1
1
1
1
1
1
1
1
1
1
1
1
Summer 2012
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Winter 2012-13
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
--
Summer 2013
0.110
3.70
3.20
3.90
7.50
4.40
6.10
9.90
0.150
0.310
0.200
0.160
0.140
0.140
0.180
0.140
0.270
0.330
0.140
1.80
0.200
0.140
0.160
0.250
0.150
Winter 2013-14
Summer 2014
Winter 2014-15
Summer 2015
Summary of Monitoring Data - Monitoring Station FF-ACES
14) SWQSs reported as PCBs
13) SWQSs report as total endosulfan.
12) Also known as p-nitrophenol.
11) SWQSs reported for total xylenes.
10) Methods: These parameters may be run using the following methods: VOCs, 624 or 8260; SVOCs, 625 or 8270; and PCB / Pesticides, 608/625 or 8081/8082 if the laboratory can pass QA with the method.
9) Depends on pH. Reported values are for pH of 7.0. Where field parameters (i.e. discrete samples) are not collected during the same storm event, the SWQS associated with a pH 7.0 will be used.
7) SWQS for total metals is provided and based on partial body contact. The SWQS for disolved metal concentration for ephemeral water is dependant on the hardness value for each sample and will in most cases be below the SWQS for partial body contact. 8) Based on total chromium.
6) Based on free-cyanide.
5) No surface water quality standard established for maximum allowable increase in ambient water temperature for ephemeral waters.
4) pH range (maximum/minimum).
3) Average flow rate for the sampling period (no more than 6 hours).
2) Surface Water Quality Standards (SWQSs) for EMF are based on that provided in A.A.C. R18-11-105(1) per 2010 MS4 Permit ADEQ Response to Comments. Partial Body Contact (PBC, shaded in brown) and Aquatic & Wildlife ( & ) - Detected above SWQS; Orange - Not detected, but reported above Ephemeral SWQS; Green - Not detected, but reported above PBC SWQS. Shaded Cells (results columns): Red
1) Analytical results shall be reported in the units specified for each category or parameter.
Bold values were reported at levels above the laboratory method reporting limit (MRL). Non-bold values are the MRL. Shaded results were detected above the SWQS. See attached laboratory analytical reports for flagged data.
Notes:
ug/L
Pesticides Aldrin
Parameter
Page 20 of 20
10.0 ASSESSMENT OF MONITORING DATA The 2010 MS4 Permit requires the City to: 1. Provide an evaluation of the sampling results for each monitoring location, including an assessment of any improvements or degradation of stormwater quality from each drainage area; 2. Compare the sampling results for each monitoring location with the applicable SWQSs; and, 3. Note any exceedance of SWQSs for the water of the United States receiving discharges during the reporting year. Additionally, the 2010 MS4 Permit provides that where monitoring data results show a recurring (more than once) exceedance of a SWQS at a monitoring location, the City shall investigate and make all reasonable efforts to identify potential source(s) of the pollutant(s) and to report this information in the annual report (see Section 4.2 and Section 8.3 of the 2010 MS4 Permit). Furthermore, in the fourth year annual report (due September 30, 2014), the City was to include a discussion of possible explanations for stormwater quality trends, including the implementation of stormwater management practices to reduce the discharge of pollutants to and from the storm sewer system. 10.1 SURFACE WATER QUALITY STANDARDS SWQSs associated with the water of the United States that has a potential to receive discharges from each monitoring location is provided with the summary of monitoring data tables in Section 9.0. 10.2 EXCEEDANCES OF SURFACE WATER QUALITY STANDARDS Exceedances of SWQSs are identified in the summary of monitoring data tables in Section 9.0. Exceedances of established SWQSs are shaded in red. In some cases, the results were non-detection but the established method detection limits were reported above the SWQS. These are shaded in either orange for Aquatic & Wildlife SWQSs or green for Partial Body Contact SWQSs.
City of Mesa, Storm Water Annual Report
Page 10-1
10.3 STORMWATER QUALITY EVALUATION - BY LOCATION The evaluation of stormwater quality for each monitoring location is provided below. An overall evaluation of stormwater quality based on the pollutants detected above applicable SWQSs is provided in Section 10.4. 10.3.1 Station AS-US60 Analytical results indicate that concentrations of E. coli, copper, lead, and zinc have been detected above the applicable SWQSs. All samples collected as part of the 2010 MS4 Permit exceeded the SWQSs for these parameters. E. coli results average 3,745 under the Most Probable Number (MPN) method with a standard deviation of 5,338. The high standard deviation in the data is due to the limited number of samples collected (6 samples) and the winter 2013-2014 result which was nearly four times the average value reported above. Copper results average 57 parts per billion (ppb) with a standard deviation of 25. Lead results average 12 ppb with a standard deviation of 3. Zinc concentrations average 250 ppb with a standard deviation of 110. With the exception of SS-US60, concentrations of lead are consistent with the other sites, and the reason these exceed the SWQSs at this location is solely due to the fact that this site discharges to an effluent dependent water where the other sites discharge to an ephemeral water. The average concentration of copper and zinc at this location tend to be higher than the average concentrations at the other monitoring locations and may be attributed to a denser population and a lower degree of on-site retention in the associated drainage area. The results do not appear to show a pattern for determining an improvement or degradation of stormwater quality. 10.3.2 Station SS-US60 Analytical results indicate that concentrations of E. coli and copper have been detected above the applicable SWQSs. All samples collected as part of the 2010 MS4 Permit exceeded the SWQSs for these parameters, except the winter 2013-2014 sample for E. coli. Additionally, the winter 2013-2014 sample results identified benz(a)anthracene and benzo(a)pyrene at concentrations slightly above SWQSs.
City of Mesa, Storm Water Annual Report
Page 10-2
E. coli results average 2,674 MPN with a standard deviation of 3,132. The high standard deviation in the data is due to the limited number of samples collected (6 samples) and the summer 2011 result which was nearly three times the average value reported above. Copper results average 37 ppb with a standard deviation of 16. Benz(a)anthracene and benzo(a)pyrene have only been detected above SWQSs at this location once and have not been detected above SWQSs at the Cityâ&#x20AC;&#x2122;s other monitoring locations. The results do not appear to show a pattern for determining an improvement or degradation of stormwater quality. 10.3.3 Station 54-EMF Analytical results indicate that concentrations of E. coli and copper have been detected above the applicable SWQSs. All samples collected as part of the 2010 MS4 Permit exceeded the SWQSs for these parameters, except the summer 2011 and summer 2013 samples for copper. E. coli results average 2,559 MPN with a standard deviation of 2,741. The high standard deviation in the data is due to the limited number of samples collected (6 samples) and the summer 2013 result which was nearly three times the average value reported above. Copper results average 27 ppb with a standard deviation of 9. The results do not show a pattern for determining an improvement or degradation of stormwater quality. 10.3.4 Station UN-EMF Analytical results indicate that concentrations of E. coli and copper have been detected above the applicable SWQSs. All samples collected as part of the 2010 MS4 Permit exceeded the SWQSs for these parameters. E. coli results average 3,685 MPN with a standard deviation of 4,237. The high standard deviation in the data is due to the limited number of samples collected (6 samples) and the winter 2011-2012 result which was greater than three times the average value reported above. Copper results average 34 ppb with a standard deviation of 6. The results do not show a pattern for determining an improvement or degradation of stormwater quality.
City of Mesa, Storm Water Annual Report
Page 10-3
10.3.5 Station FF-ACES Analytical results indicate that concentrations of copper have been detected above the applicable SWQSs. All samples collected as part of the 2010 MS4 Permit exceeded the SWQS for this parameter. Copper results average 14 ppb with a standard deviation of 7. The results do not show a pattern for determining an improvement or degradation of stormwater quality. 10.4 SWQS EXCEEDANCE INVESTIGATIONS When a reoccurring exceedance of a SWQS is identified, the City will conduct dryweather screening to visually inspect the outfall/FSP for flow (similar to that for an IDDE investigation). If flow is present, then the City would conduct a dry-weather investigation as described in the City’s Environmental Program Training Standard Operating Procedures which may include: •
Conducting a drainage area investigation;
•
Conducting a storm drain network investigation;
•
Conducting a subsurface investigation (e.g. video survey); or
•
Conducting additional monitoring.
If dry-weather flow is absent, or if the source of the flow is identified but determined not be a contributing source of the pollutant(s) exceeding the SWQS, the City will conduct a modified drainage area investigation which goes beyond looking for dry-weather flows. In order to address the metals and E. coli concentrations detected at sampling stations AS-US60, SS-US60, 54-EMF, and UN-EMF, the City conducted dry-weather screening at each of the outfall/FSP locations. This investigation took place in May 2012. No dryweather flow was identified. The City also conducted a modified drainage area investigation of each of these drainage areas. In conducting these investigations, City personnel drove through the drainage area in order to identify potential sources of the pollutants of interest, including roadway frontages, alleyways, and streets. This also included creating an inventory of
City of Mesa, Storm Water Annual Report
Page 10-4
all commercial and industrial operations that exist in these areas and conducting a cursory inspection of these operations to determine if a point source could be linked to these operations. Based on the City’s drainage area investigation no point sources for metals or E. coli could be identified. The 2010 MS4 Permit requires the City to, where a source is identified that can be linked to a reoccurring exceedance of a SWQS, immediately either work to eliminate the source; or, modify existing control measures or implement additional control measures within the control of the City that may reduce a recurring discharge of the identified pollutant(s) to the maximum extent practicable in the area the exceedance has been identified. Since the City was unable to determine a source of these contaminates, no subsequent actions were taken by the City. Please note, for sampling station FF-ACES, this is installed in an interior location at the Falcon Field Airport. This facility is permitted under the ADEQ MSGP. As such, the “outfalls” at this facility are monitored for dry-weather flows annually, and an inspection of the facility is conducted annually to meet the requirements of the MSGP. As such, the City will not be conducting any additional investigations regarding SWQS exceedances for the purposes of this permit if/when and exceedance is identified.
City of Mesa, Storm Water Annual Report
Page 10-5
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City of Mesa, Storm Water Annual Report
Page 10-6
11.0 ESTIMATE OF POLLUTANT LOADING The 2010 MS4 Permit requires the City to provide an estimate of the pollutant loadings each year from the City’s storm sewer system to waters of the United States for the following constituents: •
Biological Oxygen Demand;
•
Chemical Oxygen Demand;
•
Total Suspended Solids;
•
Total Dissolved Solids;
•
Total Nitrogen;
•
Total Ammonia;
•
Total Organic Nitrogen;
•
Total Phosphorous; and,
•
Metals.
The 2010 MS4 Permit also requires the City to include a description of the procedures for estimating pollutant loads and concentrations, including any modeling, data analysis, and calculation methods and to compare the pollutant loadings estimated each year to previous estimates of pollutant loadings. 11.1 POLLUTANT LOADING MODELING, DATA ANALYSIS, AND CALCULATIONS To meet the conditions of the 1997 Phase I Permit conditions, the City developed a model to estimate total pollutants discharged from the City’s storm sewer systerm using the “simple method” as described in EPA’s “Guidance Manual for the Preparation of Part 2 of the NPDES Permit Applications for Discharges from Municipal Separate Storm Sewer Systems.” As provided in the USEPA guidance, the regulation required system wide (cumulative) annual pollutant load calculation for each of the required pollutants, but that the single pollutant load values provide limited insights into potential problem areas and what BMPs might yield the best results. Consequently, the City decided to use the simple method to estimate “individual” pollutant loadings from drainage areas as referenced in the USEPA guidance. The individual pollutant loadings were then aggregated to derive a cumulative annual
City of Mesa, Storm Water Annual Report
Page 11-1
pollutant loading for the City’s entire storm sewer system. The pollutant loading model developed by the City was managed in an Excel® format. The City contracted Engineering and Environmental Consultants, Inc. (EEC) to update the model by: •
Conducting an assessment of rainfall data;
•
Conducting an assessment of the drainage areas associated with each of the outfall and FSP locations;
•
Evaluating weighted average of runoff coefficient data associated with land uses;
•
Re-developing the City’s model to incorporate the results of the above studies; and,
•
Providing a report summarizing the steps taken in preforming these analyses.
In addition, EEC worked with the City in re-designing the Event Mean Concentration (EMC) table that was used in the 1997 Phase I Permit. 11.1.1 Event Mean Concentration Sampling data duirng the 2010 MS4 Permit (September 2010 through August 2015) will be used to calculate the EMC as provided in the equation below.
EMC =
Sum of Sampling Data Number of Data Points
The EMC table was modified to include parameters required in the 2010 MS4 Permit and to remove parameters that were previously modeled as part of the 1997 Phase I permit but were not required to be modeled in the 2010 MS4 Permit. 11.1.2 Rainfall Data Evaluation Rainfall data obtained from the FCDMC rain gages located within the City’s incorporated area were analyzed in two ways. 1. Using data from the last five years, excluding any rain events that exceeded the 100-year 2-hour storm event - estimated at 6.99 inches. City of Mesa, Storm Water Annual Report
Page 11-2
2. Using all available FCDMC data for the 12 rain gauges and did not exclude rain events exceeding the 100-year 2-hour storm event – estimated at 7.12 inches Due to highly variable rainfall events from year to year and the impact of particularly dry or wet years is greater in smaller datasets, EEC recommended using 7.12 inches of rainfall for the average annual rainfall in the pollutant loading model. 11.1.3 Drainage Area Runoff Volumes Drainage areas runoff volumes were determined or each outfall and FSP using the following formula.
V= Where: V= P= CF = WC = A=
P * CF * WC * A 12
Annual volume discharged from drainage area (acre-feet). Annual precipitation (7.12 inches/year, see Section 7.2.2). Correction factor that adjusts for storms where no runoff occurs (0.9 used per USEPA guidance). Weighted average runoff coefficient. Drainage area.
11.1.3.1 Drainage Area Evaluation EEC evaluated the drainage areas of approximately 170 outfall and FSP locations identified by the City. The drainage area evaluation included deliniating the drainage areas included topography, storm drain line, and flow direction arrow data that was provided to EEC in the form of GIS layers of the City’s storm sewer system. This evaluation also included the use of aerial photos along with best professional judgment used to make assumptions on the probable grading and drainage patterns. The total acreage of each drainage area was then estimated and new GIS layers illustrating each drainage area were created. The drainage area evaluation also included determining various land uses whithin each drainage area. The land use areas were determined using City GIS land use data and information from the City’s the Storm Drain Master Plan. The land uses were simplified
City of Mesa, Storm Water Annual Report
Page 11-3
into eight categories corresponding to land uses including streets, residential, commercial, industrial, lawns/parks, hillside/mountain, desert, and agricultural. Streets within residential and large commercial and industiral areas were not separated out from the surronding land uses. The streets land use was generally limited to drainage areas that primarily drained only City streets. 11.1.3.2 Weighted Average Runoff Coefficient EEC reveiwed published runoff coefficients and recommended using those provided in the FCDMC hydrology manual for the purposes of the City’s pollutant loading model. EEC also recommended using the runoff coefficients as listed in the FCDMC Manual corresponding with the selected land uses for the 2-year storm event. The only exception to this was the ‘Residential’ coefficients, since the FCDMC runoff coefficients published for residential land use did not include adjacent streets. For these, the average between the 2 and 10 year events was used. Based on EEC’s evaluation and recommendations, the City’s pollutant loading model has incorporated the weighted average runoff coefficients as provided below. Land Use Residential (very low or low density) Residential (medium or high density) Commercial Industrial Lawn/Parks Desert Hillside / Moutain City Streets
Wighted Average Runoff Coefficients 0.41 0.63 0.65 0.65 0.18 0.37 0.48 0.75
11.1.4 Annual Pollutant Loading Estimate The City uses the following to calculate the annual loading. L = V * C * 0.00136 L= V= C=
Annual pollutant load (tons/year). Annual volume discharged (acre-feet). Pollutant Event Mean Concentration determined from the sampling program (mg/L).
City of Mesa, Storm Water Annual Report
Page 11-4
0.00136 = Conversion factor The pollutant loading is calculated for each required constituent, and volume discharged was the sum of individual drainage areas that discharged stormwater to the Salt River or the EMF. A copy of the pollutant loading estimates for each parameter required to be modeled is attached to back of this section. 11.2 COMPARISON OF POLLUTANT LOADING ESTIMATES A comparison between the 2011-2012 reporting year and this yearâ&#x20AC;&#x2122;s pollutant loading estimates indicate consistency in the total pollutant loads and does not show a pattern for determining an improvement or degradation of stormwater quality.
City of Mesa, Storm Water Annual Report
Page 11-5
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City of Mesa, Storm Water Annual Report
Page 11-6
Pollutant Loading Estimates FALSE
II
IV
I
Ultimate Receiving Water Pollutant
BOD5 COD High Level TDS TSS Total Nitrogen (Nitrite + Nitrate) as N Total Ammonia as N Total Kjeldal Nitrogen (TKN) as N Phosphorous Total Antimony Arsenic Barium Beryillum Cadmium Chromium Copper Lead Mercury Nickel Selinium Silver Thalium Zinc Total Pollutant Load (tons)
EMC (mg/l)
26.52 179.0 129.8 149 0.531 1.579 3.199 0.625 0.003 0.002 0.0750 0.0000 0.0003 0.006 0.0390 0.012 0.0000 0.008 0.0000 0.0000 0.0000 0.1816
Annual Load To Salt River (tons)
Annual Load To EMF (tons)
82.73 558.4 404.9 465 1.657 4.926 9.980 1.950 0.008 0.005 0.2340 0.0000 0.0009 0.020 0.1217 0.037 0.0000 0.025 0.0000 0.0000 0.0000 0.5665 1,530
47.74 322.2 233.7 268 0.956 2.842 5.759 1.125 0.005 0.003 0.1350 0.0000 0.0005 0.011 0.0702 0.021 0.0000 0.015 0.0000 0.0000 0.0000 0.3269 883
Total Annual Load (tons) 130.47 880.7 638.6 733 2.612 7.768 15.739 3.075 0.012 0.008 0.3690 0.0000 0.0015 0.031 0.1919 0.058 0.0000 0.040 0.0000 0.0000 0.0000 0.8934 2,413
(This page intentionally left blank)
12.0 ANNUAL EXPENDITURES The 2010 MS4 Permit requires the City to provide a brief statement of the expenditures incurred each reporting period (July 1 â&#x20AC;&#x201C; June 30) related exclusively to implementing and maintaining the stormwater management program, including associated monitoring and reporting activities. Additionally, the 2010 MS4 Permit requires the City to provide the estimated budget for implementing and maintaining the stormwater program in the subsequent reporting period and to include a statement of the funding sources used to support program expenditures. The Cityâ&#x20AC;&#x2122;s stormwater program during this reporting period was funded in part from an Environmental Fee that is assessed to City residents and businesses as part of their utility bills and the remaining was funded from the Cityâ&#x20AC;&#x2122;s General Fund. An Annual Expenditure Report is included as an attachment to this Annual Report (see Section 13.9 and Attachment C).
City of Mesa, Storm Water Annual Report
Page 12-1
(This page intentionally left blank)
City of Mesa, Storm Water Annual Report
Page 12-2
13.0 ATTACHMENTS The 2010 MS4 Permit requires the City to attach the following to the Annual Reports: 1. Drainage system maps 2. List of major outfalls and field screening points 3. List of changes to the major outfalls and field screening points inventory (new, out of service, other changes), including drainage area and coordinates for the monitoring locations listed in Table 1 of the permit (4th year report) 4. Laboratory reports for stormwater monitoring performed in the reporting period 5. New or revised ordinances associated with stormwater management 6. New or revised public outreach documents Other attachments include: 1. Household hazardous waste reports; and, 2. Annual expenditure reports. 13.1 DRAINAGE SYSTEM MAPS The City considers the exact location of its utility infrastructure to be confidential and for use by City personnel only. As such, the City cannot supply this information as an attachment to this document. The City would be able to supply this information to the ADEQ upon official request and only under a signed confidentiality agreement or provide a presentation of this information to the ADEQ upon request. 13.2 LISTING OF OUTFALLS & FIELD SCREENING POINTS A current version of the listing of outfalls and FSPs are included in the City’s updated SWMP dated September 2014 which is included as an addendum to this annual report. 13.3 LIST OF CHANGES TO OUTFALL & FIELD SCREENING POINTS Two FSP locations were added to the City’s inventory this reporting period. A current version of the listing of outfalls and FSPs are included in the City’s updated SWMP dated September 2014 which is included as an addendum to this annual report.
City of Mesa, Storm Water Annual Report
Page 13-1
13.4 STORMWATER MONITORING ANALYTICAL LABORATORY REPORTS During this reporting period, the City collected a total of twenty-one (21) wet-weather stormwater samples for laboratory analysis. The analytical reports associated with those samples are included as Attachment A. These reports are arranged by Order ID/Sample Number. 13.5 NEW OR REVISED STORMWATER MANAGEMENT ORDINANCES A current version of the City’s Stormwater Code is provided in the City’s updated SWMP dated September 2014 which is included as an addendum to this annual report. 13.6 NEW OR REVISED PUBLIC EDUCATION & OUTREACH DOCUMENTS Public education and outreach materials developed by the STORM organization are available at the STORM website at the following addresses: http://www.azstorm.org/brochures/ http://www.azstorm.org/storm-drain-dan/ http://www.azstorm.org/other-fun-stuff/ 13.7 HOUSEHOLD HAZARDOUS WASTE EVENT REPORTS Reports for the four HHW events conducted this reporting period are provided in Attachment B. 13.8 UPDATED CITY FACILITY INVENTORY A current version of the City facility inventory is included in the City’s updated SWMP dated September 2014 which is included as an addendum to this annual report. 13.9 ANNUAL EXPENDITURE REPORTS Expenditures associated with the City’s stormwater management program for the current reporting year and the estimated expenditures for the subsequent reporting year are provided in Attachment C.
City of Mesa, Storm Water Annual Report
Page 13-2
ATTACHMENT A WET-WEATHER SAMPLING LABORATORY ANALYTICAL REPORTS
(This page intentionally left blank)
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524005 Collection Date: 7/20/2013 Collection Time: 10:16:00 PM
Receive Date: 7/21/2013 Customer Sample#:
Collector: AC Sample Number: 13050470
Project ID: 54 Discrete-Partial Site: 54th St @ EMF RESULTS
Parameter
7/25/2013
PSERIA
SM4500-CN E
0.02
SM9223B
2.2
7/21/2013
mrexing
EPA 1664A
5
5.3 mg/L
7/30/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
10
< 10.0 mg/L
8/1/2013
TAL
pH-Field
SM4500H B
1
7.62 S.U.
7/20/2013 ACHAVEZ
SM2550B
1
30.0 째C
7/20/2013 ACHAVEZ
E. Coli, MPN Oil and Grease
Temperature-Field
Result
Analyst
MRL
Cyanide, Total
Qualifier
Analysis Date
Method No
< 0.020 mg/L 7980.0 mpn/100ml
Quality Control mg/L
BLANK Parameter
Oil and Grease Standard Parameter Cyanide, Total
Cyanide, Total Oil and Grease SPIKE RESULTS Parameter
QC BATCH
< 5 mg/L QC13073003 Actual Conc. Standard Conc. %REC mg/L
mg/L
0.2526
QC BATCH
QC TYPE
0.25
101
QC13072506
ICV
0.2612 38.7 Sample Conc.
0.25 40 Spike True Value
104 97 Final Result
QC13072506
CCV
mg/L
QC13073003 %RPD
LCS
%REC
Sample Number
QC BATCH
mg/L
mg/L
Cyanide, Total
< 0.02 mg/L
0.25
0.2595
104
13050476
QC13072506
Oil and Grease Cyanide, Total
< 5 mg/L < 0.02 mg/L
40 0.25
37.4 0.2613
92 105
13050476 13050476
QC13073003
MS
QC13072506
MSD
0.69
QUALIFIERS
COMMENTS
REVIEWED BY: _____________________________________________ Page 1 of 2
Date Signed: 8/12/2013
MS
Page 2 of 2
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524006 Collection Date: 7/15/2013 Collection Time: 7:40:00 PM
Receive Date: 7/15/2013 Customer Sample#:
Collector: AC Sample Number: 13050471
Project ID: Alma Comp-Partial Site: Alma School/ADOT Channel RESULTS Method No
MRL
Qualifier
Result
Analysis Date
Analyst
SM4500-NH3D
0.5
D2
3.84 mg/L
7/18/2013
PSERIA
Nitrogen, Nitrate-Nitrite Total
EPA 300.0
2
2.72 mg/L
7/18/2013
JPATTIS
Biochemical Oxygen Demand
SM5210B
2
86.0 mg/L
7/17/2013
NSILIDE
Chemical Oxygen Demand
SM5220D
50
534 mg/L
7/23/2013
NSILIDE
Hardness, Total
SM2340C
1
116 mg/L CaCO3
7/16/2013
NSILIDE
Antimony, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Arsenic, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Barium, Total
EPA 200.8
0.005
D1/M2
0.102 mg/L
8/9/2013
GSMITH2
Beryllium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Cadmium, Total
EPA 200.8
0.004
D1
< 0.004 mg/L
8/9/2013
GSMITH2
Chromium, Total
EPA 200.8
0.005
D1/M2
0.006 mg/L
8/9/2013
GSMITH2
Copper, Total
EPA 200.8
0.005
D1/M2
0.047 mg/L
8/9/2013
GSMITH2
Lead, Total
EPA 200.8
0.005
D1
0.009 mg/L
8/9/2013
GSMITH2
Nickel, Total
EPA 200.8
0.005
D1
0.017 mg/L
8/9/2013
GSMITH2
Selenium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Silver, Total
EPA 200.8
0.004
D1
< 0.004 mg/L
8/9/2013
GSMITH2
Thallium, Total
EPA 200.8
0.005
D1/L4/M2
< 0.005 mg/L
8/9/2013
GSMITH2
Zinc, Total
EPA 200.8
0.005
D1/M2
Mercury, Total
EPA245.1
0.0002
SM4500-Norg
Orthophosphate
EPA 300.0
Phosphorus, Total
SM4500-P
0.5
Solids, Suspended Total
SM2540D
10
Solids, Total Dissolved
SM2540C
20
Parameter Nitrogen, Ammonia Total
Nitrogen, Kjeldahl Total
0.222 mg/L
8/9/2013
GSMITH2
< 0.00020 mg/L
7/23/2013
TAL
0.5
10.6 mg/L
7/29/2013
PSERIA
0.1
0.62 mg/L
7/16/2013
TAL
1.03 mg/L
7/23/2013
PSERIA
196 mg/L
7/17/2013
NSILIDE
564 mg/L
7/17/2013
NSILIDE
D2
Quality Control
Page 1 of 5
Quality Control mg/L
BLANK Parameter
QC BATCH
Nitrogen, Ammonia Total
< 0.5 mg/L
QC13072202
Biochemical Oxygen Demand
< 2 mg/L
QC13072206
Chemical Oxygen Demand Hardness, Total Antimony, Total
Arsenic, Total Barium, Total Beryllium, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Nickel, Total
Selenium, Total Silver, Total Thallium, Total Zinc, Total
< 50 mg/L QC13072403 QC13071602 < 1 mg/L CaCO3 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.004 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201
< 0.005 mg/L QC13081201 < 0.004 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201
Nitrogen, Kjeldahl Total
< 0.5 mg/L
QC13072908
Phosphorus, Total Solids, Suspended Total
< 0.5 mg/L < 10 mg/L
QC13072404 QC13071703
Solids, Total Dissolved
Standard Parameter
< 20 mg/L QC13071801 Actual Conc. Standard Conc. %REC
QC BATCH
QC TYPE
mg/L
mg/L
Nitrogen, Ammonia Total
0.508
0.5
102
QC13072202
ICV
Nitrogen, Ammonia Total Nitrogen, Nitrate Total
0.516 0.498
0.5 0.5
103 100
QC13072202
CCV
QC13072205
LFB
Nitrogen, Nitrate Total Nitrogen, Nitrate Total
0.502 0.506
0.5 0.5
100 101
QC13072205 QC13072205
ICV CCV
Biochemical Oxygen Demand
193
198
97
QC13072206
LCS
Chemical Oxygen Demand Chemical Oxygen Demand
490 484
500 500
98 97
QC13072403 QC13072403
CCV
ICV
Hardness, Total
102.16
100
102
QC13071602
LCS
Antimony, Total Antimony, Total
0.04853 0.01049
0.05 0.01
97 105
QC13081201
LFB
QC13081201
ICV
Antimony, Total Arsenic, Total
0.05305 0.04553
0.05 0.05
106 91
QC13081201
CCV
QC13081201
LFB
Arsenic, Total
0.01020
0.01
102
QC13081201
ICV
Arsenic, Total Barium, Total
0.04939 0.04515
0.05 0.05
99 90
QC13081201
CCV
QC13081201
LFB
Barium, Total
0.01028
0.01
103
QC13081201
ICV
Barium, Total Beryllium, Total
0.05029 0.06647
0.05 0.05
101 133
QC13081201
CCV
QC13081201
LFB
Beryllium, Total Beryllium, Total
0.01008 0.04816
0.01 0.05
101 96
QC13081201
ICV
QC13081201
CCV
Cadmium, Total
0.04672
0.05
93
QC13081201
LFB
Cadmium, Total Cadmium, Total
0.01030 0.05128
0.01 0.05
103 103
QC13081201
ICV
QC13081201
CCV
Chromium, Total
0.04371
0.05
87
QC13081201
LFB ICV
Chromium, Total Chromium, Total
0.01068 0.04775
0.01 0.05
107 96
QC13081201 QC13081201
CCV
Copper, Total
0.04512
0.05
90
QC13081201
LFB
Copper, Total
0.01025
0.01
103
QC13081201
ICV
Copper, Total
0.05745
0.05
115
QC13081201
CCV
Lead, Total
0.04560
0.05
91
QC13081201
LFB
Page 2 of 5
Lead, Total
0.00995
0.01
100
QC13081201
ICV
Lead, Total
0.05152
0.05
103
Nickel, Total
0.04411
0.05
88
QC13081201 QC13081201
CCV LFB
Nickel, Total
0.01013
0.01
101
QC13081201
ICV
Nickel, Total Selenium, Total
0.04997 0.04916
0.05 0.05
100 98
QC13081201 QC13081201
CCV LFB
Selenium, Total
0.01049
0.01
105
QC13081201
ICV
Selenium, Total Silver, Total
0.04989 0.05166
0.05 0.05
100 103
QC13081201 QC13081201
CCV LFB
Silver, Total
0.00988
0.01
99
Silver, Total Thallium, Total
0.05443 0.03484
0.05 0.05
109 70
QC13081201 QC13081201
ICV CCV
QC13081201
LFB
Thallium, Total Thallium, Total
0.00967 0.05025
0.01 0.05
97 101
QC13081201 QC13081201
ICV CCV
Zinc, Total
0.04803
0.05
96
QC13081201
LFB
Zinc, Total Zinc, Total
0.01045 0.05402
0.01 0.05
105 108
QC13081201 QC13081201
ICV CCV
QC13072908 QC13072908
LFB CCV
Nitrogen, Kjeldahl Total
4.92
5
98
Nitrogen, Kjeldahl Total Phosphorus, Total
24.94 0.3054
25 0.3
100 102
QC13072404
ICV
Phosphorus, Total Solids, Suspended Total
0.3054 204
0.3 200
102 102
QC13072404 QC13071703
CCV LCS
Solids, Total Dissolved
496 Actual Conc.
495 Duplicate Conc.
100 %RPD
QC13071801
LCS
mg/L
mg/L
197 mg/L
202
196 mg/L 192 564 mg/L 582 Sample Conc. Spike True Value
Duplicate Parameter Biochemical Oxygen Demand Solids, Suspended Total Solids, Total Dissolved SPIKE RESULTS Parameter
mg/L Antimony, Total Arsenic, Total
Sample Number
QC BATCH
2.51
13070330
QC13072206
2.06 3.14 Final Result
13050471 13050471 %REC %RPD
QC13071703 QC13071801 Sample Number QC BATCH
mg/L
mg/L
< 0.025 mg/L < 0.025 mg/L
0.05 0.05
0.04059 0.03922
81 78
13050477 13050477
QC13081201 QC13081201
MS MS
Barium, Total
0.030 mg/L
0.05
0.06128
63
13050477
QC13081201
MS
Beryllium, Total Cadmium, Total
< 0.025 mg/L 0.001 mg/L
0.05 0.05
0.04431 0.03999
89 76
13050477 13050477
QC13081201
MS MS
Chemical Oxygen Demand Chromium, Total
56 mg/L < 0.025 mg/L
500 0.05
533 0.04384
95 63
13050477 13050477
QC13072403 QC13081201
MS MS
< 0.025 mg/L
0.05
0.04339
67
13050477
QC13081201
MS
116 mg/L CaCO3 50 < 0.025 mg/L 0.05
168.88 0.04910
105 73
13050471 13050477
QC13071602 QC13081201
MS MS
Copper, Total
Hardness, Total Lead, Total
QC13081201
Nickel, Total
< 0.025 mg/L
0.05
0.04052
73
13050477
QC13081201
MS
Nitrogen, Ammonia Total Nitrogen, Kjeldahl Total
0.104 mg/L 3.63 mg/L
0.5 5
0.620 8.63
103 100
13070203 13050469
QC13072202
MS MS
Phosphorus, Total Selenium, Total
0.15 mg/L < 0.025 mg/L
0.3 0.05
0.4462 0.04358
99 87
13050477 13050477
QC13072404 QC13081201
MS MS
Silver, Total
< 0.001 mg/L
0.05
0.04785
96
13050477
QC13081201
MS
Thallium, Total Zinc, Total
< 0.025 mg/L 0.123 mg/L
0.05 0.05
0.03283 0.13415
66 22
13050477 13050477
QC13081201 QC13081201
MS MS
500
522
93
2.09
13050477
QC13072403
MSD
169.28 0.629
105 105
0.24
QC13071602
1.44
13050471 13070203
QC13072202
MSD MSD
Chemical Oxygen Demand Hardness, Total Nitrogen, Ammonia Total
56 mg/L
116 mg/L CaCO3 50 0.104 mg/L 0.5
QC13072908
Nitrogen, Kjeldahl Total
3.63 mg/L
5
8.72
102
1.04
13050469
QC13072908
MSD
Phosphorus, Total
0.15 mg/L
0.3
0.4442
98
0.45
13050477
QC13072404
MSD
Page 3 of 5
QUALIFIERS D1
Sample diluted due to matrix interference.
D2
Sample diluted due to high concentration.
COMMENTS D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable.
Analyzed 8/13/13, QC available upon request. GS D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable. Analyzed 8/13/13, QC available upon request. GS
D1 = Sample required dilution due to matrix. L4 = Associated blank spike (Tl) recovery was below method limits. M2 = Matrix spike recovery low. Zn, Cr, Cu, Ba, Tl: D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike is acceptable.
REVIEWED BY: _____________________________________________
Page 4 of 5
Date Signed: 9/16/2013
Page 5 of 5
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524007 Collection Date: 7/15/2013 Collection Time: 7:17:00 PM
Receive Date: 7/15/2013 Customer Sample#:
Collector: AC Sample Number: 13050472
Project ID: Alma Discrete-Partial Site: Alma School/ADOT Channel RESULTS
Parameter
7/25/2013
PSERIA
SM4500-CN E
0.02
SM9223B
2.2
7/15/2013
mrexing
EPA 1664A
5
< 5.0 mg/L
7/24/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
5.7
< 5.70 mg/L
7/25/2013
TAL
pH-Field
SM4500H B
1
7.15 S.U.
7/15/2013 ACHAVEZ
SM2550B
1
33.0 째C
7/15/2013 ACHAVEZ
E. Coli, MPN Oil and Grease
Temperature-Field
Result
Analyst
MRL
Cyanide, Total
Qualifier
Analysis Date
Method No
< 0.020 mg/L 1300.0 mpn/100ml
Quality Control mg/L
BLANK Parameter
Oil and Grease Standard Parameter Cyanide, Total
Cyanide, Total Oil and Grease SPIKE RESULTS Parameter
QC BATCH
< 5 mg/L QC13072406 Actual Conc. Standard Conc. %REC mg/L
mg/L
0.2526
QC BATCH
QC TYPE
0.25
101
QC13072506
ICV
0.2612 38.8 Sample Conc.
0.25 40 Spike True Value
104 97 Final Result
QC13072506
CCV
mg/L
QC13072406 %RPD
LCS
%REC
Sample Number
QC BATCH
mg/L
mg/L
Cyanide, Total
< 0.02 mg/L
0.25
0.2595
104
13050476
QC13072506
Oil and Grease Cyanide, Total
< 5 mg/L < 0.02 mg/L
40 0.25
39.4 0.2613
98 105
13060326 13050476
QC13072406
MS
QC13072506
MSD
0.69
QUALIFIERS
COMMENTS
REVIEWED BY: _____________________________________________ Page 1 of 2
Date Signed: 8/12/2013
MS
Page 2 of 2
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524012 Collection Date: 7/21/2013 Collection Time: 11:45:00 AM
Receive Date: 7/22/2013 Customer Sample#:
Collector: D. Cameron Sample Number: 13050477
Project ID: FF Comp-Partial Site: Falcon Field RESULTS
Method No
MRL
Qualifier
Result
Analysis Date
Analyst
SM4500-NH3D
0.5
D2
1.56 mg/L
7/31/2013
PSERIA
Nitrogen, Nitrate-Nitrite Total
EPA 300.0
2
< 2.00 mg/L
7/24/2013
JPATTIS
Biochemical Oxygen Demand
SM5210B
2
7.00 mg/L
7/27/2013
PSERIA
Chemical Oxygen Demand
SM5220D
50
56 mg/L
7/23/2013
NSILIDE
Hardness, Total
SM2340C
1
7/23/2013
NSILIDE
Antimony, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/2/2013
GSMITH2
Arsenic, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/2/2013
GSMITH2
Barium, Total
EPA 200.8
0.005
D1/M2
0.030 mg/L
8/2/2013
GSMITH2
Beryllium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/2/2013
GSMITH2
Cadmium, Total
EPA 200.8
0.001
0.001 mg/L
8/2/2013
GSMITH2
Chromium, Total
EPA 200.8
0.005
D1/M2
0.012 mg/L
8/2/2013
GSMITH2
Copper, Total
EPA 200.8
0.005
D1/M2
0.010 mg/L
8/2/2013
GSMITH2
Lead, Total
EPA 200.8
0.005
D1
0.012 mg/L
8/2/2013
GSMITH2
Nickel, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/2/2013
GSMITH2
Selenium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/2/2013
GSMITH2
Silver, Total
EPA 200.8
0.001
< 0.001 mg/L
8/2/2013
GSMITH2
Thallium, Total
EPA 200.8
0.005
D1/L4/M2
< 0.005 mg/L
8/2/2013
GSMITH2
Zinc, Total
EPA 200.8
0.005
D1/M2
Mercury, Total
EPA245.1
0.0002
SM4500-Norg
Orthophosphate
EPA 300.0
Phosphorus, Total
SM4500-P
Solids, Suspended Total
SM2540D
Solids, Total Dissolved
SM2540C
Parameter Nitrogen, Ammonia Total
Nitrogen, Kjeldahl Total
18.0 mg/L CaCO3
0.123 mg/L
8/2/2013
GSMITH2
< 0.00020 mg/L
7/29/2013
TAL
0.5
2.09 mg/L
7/29/2013
PSERIA
0.2
0.22 mg/L
7/22/2013
TAL
0.1
0.15 mg/L
7/23/2013
PSERIA
10
58.0 mg/L
7/23/2013
NSILIDE
20
192 mg/L
7/23/2013
NSILIDE
Quality Control
Page 1 of 5
Quality Control mg/L
BLANK Parameter
QC BATCH
Nitrogen, Ammonia Total
< 0.5 mg/L
QC13073103
Biochemical Oxygen Demand
< 2 mg/L
QC13072801
Chemical Oxygen Demand Hardness, Total Antimony, Total
Arsenic, Total Barium, Total Beryllium, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Nickel, Total
Selenium, Total Silver, Total Thallium, Total Zinc, Total
< 50 mg/L QC13072403 QC13072301 < 1 mg/L CaCO3 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.001 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201
< 0.005 mg/L QC13081201 < 0.001 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201
Nitrogen, Kjeldahl Total
< 0.5 mg/L
QC13072908
Phosphorus, Total Solids, Suspended Total
< 0.1 mg/L < 10 mg/L
QC13072404 QC13072402
Solids, Total Dissolved
Standard Parameter
< 20 mg/L QC13072405 Actual Conc. Standard Conc. %REC
QC BATCH
QC TYPE
mg/L
mg/L
Nitrogen, Ammonia Total
0.504
0.5
101
QC13073103
ICV
Nitrogen, Ammonia Total Fluoride
0.510 0.486
0.5 0.5
102 97
QC13073103
CCV
QC13072501
LFB
Fluoride Fluoride
0.489 0.491
0.5 0.5
98 98
QC13072501 QC13072501
ICV CCV
Nitrogen, Nitrate Total
0.492
0.5
98
QC13072501
LFB
Nitrogen, Nitrate Total Nitrogen, Nitrate Total
0.496 0.511
0.5 0.5
99 102
QC13072501 QC13072501
CCV
Biochemical Oxygen Demand
223
198
113
QC13072801
LCS
Chemical Oxygen Demand Chemical Oxygen Demand
490 484
500 500
98 97
QC13072403
ICV
QC13072403
CCV
Hardness, Total Antimony, Total
102 0.04853
100 0.05
102 97
QC13072301
LCS
QC13081201
LFB
Antimony, Total
0.01049
0.01
105
QC13081201
ICV
Antimony, Total Arsenic, Total
0.05305 0.04553
0.05 0.05
106 91
QC13081201
CCV
QC13081201
LFB
Arsenic, Total
0.01020
0.01
102
QC13081201
ICV
Arsenic, Total Barium, Total
0.04939 0.04515
0.05 0.05
99 90
QC13081201
CCV
QC13081201
LFB
Barium, Total Barium, Total
0.01028 0.05029
0.01 0.05
103 101
QC13081201
ICV
QC13081201
CCV
Beryllium, Total
0.06647
0.05
133
QC13081201
LFB
Beryllium, Total Beryllium, Total
0.01008 0.04816
0.01 0.05
101 96
QC13081201
ICV
QC13081201
CCV
Cadmium, Total
0.04672
0.05
93
QC13081201
LFB ICV
ICV
Cadmium, Total Cadmium, Total
0.01030 0.05128
0.01 0.05
103 103
QC13081201 QC13081201
CCV
Chromium, Total
0.04371
0.05
87
QC13081201
LFB
Chromium, Total
0.01068
0.01
107
QC13081201
ICV
Chromium, Total
0.04775
0.05
96
QC13081201
CCV
Copper, Total
0.04512
0.05
90
QC13081201
LFB
Page 2 of 5
Copper, Total
0.01025
0.01
103
QC13081201
ICV
Copper, Total
0.05745
0.05
115
Lead, Total
0.04560
0.05
91
QC13081201 QC13081201
CCV LFB
Lead, Total
0.00995
0.01
100
QC13081201
ICV
Lead, Total Nickel, Total
0.05152 0.04411
0.05 0.05
103 88
QC13081201 QC13081201
CCV LFB
Nickel, Total
0.01013
0.01
101
QC13081201
ICV
Nickel, Total Selenium, Total
0.04997 0.04916
0.05 0.05
100 98
QC13081201 QC13081201
CCV LFB
Selenium, Total
0.01049
0.01
105
Selenium, Total Silver, Total
0.04989 0.05166
0.05 0.05
100 103
QC13081201 QC13081201
ICV CCV
QC13081201
LFB
Silver, Total Silver, Total
0.00988 0.05443
0.01 0.05
99 109
QC13081201 QC13081201
ICV CCV
Thallium, Total
0.03484
0.05
70
QC13081201
LFB
Thallium, Total Thallium, Total
0.00967 0.05025
0.01 0.05
97 101
QC13081201 QC13081201
ICV CCV
Zinc, Total
0.04803
0.05
96
Zinc, Total Zinc, Total
0.01045 0.05402
0.01 0.05
105 108
QC13081201 QC13081201
LFB ICV
QC13081201
CCV
Nitrogen, Kjeldahl Total Nitrogen, Kjeldahl Total
4.92 24.94
5 25
98 100
QC13072908 QC13072908
LFB CCV
Phosphorus, Total
0.3054
0.3
102
QC13072404
ICV
Phosphorus, Total Solids, Suspended Total
0.3054 202
0.3 200
102 101
QC13072404 QC13072402
CCV LCS
Solids, Total Dissolved
474 Actual Conc.
495 Duplicate Conc.
96 %RPD
QC13072405 Sample Number
LCS
mg/L
mg/L
Duplicate Parameter Biochemical Oxygen Demand Solids, Suspended Total Solids, Total Dissolved
SPIKE RESULTS Parameter
41.0 mg/L 4060 mg/L
38 4140
7.59 1.95
13050481 13070263
212 mg/L 206 Sample Conc. Spike True Value
2.87 Final Result
13050469 %REC %RPD
mg/L
QC BATCH QC13072801 QC13072402 QC13072405 Sample Number QC BATCH
mg/L
mg/L
Antimony, Total Arsenic, Total
< 0.025 mg/L < 0.025 mg/L
0.05 0.05
0.04059 0.03922
81 78
13050477 13050477
QC13081201
Barium, Total Beryllium, Total
0.030 mg/L < 0.025 mg/L
0.05 0.05
0.06128 0.04431
63 89
13050477 13050477
QC13081201 QC13081201
MS MS
Cadmium, Total
0.001 mg/L
0.05
0.03999
76
13050477
QC13081201
MS
Chemical Oxygen Demand Chromium, Total
56 mg/L < 0.025 mg/L
500 0.05
533 0.04384
95 63
13050477 13050477
QC13072403 QC13081201
MS MS
< 0.025 mg/L
0.05
0.04339
67
13050477
QC13081201
MS
18.0 mg/L CaCO3 50 < 0.025 mg/L 0.05
70 0.04910
104 73
13050477 13050477
QC13072301
MS MS
0.04052 4.03
73 99
13050477 13050479
QC13081201 QC13073103
MS MS
Copper, Total Hardness, Total Lead, Total Nickel, Total Nitrogen, Ammonia Total
< 0.025 mg/L < 2.5 mg/L
0.05 2.5
QC13081201
QC13081201
MS MS
5
8.63
100
13050469
QC13072908
MS
Phosphorus, Total Selenium, Total
0.15 mg/L < 0.025 mg/L
0.3 0.05
0.4462 0.04358
99 87
13050477 13050477
QC13072404 QC13081201
MS MS
Silver, Total
< 0.001 mg/L
0.05
0.04785
96
13050477
QC13081201
MS
Thallium, Total Zinc, Total
< 0.025 mg/L 0.123 mg/L
0.05 0.05
0.03283 0.13415
66 22
13050477 13050477
QC13081201 QC13081201
MS MS
500
522
93
2.09
13050477
QC13072403
MSD
18.0 mg/L CaCO3 50
69
102
1.44
13050477
QC13072301
MSD
Nitrogen, Kjeldahl Total
Chemical Oxygen Demand Hardness, Total
3.63 mg/L
56 mg/L
Nitrogen, Ammonia Total
< 2.5 mg/L
2.5
4.065
100
0.86
13050479
QC13073103
MSD
Nitrogen, Kjeldahl Total
3.63 mg/L
5
8.72
102
1.04
13050469
QC13072908
MSD
Page 3 of 5
Phosphorus, Total
0.15 mg/L
0.3
0.4442
98
0.45
13050477
QC13072404
QUALIFIERS D1
Sample diluted due to matrix interference.
D2
Sample diluted due to high concentration.
COMMENTS D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable.
Analyzed 8/13/13, QC available upon request. GS D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable. Analyzed 8/13/13, QC available upon request. GS
D1 = Sample required dilution due to matrix. L4 = Associated blank spike (Tl) recovery was below method limits. M2 = Matrix spike recovery low. D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable.
REVIEWED BY: _____________________________________________
Page 4 of 5
Date Signed: 9/16/2013
MSD
Page 5 of 5
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524013 Collection Date: 9/8/2013 Collection Time: 9:55:00 AM
Receive Date: 9/8/2013 Customer Sample#:
Collector: AC Sample Number: 13050478
Project ID: FF Discrete-Partial Site: Falcon Field RESULTS
Parameter
Analysis Date
Analyst
9/12/2013
PSERIA
9/8/2013
mrexing
< 5.0 mg/L
9/11/2013
NSILIDE
11
< 11.0 mg/L
9/20/2013
TAL
1
7.32 S.U.
9/8/2013
DCAMERO
1
25.6 째C
9/8/2013
DCAMERO
Method No
MRL
SM4500-CN E
0.02
SM9223B
2.2
Oil and Grease
EPA 1664A
5
Petroleum Hyrodcarbons, Total
EPA 1664A
pH-Field
SM4500H B SM2550B
Cyanide, Total E. Coli, MPN
Temperature-Field
Qualifier
Result
< 0.020 mg/L 51.2 mpn/100ml
Quality Control mg/L
BLANK Parameter Cyanide, Total Oil and Grease Standard Parameter
QC BATCH
< 0.02 mg/L QC13091602 < 5 mg/L QC13091101 Actual Conc. Standard Conc. %REC
QC BATCH
QC TYPE
mg/L
mg/L
Cyanide, Total
0.2476
0.25
99
QC13091602
ICV
Cyanide, Total
0.2458
0.25
98
QC13091602
CCV
36.6 Sample Conc.
40 Spike True Value
92 Final Result
mg/L
mg/L
mg/L
0.25 40 0.25
0.2461 38.5 0.2438
Oil and Grease SPIKE RESULTS Parameter
Cyanide, Total Oil and Grease Cyanide, Total
< 0.02 mg/L < 5 mg/L < 0.02 mg/L
QC13091101 %REC %RPD
98 94 98
QUALIFIERS
COMMENTS
Page 1 of 2
0.94
LCS Sample Number
QC BATCH
13090360 13090360 13090360
QC13091602 QC13091101 QC13091602
MS MS MSD
REVIEWED BY: _____________________________________________
Page 2 of 2
Date Signed: 9/27/2013
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524014 Collection Date: 7/27/2013 Collection Time: 1:23:00 AM
Receive Date: 7/27/2013 Customer Sample#:
Collector: J. Meyer Sample Number: 13050479
Project ID: SS Comp-Partial Site: Superstition Springs/US 60 RESULTS Method No
MRL
Qualifier
Result
Analysis Date
Analyst
SM4500-NH3D
0.5
D2
1.56 mg/L
7/31/2013
PSERIA
Nitrogen, Nitrate-Nitrite Total
EPA 300.0
0.5
D1
0.828 mg/L
7/31/2013
JPATTIS
Biochemical Oxygen Demand
SM5210B
2
9.20 mg/L
7/27/2013 KHUNTER
Chemical Oxygen Demand
SM5220D
50
< 50 mg/L
8/15/2013
NSILIDE
Hardness, Total
SM2340C
1
12.0 mg/L CaCO3
7/29/2013
NSILIDE
Antimony, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Arsenic, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Barium, Total
EPA 200.8
0.005
D1/M2
0.021 mg/L
8/9/2013
GSMITH2
Beryllium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Cadmium, Total
EPA 200.8
0.001
< 0.001 mg/L
8/9/2013
GSMITH2
Chromium, Total
EPA 200.8
0.005
D1/M2
0.005 mg/L
8/9/2013
GSMITH2
Copper, Total
EPA 200.8
0.005
D1/M2
0.028 mg/L
8/9/2013
GSMITH2
Lead, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Nickel, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Selenium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Silver, Total
EPA 200.8
0.001
< 0.001 mg/L
8/9/2013
GSMITH2
Thallium, Total
EPA 200.8
0.005
D1/L4/M2
< 0.005 mg/L
8/9/2013
GSMITH2
Zinc, Total
EPA 200.8
0.005
D1/M2
Mercury, Total
EPA245.1
0.0002
SM4500-Norg
Orthophosphate
EPA 300.0
Phosphorus, Total
SM4500-P
Solids, Suspended Total
SM2540D
Solids, Total Dissolved
SM2540C
Parameter Nitrogen, Ammonia Total
Nitrogen, Kjeldahl Total
0.066 mg/L
8/9/2013
GSMITH2
< 0.00020 mg/L
8/2/2013
TAL
0.5
2.30 mg/L
7/29/2013
PSERIA
0.2
< 0.20 mg/L
7/27/2013
TAL
0.1
0.35 mg/L
8/2/2013
PSERIA
10
25.0 mg/L
8/1/2013
NSILIDE
20
120 mg/L
7/31/2013
NSILIDE
Quality Control
Page 1 of 5
Quality Control mg/L
BLANK Parameter
QC BATCH
Nitrogen, Ammonia Total
< 0.5 mg/L
QC13073103
Nitrogen, Nitrate-Nitrite Total
< 0.5 mg/L
QC13080202
Biochemical Oxygen Demand Chemical Oxygen Demand
< 2 mg/L < 50 mg/L
QC13080101 QC13081506
Antimony, Total
Arsenic, Total Barium, Total Beryllium, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Nickel, Total
Selenium, Total Silver, Total Thallium, Total Zinc, Total
< 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.001 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201
< 0.005 mg/L QC13081201 < 0.001 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201
Nitrogen, Kjeldahl Total
< 0.5 mg/L
QC13072908
Phosphorus, Total Solids, Suspended Total
< 0.1 mg/L < 10 mg/L
QC13080205 QC13080103
Solids, Total Dissolved
Standard Parameter
< 20 mg/L QC13080102 Actual Conc. Standard Conc. %REC
QC BATCH
QC TYPE
mg/L
mg/L
Nitrogen, Ammonia Total
0.504
0.5
101
QC13073103
ICV
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
0.510 0.495
0.5 0.5
102 99
QC13073103
CCV
QC13080202
LFB
Nitrogen, Nitrate-Nitrite Total Biochemical Oxygen Demand
0.503 199
0.5 198
101 101
QC13080202 QC13080101
CCV LCS
Chemical Oxygen Demand
493
500
99
QC13081506
ICV
Chemical Oxygen Demand Hardness, Total
512 99.80
500 100
102 100
QC13081506 QC13072904
CCV LCS
Antimony, Total
0.04853
0.05
97
QC13081201
LFB
Antimony, Total Antimony, Total
0.01049 0.05305
0.01 0.05
105 106
QC13081201
ICV
QC13081201
CCV
Arsenic, Total Arsenic, Total
0.04553 0.01020
0.05 0.01
91 102
QC13081201
LFB
QC13081201
ICV
Arsenic, Total
0.04939
0.05
99
QC13081201
CCV
Barium, Total Barium, Total
0.04515 0.01028
0.05 0.01
90
QC13081201
LFB
103
QC13081201
ICV
Barium, Total
0.05029
0.05
101
QC13081201
CCV
Beryllium, Total Beryllium, Total
0.06647 0.01008
0.05 0.01
133 101
QC13081201
LFB
QC13081201
ICV
Beryllium, Total Cadmium, Total
0.04816 0.04672
0.05 0.05
96 93
QC13081201
CCV
QC13081201
LFB
Cadmium, Total
0.01030
0.01
103
QC13081201
ICV
Cadmium, Total Chromium, Total
0.05128 0.04371
0.05 0.05
103 87
QC13081201
CCV
QC13081201
LFB
107
QC13081201
ICV CCV
QC13081201
LFB
Chromium, Total
0.01068
0.01
Chromium, Total Copper, Total
0.04775 0.04512
0.05 0.05
96 90
QC13081201
Copper, Total
0.01025
0.01
103
QC13081201
ICV
Copper, Total
0.05745
0.05
115
QC13081201
CCV
Lead, Total
0.04560
0.05
91
QC13081201
LFB
Lead, Total
0.00995
0.01
100
QC13081201
ICV
Page 2 of 5
Lead, Total
0.05152
0.05
103
QC13081201
CCV
Nickel, Total
0.04411
0.05
88
Nickel, Total
0.01013
0.01
101
QC13081201 QC13081201
LFB ICV
Nickel, Total
0.04997
0.05
100
QC13081201
CCV
Selenium, Total Selenium, Total
0.04916 0.01049
0.05 0.01
98 105
QC13081201 QC13081201
LFB ICV
Selenium, Total
0.04989
0.05
100
QC13081201
CCV
Silver, Total Silver, Total
0.05166 0.00988
0.05 0.01
103 99
QC13081201 QC13081201
LFB ICV
QC13081201 QC13081201
CCV LFB
Silver, Total
0.05443
0.05
109
Thallium, Total Thallium, Total
0.03484 0.00967
0.05 0.01
70 97
QC13081201
ICV
Thallium, Total Zinc, Total
0.05025 0.04803
0.05 0.05
101 96
QC13081201 QC13081201
CCV LFB
Zinc, Total
0.01045
0.01
105
QC13081201
ICV
Zinc, Total Nitrogen, Kjeldahl Total
0.05402 4.92
0.05 5
108 98
QC13081201 QC13072908
CCV LFB
QC13072908 QC13080205
CCV ICV
QC13080205
CCV
QC13080103 QC13080102 Sample Number
LCS LCS
Nitrogen, Kjeldahl Total
24.94
25
100
Phosphorus, Total Phosphorus, Total
0.2970 0.3043
0.3 0.3
99 101
Solids, Suspended Total Solids, Total Dissolved
194 502 Actual Conc.
200 495 Duplicate Conc.
97 101 %RPD
mg/L
mg/L
Duplicate Parameter
QC BATCH
Biochemical Oxygen Demand
9.20 mg/L
9.3
1.08
13050479
QC13080101
Solids, Suspended Total
228 mg/L
230
0.87
13070837
QC13080103
120 mg/L 126 Sample Conc. Spike True Value
4.88 Final Result
13050479 %REC %RPD
Solids, Total Dissolved SPIKE RESULTS Parameter
mg/L
QC13080102 Sample Number
QC BATCH
mg/L
mg/L
Antimony, Total
< 0.025 mg/L
0.05
0.04059
81
13050477
QC13081201
MS
Arsenic, Total Barium, Total
< 0.025 mg/L 0.030 mg/L
0.05 0.05
0.03922 0.06128
78 63
13050477 13050477
QC13081201 QC13081201
MS MS
Beryllium, Total
< 0.025 mg/L
0.05
0.04431
89
13050477
QC13081201
MS
Cadmium, Total Chemical Oxygen Demand
0.001 mg/L < 50 mg/L
0.05 500
0.03999 533
76 97
13050477 13050479
QC13081201
MS MS
Chromium, Total Copper, Total
< 0.025 mg/L < 0.025 mg/L
0.05 0.05
0.04384 0.04339
63 67
13050477 13050477
QC13081201 QC13081201
MS MS
Hardness, Total
QC13081506
62.84
101
13050479
QC13072904
MS
0.04910 0.04052
73 73
13050477 13050477
QC13081201 QC13081201
MS MS
2.5
4.03
99
13050479
QC13073103
MS
0.5 0.3
1.281 0.6603
91 102
13050479 13050479
QC13080202
MS MS
12.0 mg/L CaCO3 50
Lead, Total Nickel, Total
< 0.025 mg/L < 0.025 mg/L
0.05 0.05
Nitrogen, Ammonia Total
< 2.5 mg/L
Nitrogen, Nitrate-Nitrite Total Phosphorus, Total
< 1 mg/L 0.35 mg/L
QC13080205
Selenium, Total Silver, Total
< 0.025 mg/L < 0.001 mg/L
0.05 0.05
0.04358 0.04785
87 96
13050477 13050477
QC13081201 QC13081201
MS MS
Thallium, Total
< 0.025 mg/L
0.05
0.03283
66
13050477
QC13081201
MS
Zinc, Total Chemical Oxygen Demand
0.123 mg/L < 50 mg/L
0.05 500
0.13415 532
22 97
QC13081201
MS
0.19
13050477 13050479
QC13081506
MSD
64.08
103
1.95
13050479
QC13072904
MSD
QC13073103 QC13080202
MSD MSD
QC13080205
MSD
Hardness, Total
12.0 mg/L CaCO3 50
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 2.5 mg/L < 1 mg/L
2.5 0.5
4.065 1.284
100 91
0.86 0.23
13050479 13050479
Phosphorus, Total
0.35 mg/L
0.3
0.6585
101
0.27
13050479
QUALIFIERS Page 3 of 5
D1
Sample diluted due to matrix interference.
D2
Sample diluted due to high concentration.
COMMENTS NO3 ICV = 99% recovery. D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable. D1 = Sample required dilution due to matrix. Analyzed 8/13/13, QC available upon request. GS D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable. Analyzed 8/13/13, QC available upon request. GS
D1 = Sample required dilution due to matrix. L4 = Associated blank spike (Tl) recovery was below method limits. M2 = Matrix spike recovery low. D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable.
REVIEWED BY: _____________________________________________
Page 4 of 5
Date Signed: 9/17/2013
Page 5 of 5
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524015 Collection Date: 7/27/2013 Collection Time: 1:35:00 AM
Receive Date: 7/27/2013 Customer Sample#:
Collector: J. Meyer Sample Number: 13050480
Project ID: SS Discrete-Partial Site: Superstition Springs/US 60 RESULTS
Parameter
Method No
MRL
Qualifier
Result
Analysis Date
Analyst
8/8/2013
PSERIA
7/27/2013
mrexing
SM4500-CN E
0.02
SM9223B
2.2
Oil and Grease
EPA 1664A
5
< 5.0 mg/L
8/12/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
10
< 10.0 mg/L
8/7/2013
TAL
pH-Field
SM4500H B
1
7.28 S.U.
7/27/2013
AC
SM2550B
1
28.2 째C
7/27/2013
AC
Cyanide, Total E. Coli, MPN
Temperature-Field
< 0.020 mg/L 1990.0 mpn/100ml
Quality Control mg/L
BLANK Parameter
< 0.02 mg/L QC13080804
Cyanide, Total
Oil and Grease Standard Parameter
QC BATCH
< 5 mg/L QC13081207 Actual Conc. Standard Conc. %REC
QC BATCH
QC TYPE
QC13080804 QC13080804
ICV CCV
mg/L
mg/L
Cyanide, Total
0.2525
0.25
101
Cyanide, Total
0.2598
0.25
104
37.7 Sample Conc.
40 Spike True Value
94 Final Result
mg/L
mg/L
mg/L
0.25
0.2631
40
39.4
0.25
0.2635
105
Oil and Grease SPIKE RESULTS Parameter Cyanide, Total
< 0.02 mg/L
Oil and Grease
< 5 mg/L
Cyanide, Total
< 0.02 mg/L
QC13081207 %REC %RPD
LCS Sample Number
QC BATCH
105
13070477
QC13080804
99
13070477
QC13081207
MS
13070477
QC13080804
MSD
QUALIFIERS
COMMENTS
Page 1 of 2
0.15
MS
REVIEWED BY: _____________________________________________
Page 2 of 2
Date Signed: 8/20/2013
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524016 Collection Date: 7/20/2013 Collection Time: 10:45:00 PM
Receive Date: 7/21/2013 Customer Sample#:
Collector: AC Sample Number: 13050481
Project ID: Univ Comp-Partial Site: Univ Dr @ EMF RESULTS Method No
MRL
Qualifier
Result
Analysis Date
Analyst
SM4500-NH3D
1
D2
2.75 mg/L
7/31/2013
PSERIA
Nitrogen, Nitrate-Nitrite Total
EPA 300.0
0.4
< 0.400 mg/L
7/24/2013
JPATTIS
Biochemical Oxygen Demand
SM5210B
2
41.0 mg/L
7/27/2013
PSERIA
Chemical Oxygen Demand
SM5220D
50
267 mg/L
7/23/2013
NSILIDE
Hardness, Total
SM2340C
1
87.0 mg/L CaCO3
7/23/2013
NSILIDE
Antimony, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Arsenic, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Barium, Total
EPA 200.8
0.005
D1/M2
0.101 mg/L
8/9/2013
GSMITH2
Beryllium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Cadmium, Total
EPA 200.8
0.001
< 0.001 mg/L
8/9/2013
GSMITH2
Chromium, Total
EPA 200.8
0.005
D1/M2
0.007 mg/L
8/9/2013
GSMITH2
Copper, Total
EPA 200.8
0.005
D1/M2
0.044 mg/L
8/9/2013
GSMITH2
Lead, Total
EPA 200.8
0.005
D1
0.010 mg/L
8/9/2013
GSMITH2
Nickel, Total
EPA 200.8
0.005
D1
0.016 mg/L
8/9/2013
GSMITH2
Selenium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
8/9/2013
GSMITH2
Silver, Total
EPA 200.8
0.001
< 0.001 mg/L
8/9/2013
GSMITH2
Thallium, Total
EPA 200.8
0.005
D1/L4/M2
< 0.005 mg/L
8/9/2013
GSMITH2
Zinc, Total
EPA 200.8
0.005
D1/M2
Mercury, Total
EPA245.1
0.0002
SM4500-Norg
Orthophosphate
EPA 300.0
Phosphorus, Total
SM4500-P
Solids, Suspended Total
SM2540D
Solids, Total Dissolved
SM2540C
Parameter Nitrogen, Ammonia Total
Nitrogen, Kjeldahl Total
0.215 mg/L
8/9/2013
GSMITH2
< 0.00020 mg/L
7/29/2013
TAL
0.5
6.27 mg/L
7/29/2013
PSERIA
0.2
0.22 mg/L
7/22/2013
TAL
0.1
0.71 mg/L
7/23/2013
PSERIA
10
152 mg/L
7/23/2013
NSILIDE
20
180 mg/L
7/23/2013
NSILIDE
Quality Control
Page 1 of 5
Quality Control mg/L
BLANK Parameter
QC BATCH
Nitrogen, Ammonia Total
< 1 mg/L
QC13073103
Biochemical Oxygen Demand
< 2 mg/L
QC13072801
Chemical Oxygen Demand Hardness, Total Antimony, Total
Arsenic, Total Barium, Total Beryllium, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Nickel, Total
Selenium, Total Silver, Total Thallium, Total Zinc, Total
< 50 mg/L QC13072403 QC13072301 < 1 mg/L CaCO3 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.001 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201
< 0.005 mg/L QC13081201 < 0.001 mg/L QC13081201 < 0.005 mg/L QC13081201 < 0.005 mg/L QC13081201
Nitrogen, Kjeldahl Total
< 0.5 mg/L
QC13072908
Phosphorus, Total Solids, Suspended Total
< 0.1 mg/L < 10 mg/L
QC13072404 QC13072402
Solids, Total Dissolved
Standard Parameter
< 20 mg/L QC13072405 Actual Conc. Standard Conc. %REC
QC BATCH
QC TYPE
mg/L
mg/L
Nitrogen, Ammonia Total
0.504
0.5
101
QC13073103
ICV
Nitrogen, Ammonia Total Fluoride
0.510 0.486
0.5 0.5
102 97
QC13073103
CCV
QC13072501
LFB
Fluoride Fluoride
0.489 0.491
0.5 0.5
98 98
QC13072501 QC13072501
ICV CCV
Nitrogen, Nitrate Total
0.492
0.5
98
QC13072501
LFB
Nitrogen, Nitrate Total Nitrogen, Nitrate Total
0.496 0.511
0.5 0.5
99 102
QC13072501 QC13072501
CCV
Biochemical Oxygen Demand
223
198
113
QC13072801
LCS
Chemical Oxygen Demand Chemical Oxygen Demand
490 484
500 500
98 97
QC13072403
ICV
QC13072403
CCV
Hardness, Total Antimony, Total
102 0.04853
100 0.05
102 97
QC13072301
LCS
QC13081201
LFB
Antimony, Total
0.01049
0.01
105
QC13081201
ICV
Antimony, Total Arsenic, Total
0.05305 0.04553
0.05 0.05
106 91
QC13081201
CCV
QC13081201
LFB
Arsenic, Total
0.01020
0.01
102
QC13081201
ICV
Arsenic, Total Barium, Total
0.04939 0.04515
0.05 0.05
99 90
QC13081201
CCV
QC13081201
LFB
Barium, Total Barium, Total
0.01028 0.05029
0.01 0.05
103 101
QC13081201
ICV
QC13081201
CCV
Beryllium, Total
0.06647
0.05
133
QC13081201
LFB
Beryllium, Total Beryllium, Total
0.01008 0.04816
0.01 0.05
101 96
QC13081201
ICV
QC13081201
CCV
Cadmium, Total
0.04672
0.05
93
QC13081201
LFB ICV
ICV
Cadmium, Total Cadmium, Total
0.01030 0.05128
0.01 0.05
103 103
QC13081201 QC13081201
CCV
Chromium, Total
0.04371
0.05
87
QC13081201
LFB
Chromium, Total
0.01068
0.01
107
QC13081201
ICV
Chromium, Total
0.04775
0.05
96
QC13081201
CCV
Copper, Total
0.04512
0.05
90
QC13081201
LFB
Page 2 of 5
Copper, Total
0.01025
0.01
103
QC13081201
ICV
Copper, Total
0.05745
0.05
115
Lead, Total
0.04560
0.05
91
QC13081201 QC13081201
CCV LFB
Lead, Total
0.00995
0.01
100
QC13081201
ICV
Lead, Total Nickel, Total
0.05152 0.04411
0.05 0.05
103 88
QC13081201 QC13081201
CCV LFB
Nickel, Total
0.01013
0.01
101
QC13081201
ICV
Nickel, Total Selenium, Total
0.04997 0.04916
0.05 0.05
100 98
QC13081201 QC13081201
CCV LFB
Selenium, Total
0.01049
0.01
105
Selenium, Total Silver, Total
0.04989 0.05166
0.05 0.05
100 103
QC13081201 QC13081201
ICV CCV
QC13081201
LFB
Silver, Total Silver, Total
0.00988 0.05443
0.01 0.05
99 109
QC13081201 QC13081201
ICV CCV
Thallium, Total
0.03484
0.05
70
QC13081201
LFB
Thallium, Total Thallium, Total
0.00967 0.05025
0.01 0.05
97 101
QC13081201 QC13081201
ICV CCV
Zinc, Total
0.04803
0.05
96
Zinc, Total Zinc, Total
0.01045 0.05402
0.01 0.05
105 108
QC13081201 QC13081201
LFB ICV
QC13081201
CCV
Nitrogen, Kjeldahl Total Nitrogen, Kjeldahl Total
4.92 24.94
5 25
98 100
QC13072908 QC13072908
LFB CCV
Phosphorus, Total
0.3054
0.3
102
QC13072404
ICV
Phosphorus, Total Solids, Suspended Total
0.3054 202
0.3 200
102 101
QC13072404 QC13072402
CCV LCS
Solids, Total Dissolved
474 Actual Conc.
495 Duplicate Conc.
96 %RPD
QC13072405 Sample Number
LCS
mg/L
mg/L
Duplicate Parameter Biochemical Oxygen Demand Solids, Suspended Total Solids, Total Dissolved
SPIKE RESULTS Parameter
41.0 mg/L 4060 mg/L
38 4140
7.59 1.95
13050481 13070263
212 mg/L 206 Sample Conc. Spike True Value
2.87 Final Result
13050469 %REC %RPD
mg/L
QC BATCH QC13072801 QC13072402 QC13072405 Sample Number QC BATCH
mg/L
mg/L
Antimony, Total Arsenic, Total
< 0.025 mg/L < 0.025 mg/L
0.05 0.05
0.04059 0.03922
81 78
13050477 13050477
QC13081201
Barium, Total Beryllium, Total
0.030 mg/L < 0.025 mg/L
0.05 0.05
0.06128 0.04431
63 89
13050477 13050477
QC13081201 QC13081201
MS MS
Cadmium, Total
0.001 mg/L
0.05
0.03999
76
13050477
QC13081201
MS
Chemical Oxygen Demand Chromium, Total
56 mg/L < 0.025 mg/L
500 0.05
533 0.04384
95 63
13050477 13050477
QC13072403 QC13081201
MS MS
< 0.025 mg/L
0.05
0.04339
67
13050477
QC13081201
MS
18.0 mg/L CaCO3 50 < 0.025 mg/L 0.05
70 0.04910
104 73
13050477 13050477
QC13072301
MS MS
0.04052 4.03
73 99
13050477 13050479
QC13081201 QC13073103
MS MS
Copper, Total Hardness, Total Lead, Total Nickel, Total Nitrogen, Ammonia Total
< 0.025 mg/L < 2.5 mg/L
0.05 2.5
QC13081201
QC13081201
MS MS
5
8.63
100
13050469
QC13072908
MS
Phosphorus, Total Selenium, Total
0.15 mg/L < 0.025 mg/L
0.3 0.05
0.4462 0.04358
99 87
13050477 13050477
QC13072404 QC13081201
MS MS
Silver, Total
< 0.001 mg/L
0.05
0.04785
96
13050477
QC13081201
MS
Thallium, Total Zinc, Total
< 0.025 mg/L 0.123 mg/L
0.05 0.05
0.03283 0.13415
66 22
13050477 13050477
QC13081201 QC13081201
MS MS
500
522
93
2.09
13050477
QC13072403
MSD
18.0 mg/L CaCO3 50
69
102
1.44
13050477
QC13072301
MSD
Nitrogen, Kjeldahl Total
Chemical Oxygen Demand Hardness, Total
3.63 mg/L
56 mg/L
Nitrogen, Ammonia Total
< 2.5 mg/L
2.5
4.065
100
0.86
13050479
QC13073103
MSD
Nitrogen, Kjeldahl Total
3.63 mg/L
5
8.72
102
1.04
13050469
QC13072908
MSD
Page 3 of 5
Phosphorus, Total
0.15 mg/L
0.3
0.4442
98
0.45
13050477
QC13072404
QUALIFIERS D1
Sample diluted due to matrix interference.
D2
Sample diluted due to high concentration.
COMMENTS D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable.
Cd analyzed 8/13/13, QC available upon request. GS D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable. Ag analyzed 8/13/13, QC available upon request. GS
D1 = Sample required dilution due to matrix. L4 = Associated blank spike (Tl) recovery was below method limits. M2 = Matrix spike recovery low. D1 = Sample required dilution due to matrix. M2 = Matrix spike recovery low; the associated blank spike acceptable.
REVIEWED BY: _____________________________________________
Page 4 of 5
Date Signed: 9/16/2013
MSD
Page 5 of 5
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: Scott Bouchie OrderID: 130524017 Collection Date: 7/20/2013 Collection Time: 10:50:00 PM
Receive Date: 7/21/2013 Customer Sample#:
Collector: AC Sample Number: 13050482
Project ID: Univ Discrete-Partial Site: Univ Dr @ EMF RESULTS
Parameter
7/25/2013
PSERIA
SM4500-CN E
0.02
SM9223B
2.2
7/21/2013
mrexing
EPA 1664A
5
< 5.0 mg/L
7/30/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
11
< 11.0 mg/L
8/1/2013
TAL
pH-Field
SM4500H B
1
7.07 S.U.
7/20/2013 ACHAVEZ
SM2550B
1
29.5 째C
7/20/2013 ACHAVEZ
E. Coli, MPN Oil and Grease
Temperature-Field
Result
Analyst
MRL
Cyanide, Total
Qualifier
Analysis Date
Method No
< 0.020 mg/L 2260.0 mpn/100ml
Quality Control mg/L
BLANK Parameter
Oil and Grease Standard Parameter Cyanide, Total
Cyanide, Total Oil and Grease SPIKE RESULTS Parameter
QC BATCH
< 5 mg/L QC13073003 Actual Conc. Standard Conc. %REC mg/L
mg/L
0.2526
QC BATCH
QC TYPE
0.25
101
QC13072506
ICV
0.2612 38.7 Sample Conc.
0.25 40 Spike True Value
104 97 Final Result
QC13072506
CCV
mg/L
QC13073003 %RPD
LCS
%REC
Sample Number
QC BATCH
mg/L
mg/L
Cyanide, Total
< 0.02 mg/L
0.25
0.2595
104
13050476
QC13072506
Oil and Grease Cyanide, Total
< 5 mg/L < 0.02 mg/L
40 0.25
37.4 0.2613
92 105
13050476 13050476
QC13073003
MS
QC13072506
MSD
0.69
QUALIFIERS
COMMENTS
REVIEWED BY: _____________________________________________ Page 1 of 2
Date Signed: 8/14/2013
MS
Page 2 of 2
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 130815016 Collection Date: 8/30/2013 Collection Time: 7:10:00 PM
Receive Date: 8/31/2013 Customer Sample#:
Collector: D. Cameron Sample Number: 13080554
Project ID: 54 Comp-Partial Site: 54th St @ EMF RESULTS
Parameter
Analysis Date
Method No
MRL
Qualifier
Result
SM4500-NH3D
0.2
D2
1.42 mg/L
9/5/2013
PSERIA
EPA 300.0
0.5
D1
1.14 mg/L
9/10/2013
JPATTIS
Biochemical Oxygen Demand
SM5210B
2
K5
13.2 mg/L
9/6/2013
KH/GS
Chemical Oxygen Demand
SM5220D
50
86 mg/L
9/3/2013
NSILIDE
Hardness, Total
SM2340C
1
9/3/2013
NSILIDE
Antimony, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
9/4/2013
GSMITH2
Arsenic, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
9/4/2013
GSMITH2
Barium, Total
EPA 200.8
0.005
D1
0.048 mg/L
9/4/2013
GSMITH2
Beryllium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
9/4/2013
GSMITH2
Cadmium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
9/4/2013
GSMITH2
Chromium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
9/4/2013
GSMITH2
Copper, Total
EPA 200.8
0.005
D1
0.015 mg/L
9/4/2013
GSMITH2
Lead, Total
EPA 200.8
0.005
D1
0.007 mg/L
9/4/2013
GSMITH2
Nickel, Total
EPA 200.8
0.005
D1
0.006 mg/L
9/4/2013
GSMITH2
Selenium, Total
EPA 200.8
0.005
D1/M1/V3
< 0.005 mg/L
9/4/2013
GSMITH2
Silver, Total
EPA 200.8
0.001
D1
< 0.001 mg/L
9/4/2013
GSMITH2
Thallium, Total
EPA 200.8
0.005
D1
< 0.005 mg/L
9/4/2013
GSMITH2
Zinc, Total
EPA 200.8
0.005
D1/M1
0.068 mg/L
9/4/2013
GSMITH2
D1
< 0.00020 mg/L
9/10/2013
TAL
2.80 mg/L
9/5/2013
PSERIA
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
28.0 mg/L CaCO3
Analyst
EPA245.1
0.0002
SM4500-Norg
0.5
Orthophosphate
EPA 300.0
0.2
0.22 mg/L
8/31/2013
TAL
Phosphorus, Total
SM4500-P
0.1
0.44 mg/L
9/3/2013
PSERIA
Solids, Suspended Total
SM2540D
10
62.0 mg/L
9/5/2013
NSILIDE
Solids, Total Dissolved
SM2540C
20
122 mg/L
9/4/2013
NSILIDE
Mercury, Total Nitrogen, Kjeldahl Total
D1
Quality Control
Page 1 of 5
Quality Control mg/L
BLANK Parameter Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total Biochemical Oxygen Demand Chemical Oxygen Demand Hardness, Total Antimony, Total Arsenic, Total Barium, Total Beryllium, Total Cadmium, Total Chromium, Total Copper, Total Lead, Total Nickel, Total Selenium, Total Silver, Total Thallium, Total Zinc, Total Nitrogen, Kjeldahl Total Phosphorus, Total Solids, Suspended Total Solids, Total Dissolved Standard Parameter
< 0.2 mg/L < 0.5 mg/L < 2 mg/L < 50 mg/L
QC BATCH QC13090506 QC13091201 QC13090901 QC13090307
QC13090304 < 1 mg/L CaCO3 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.001 mg/L QC13091001 < 0.005 mg/L QC13091001 < 0.005 mg/L QC13091001
< 0.5 mg/L QC13090507 < 0.1 mg/L QC13090309 < 10 mg/L QC13090502 < 20 mg/L QC13090503 Actual Conc. Standard Conc. %REC mg/L mg/L
Nitrogen, Ammonia Total Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total Nitrogen, Nitrate-Nitrite Total Nitrogen, Nitrate-Nitrite Total Biochemical Oxygen Demand Chemical Oxygen Demand Chemical Oxygen Demand Hardness, Total Antimony, Total Antimony, Total Antimony, Total Arsenic, Total Arsenic, Total Arsenic, Total Barium, Total Barium, Total Barium, Total Beryllium, Total Beryllium, Total Beryllium, Total
0.501 0.510 1.19 1.18 1.213 208.0 496 498 99 0.05193 0.01009 0.04949 0.05518 0.00981 0.05999 0.04901 0.01005 0.04630 0.05108 0.01025 0.04742
0.5 0.5 1.25 1.25 1.25 198 500 500 100 0.05 0.01 0.05 0.05 0.01 0.05 0.05 0.01 0.05 0.05 0.01 0.05
100 102 95 94 97 105 99 100 99 104 101 99 110 98 120 98 101 93 102 103 95
Cadmium, Total Cadmium, Total Cadmium, Total Chromium, Total Chromium, Total Chromium, Total Copper, Total Copper, Total Copper, Total
0.04917 0.00993 0.04793 0.04979 0.01029 0.04779 0.05066 0.00972 0.05034
0.05 98 0.01 99 0.05 96 0.05 100 0.01 103 0.05 96 0.05 101 0.01 97 0.05 101 Page 2 of 5
QC BATCH
QC TYPE
QC13090506
ICV
QC13090506
CCV
QC13091201
LFB
QC13091201
ICV
QC13091201
CCV
QC13090901
LCS
QC13090307
ICV
QC13090307
CCV
QC13090304
LCS
QC13091001
LFB
QC13091001
ICV
QC13091001
CCV
QC13091001
LFB
QC13091001
ICV
QC13091001
CCV
QC13091001
LFB
QC13091001 QC13091001 QC13091001 QC13091001 QC13091001 QC13091001
ICV CCV LFB ICV CCV LFB
QC13091001
ICV
QC13091001
CCV
QC13091001
LFB
QC13091001
ICV
QC13091001
CCV
QC13091001
LFB
QC13091001
ICV
QC13091001
CCV
Lead, Total Lead, Total Lead, Total Nickel, Total Nickel, Total
0.04885 0.00967 0.04914 0.05063 0.00962
0.05 0.01 0.05 0.05 0.01
98 97 98 101 96
Nickel, Total
0.05065 0.05782 0.01004 0.06831 0.05001 0.00980 0.05752 0.04786 0.00949 0.04709 0.05182 0.00939 0.04935 4.99 25.10 0.3026 0.3034 190 534 Actual Conc. mg/L
0.05 0.05 0.01 0.05 0.05 0.01 0.05 0.05 0.01 0.05 0.05 0.01 0.05 5 25 0.3 0.3 200 495 Duplicate Conc. mg/L
101 116 100 137 100 98 115 96 95 94 104 94 99 100 100 101 101 95 108 %RPD
Selenium, Total Selenium, Total Selenium, Total Silver, Total Silver, Total Silver, Total Thallium, Total Thallium, Total Thallium, Total Zinc, Total Zinc, Total Zinc, Total Nitrogen, Kjeldahl Total Nitrogen, Kjeldahl Total
Phosphorus, Total Phosphorus, Total Solids, Suspended Total Solids, Total Dissolved Duplicate Parameter Biochemical Oxygen Demand Solids, Suspended Total Solids, Total Dissolved SPIKE RESULTS Parameter
13.2 mg/L 13.3 62.0 mg/L 64 122 mg/L 120 Sample Conc. Spike True Value mg/L
0.75 3.17 1.65 Final Result
QC13091001 QC13091001 QC13091001 QC13091001 QC13091001 QC13091001
LFB ICV CCV LFB ICV CCV
QC13091001
LFB
QC13091001
ICV
QC13091001
CCV
QC13091001
LFB
QC13091001
ICV
QC13091001
CCV
QC13091001
LFB
QC13091001
ICV
QC13091001
CCV
QC13091001
LFB
QC13091001
ICV
QC13091001
CCV
QC13090507
LFB
QC13090507
CCV
QC13090309 QC13090309 QC13090502 QC13090503 Sample Number
ICV CCV LCS LCS QC BATCH
13080554 13080554 13080554 %REC %RPD
QC13090901 QC13090502 QC13090503 Sample Number QC BATCH
mg/L
mg/L
Antimony, Total
< 0.025 mg/L
0.05
0.04454
87
13080554
QC13091001
MS
Arsenic, Total
< 0.025 mg/L
0.05
0.06391
128
13080554
QC13091001
MS
Barium, Total
0.048 mg/L
0.05
0.11071
126
13080554
QC13091001
MS
Beryllium, Total
< 0.025 mg/L
0.05
0.0483
97
13080554
QC13091001
MS
Cadmium, Total
< 0.025 mg/L
0.05
0.05075
102
13080554
QC13091001
MS
500
559
95
13080554
QC13090307
MS
Chemical Oxygen Demand
86 mg/L
Chromium, Total
< 0.025 mg/L
0.05
0.05127
94
13080554
QC13091001
MS
Copper, Total
< 0.025 mg/L
0.05
0.07114
113
13080554
QC13091001
MS
80.2
104
13080554
QC13090304
MS
Hardness, Total
28.0 mg/L CaCO3 50
Lead, Total
< 0.025 mg/L
0.05
0.06155
108
13080554
QC13091001
MS
Nickel, Total Nitrogen, Ammonia Total Nitrogen, Kjeldahl Total Nitrogen, Nitrate-Nitrite Total Phosphorus, Total
< 0.025 mg/L 0.380 mg/L 2.80 mg/L 1.14 mg/L 0.44 mg/L
0.05 0.5 5 1 0.3
0.06017 0.886 7.89 1.974 0.7654
109 100 102 84 108
13080554 13080757 13080554 13080554 13080554
MS MS MS MS MS
Selenium, Total Silver, Total Thallium, Total Zinc, Total Antimony, Total Arsenic, Total Barium, Total Beryllium, Total Cadmium, Total
< 0.025 mg/L < 0.005 mg/L < 0.025 mg/L 0.068 mg/L < 0.025 mg/L < 0.025 mg/L 0.048 mg/L < 0.025 mg/L < 0.025 mg/L
0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05 0.05
0.07345 0.05740 0.04548 0.13923 0.04258 0.06120 0.10733 0.04780 0.04970 Page 3 of 5
145 115 91 142 83 122 119 96 99
13080554 13080554 13080554 13080554 13080554 13080554 13080554 13080554 13080554
QC13091001 QC13090506 QC13090507 QC13091201 QC13090309 QC13091001
4.50 4.33 6.36 1.04 2.09
QC13091001 QC13091001 QC13091001 QC13091001 QC13091001 QC13091001 QC13091001 QC13091001
MS MS MS MS MSD MSD MSD MSD MSD
Chemical Oxygen Demand Chromium, Total Copper, Total Hardness, Total Lead, Total Nickel, Total Nitrogen, Ammonia Total Nitrogen, Kjeldahl Total Nitrogen, Nitrate-Nitrite Total Phosphorus, Total Selenium, Total Silver, Total Thallium, Total Zinc, Total
86 mg/L < 0.025 mg/L < 0.025 mg/L 28.0 mg/L CaCO3 < 0.025 mg/L < 0.025 mg/L 0.380 mg/L 2.80 mg/L 1.14 mg/L 0.44 mg/L < 0.025 mg/L < 0.005 mg/L < 0.025 mg/L 0.068 mg/L
500 0.05 0.05 50 0.05
559 0.04997 0.06877 79.9 0.05794
95 92 108 104 101
0.05 0.5 5 1 0.3 0.05 0.05 0.05 0.05
0.05817 0.902 7.91 1.991 0.7611 0.07066 0.05566 0.04457 0.13860
105 104 102 85 106 139 111 89 140
0.00 2.57 3.39 0.37 6.04 3.38 1.79 0.25 0.86 0.56 3.87 3.08 2.02 0.45
13080554 13080554 13080554 13080554 13080554 13080554 13080757 13080554 13080554 13080554 13080554 13080554 13080554 13080554
QC13090307 QC13091001 QC13091001 QC13090304 QC13091001 QC13091001 QC13090506 QC13090507 QC13091201 QC13090309 QC13091001 QC13091001 QC13091001 QC13091001
QUALIFIERS D1
Sample diluted due to matrix interference.
D2
K5
The dilution water D.O. depletion was > 0.2 mg/L.
Sample diluted due to high concentration.
COMMENTS D1 = Sample required dilution due to matrix. V3 = (Se) CCV recovery was above method acceptance limits. M1 = (Se/Zn) matrix spike recovery was high; the associated blank spike recovery was acceptable. D1 = Sample required dilution due to matrix. M1 = (Se/Zn) matrix spike recovery was high; the associated blank spike recovery was acceptable.
REVIEWED BY: _____________________________________________
Page 4 of 5
Date Signed: 9/17/2013
MSD MSD MSD MSD MSD MSD MSD MSD MSD MSD MSD MSD MSD MSD
Page 5 of 5
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101004 Collection Date: 11/21/2013 Collection Time: 12:30:00 AM
Receive Date: 11/22/2013 Customer Sample#:
Collector: AC Sample Number: 13110004
Project ID: 54 Comp-Full Site: 54th St @ EMF RESULTS
Parameter Nitrogen, Ammonia Total
Method No
MRL
SM4500-NH3D
Qualifier
Result
Analysis Date
Analyst
1.00 mg/L
11/27/2013
PSERIA
0.5
D2
EPA 300.0
0.5
D1
1.02 mg/L
11/26/2013
PSERIA
1,2,4-Trichlorobenzene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
1,2-Diphenylhydrazine
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
2,4,6-Trichlorophenol
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
2,4-Dichlorophenol
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
2,4-Dimethylphenol
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
2,4-Dinitrophenol
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
2,4-Dinitrotoluene
EPA625TAL
0.11
< 0.110 mg/L
11/30/2013
TAL
2,6-Dinitrotoluene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
2-Chlorophenol
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
2-Nitrophenol
EPA625TAL
0.032
< 0.032 mg/L
11/30/2013
TAL
3,3-Dichlorobenzidine
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
4,6-Dinitro-o-cresol
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
4-Nitrophenol
EPA625TAL
0.053
< 0.053 mg/L
11/30/2013
TAL
Acenaphthene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Acenaphthylene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Anthracene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Diethyl phthalate
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Dimethyl phthalate
EPA625TAL
0.043
< 0.043 mg/L
11/30/2013
TAL
Di-n-butylphthalate
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Di-n-octyl phthalate
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Flouranthene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Flourene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Hexachlorobenzene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Hexachlorobutadiene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Hexachlorocyclopentadiene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Hexachloroethane
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Nitrogen, Nitrate-Nitrite Total
Page 1 of 6
Indeno(1,2,3-cd)pyrene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Isophorone
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Naphthalene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Nitrobenzene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
n-Nitrosodimethylamine
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
n-Nitroso-di-n-propylamine
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
n-Nitrosodiphenylamine
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
p-Chloro-m-cresol
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Pentachlorophenol
EPA625TAL
0.11
< 0.110 mg/L
11/30/2013
TAL
Phenanthrene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Phenol
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Pyrene
EPA625TAL
0.021
< 0.021 mg/L
11/30/2013
TAL
Biochemical Oxygen Demand
SM5210B
2
17.6 mg/L
11/22/2013 GSMITH2
Chemical Oxygen Demand
SM5220D
20
140 mg/L
11/25/2013
Hardness, Total
SM2340C
1
42.0 mg/L CaCO3 11/25/2013
Antimony, Total
EPA 200.8
0.001
Arsenic, Total
EPA 200.8
0.001
Barium, Total
EPA 200.8
Beryllium, Total
EPA 200.8
Cadmium, Total
TAL NSILIDE
0.002 mg/L
12/12/2013 GSMITH2
0.003 mg/L
12/12/2013 GSMITH2
0.001
0.094 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
EPA 200.8
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
Chromium, Total
EPA 200.8
0.001
0.007 mg/L
12/12/2013 GSMITH2
Copper, Total
EPA 200.8
0.001
0.028 mg/L
12/12/2013 GSMITH2
Lead, Total
EPA 200.8
0.001
0.012 mg/L
12/12/2013 GSMITH2
Nickel, Total
EPA 200.8
0.001
0.009 mg/L
12/12/2013 GSMITH2
Selenium, Total
EPA 200.8
0.001
M1
< 0.001 mg/L
12/12/2013 GSMITH2
Silver, Total
EPA 200.8
0.001
V9
< 0.001 mg/L
12/12/2013 GSMITH2
Thallium, Total
EPA 200.8
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
Zinc, Total
EPA 200.8
0.001
0.178 mg/L
12/12/2013 GSMITH2
Mercury, Total
EPA245.1
0.0002
< 0.00020 mg/L
11/26/2013
TAL
M1
SM4500-Norg
1
3.20 mg/L
12/2/2013
TAL
4,4'-DDD
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
4,4'-DDE
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
4,4'-DDT
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Aldrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
alpha-BHC
EPA608TAL
0.0005
< 0.000500 mg/L
12/4/2013
TAL
Aroclor 1016
EPA608TAL
0.0037
< 0.00370 mg/L
12/4/2013
TAL
Aroclor 1221
EPA608TAL
0.0044
< 0.00440 mg/L
12/4/2013
TAL
Aroclor 1232
EPA608TAL
0.0077
< 0.00770 mg/L
12/4/2013
TAL
Aroclor 1242
EPA608TAL
0.01
< 0.0100 mg/L
12/4/2013
TAL
Aroclor 1248
EPA608TAL
0.022
< 0.0220 mg/L
12/4/2013
TAL
Aroclor 1254
EPA608TAL
0.004
< 0.00400 mg/L
12/4/2013
TAL
Aroclor 1260
EPA608TAL
0.0033
< 0.00330 mg/L
12/4/2013
TAL
beta-BHC
EPA608TAL
0.0005
< 0.000500 mg/L
12/4/2013
TAL
Chlordane
EPA608TAL
0.0018
< 0.00180 mg/L
12/4/2013
TAL
Nitrogen, Kjeldahl Total
Page 2 of 6
delta-BHC
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Dieldrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan I (Alpha)
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan II (Beta)
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan sulfate
EPA608TAL
0.0005
< 0.000500 mg/L
12/4/2013
TAL
Endrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endrin aldehyde
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Heptachlor
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Heptachlor epoxide
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Lindane
EPA608TAL
0.0005
< 0.000500 mg/L
12/4/2013
TAL
Toxaphene
EPA608TAL
0.011
< 0.0110 mg/L
12/4/2013
TAL
Orthophosphate
EPA 300.0
0.2
0.36 mg/L
11/22/2013
TAL
Benzo (a) pyrene
EPA 8310
0.000052
< 0.000052 mg/L
11/26/2013
TAL
Benzo(a)anthracene
EPA 8310
0.00021
< 0.00021 mg/L
11/26/2013
TAL
Benzo(b)fluoranthene
EPA 8310
0.0001
< 0.00010 mg/L
11/26/2013
TAL
Benzo(g,h,i)perylene
EPA 8310
0.0001
< 0.00010 mg/L
11/26/2013
TAL
Benzo(k)fluoranthene
EPA 8310
0.000052
< 0.000052 mg/L
11/26/2013
TAL
Chrysene
EPA 8310
0.0001
< 0.00010 mg/L
11/26/2013
TAL
Dibenz(a,h)anthracene
EPA 8310
0.0001
< 0.00010 mg/L
11/26/2013
TAL
Ideno(1,2,3-cd)pyrene
EPA 8310
0.0001
< 0.00010 mg/L
11/26/2013
TAL
Phosphorus, Total
SM4500-P
0.5
1.30 mg/L
11/25/2013
TAL
Solids, Suspended Total
SM2540D
10
248 mg/L
11/25/2013
NSILIDE
Solids, Total Dissolved
SM2540C
20
118 mg/L
11/25/2013
NSILIDE
Quality Control BLANK Parameter
mg/L
QC BATCH
Nitrogen, Ammonia Total
< 0.5 mg/L
QC13120301
Nitrogen, Nitrate-Nitrite Total
< 0.5 mg/L
QC13120304
Biochemical Oxygen Demand
< 2 mg/L
QC13112701
Hardness, Total Antimony, Total Arsenic, Total
Barium, Total Beryllium, Total Cadmium, Total
Chromium, Total Copper, Total Lead, Total Nickel, Total
QC13112502 < 1 mg/L CaCO3 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801
< 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801
Thallium, Total
< 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801
Zinc, Total
< 0.001 mg/L QC13121801
Selenium, Total
Silver, Total
Solids, Suspended Total
< 10 mg/L
Solids, Total Dissolved
< 20 mg/L
QC13112601 QC13112603
Page 3 of 6
Standard Parameter
Actual Conc.
Standard Conc.
mg/L
mg/L
%REC
QC BATCH
Nitrogen, Ammonia Total
0.497
Nitrogen, Ammonia Total
0.507
0.5
99
QC13120301
ICV
0.5
101
QC13120301
CCV
Nitrogen, Nitrate Total Nitrogen, Nitrate Total
N/A N/A
1 20
0 0
QC13120304 QC13120304
LFB ICV
QC TYPE
Nitrogen, Nitrate Total
N/A
1
0
QC13120304
CCV
Nitrogen, Nitrate-Nitrite Total Nitrogen, Nitrate-Nitrite Total
1.944 1.884
2 2
97 94
QC13120304 QC13120304
LFB ICV
Nitrogen, Nitrate-Nitrite Total
1.957
2
98
Nitrogen, Nitrite Total Nitrogen, Nitrite Total
N/A N/A
1 1
0 0
QC13120304 QC13120304
CCV LFB
QC13120304
ICV
Nitrogen, Nitrite Total Biochemical Oxygen Demand
N/A 219
1 198
0 111
QC13120304 QC13112701
CCV LCS
Hardness, Total
100.48
100
100
QC13112502
LCS
Antimony, Total Antimony, Total
0.05521 0.01004
0.05 0.01
110 100
QC13121801 QC13121801
LFB ICV
Antimony, Total
0.04857
0.05
97
Arsenic, Total Arsenic, Total
0.05534 0.00975
0.05 0.01
111 98
QC13121801 QC13121801
CCV LFB
QC13121801
ICV
Arsenic, Total Barium, Total
0.04779 0.05372
0.05 0.05
96 107
QC13121801 QC13121801
CCV LFB
Barium, Total
0.01001
0.01
100
QC13121801
ICV
Barium, Total Beryllium, Total
0.04993 0.05854
0.05 0.05
100 117
QC13121801 QC13121801
CCV LFB
Beryllium, Total
0.00990
0.01
99
QC13121801
ICV
Beryllium, Total Cadmium, Total
0.05568 0.05319
0.05 0.05
111 106
QC13121801
CCV
QC13121801
LFB
Cadmium, Total Cadmium, Total
0.00986 0.05039
0.01 0.05
99 101
QC13121801 QC13121801
ICV CCV
Chromium, Total
0.05684
0.05
114
QC13121801
LFB
Chromium, Total Chromium, Total
0.01011 0.05277
0.01 0.05
101 106
QC13121801 QC13121801
CCV
Copper, Total
0.05557
0.05
111
QC13121801
LFB
Copper, Total Copper, Total
0.00922 0.04773
0.01 0.05
92 95
QC13121801
ICV
QC13121801
CCV
Lead, Total Lead, Total
0.05374 0.00965
0.05 0.01
107 97
QC13121801
LFB
QC13121801
ICV
Lead, Total
0.05051
0.05
101
QC13121801
CCV
Nickel, Total Nickel, Total
0.05630 0.00966
0.05 0.01
113 97
QC13121801
LFB
QC13121801
ICV
Nickel, Total
0.05072
0.05
101
QC13121801
CCV
Selenium, Total Selenium, Total
0.05761 0.00973
0.05 0.01
115 97
QC13121801
LFB
QC13121801
ICV
Selenium, Total Silver, Total
0.04992 0.05213
0.05 0.05
100 104
QC13121801
CCV
QC13121801
LFB
Silver, Total
0.00963
0.01
96
QC13121801
ICV
Silver, Total Thallium, Total
0.05421 0.05287
0.05 0.05
108 106
QC13121801
CCV
QC13121801
LFB
90
QC13121801
ICV CCV
QC13121801
LFB
Thallium, Total
0.00900
0.01
ICV
Thallium, Total Zinc, Total
0.05134 0.05748
0.05 0.05
103 115
QC13121801
Zinc, Total
0.00913
0.01
91
QC13121801
ICV
Zinc, Total
0.04921
0.05
98
QC13121801
CCV
Solids, Suspended Total
194
200
97
QC13112601
LCS
Solids, Total Dissolved
508
495
103
QC13112603
LCS
Page 4 of 6
Actual Conc.
Duplicate Conc.
mg/L
mg/L
Biochemical Oxygen Demand
183 mg/L
Solids, Suspended Total
610 mg/L
Duplicate Parameter
Solids, Total Dissolved SPIKE RESULTS Parameter
%RPD
Sample Number
QC BATCH
179
2.21
13110271
QC13112701
590
3.33
13110269
QC13112601
926 mg/L 932 Sample Conc. Spike True Value
0.65 Final Result
13110240 %REC %RPD
mg/L
QC13112603 Sample Number QC BATCH
mg/L
mg/L
Antimony, Total
0.004 mg/L
0.05
0.05615
104
13110010
QC13121801
MS
Arsenic, Total
0.001 mg/L
0.05
0.06682
131
13110010
MS
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
0.09089 0.05140
107 103
13110010 13110010
QC13121801 QC13121801
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L
0.05 0.05
0.05444 0.05618
109 105
0.063 mg/L
0.05
0.11215
279 mg/L CaCO3 50 0.004 mg/L 0.05
332 0.05941
Copper, Total
Hardness, Total Lead, Total
QC13121801
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
99
13110010
QC13121801
MS
106 111
13110240 13110010
QC13112502 QC13121801
MS MS
QC13121801 QC13120301
MS
Nickel, Total
0.006 mg/L
0.05
0.05814
105
13110010
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.571 6.799
104 97
13110208 13110371
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07340 0.06164
147 123
Thallium, Total
< 0.001 mg/L
0.05
0.05720
Zinc, Total Antimony, Total
0.208 mg/L 0.004 mg/L
0.05 0.05
0.25304 0.05431
Arsenic, Total
0.001 mg/L
0.05
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L 0.063 mg/L
Copper, Total
Hardness, Total Lead, Total
QC13120304
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
114
13110010
QC13121801
MS
91 101
3.33
13110010 13110010
QC13121801 QC13121801
MS MSD
0.06427
126
3.89
13110010
QC13121801
MSD
0.08803 0.04824
102 96
3.20
QC13121801
6.34
13110010 13110010
QC13121801
MSD MSD
0.05 0.05
0.05279 0.05547
106 104
3.08 1.27
13110010 13110010
QC13121801 QC13121801
MSD MSD
0.05
0.10852
92
3.29
13110010
QC13121801
MSD
279 mg/L CaCO3 50 0.004 mg/L 0.05
333 0.05717
108 107
0.30 3.84
13110240 13110010
QC13112502 QC13121801
MSD MSD
Nickel, Total
0.006 mg/L
0.05
0.05642
101
3.00
13110010
QC13121801
MSD
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.561 6.787
102 97
1.77
13110208 13110371
QC13120301
MSD MSD
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07010 0.05604
140 112
4.60
13110010 13110010
QC13121801
9.52
QC13121801
MSD MSD
Thallium, Total
< 0.001 mg/L
0.05
0.05513
110
3.69
13110010
QC13121801
MSD
Zinc, Total
0.208 mg/L
0.05
0.24567
76
2.96
13110010
QC13121801
MSD
0.18
QC13120304
QUALIFIERS D2
Sample diluted due to high concentration.
D1
Sample diluted due to matrix interference.
M1
Matrix spike rec. high, control rec. acceptable.
V9
CCV recovery below method limits.
COMMENTS M1 = As/Se MS/MSD spike recoveries high; associated blank spike recovery was acceptable. V9 = Ag CCV recovery was below method limits; target analyte was not detected in samples.
REVIEWED BY: _____________________________________________ Page 5 of 6
Date Signed: 2/6/2014
Page 6 of 6
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101006 Collection Date: 11/21/2013 Collection Time: 10:48:00 PM
Receive Date: 11/22/2013 Customer Sample#:
Collector: D. Cameron Sample Number: 13110006
Project ID: Alma Comp-Full Site: Alma School/ADOT Channel RESULTS
Parameter Nitrogen, Ammonia Total
Method No
MRL
SM4500-NH3D
Qualifier
Result
Analysis Date
Analyst
1.37 mg/L
11/27/2013
PSERIA
0.5
D2
EPA 300.0
0.5
D1
0.807 mg/L
11/26/2013
PSERIA
1,2,4-Trichlorobenzene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
1,2-Diphenylhydrazine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,4,6-Trichlorophenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,4-Dichlorophenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,4-Dimethylphenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,4-Dinitrophenol
EPA625TAL
0.22
< 0.220 mg/L
11/30/2013
TAL
2,4-Dinitrotoluene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,6-Dinitrotoluene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2-Chlorophenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2-Nitrophenol
EPA625TAL
0.067
< 0.067 mg/L
11/30/2013
TAL
3,3-Dichlorobenzidine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
4,6-Dinitro-o-cresol
EPA625TAL
0.22
< 0.220 mg/L
11/30/2013
TAL
4-Nitrophenol
EPA625TAL
0.11
< 0.110 mg/L
11/30/2013
TAL
Acenaphthene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Acenaphthylene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Anthracene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Diethyl phthalate
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Dimethyl phthalate
EPA625TAL
0.089
< 0.089 mg/L
11/30/2013
TAL
Di-n-butylphthalate
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Di-n-octyl phthalate
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Flouranthene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Flourene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Hexachlorobenzene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Hexachlorobutadiene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Hexachlorocyclopentadiene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Hexachloroethane
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Nitrogen, Nitrate-Nitrite Total
Page 1 of 6
Isophorone
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Naphthalene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Nitrobenzene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
n-Nitrosodimethylamine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
n-Nitroso-di-n-propylamine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
n-Nitrosodiphenylamine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
p-Chloro-m-cresol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Pentachlorophenol
EPA625TAL
0.22
< 0.220 mg/L
11/30/2013
TAL
Phenanthrene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Phenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Pyrene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Biochemical Oxygen Demand
SM5210B
2
Chemical Oxygen Demand
SM5220D
Hardness, Total
SM2340C
Antimony, Total
EPA 200.8
0.001
Arsenic, Total
EPA 200.8
0.001
Barium, Total
EPA 200.8
Beryllium, Total
EPA 200.8
Cadmium, Total
EPA 200.8
Chromium, Total
30.4 mg/L
11/22/2013 GSMITH2
20
170 mg/L
11/25/2013
1
51.0 mg/L CaCO3 11/25/2013
NSILIDE
0.005 mg/L
12/12/2013 GSMITH2
0.002 mg/L
12/12/2013 GSMITH2
0.001
0.056 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
EPA 200.8
0.001
0.005 mg/L
12/12/2013 GSMITH2
Copper, Total
EPA 200.8
0.001
0.035 mg/L
12/12/2013 GSMITH2
Lead, Total
EPA 200.8
0.001
0.008 mg/L
12/12/2013 GSMITH2
Nickel, Total
EPA 200.8
0.001
0.008 mg/L
12/12/2013 GSMITH2
Selenium, Total
EPA 200.8
0.001
M1
< 0.001 mg/L
12/12/2013 GSMITH2
Silver, Total
EPA 200.8
0.001
V9
< 0.001 mg/L
12/12/2013 GSMITH2
Thallium, Total
EPA 200.8
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
Zinc, Total
EPA 200.8
0.001
0.159 mg/L
12/12/2013 GSMITH2
< 0.00020 mg/L
11/26/2013
TAL
3.30 mg/L
12/2/2013
TAL
M1
EPA245.1
0.0002
SM4500-Norg
1
4,4'-DDD
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
4,4'-DDE
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
4,4'-DDT
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Aldrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
alpha-BHC
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Aroclor 1016
EPA608TAL
0.0037
< 0.00370 mg/L
12/4/2013
TAL
Aroclor 1221
EPA608TAL
0.0044
< 0.00440 mg/L
12/4/2013
TAL
Aroclor 1232
EPA608TAL
0.0077
< 0.00770 mg/L
12/4/2013
TAL
Aroclor 1242
EPA608TAL
0.01
< 0.0100 mg/L
12/4/2013
TAL
Aroclor 1248
EPA608TAL
0.004
< 0.00400 mg/L
12/4/2013
TAL
Aroclor 1254
EPA608TAL
0.0063
< 0.00630 mg/L
12/4/2013
TAL
Aroclor 1260
EPA608TAL
0.0033
< 0.00330 mg/L
12/4/2013
TAL
beta-BHC
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Chlordane
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
delta-BHC
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Mercury, Total Nitrogen, Kjeldahl Total
Page 2 of 6
Dieldrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan I (Alpha)
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan II (Beta)
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan sulfate
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endrin aldehyde
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Heptachlor
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Heptachlor epoxide
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Lindane
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Toxaphene
EPA608TAL
0.022
< 0.0220 mg/L
12/4/2013
TAL
Orthophosphate
EPA 300.0
0.2
0.29 mg/L
11/22/2013
TAL
Benzo (a) pyrene
EPA 8310
0.000055
0.000100 mg/L
11/27/2013
TAL
Benzo(a)anthracene
EPA 8310
0.00022
< 0.00022 mg/L
11/27/2013
TAL
Benzo(b)fluoranthene
EPA 8310
0.00011
0.00033 mg/L
11/27/2013
TAL
Benzo(g,h,i)perylene
EPA 8310
0.00011
< 0.00011 mg/L
11/27/2013
TAL
Benzo(k)fluoranthene
EPA 8310
0.000055
0.000170 mg/L
11/27/2013
TAL
Chrysene
EPA 8310
0.00018
0.00023 mg/L
11/27/2013
TAL
Dibenz(a,h)anthracene
EPA 8310
0.00011
< 0.00011 mg/L
11/27/2013
TAL
Ideno(1,2,3-cd)pyrene
EPA 8310
0.00011
0.00011 mg/L
11/27/2013
TAL
Phosphorus, Total
SM4500-P
0.1
0.45 mg/L
11/25/2013
TAL
Solids, Suspended Total
SM2540D
10
80.0 mg/L
11/25/2013
NSILIDE
Solids, Total Dissolved
SM2540C
20
158 mg/L
11/25/2013
NSILIDE
Quality Control BLANK Parameter
mg/L
QC BATCH
Nitrogen, Ammonia Total
< 0.5 mg/L
QC13120301
Nitrogen, Nitrate-Nitrite Total
< 0.5 mg/L
QC13120304
Biochemical Oxygen Demand Hardness, Total Antimony, Total Arsenic, Total Barium, Total
Beryllium, Total Cadmium, Total
Chromium, Total Copper, Total Lead, Total Nickel, Total Selenium, Total Silver, Total
Thallium, Total Zinc, Total Solids, Suspended Total Solids, Total Dissolved
< 2 mg/L QC13112701 QC13112502 < 1 mg/L CaCO3 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 10 mg/L QC13112601 < 20 mg/L
QC13112603
Page 3 of 6
Standard Parameter
Actual Conc.
Standard Conc.
mg/L
mg/L
%REC
QC BATCH
Nitrogen, Ammonia Total
0.497
Nitrogen, Ammonia Total
0.507
0.5
99
QC13120301
ICV
0.5
101
QC13120301
CCV
Nitrogen, Nitrate Total Nitrogen, Nitrate Total
N/A N/A
1 20
0 0
QC13120304 QC13120304
LFB ICV
QC TYPE
Nitrogen, Nitrate Total
N/A
1
0
QC13120304
CCV
Nitrogen, Nitrate-Nitrite Total Nitrogen, Nitrate-Nitrite Total
1.944 1.884
2 2
97 94
QC13120304 QC13120304
LFB ICV
Nitrogen, Nitrate-Nitrite Total
1.957
2
98
Nitrogen, Nitrite Total Nitrogen, Nitrite Total
N/A N/A
1 1
0 0
QC13120304 QC13120304
CCV LFB
QC13120304
ICV
Nitrogen, Nitrite Total Biochemical Oxygen Demand
N/A 219
1 198
0 111
QC13120304 QC13112701
CCV LCS
Hardness, Total
100.48
100
100
QC13112502
LCS
Antimony, Total Antimony, Total
0.05521 0.01004
0.05 0.01
110 100
QC13121801 QC13121801
LFB ICV
Antimony, Total
0.04857
0.05
97
Arsenic, Total Arsenic, Total
0.05534 0.00975
0.05 0.01
111 98
QC13121801 QC13121801
CCV LFB
QC13121801
ICV
Arsenic, Total Barium, Total
0.04779 0.05372
0.05 0.05
96 107
QC13121801 QC13121801
CCV LFB
Barium, Total
0.01001
0.01
100
QC13121801
ICV
Barium, Total Beryllium, Total
0.04993 0.05854
0.05 0.05
100 117
QC13121801 QC13121801
CCV LFB
Beryllium, Total
0.00990
0.01
99
QC13121801
ICV
Beryllium, Total Cadmium, Total
0.05568 0.05319
0.05 0.05
111 106
QC13121801
CCV
QC13121801
LFB
Cadmium, Total Cadmium, Total
0.00986 0.05039
0.01 0.05
99 101
QC13121801 QC13121801
ICV CCV
Chromium, Total
0.05684
0.05
114
QC13121801
LFB
Chromium, Total Chromium, Total
0.01011 0.05277
0.01 0.05
101 106
QC13121801 QC13121801
CCV
Copper, Total
0.05557
0.05
111
QC13121801
LFB
Copper, Total Copper, Total
0.00922 0.04773
0.01 0.05
92 95
QC13121801
ICV
QC13121801
CCV
Lead, Total Lead, Total
0.05374 0.00965
0.05 0.01
107 97
QC13121801
LFB
QC13121801
ICV
Lead, Total
0.05051
0.05
101
QC13121801
CCV
Nickel, Total Nickel, Total
0.05630 0.00966
0.05 0.01
113 97
QC13121801
LFB
QC13121801
ICV
Nickel, Total
0.05072
0.05
101
QC13121801
CCV
Selenium, Total Selenium, Total
0.05761 0.00973
0.05 0.01
115 97
QC13121801
LFB
QC13121801
ICV
Selenium, Total Silver, Total
0.04992 0.05213
0.05 0.05
100 104
QC13121801
CCV
QC13121801
LFB
Silver, Total
0.00963
0.01
96
QC13121801
ICV
Silver, Total Thallium, Total
0.05421 0.05287
0.05 0.05
108 106
QC13121801
CCV
QC13121801
LFB
90
QC13121801
ICV CCV
QC13121801
LFB
Thallium, Total
0.00900
0.01
ICV
Thallium, Total Zinc, Total
0.05134 0.05748
0.05 0.05
103 115
QC13121801
Zinc, Total
0.00913
0.01
91
QC13121801
ICV
Zinc, Total
0.04921
0.05
98
QC13121801
CCV
Solids, Suspended Total
194
200
97
QC13112601
LCS
Solids, Total Dissolved
508
495
103
QC13112603
LCS
Page 4 of 6
Actual Conc.
Duplicate Conc.
mg/L
mg/L
Biochemical Oxygen Demand
183 mg/L
Solids, Suspended Total
610 mg/L
Duplicate Parameter
Solids, Total Dissolved SPIKE RESULTS Parameter
%RPD
Sample Number
QC BATCH
179
2.21
13110271
QC13112701
590
3.33
13110269
QC13112601
926 mg/L 932 Sample Conc. Spike True Value
0.65 Final Result
13110240 %REC %RPD
mg/L
QC13112603 Sample Number QC BATCH
mg/L
mg/L
Antimony, Total
0.004 mg/L
0.05
0.05615
104
13110010
QC13121801
MS
Arsenic, Total
0.001 mg/L
0.05
0.06682
131
13110010
MS
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
0.09089 0.05140
107 103
13110010 13110010
QC13121801 QC13121801
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L
0.05 0.05
0.05444 0.05618
109 105
0.063 mg/L
0.05
0.11215
279 mg/L CaCO3 50 0.004 mg/L 0.05
332 0.05941
Copper, Total
Hardness, Total Lead, Total
QC13121801
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
99
13110010
QC13121801
MS
106 111
13110240 13110010
QC13112502 QC13121801
MS MS
QC13121801 QC13120301
MS
Nickel, Total
0.006 mg/L
0.05
0.05814
105
13110010
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.571 6.799
104 97
13110208 13110371
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07340 0.06164
147 123
Thallium, Total
< 0.001 mg/L
0.05
0.05720
Zinc, Total Antimony, Total
0.208 mg/L 0.004 mg/L
0.05 0.05
0.25304 0.05431
Arsenic, Total
0.001 mg/L
0.05
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L 0.063 mg/L
Copper, Total
Hardness, Total Lead, Total
QC13120304
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
114
13110010
QC13121801
MS
91 101
3.33
13110010 13110010
QC13121801 QC13121801
MS MSD
0.06427
126
3.89
13110010
QC13121801
MSD
0.08803 0.04824
102 96
3.20
QC13121801
6.34
13110010 13110010
QC13121801
MSD MSD
0.05 0.05
0.05279 0.05547
106 104
3.08 1.27
13110010 13110010
QC13121801 QC13121801
MSD MSD
0.05
0.10852
92
3.29
13110010
QC13121801
MSD
279 mg/L CaCO3 50 0.004 mg/L 0.05
333 0.05717
108 107
0.30 3.84
13110240 13110010
QC13112502 QC13121801
MSD MSD
Nickel, Total
0.006 mg/L
0.05
0.05642
101
3.00
13110010
QC13121801
MSD
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.561 6.787
102 97
1.77
13110208 13110371
QC13120301
MSD MSD
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07010 0.05604
140 112
4.60
13110010 13110010
QC13121801
9.52
QC13121801
MSD MSD
Thallium, Total
< 0.001 mg/L
0.05
0.05513
110
3.69
13110010
QC13121801
MSD
Zinc, Total
0.208 mg/L
0.05
0.24567
76
2.96
13110010
QC13121801
MSD
0.18
QC13120304
QUALIFIERS D2
Sample diluted due to high concentration.
D1
Sample diluted due to matrix interference.
M1
Matrix spike rec. high, control rec. acceptable.
V9
CCV recovery below method limits.
COMMENTS M1 = As/Se MS/MSD spike recoveries high; associated blank spike recovery was acceptable. V9 = Ag CCV recovery was below method limits; target analyte was not detected in samples.
REVIEWED BY: _____________________________________________ Page 5 of 6
Date Signed: 2/5/2014
Page 6 of 6
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101007 Collection Date: 11/21/2013 Collection Time: 10:48:00 PM
Receive Date: 11/22/2013 Customer Sample#:
Collector: AC Sample Number: 13110007
Project ID: Alma Discrete-Full Site: Alma School/ADOT Channel RESULTS
Parameter
Method No
MRL
Qualifier
Result
Analysis Date
Analyst
2-Chloroethyl vinyl ether
EPA624TAL
0.001
< 0.00100 mg/L
11/23/2013
TAL
Acrolein
EPA624TAL
0.03
< 0.030 mg/L
11/23/2013
TAL
Acrylonitrile
EPA624TAL
0.001
< 0.001 mg/L
11/23/2013
TAL
SM4500-CN E
0.02
< 0.020 mg/L
11/29/2013
TAL
SM9223B
2.2
14600.0 mpn/100ml
11/22/2013
mrexing
Cyanide, Total
E. Coli, MPN Oil and Grease
EPA 1664A
5
9.4 mg/L
12/10/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
11
< 11.0 mg/L
11/29/2013
TAL
pH-Field
SM4500H B
1
7.65 S.U.
11/21/2013 DCAMERO
SM2550B
1
19.0 째C
11/21/2013 DCAMERO
1,1,1-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
1,1,2,2-Tetrachloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
1,1,2-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
1,1-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
1,1-Dichloroethylene
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
1,2,4-Trimethylbenzene
EPA624_LL
0.002
< 0.0020 mg/L
12/2/2013
TAL
1,2-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
12/2/2013
TAL
1,2-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
1,2-Dichloropropane
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
1,3-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
12/2/2013
TAL
1,3-Dichloropropene, Total
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
1,4-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
12/2/2013
TAL
Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Bromodichloromethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Bromoform
EPA624_LL
0.001
< 0.0010 mg/L
12/2/2013
TAL
Carbon Tetrachloride
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Chlorobenzene
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Chlorodibromomethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Chloroethane
EPA624_LL
0.001
< 0.0010 mg/L
12/2/2013
TAL
Temperature-Field
Page 1 of 3
Chloroform
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Ethyl Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Methyl Bromide
EPA624_LL
0.001
< 0.0010 mg/L
12/2/2013
TAL
Methyl Chloride
EPA624_LL
0.001
< 0.0010 mg/L
12/2/2013
TAL
Methylene chloride
EPA624_LL
0.005
< 0.0050 mg/L
12/2/2013
TAL
Tetrachloroethylene (PCE)
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Toluene
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
trans-1,2-Dichloroethene
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Trichloroethylene (TCE)
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Vinyl Chloride
EPA624_LL
0.0005
< 0.0005 mg/L
12/2/2013
TAL
Xylene, Total
EPA624_LL
0.0015
< 0.0015 mg/L
12/2/2013
TAL
Quality Control mg/L
BLANK Parameter Oil and Grease Standard Parameter Oil and Grease SPIKE RESULTS Parameter Oil and Grease
QC BATCH
< 5 mg/L QC13121203 Actual Conc. Standard Conc. %REC mg/L 37.4 Sample Conc.
40 Spike True Value
94 Final Result
mg/L
mg/L
mg/L
40
36.6
< 5 mg/L
QC BATCH
QC TYPE
mg/L QC13121203 %RPD
LCS
%REC
Sample Number
QC BATCH
89
13110240
QC13121203
QUALIFIERS
COMMENTS
REVIEWED BY: _____________________________________________
Page 2 of 3
Date Signed: 12/30/2013
MS
Page 3 of 3
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101008 Collection Date: 11/22/2013 Collection Time: 5:14:00 AM
Receive Date: 11/22/2013 Customer Sample#:
Collector: D. Cameron Sample Number: 13110008
Project ID: FF Comp-Full Site: Falcon Field RESULTS
Parameter Nitrogen, Ammonia Total
Method No
MRL
SM4500-NH3D
0.1
Qualifier
Result
Analysis Date
Analyst
0.29 mg/L
11/27/2013
PSERIA
EPA 300.0
0.5
< 0.500 mg/L
11/26/2013
PSERIA
1,2,4-Trichlorobenzene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
1,2-Diphenylhydrazine
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
2,4,6-Trichlorophenol
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
2,4-Dichlorophenol
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
2,4-Dimethylphenol
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
2,4-Dinitrophenol
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
2,4-Dinitrotoluene
EPA625TAL
0.12
< 0.120 mg/L
11/29/2013
TAL
2,6-Dinitrotoluene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
2-Chlorophenol
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
2-Nitrophenol
EPA625TAL
0.035
< 0.035 mg/L
11/29/2013
TAL
3,3-Dichlorobenzidine
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
4,6-Dinitro-o-cresol
EPA625TAL
0.12
< 0.120 mg/L
11/29/2013
TAL
4-Nitrophenol
EPA625TAL
0.059
< 0.059 mg/L
11/29/2013
TAL
Acenaphthene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Acenaphthylene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Anthracene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Diethyl phthalate
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Dimethyl phthalate
EPA625TAL
0.047
< 0.047 mg/L
11/29/2013
TAL
Di-n-butylphthalate
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Di-n-octyl phthalate
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Flouranthene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Flourene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Hexachlorobenzene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Hexachlorobutadiene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Hexachlorocyclopentadiene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Hexachloroethane
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Nitrogen, Nitrate-Nitrite Total
Page 1 of 6
D1
Isophorone
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Naphthalene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Nitrobenzene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
n-Nitrosodimethylamine
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
n-Nitroso-di-n-propylamine
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
n-Nitrosodiphenylamine
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
p-Chloro-m-cresol
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Pentachlorophenol
EPA625TAL
0.12
< 0.120 mg/L
11/29/2013
TAL
Phenanthrene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Phenol
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Pyrene
EPA625TAL
0.024
< 0.024 mg/L
11/29/2013
TAL
Biochemical Oxygen Demand
SM5210B
2
Chemical Oxygen Demand
SM5220D
20
Hardness, Total
SM2340C
1
Antimony, Total
EPA 200.8
0.001
Arsenic, Total
EPA 200.8
0.001
Barium, Total
EPA 200.8
Beryllium, Total
EPA 200.8
Cadmium, Total
EPA 200.8
Chromium, Total
2.10 mg/L 38 mg/L
11/22/2013 GSMITH2 11/25/2013
21.0 mg/L CaCO3 11/25/2013
TAL NSILIDE
< 0.001 mg/L
12/12/2013 GSMITH2
0.001 mg/L
12/12/2013 GSMITH2
0.001
0.047 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
EPA 200.8
0.001
0.004 mg/L
12/12/2013 GSMITH2
Copper, Total
EPA 200.8
0.001
0.008 mg/L
12/12/2013 GSMITH2
Lead, Total
EPA 200.8
0.001
0.008 mg/L
12/12/2013 GSMITH2
Nickel, Total
EPA 200.8
0.001
0.005 mg/L
12/12/2013 GSMITH2
Selenium, Total
EPA 200.8
0.001
M1
< 0.001 mg/L
12/12/2013 GSMITH2
Silver, Total
EPA 200.8
0.001
V9
< 0.001 mg/L
12/12/2013 GSMITH2
Thallium, Total
EPA 200.8
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
Zinc, Total
EPA 200.8
0.001
0.060 mg/L
12/12/2013 GSMITH2
< 0.00020 mg/L
11/26/2013
TAL
1.10 mg/L
12/2/2013
TAL
M1
EPA245.1
0.0002
SM4500-Norg
0.16
4,4'-DDD
EPA608TAL
0.00027
< 0.000270 mg/L
12/4/2013
TAL
4,4'-DDE
EPA608TAL
0.00014
0.000330 mg/L
12/4/2013
TAL
4,4'-DDT
EPA608TAL
0.00014
< 0.000140 mg/L
12/4/2013
TAL
Aldrin
EPA608TAL
0.00015
< 0.000150 mg/L
12/4/2013
TAL
alpha-BHC
EPA608TAL
0.00025
< 0.000250 mg/L
12/4/2013
TAL
Aroclor 1016
EPA608TAL
0.0037
< 0.00370 mg/L
12/4/2013
TAL
Aroclor 1221
EPA608TAL
0.0044
< 0.00440 mg/L
12/4/2013
TAL
Aroclor 1232
EPA608TAL
0.0075
< 0.00750 mg/L
12/4/2013
TAL
Aroclor 1242
EPA608TAL
0.0099
< 0.00990 mg/L
12/4/2013
TAL
Aroclor 1248
EPA608TAL
0.0039
< 0.00390 mg/L
12/4/2013
TAL
Aroclor 1254
EPA608TAL
0.0061
< 0.00610 mg/L
12/4/2013
TAL
Aroclor 1260
EPA608TAL
0.0032
< 0.00320 mg/L
12/4/2013
TAL
beta-BHC
EPA608TAL
0.00016
< 0.000160 mg/L
12/4/2013
TAL
Chlordane
EPA608TAL
0.0018
< 0.00180 mg/L
12/4/2013
TAL
delta-BHC
EPA608TAL
0.0002
< 0.000200 mg/L
12/4/2013
TAL
Mercury, Total Nitrogen, Kjeldahl Total
Page 2 of 6
Dieldrin
EPA608TAL
0.00014
< 0.000140 mg/L
12/4/2013
TAL
Endosulfan I (Alpha)
EPA608TAL
0.00018
< 0.000180 mg/L
12/4/2013
TAL
Endosulfan II (Beta)
EPA608TAL
0.00014
< 0.000140 mg/L
12/4/2013
TAL
Endosulfan sulfate
EPA608TAL
0.00014
< 0.000140 mg/L
12/4/2013
TAL
Endrin
EPA608TAL
0.00016
< 0.000160 mg/L
12/4/2013
TAL
Endrin aldehyde
EPA608TAL
0.0002
< 0.000200 mg/L
12/4/2013
TAL
Heptachlor
EPA608TAL
0.00031
< 0.000310 mg/L
12/4/2013
TAL
Heptachlor epoxide
EPA608TAL
0.00015
< 0.000150 mg/L
12/4/2013
TAL
Lindane
EPA608TAL
0.00014
< 0.000140 mg/L
12/4/2013
TAL
Toxaphene
EPA608TAL
0.00011
< 0.000110 mg/L
12/4/2013
TAL
Orthophosphate
EPA 300.0
0.2
< 0.20 mg/L
11/22/2013
TAL
Benzo (a) pyrene
EPA 8310
0.000053
< 0.000053 mg/L
11/26/2013
TAL
Benzo(a)anthracene
EPA 8310
0.00021
< 0.00021 mg/L
11/26/2013
TAL
Benzo(b)fluoranthene
EPA 8310
0.00011
< 0.00011 mg/L
11/26/2013
TAL
Benzo(g,h,i)perylene
EPA 8310
0.00011
< 0.00011 mg/L
11/26/2013
TAL
Benzo(k)fluoranthene
EPA 8310
0.000053
< 0.000053 mg/L
11/26/2013
TAL
Chrysene
EPA 8310
0.00011
< 0.00011 mg/L
11/26/2013
TAL
Dibenz(a,h)anthracene
EPA 8310
0.00011
< 0.00011 mg/L
11/26/2013
TAL
Ideno(1,2,3-cd)pyrene
EPA 8310
0.00011
< 0.00011 mg/L
11/26/2013
TAL
Phosphorus, Total
SM4500-P
0.1
0.24 mg/L
11/25/2013
TAL
Solids, Suspended Total
SM2540D
10
140 mg/L
11/25/2013
NSILIDE
Solids, Total Dissolved
SM2540C
20
49.0 mg/L
11/25/2013
NSILIDE
Quality Control BLANK Parameter
mg/L
QC BATCH
Nitrogen, Ammonia Total
< 0.1 mg/L
QC13120301
Nitrogen, Nitrate-Nitrite Total
< 0.5 mg/L
QC13120304
Biochemical Oxygen Demand Hardness, Total Antimony, Total Arsenic, Total Barium, Total
Beryllium, Total Cadmium, Total
Chromium, Total Copper, Total Lead, Total Nickel, Total Selenium, Total Silver, Total
Thallium, Total Zinc, Total Solids, Suspended Total Solids, Total Dissolved
< 2 mg/L QC13112701 QC13112502 < 1 mg/L CaCO3 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 10 mg/L QC13112601 < 20 mg/L
QC13112603
Page 3 of 6
Standard Parameter
Actual Conc.
Standard Conc.
mg/L
mg/L
%REC
QC BATCH
Nitrogen, Ammonia Total
0.497
Nitrogen, Ammonia Total
0.507
0.5
99
QC13120301
ICV
0.5
101
QC13120301
CCV
Nitrogen, Nitrate Total Nitrogen, Nitrate Total
N/A N/A
1 20
0 0
QC13120304 QC13120304
LFB ICV
QC TYPE
Nitrogen, Nitrate Total
N/A
1
0
QC13120304
CCV
Nitrogen, Nitrate-Nitrite Total Nitrogen, Nitrate-Nitrite Total
1.944 1.884
2 2
97 94
QC13120304 QC13120304
LFB ICV
Nitrogen, Nitrate-Nitrite Total
1.957
2
98
Nitrogen, Nitrite Total Nitrogen, Nitrite Total
N/A N/A
1 1
0 0
QC13120304 QC13120304
CCV LFB
QC13120304
ICV
Nitrogen, Nitrite Total Biochemical Oxygen Demand
N/A 219
1 198
0 111
QC13120304 QC13112701
CCV LCS
Hardness, Total
100.48
100
100
QC13112502
LCS
Antimony, Total Antimony, Total
0.05521 0.01004
0.05 0.01
110 100
QC13121801 QC13121801
LFB ICV
Antimony, Total
0.04857
0.05
97
Arsenic, Total Arsenic, Total
0.05534 0.00975
0.05 0.01
111 98
QC13121801 QC13121801
CCV LFB
QC13121801
ICV
Arsenic, Total Barium, Total
0.04779 0.05372
0.05 0.05
96 107
QC13121801 QC13121801
CCV LFB
Barium, Total
0.01001
0.01
100
QC13121801
ICV
Barium, Total Beryllium, Total
0.04993 0.05854
0.05 0.05
100 117
QC13121801 QC13121801
CCV LFB
Beryllium, Total
0.00990
0.01
99
QC13121801
ICV
Beryllium, Total Cadmium, Total
0.05568 0.05319
0.05 0.05
111 106
QC13121801
CCV
QC13121801
LFB
Cadmium, Total Cadmium, Total
0.00986 0.05039
0.01 0.05
99 101
QC13121801 QC13121801
ICV CCV
Chromium, Total
0.05684
0.05
114
QC13121801
LFB
Chromium, Total Chromium, Total
0.01011 0.05277
0.01 0.05
101 106
QC13121801 QC13121801
CCV
Copper, Total
0.05557
0.05
111
QC13121801
LFB
Copper, Total Copper, Total
0.00922 0.04773
0.01 0.05
92 95
QC13121801
ICV
QC13121801
CCV
Lead, Total Lead, Total
0.05374 0.00965
0.05 0.01
107 97
QC13121801
LFB
QC13121801
ICV
Lead, Total
0.05051
0.05
101
QC13121801
CCV
Nickel, Total Nickel, Total
0.05630 0.00966
0.05 0.01
113 97
QC13121801
LFB
QC13121801
ICV
Nickel, Total
0.05072
0.05
101
QC13121801
CCV
Selenium, Total Selenium, Total
0.05761 0.00973
0.05 0.01
115 97
QC13121801
LFB
QC13121801
ICV
Selenium, Total Silver, Total
0.04992 0.05213
0.05 0.05
100 104
QC13121801
CCV
QC13121801
LFB
Silver, Total
0.00963
0.01
96
QC13121801
ICV
Silver, Total Thallium, Total
0.05421 0.05287
0.05 0.05
108 106
QC13121801
CCV
QC13121801
LFB
90
QC13121801
ICV CCV
QC13121801
LFB
Thallium, Total
0.00900
0.01
ICV
Thallium, Total Zinc, Total
0.05134 0.05748
0.05 0.05
103 115
QC13121801
Zinc, Total
0.00913
0.01
91
QC13121801
ICV
Zinc, Total
0.04921
0.05
98
QC13121801
CCV
Solids, Suspended Total
194
200
97
QC13112601
LCS
Solids, Total Dissolved
508
495
103
QC13112603
LCS
Page 4 of 6
Actual Conc.
Duplicate Conc.
mg/L
mg/L
Biochemical Oxygen Demand
183 mg/L
Solids, Suspended Total
610 mg/L
Duplicate Parameter
Solids, Total Dissolved SPIKE RESULTS Parameter
%RPD
Sample Number
QC BATCH
179
2.21
13110271
QC13112701
590
3.33
13110269
QC13112601
926 mg/L 932 Sample Conc. Spike True Value
0.65 Final Result
13110240 %REC %RPD
mg/L
QC13112603 Sample Number QC BATCH
mg/L
mg/L
Antimony, Total
0.004 mg/L
0.05
0.05615
104
13110010
QC13121801
MS
Arsenic, Total
0.001 mg/L
0.05
0.06682
131
13110010
MS
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
0.09089 0.05140
107 103
13110010 13110010
QC13121801 QC13121801
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L
0.05 0.05
0.05444 0.05618
109 105
0.063 mg/L
0.05
0.11215
279 mg/L CaCO3 50 0.004 mg/L 0.05
332 0.05941
Copper, Total
Hardness, Total Lead, Total
QC13121801
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
99
13110010
QC13121801
MS
106 111
13110240 13110010
QC13112502 QC13121801
MS MS
QC13121801 QC13120301
MS
Nickel, Total
0.006 mg/L
0.05
0.05814
105
13110010
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.571 6.799
104 97
13110208 13110371
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07340 0.06164
147 123
Thallium, Total
< 0.001 mg/L
0.05
0.05720
Zinc, Total Antimony, Total
0.208 mg/L 0.004 mg/L
0.05 0.05
0.25304 0.05431
Arsenic, Total
0.001 mg/L
0.05
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L 0.063 mg/L
Copper, Total
Hardness, Total Lead, Total
QC13120304
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
114
13110010
QC13121801
MS
91 101
3.33
13110010 13110010
QC13121801 QC13121801
MS MSD
0.06427
126
3.89
13110010
QC13121801
MSD
0.08803 0.04824
102 96
3.20
QC13121801
6.34
13110010 13110010
QC13121801
MSD MSD
0.05 0.05
0.05279 0.05547
106 104
3.08 1.27
13110010 13110010
QC13121801 QC13121801
MSD MSD
0.05
0.10852
92
3.29
13110010
QC13121801
MSD
279 mg/L CaCO3 50 0.004 mg/L 0.05
333 0.05717
108 107
0.30 3.84
13110240 13110010
QC13112502 QC13121801
MSD MSD
Nickel, Total
0.006 mg/L
0.05
0.05642
101
3.00
13110010
QC13121801
MSD
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.561 6.787
102 97
1.77
13110208 13110371
QC13120301
MSD MSD
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07010 0.05604
140 112
4.60
13110010 13110010
QC13121801
9.52
QC13121801
MSD MSD
Thallium, Total
< 0.001 mg/L
0.05
0.05513
110
3.69
13110010
QC13121801
MSD
Zinc, Total
0.208 mg/L
0.05
0.24567
76
2.96
13110010
QC13121801
MSD
0.18
QC13120304
QUALIFIERS D1
Sample diluted due to matrix interference.
V9
CCV recovery below method limits.
M1
Matrix spike rec. high, control rec. acceptable.
COMMENTS
REVIEWED BY: _____________________________________________ Page 5 of 6
Date Signed: 2/5/2014
Page 6 of 6
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101009 Collection Date: 11/22/2013 Collection Time: 1:20:00 AM
Receive Date: 11/22/2013 Customer Sample#:
Collector: AC Sample Number: 13110009
Project ID: FF Discrete-Full Site: Falcon Field RESULTS
Parameter
Method No
MRL
Qualifier
Result
Analysis Date
Analyst
2-Chloroethyl vinyl ether
EPA624TAL
0.005
< 0.00500 mg/L
11/23/2013
TAL
Acrolein
EPA624TAL
0.05
< 0.050 mg/L
11/23/2013
TAL
Acrylonitrile
EPA624TAL
0.01
< 0.010 mg/L
11/23/2013
TAL
SM4500-CN E
0.02
< 0.020 mg/L
11/29/2013
TAL
SM9223B
2.2
11/22/2013
mrexing
Cyanide, Total
E. Coli, MPN
178.0 mpn/100ml
Oil and Grease
EPA 1664A
5
< 5.0 mg/L
12/9/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
11
< 11.0 mg/L
11/23/2013
TAL
pH-Field
SM4500H B
1
7.43 S.U.
11/22/2013 DCAMERO
SM2550B
1
17.0 째C
11/22/2013 DCAMERO
1,1,1-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1,2,2-Tetrachloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1,2-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1-Dichloroethylene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,2,4-Trimethylbenzene
EPA624_LL
0.002
< 0.0020 mg/L
11/27/2013
TAL
1,2-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
1,2-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,2-Dichloropropane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,3-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
1,3-Dichloropropene, Total
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,4-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Bromodichloromethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Bromoform
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Carbon Tetrachloride
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chlorobenzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chlorodibromomethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chloroethane
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Temperature-Field
Page 1 of 3
Chloroform
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Ethyl Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Methyl Bromide
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Methyl Chloride
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Methylene chloride
EPA624_LL
0.005
< 0.0050 mg/L
11/27/2013
TAL
Tetrachloroethylene (PCE)
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Toluene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
trans-1,2-Dichloroethene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Trichloroethylene (TCE)
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Vinyl Chloride
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Xylene, Total
EPA624_LL
0.0015
< 0.0015 mg/L
11/27/2013
TAL
Quality Control mg/L
BLANK Parameter Oil and Grease Standard Parameter Oil and Grease
QC BATCH
< 5 mg/L QC13121202 Actual Conc. Standard Conc. %REC mg/L
mg/L
36.7
40
92
QC BATCH
QC TYPE
QC13121202
LCS
QUALIFIERS
COMMENTS
REVIEWED BY: _____________________________________________
Page 2 of 3
Date Signed: 12/30/2013
Page 3 of 3
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101010 Collection Date: 11/22/2013 Collection Time: 12:05:00 AM
Receive Date: 11/22/2013 Customer Sample#:
Collector: AC Sample Number: 13110010
Project ID: SS Comp-Full Site: Superstition Springs/US 60 RESULTS
Parameter Nitrogen, Ammonia Total
Method No
MRL
SM4500-NH3D
Qualifier
Result
Analysis Date
Analyst
1.88 mg/L
11/27/2013
PSERIA
0.5
D2
EPA 300.0
0.5
D1
1.06 mg/L
11/26/2013
PSERIA
1,2,4-Trichlorobenzene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
1,2-Diphenylhydrazine
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
2,4,6-Trichlorophenol
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
2,4-Dichlorophenol
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
2,4-Dimethylphenol
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
2,4-Dinitrophenol
EPA625TAL
0.11
< 0.110 mg/L
11/29/2013
TAL
2,4-Dinitrotoluene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
2,6-Dinitrotoluene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
2-Chlorophenol
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
2-Nitrophenol
EPA625TAL
0.033
< 0.033 mg/L
11/29/2013
TAL
3,3-Dichlorobenzidine
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
4,6-Dinitro-o-cresol
EPA625TAL
0.11
< 0.110 mg/L
11/29/2013
TAL
4-Nitrophenol
EPA625TAL
0.054
< 0.054 mg/L
11/29/2013
TAL
Acenaphthene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Acenaphthylene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Anthracene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Diethyl phthalate
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Dimethyl phthalate
EPA625TAL
0.043
< 0.043 mg/L
11/29/2013
TAL
Di-n-butylphthalate
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Di-n-octyl phthalate
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Flouranthene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Flourene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Hexachlorobenzene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Hexachlorobutadiene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Hexachlorocyclopentadiene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Hexachloroethane
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Nitrogen, Nitrate-Nitrite Total
Page 1 of 6
Isophorone
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Naphthalene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Nitrobenzene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
n-Nitrosodimethylamine
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
n-Nitroso-di-n-propylamine
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
n-Nitrosodiphenylamine
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
p-Chloro-m-cresol
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Pentachlorophenol
EPA625TAL
0.11
< 0.110 mg/L
11/29/2013
TAL
Phenanthrene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Phenol
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Pyrene
EPA625TAL
0.022
< 0.022 mg/L
11/29/2013
TAL
Biochemical Oxygen Demand
SM5210B
2
Chemical Oxygen Demand
SM5220D
Hardness, Total
SM2340C
Antimony, Total
EPA 200.8
0.001
Arsenic, Total
EPA 200.8
0.001
Barium, Total
EPA 200.8
Beryllium, Total
EPA 200.8
Cadmium, Total
EPA 200.8
Chromium, Total
K2
23.4 mg/L
11/22/2013 GSMITH2
20
220 mg/L
11/25/2013
1
47.0 mg/L CaCO3 11/25/2013
TAL NSILIDE
0.004 mg/L
12/12/2013 GSMITH2
0.001 mg/L
12/12/2013 GSMITH2
0.001
0.037 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
EPA 200.8
0.001
0.003 mg/L
12/12/2013 GSMITH2
Copper, Total
EPA 200.8
0.001
0.063 mg/L
12/12/2013 GSMITH2
Lead, Total
EPA 200.8
0.001
0.004 mg/L
12/12/2013 GSMITH2
Nickel, Total
EPA 200.8
0.001
0.006 mg/L
12/12/2013 GSMITH2
Selenium, Total
EPA 200.8
0.001
M1
< 0.001 mg/L
12/12/2013 GSMITH2
Silver, Total
EPA 200.8
0.001
V9
< 0.001 mg/L
12/12/2013 GSMITH2
Thallium, Total
EPA 200.8
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
Zinc, Total
EPA 200.8
0.001
0.208 mg/L
12/12/2013 GSMITH2
< 0.00020 mg/L
11/26/2013
TAL
4.40 mg/L
12/2/2013
TAL
M1
EPA245.1
0.0002
SM4500-Norg
1
4,4'-DDD
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
4,4'-DDE
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
4,4'-DDT
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Aldrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
alpha-BHC
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Aroclor 1016
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
Aroclor 1221
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
Aroclor 1232
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
Aroclor 1242
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
Aroclor 1248
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
Aroclor 1254
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
Aroclor 1260
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
beta-BHC
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Chlordane
EPA608TAL
0.011
< 0.0110 mg/L
12/4/2013
TAL
delta-BHC
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Mercury, Total Nitrogen, Kjeldahl Total
Page 2 of 6
Dieldrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan I (Alpha)
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan II (Beta)
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endosulfan sulfate
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endrin
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Endrin aldehyde
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Heptachlor
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Heptachlor epoxide
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Lindane
EPA608TAL
0.0011
< 0.00110 mg/L
12/4/2013
TAL
Toxaphene
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
Orthophosphate
EPA 300.0
0.2
0.37 mg/L
11/22/2013
TAL
Benzo (a) pyrene
EPA 8310
0.000055
0.000330 mg/L
11/26/2013
TAL
Benzo(a)anthracene
EPA 8310
0.00022
0.00023 mg/L
11/26/2013
TAL
Benzo(b)fluoranthene
EPA 8310
0.00011
0.00089 mg/L
11/26/2013
TAL
Benzo(g,h,i)perylene
EPA 8310
0.00011
< 0.00011 mg/L
11/26/2013
TAL
Benzo(k)fluoranthene
EPA 8310
0.000055
0.000410 mg/L
11/26/2013
TAL
Chrysene
EPA 8310
0.00011
0.00078 mg/L
11/26/2013
TAL
Dibenz(a,h)anthracene
EPA 8310
0.00011
< 0.00011 mg/L
11/26/2013
TAL
Ideno(1,2,3-cd)pyrene
EPA 8310
0.00011
0.00032 mg/L
11/26/2013
TAL
Phosphorus, Total
SM4500-P
0.1
0.37 mg/L
11/25/2013
TAL
Solids, Suspended Total
SM2540D
10
64.0 mg/L
11/25/2013
NSILIDE
Solids, Total Dissolved
SM2540C
20
169 mg/L
11/25/2013
NSILIDE
Quality Control BLANK Parameter
mg/L
QC BATCH
Nitrogen, Ammonia Total
< 0.5 mg/L
QC13120301
Nitrogen, Nitrate-Nitrite Total
< 0.5 mg/L
QC13120304
Biochemical Oxygen Demand Hardness, Total Antimony, Total Arsenic, Total Barium, Total
Beryllium, Total Cadmium, Total
Chromium, Total Copper, Total Lead, Total Nickel, Total Selenium, Total Silver, Total
Thallium, Total Zinc, Total Solids, Suspended Total Solids, Total Dissolved
< 2 mg/L QC13112701 QC13112502 < 1 mg/L CaCO3 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 10 mg/L QC13112601 < 20 mg/L
QC13112603
Page 3 of 6
Standard Parameter
Actual Conc.
Standard Conc.
mg/L
mg/L
%REC
QC BATCH
Nitrogen, Ammonia Total
0.497
Nitrogen, Ammonia Total
0.507
0.5
99
QC13120301
ICV
0.5
101
QC13120301
CCV
Nitrogen, Nitrate Total Nitrogen, Nitrate Total
N/A N/A
1 20
0 0
QC13120304 QC13120304
LFB ICV
QC TYPE
Nitrogen, Nitrate Total
N/A
1
0
QC13120304
CCV
Nitrogen, Nitrate-Nitrite Total Nitrogen, Nitrate-Nitrite Total
1.944 1.884
2 2
97 94
QC13120304 QC13120304
LFB ICV
Nitrogen, Nitrate-Nitrite Total
1.957
2
98
Nitrogen, Nitrite Total Nitrogen, Nitrite Total
N/A N/A
1 1
0 0
QC13120304 QC13120304
CCV LFB
QC13120304
ICV
Nitrogen, Nitrite Total Biochemical Oxygen Demand
N/A 219
1 198
0 111
QC13120304 QC13112701
CCV LCS
Hardness, Total
100.48
100
100
QC13112502
LCS
Antimony, Total Antimony, Total
0.05521 0.01004
0.05 0.01
110 100
QC13121801 QC13121801
LFB ICV
Antimony, Total
0.04857
0.05
97
Arsenic, Total Arsenic, Total
0.05534 0.00975
0.05 0.01
111 98
QC13121801 QC13121801
CCV LFB
QC13121801
ICV
Arsenic, Total Barium, Total
0.04779 0.05372
0.05 0.05
96 107
QC13121801 QC13121801
CCV LFB
Barium, Total
0.01001
0.01
100
QC13121801
ICV
Barium, Total Beryllium, Total
0.04993 0.05854
0.05 0.05
100 117
QC13121801 QC13121801
CCV LFB
Beryllium, Total
0.00990
0.01
99
QC13121801
ICV
Beryllium, Total Cadmium, Total
0.05568 0.05319
0.05 0.05
111 106
QC13121801
CCV
QC13121801
LFB
Cadmium, Total Cadmium, Total
0.00986 0.05039
0.01 0.05
99 101
QC13121801 QC13121801
ICV CCV
Chromium, Total
0.05684
0.05
114
QC13121801
LFB
Chromium, Total Chromium, Total
0.01011 0.05277
0.01 0.05
101 106
QC13121801 QC13121801
CCV
Copper, Total
0.05557
0.05
111
QC13121801
LFB
Copper, Total Copper, Total
0.00922 0.04773
0.01 0.05
92 95
QC13121801
ICV
QC13121801
CCV
Lead, Total Lead, Total
0.05374 0.00965
0.05 0.01
107 97
QC13121801
LFB
QC13121801
ICV
Lead, Total
0.05051
0.05
101
QC13121801
CCV
Nickel, Total Nickel, Total
0.05630 0.00966
0.05 0.01
113 97
QC13121801
LFB
QC13121801
ICV
Nickel, Total
0.05072
0.05
101
QC13121801
CCV
Selenium, Total Selenium, Total
0.05761 0.00973
0.05 0.01
115 97
QC13121801
LFB
QC13121801
ICV
Selenium, Total Silver, Total
0.04992 0.05213
0.05 0.05
100 104
QC13121801
CCV
QC13121801
LFB
Silver, Total
0.00963
0.01
96
QC13121801
ICV
Silver, Total Thallium, Total
0.05421 0.05287
0.05 0.05
108 106
QC13121801
CCV
QC13121801
LFB
90
QC13121801
ICV CCV
QC13121801
LFB
Thallium, Total
0.00900
0.01
ICV
Thallium, Total Zinc, Total
0.05134 0.05748
0.05 0.05
103 115
QC13121801
Zinc, Total
0.00913
0.01
91
QC13121801
ICV
Zinc, Total
0.04921
0.05
98
QC13121801
CCV
Solids, Suspended Total
194
200
97
QC13112601
LCS
Solids, Total Dissolved
508
495
103
QC13112603
LCS
Page 4 of 6
Actual Conc.
Duplicate Conc.
mg/L
mg/L
Biochemical Oxygen Demand
183 mg/L
Solids, Suspended Total
610 mg/L
Duplicate Parameter
Solids, Total Dissolved SPIKE RESULTS Parameter
%RPD
Sample Number
QC BATCH
179
2.21
13110271
QC13112701
590
3.33
13110269
QC13112601
926 mg/L 932 Sample Conc. Spike True Value
0.65 Final Result
13110240 %REC %RPD
mg/L
QC13112603 Sample Number QC BATCH
mg/L
mg/L
Antimony, Total
0.004 mg/L
0.05
0.05615
104
13110010
QC13121801
MS
Arsenic, Total
0.001 mg/L
0.05
0.06682
131
13110010
MS
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
0.09089 0.05140
107 103
13110010 13110010
QC13121801 QC13121801
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L
0.05 0.05
0.05444 0.05618
109 105
0.063 mg/L
0.05
0.11215
279 mg/L CaCO3 50 0.004 mg/L 0.05
332 0.05941
Copper, Total
Hardness, Total Lead, Total
QC13121801
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
99
13110010
QC13121801
MS
106 111
13110240 13110010
QC13112502 QC13121801
MS MS
QC13121801 QC13120301
MS
Nickel, Total
0.006 mg/L
0.05
0.05814
105
13110010
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.571 6.799
104 97
13110208 13110371
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07340 0.06164
147 123
Thallium, Total
< 0.001 mg/L
0.05
0.05720
Zinc, Total Antimony, Total
0.208 mg/L 0.004 mg/L
0.05 0.05
0.25304 0.05431
Arsenic, Total
0.001 mg/L
0.05
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L 0.063 mg/L
Copper, Total
Hardness, Total Lead, Total
QC13120304
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
114
13110010
QC13121801
MS
91 101
3.33
13110010 13110010
QC13121801 QC13121801
MS MSD
0.06427
126
3.89
13110010
QC13121801
MSD
0.08803 0.04824
102 96
3.20
QC13121801
6.34
13110010 13110010
QC13121801
MSD MSD
0.05 0.05
0.05279 0.05547
106 104
3.08 1.27
13110010 13110010
QC13121801 QC13121801
MSD MSD
0.05
0.10852
92
3.29
13110010
QC13121801
MSD
279 mg/L CaCO3 50 0.004 mg/L 0.05
333 0.05717
108 107
0.30 3.84
13110240 13110010
QC13112502 QC13121801
MSD MSD
Nickel, Total
0.006 mg/L
0.05
0.05642
101
3.00
13110010
QC13121801
MSD
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.561 6.787
102 97
1.77
13110208 13110371
QC13120301
MSD MSD
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07010 0.05604
140 112
4.60
13110010 13110010
QC13121801
9.52
QC13121801
MSD MSD
Thallium, Total
< 0.001 mg/L
0.05
0.05513
110
3.69
13110010
QC13121801
MSD
Zinc, Total
0.208 mg/L
0.05
0.24567
76
2.96
13110010
QC13121801
MSD
0.18
QC13120304
QUALIFIERS K2
Analysis didn't meet residual DO >/= 1 mg/L.
D2
Sample diluted due to high concentration.
D1
Sample diluted due to matrix interference.
M1
Matrix spike rec. high, control rec. acceptable.
V9
CCV recovery below method limits.
COMMENTS Residual D.O. was 0.08 mg/L. Reported result is an estimated value.
Page 5 of 6
REVIEWED BY: _____________________________________________
Page 6 of 6
Date Signed: 2/5/2014
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101011 Collection Date: 11/22/2013 Collection Time: 12:05:00 AM
Receive Date: 11/22/2013 Customer Sample#:
Collector: AC Sample Number: 13110011
Project ID: SS Discrete-Full Site: Superstition Springs/US 60 RESULTS
Parameter
Method No
MRL
Qualifier
Result
Analysis Date
Analyst
2-Chloroethyl vinyl ether
EPA624TAL
0.005
< 0.00500 mg/L
11/23/2013
TAL
Acrolein
EPA624TAL
0.05
< 0.050 mg/L
11/23/2013
TAL
Acrylonitrile
EPA624TAL
0.01
< 0.010 mg/L
11/23/2013
TAL
SM4500-CN E
0.008
< 0.008 mg/L
11/29/2013
TAL
SM9223B
2.2
11/22/2013
mrexing
Cyanide, Total
E. Coli, MPN
218.0 mpn/100ml
Oil and Grease
EPA 1664A
5
< 5.0 mg/L
12/9/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
11
< 11.0 mg/L
11/29/2013
TAL
pH-Field
SM4500H B
1
7.24 S.U.
11/22/2013 DCAMERO
SM2550B
1
21.0 째C
11/22/2013 DCAMERO
Temperature-Field
Quality Control mg/L
BLANK Parameter Oil and Grease Standard Parameter
Oil and Grease
QC BATCH
< 5 mg/L QC13121202 Actual Conc. Standard Conc. %REC mg/L
mg/L
36.7
40
92
QC BATCH
QC TYPE
QC13121202
LCS
QUALIFIERS
COMMENTS Separate order ID needed for 624s due to LIMS error.
Oil&Grease MS recovered at 86.5%. Sample 12070746 spiked. (Stormwater FB) Kc 123013
REVIEWED BY: _____________________________________________
Page 1 of 2
Date Signed: 12/30/2013
Page 2 of 2
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101012 Collection Date: 11/22/2013 Collection Time: 1:05:00 AM
Receive Date: 11/22/2013 Customer Sample#:
Collector: AC Sample Number: 13110012
Project ID: Univ Comp-Full Site: Univ Dr @ EMF RESULTS
Parameter Nitrogen, Ammonia Total
Method No
MRL
SM4500-NH3D
Qualifier
Result
Analysis Date
Analyst
1.57 mg/L
11/27/2013
PSERIA
0.5
D2
EPA 300.0
0.5
D1
1.04 mg/L
11/26/2013
PSERIA
1,2,4-Trichlorobenzene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
1,2-Diphenylhydrazine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,4,6-Trichlorophenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,4-Dichlorophenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,4-Dimethylphenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,4-Dinitrophenol
EPA625TAL
0.22
< 0.220 mg/L
11/30/2013
TAL
2,4-Dinitrotoluene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2,6-Dinitrotoluene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2-Chlorophenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
2-Nitrophenol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
3,3-Dichlorobenzidine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
4,6-Dinitro-o-cresol
EPA625TAL
0.22
< 0.220 mg/L
11/30/2013
TAL
4-Nitrophenol
EPA625TAL
0.1
< 0.100 mg/L
11/30/2013
TAL
Acenaphthene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Acenaphthylene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Anthracene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Diethyl phthalate
EPA625TAL
0.22
< 0.220 mg/L
11/30/2013
TAL
Dimethyl phthalate
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Di-n-butylphthalate
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Di-n-octyl phthalate
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Flouranthene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Flourene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Hexachlorobenzene
EPA625TAL
0.22
< 0.220 mg/L
11/30/2013
TAL
Hexachlorobutadiene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Hexachlorocyclopentadiene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Hexachloroethane
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Nitrogen, Nitrate-Nitrite Total
Page 1 of 6
Isophorone
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Naphthalene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Nitrobenzene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
n-Nitrosodimethylamine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
n-Nitroso-di-n-propylamine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
n-Nitrosodiphenylamine
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
p-Chloro-m-cresol
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Pentachlorophenol
EPA625TAL
0.22
< 0.220 mg/L
11/30/2013
TAL
Phenanthrene
EPA625TAL
0.044
< 0.044 mg/L
11/30/2013
TAL
Phenol
EPA625TAL
0.024
< 0.024 mg/L
11/30/2013
TAL
Pyrene
EPA625TAL
0.024
< 0.024 mg/L
11/30/2013
TAL
Biochemical Oxygen Demand
SM5210B
2
Chemical Oxygen Demand
SM5220D
Hardness, Total
SM2340C
Antimony, Total
EPA 200.8
0.001
Arsenic, Total
EPA 200.8
0.001
Barium, Total
EPA 200.8
Beryllium, Total
EPA 200.8
Cadmium, Total
EPA 200.8
Chromium, Total
22.2 mg/L
11/22/2013 GSMITH2
20
180 mg/L
11/25/2013
1
77.0 mg/L CaCO3 11/25/2013
TAL NSILIDE
0.002 mg/L
12/12/2013 GSMITH2
0.002 mg/L
12/12/2013 GSMITH2
0.001
0.075 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
EPA 200.8
0.001
0.004 mg/L
12/12/2013 GSMITH2
Copper, Total
EPA 200.8
0.001
0.031 mg/L
12/12/2013 GSMITH2
Lead, Total
EPA 200.8
0.001
0.008 mg/L
12/12/2013 GSMITH2
Nickel, Total
EPA 200.8
0.001
0.006 mg/L
12/12/2013 GSMITH2
Selenium, Total
EPA 200.8
0.001
M1
< 0.001 mg/L
12/12/2013 GSMITH2
Silver, Total
EPA 200.8
0.001
V9
< 0.001 mg/L
12/12/2013 GSMITH2
Thallium, Total
EPA 200.8
0.001
< 0.001 mg/L
12/12/2013 GSMITH2
Zinc, Total
EPA 200.8
0.001
0.169 mg/L
12/12/2013 GSMITH2
< 0.00020 mg/L
11/26/2013
TAL
4.70 mg/L
12/2/2013
TAL
M1
EPA245.1
0.0002
SM4500-Norg
1
4,4'-DDD
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
4,4'-DDE
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
4,4'-DDT
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Aldrin
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
alpha-BHC
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Aroclor 1016
EPA608TAL
0.0034
< 0.00340 mg/L
12/4/2013
TAL
Aroclor 1221
EPA608TAL
0.0041
< 0.00410 mg/L
12/4/2013
TAL
Aroclor 1232
EPA608TAL
0.007
< 0.00700 mg/L
12/4/2013
TAL
Aroclor 1242
EPA608TAL
0.0093
< 0.00930 mg/L
12/4/2013
TAL
Aroclor 1248
EPA608TAL
0.0037
< 0.00370 mg/L
12/4/2013
TAL
Aroclor 1254
EPA608TAL
0.0058
< 0.00580 mg/L
12/4/2013
TAL
Aroclor 1260
EPA608TAL
0.003
< 0.00300 mg/L
12/4/2013
TAL
beta-BHC
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Chlordane
EPA608TAL
0.01
< 0.0100 mg/L
12/4/2013
TAL
delta-BHC
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Mercury, Total Nitrogen, Kjeldahl Total
Page 2 of 6
Dieldrin
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Endosulfan I (Alpha)
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Endosulfan II (Beta)
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Endosulfan sulfate
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Endrin
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Endrin aldehyde
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Heptachlor
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Heptachlor epoxide
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Lindane
EPA608TAL
0.001
< 0.00100 mg/L
12/4/2013
TAL
Toxaphene
EPA608TAL
0.021
< 0.0210 mg/L
12/4/2013
TAL
Orthophosphate
EPA 300.0
0.2
< 0.20 mg/L
11/22/2013
TAL
Benzo (a) pyrene
EPA 8310
0.000051
< 0.000051 mg/L
11/27/2013
TAL
Benzo(a)anthracene
EPA 8310
0.0002
< 0.00020 mg/L
11/27/2013
TAL
Benzo(b)fluoranthene
EPA 8310
0.0001
0.00019 mg/L
11/27/2013
TAL
Benzo(g,h,i)perylene
EPA 8310
0.0001
0.00021 mg/L
11/27/2013
TAL
Benzo(k)fluoranthene
EPA 8310
0.000051
0.000093 mg/L
11/27/2013
TAL
Chrysene
EPA 8310
0.0001
0.00012 mg/L
11/27/2013
TAL
Dibenz(a,h)anthracene
EPA 8310
0.0001
< 0.00010 mg/L
11/27/2013
TAL
Ideno(1,2,3-cd)pyrene
EPA 8310
0.0001
< 0.00010 mg/L
11/27/2013
TAL
Phosphorus, Total
SM4500-P
0.1
0.47 mg/L
11/25/2013
TAL
Solids, Suspended Total
SM2540D
10
88.0 mg/L
11/25/2013
NSILIDE
Solids, Total Dissolved
SM2540C
20
220 mg/L
11/25/2013
NSILIDE
Quality Control BLANK Parameter
mg/L
QC BATCH
Nitrogen, Ammonia Total
< 0.5 mg/L
QC13120301
Nitrogen, Nitrate-Nitrite Total
< 0.5 mg/L
QC13120304
Biochemical Oxygen Demand Hardness, Total Antimony, Total Arsenic, Total Barium, Total
Beryllium, Total Cadmium, Total
Chromium, Total Copper, Total Lead, Total Nickel, Total Selenium, Total Silver, Total
Thallium, Total Zinc, Total Solids, Suspended Total Solids, Total Dissolved
< 2 mg/L QC13112701 QC13112502 < 1 mg/L CaCO3 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 0.001 mg/L QC13121801 < 10 mg/L QC13112601 < 20 mg/L
QC13112603
Page 3 of 6
Standard Parameter
Actual Conc.
Standard Conc.
mg/L
mg/L
%REC
QC BATCH
Nitrogen, Ammonia Total
0.497
Nitrogen, Ammonia Total
0.507
0.5
99
QC13120301
ICV
0.5
101
QC13120301
CCV
Nitrogen, Nitrate Total Nitrogen, Nitrate Total
N/A N/A
1 20
0 0
QC13120304 QC13120304
LFB ICV
QC TYPE
Nitrogen, Nitrate Total
N/A
1
0
QC13120304
CCV
Nitrogen, Nitrate-Nitrite Total Nitrogen, Nitrate-Nitrite Total
1.944 1.884
2 2
97 94
QC13120304 QC13120304
LFB ICV
Nitrogen, Nitrate-Nitrite Total
1.957
2
98
Nitrogen, Nitrite Total Nitrogen, Nitrite Total
N/A N/A
1 1
0 0
QC13120304 QC13120304
CCV LFB
QC13120304
ICV
Nitrogen, Nitrite Total Biochemical Oxygen Demand
N/A 219
1 198
0 111
QC13120304 QC13112701
CCV LCS
Hardness, Total
100.48
100
100
QC13112502
LCS
Antimony, Total Antimony, Total
0.05521 0.01004
0.05 0.01
110 100
QC13121801 QC13121801
LFB ICV
Antimony, Total
0.04857
0.05
97
Arsenic, Total Arsenic, Total
0.05534 0.00975
0.05 0.01
111 98
QC13121801 QC13121801
CCV LFB
QC13121801
ICV
Arsenic, Total Barium, Total
0.04779 0.05372
0.05 0.05
96 107
QC13121801 QC13121801
CCV LFB
Barium, Total
0.01001
0.01
100
QC13121801
ICV
Barium, Total Beryllium, Total
0.04993 0.05854
0.05 0.05
100 117
QC13121801 QC13121801
CCV LFB
Beryllium, Total
0.00990
0.01
99
QC13121801
ICV
Beryllium, Total Cadmium, Total
0.05568 0.05319
0.05 0.05
111 106
QC13121801
CCV
QC13121801
LFB
Cadmium, Total Cadmium, Total
0.00986 0.05039
0.01 0.05
99 101
QC13121801 QC13121801
ICV CCV
Chromium, Total
0.05684
0.05
114
QC13121801
LFB
Chromium, Total Chromium, Total
0.01011 0.05277
0.01 0.05
101 106
QC13121801 QC13121801
CCV
Copper, Total
0.05557
0.05
111
QC13121801
LFB
Copper, Total Copper, Total
0.00922 0.04773
0.01 0.05
92 95
QC13121801
ICV
QC13121801
CCV
Lead, Total Lead, Total
0.05374 0.00965
0.05 0.01
107 97
QC13121801
LFB
QC13121801
ICV
Lead, Total
0.05051
0.05
101
QC13121801
CCV
Nickel, Total Nickel, Total
0.05630 0.00966
0.05 0.01
113 97
QC13121801
LFB
QC13121801
ICV
Nickel, Total
0.05072
0.05
101
QC13121801
CCV
Selenium, Total Selenium, Total
0.05761 0.00973
0.05 0.01
115 97
QC13121801
LFB
QC13121801
ICV
Selenium, Total Silver, Total
0.04992 0.05213
0.05 0.05
100 104
QC13121801
CCV
QC13121801
LFB
Silver, Total
0.00963
0.01
96
QC13121801
ICV
Silver, Total Thallium, Total
0.05421 0.05287
0.05 0.05
108 106
QC13121801
CCV
QC13121801
LFB
90
QC13121801
ICV CCV
QC13121801
LFB
Thallium, Total
0.00900
0.01
ICV
Thallium, Total Zinc, Total
0.05134 0.05748
0.05 0.05
103 115
QC13121801
Zinc, Total
0.00913
0.01
91
QC13121801
ICV
Zinc, Total
0.04921
0.05
98
QC13121801
CCV
Solids, Suspended Total
194
200
97
QC13112601
LCS
Solids, Total Dissolved
508
495
103
QC13112603
LCS
Page 4 of 6
Actual Conc.
Duplicate Conc.
mg/L
mg/L
Biochemical Oxygen Demand
183 mg/L
Solids, Suspended Total
610 mg/L
Duplicate Parameter
Solids, Total Dissolved SPIKE RESULTS Parameter
%RPD
Sample Number
QC BATCH
179
2.21
13110271
QC13112701
590
3.33
13110269
QC13112601
926 mg/L 932 Sample Conc. Spike True Value
0.65 Final Result
13110240 %REC %RPD
mg/L
QC13112603 Sample Number QC BATCH
mg/L
mg/L
Antimony, Total
0.004 mg/L
0.05
0.05615
104
13110010
QC13121801
MS
Arsenic, Total
0.001 mg/L
0.05
0.06682
131
13110010
MS
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
0.09089 0.05140
107 103
13110010 13110010
QC13121801 QC13121801
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L
0.05 0.05
0.05444 0.05618
109 105
0.063 mg/L
0.05
0.11215
279 mg/L CaCO3 50 0.004 mg/L 0.05
332 0.05941
Copper, Total
Hardness, Total Lead, Total
QC13121801
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
99
13110010
QC13121801
MS
106 111
13110240 13110010
QC13112502 QC13121801
MS MS
QC13121801 QC13120301
MS
Nickel, Total
0.006 mg/L
0.05
0.05814
105
13110010
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.571 6.799
104 97
13110208 13110371
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07340 0.06164
147 123
Thallium, Total
< 0.001 mg/L
0.05
0.05720
Zinc, Total Antimony, Total
0.208 mg/L 0.004 mg/L
0.05 0.05
0.25304 0.05431
Arsenic, Total
0.001 mg/L
0.05
Barium, Total Beryllium, Total
0.037 mg/L < 0.001 mg/L
0.05 0.05
Cadmium, Total Chromium, Total
< 0.001 mg/L 0.003 mg/L 0.063 mg/L
Copper, Total
Hardness, Total Lead, Total
QC13120304
MS MS
13110010 13110010
QC13121801 QC13121801
MS MS
114
13110010
QC13121801
MS
91 101
3.33
13110010 13110010
QC13121801 QC13121801
MS MSD
0.06427
126
3.89
13110010
QC13121801
MSD
0.08803 0.04824
102 96
3.20
QC13121801
6.34
13110010 13110010
QC13121801
MSD MSD
0.05 0.05
0.05279 0.05547
106 104
3.08 1.27
13110010 13110010
QC13121801 QC13121801
MSD MSD
0.05
0.10852
92
3.29
13110010
QC13121801
MSD
279 mg/L CaCO3 50 0.004 mg/L 0.05
333 0.05717
108 107
0.30 3.84
13110240 13110010
QC13112502 QC13121801
MSD MSD
Nickel, Total
0.006 mg/L
0.05
0.05642
101
3.00
13110010
QC13121801
MSD
Nitrogen, Ammonia Total Nitrogen, Nitrate-Nitrite Total
< 0.1 mg/L 4.85 mg/L
0.5 2
0.561 6.787
102 97
1.77
13110208 13110371
QC13120301
MSD MSD
Selenium, Total Silver, Total
< 0.001 mg/L < 0.001 mg/L
0.05 0.05
0.07010 0.05604
140 112
4.60
13110010 13110010
QC13121801
9.52
QC13121801
MSD MSD
Thallium, Total
< 0.001 mg/L
0.05
0.05513
110
3.69
13110010
QC13121801
MSD
Zinc, Total
0.208 mg/L
0.05
0.24567
76
2.96
13110010
QC13121801
MSD
0.18
QC13120304
QUALIFIERS D2
Sample diluted due to high concentration.
D1
Sample diluted due to matrix interference.
M1
Matrix spike rec. high, control rec. acceptable.
V9
CCV recovery below method limits.
COMMENTS M1 = As/Se MS/MSD spike recoveries high; associated blank spike recovery was acceptable. V9 = Ag CCV recovery was below method limits; target analyte was not detected in samples.
REVIEWED BY: _____________________________________________ Page 5 of 6
Date Signed: 2/5/2014
Page 6 of 6
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131101013 Collection Date: 11/22/2013 Collection Time: 1:05:00 AM
Receive Date: 11/22/2013 Customer Sample#:
Collector: AC Sample Number: 13110013
Project ID: Univ Discrete-Full Site: Univ Dr @ EMF RESULTS
Parameter
Method No
MRL
Qualifier
Result
Analysis Date
Analyst
2-Chloroethyl vinyl ether
EPA624TAL
0.001
< 0.00100 mg/L
11/23/2013
TAL
Acrolein
EPA624TAL
0.05
< 0.050 mg/L
11/23/2013
TAL
Acrylonitrile
EPA624TAL
0.01
< 0.010 mg/L
11/23/2013
TAL
SM4500-CN E
0.02
< 0.020 mg/L
11/29/2013
TAL
SM9223B
2.2
2420.0 mpn/100ml
11/22/2013
mrexing
Cyanide, Total
E. Coli, MPN Oil and Grease
EPA 1664A
5
< 5.0 mg/L
12/9/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
11
< 11.0 mg/L
11/29/2013
TAL
pH-Field
SM4500H B
1
7.32 S.U.
11/22/2013 DCAMERO
SM2550B
1
19.5 째C
11/22/2013 DCAMERO
1,1,1-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1,2,2-Tetrachloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1,2-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1-Dichloroethylene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,2,4-Trimethylbenzene
EPA624_LL
0.002
< 0.0020 mg/L
11/27/2013
TAL
1,2-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
1,2-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,2-Dichloropropane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,3-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
1,3-Dichloropropene, Total
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,4-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Bromodichloromethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Bromoform
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Carbon Tetrachloride
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chlorobenzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chlorodibromomethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chloroethane
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Temperature-Field
Page 1 of 3
Chloroform
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Ethyl Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Methyl Bromide
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Methyl Chloride
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Methylene chloride
EPA624_LL
0.005
< 0.0050 mg/L
11/27/2013
TAL
Tetrachloroethylene (PCE)
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Toluene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
trans-1,2-Dichloroethene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Trichloroethylene (TCE)
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Vinyl Chloride
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Xylene, Total
EPA624_LL
0.0015
< 0.0015 mg/L
11/27/2013
TAL
Quality Control mg/L
BLANK Parameter Oil and Grease Standard Parameter Oil and Grease
QC BATCH
< 5 mg/L QC13121202 Actual Conc. Standard Conc. %REC mg/L
mg/L
36.7
40
92
QC BATCH
QC TYPE
QC13121202
LCS
QUALIFIERS
COMMENTS
REVIEWED BY: _____________________________________________
Page 2 of 3
Date Signed: 12/30/2013
Page 3 of 3
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131219007 Collection Date: 11/22/2013 Collection Time: 12:05:00 PM
Receive Date: 11/22/2013 Customer Sample#:
Collector: AC Sample Number: 13120639
Project ID: SS Discrete-Full Site: Superstition Springs/US 60 RESULTS
Parameter
Method No
MRL
Qualifier
Result
Analysis Date
Analyst
1,1,1-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1,2,2-Tetrachloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1,2-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,1-Dichloroethylene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,2,4-Trimethylbenzene
EPA624_LL
0.002
< 0.0020 mg/L
11/27/2013
TAL
1,2-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
1,2-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,2-Dichloropropane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,3-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
1,3-Dichloropropene, Total
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
1,4-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Bromodichloromethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Bromoform
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Carbon Tetrachloride
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chlorobenzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chlorodibromomethane
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Chloroethane
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Chloroform
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Ethyl Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Methyl Bromide
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Methyl Chloride
EPA624_LL
0.001
< 0.0010 mg/L
11/27/2013
TAL
Methylene chloride
EPA624_LL
0.005
< 0.0050 mg/L
11/27/2013
TAL
Tetrachloroethylene (PCE)
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Toluene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
trans-1,2-Dichloroethene
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Trichloroethylene (TCE)
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Page 1 of 2
Vinyl Chloride
EPA624_LL
0.0005
< 0.0005 mg/L
11/27/2013
TAL
Xylene, Total
EPA624_LL
0.0015
< 0.0015 mg/L
11/27/2013
TAL
Quality Control QUALIFIERS
COMMENTS
REVIEWED BY: _____________________________________________
Page 2 of 2
Date Signed: 12/30/2013
CITY OF MESA COMPLIANCE LABORATORY 640 NORTH MESA DRIVE MESA, ARIZONA 85211 Environmental Laboratory License AZ0410 LABORATORY SUPERVISOR: MATTHEW REXING Ph (480)644-5403 QUALITY ASSURANCE COORDINATOR: KIM CAGGIANO Ph (480)644-5404
Attn: John Meyer OrderID: 131223007 Collection Date: 12/20/2013 Collection Time: 4:30:00 AM
Receive Date: 12/20/2013 Customer Sample#:
Collector: AC Sample Number: 13120682
Project ID: 54 Discrete-Full Site: 54th St @ EMF RESULTS
Parameter
Method No
MRL
Qualifier
Result
Analysis Date
Analyst
2-Chloroethyl vinyl ether
EPA624TAL
0.005
< 0.00500 mg/L
12/21/2013
TAL
Acrolein
EPA624TAL
0.05
< 0.050 mg/L
12/21/2013
TAL
Acrylonitrile
EPA624TAL
0.01
< 0.010 mg/L
12/21/2013
TAL
SM4500-CN E
0.008
< 0.008 mg/L
12/27/2013
TAL
SM9223B
2.2
1990.0 mpn/100ml
12/20/2013 GSMITH2
Cyanide, Total
E. Coli, MPN Oil and Grease
EPA 1664A
5
< 5.0 mg/L
12/26/2013
NSILIDE
Petroleum Hyrodcarbons, Total
EPA 1664A
11
< 11.0 mg/L
12/26/2013
TAL
pH-Field
SM4500H B
1
7.37 S.U.
12/20/2013 DCAMERO
SM2550B
1
12.0 째C
12/20/2013 DCAMERO
1,1,1-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
1,1,2,2-Tetrachloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
1,1,2-Trichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
1,1-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
1,2,4-Trimethylbenzene
EPA624_LL
0.002
< 0.0020 mg/L
12/27/2013
TAL
1,2-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
12/27/2013
TAL
1,2-Dichloroethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
1,2-Dichloropropane
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
1,3-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
12/27/2013
TAL
1,3-Dichloropropene, Total
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
1,4-Dichlorobenzene
EPA624_LL
0.001
< 0.0010 mg/L
12/27/2013
TAL
Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Bromodichloromethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Bromoform
EPA624_LL
0.001
< 0.0010 mg/L
12/27/2013
TAL
Carbon Tetrachloride
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Chlorobenzene
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Chlorodibromomethane
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Chloroethane
EPA624_LL
0.001
< 0.0010 mg/L
12/27/2013
TAL
Chloroform
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Temperature-Field
Page 1 of 3
Ethyl Benzene
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Methyl Bromide
EPA624_LL
0.001
< 0.0010 mg/L
12/27/2013
TAL
Methyl Chloride
EPA624_LL
0.001
< 0.0010 mg/L
12/27/2013
TAL
Methylene chloride
EPA624_LL
0.005
< 0.0050 mg/L
12/27/2013
TAL
Tetrachloroethylene (PCE)
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Toluene
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
trans-1,2-Dichloroethene
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Trichloroethylene (TCE)
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Vinyl Chloride
EPA624_LL
0.0005
< 0.0005 mg/L
12/27/2013
TAL
Xylene, Total
EPA624_LL
0.0015
< 0.0015 mg/L
12/27/2013
TAL
Quality Control mg/L
BLANK Parameter Oil and Grease Standard Parameter Oil and Grease SPIKE RESULTS Parameter Oil and Grease
QC BATCH
< 5 mg/L QC13122602 Actual Conc. Standard Conc. %REC mg/L 35.8 Sample Conc.
40 Spike True Value
90 Final Result
mg/L
mg/L
mg/L
40
36.6
< 5 mg/L
QC BATCH
QC TYPE
mg/L QC13122602 %REC %RPD
91
LCS Sample Number
QC BATCH
13070478
QC13122602
QUALIFIERS
COMMENTS
REVIEWED BY: _____________________________________________
Page 2 of 3
Date Signed: 1/28/2014
MS
Page 3 of 3
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ATTACHMENT B HOUSEHOLD HAZARDOUS WASTE EVENT REPORTS
(This page intentionally left blank)
HHW Event Report Date of Event October 19, 2013
Event Lead Greg Edwards
Location East Mesa Waste Storage Area Vehicle Information Customers came from... Mesa
1495
Gilbert
0
Chandler
0
County
0
Other
0
TOTAL
1495
Hazardous Waste Collected DOT Description Aerosols, 2.1, UN1950
Gallons 1616
Ammonia solutions, corrosive, 8, 8, UN2672
55
Batteries, wet, filled with acid, electric storage, 8, UN2794
85
Batteries, wet, filled with acid, electric storage, 8, UN2794
160
Batteries, wet, non-spillable, electric storage, 8, UN2800
15
Consumer Commodity, ORM-D
130
Corrosive liquid, acidic, inorganic, n.o.s., 8, UN3264
330
Corrosive liquid, basic, inorganic, n.o.s., 8, UN3266
165
Environmentally Hazardous substance, solid, 9, UN3077
90
Environmentally Hazardous substance, solid, 9, UN3077
55
Environmentally Hazardous substance, solid, 9, UN3077
60
Environmentally Hazardous substances, liquid, 9, UN3082
330
Environmentally Hazardous substances, liquid, 9, UN3082
660
Flammable liquids, n.o.s., 3, UN1993
110
Flammable liquids, n.o.s., 3, UN1993
385
Flammable solids, organic, n.o.s., 4.1, UN1325
55
Hydrofluoric acid, solution, 8, UN1790
15
Mercury contained in manufactured articles, 8, UN2809 Non-DOT Regulated Material
Page 1 of 3
5 55
February 10, 2014
HHW Event Report Date of Event October 19, 2013
Event Lead Greg Edwards
Location East Mesa Waste Storage Area DOT Description Non-RCRA/Non-DOT Solid Oxidizing solid, n.o.s., 5.1, UN1479
Gallons 5 165
Paint related material, 3, UN1263
55
Paint related material, 3, UN1263
4443
Pesticides, liquid, flammable, toxic, 3, 6.1, UN3021
1210
Pesticides, liquid, flammable, toxic, 3, 6.1, UN3021
110
Propane, 2.1, UN1978
47
Refrigerant gases, n.o.s., 2.2, UN1078
1
Regulated medical waste, 6.2, UN3291
15
Regulated medical waste, 6.2, UN3291
60
Toxic solids, organic, n.o.s., 6.1, UN2811
55
Toxic solids, organic, n.o.s., 6.1, UN2811
404
Used AntiFreeze
55
Used AntiFreeze
165
Used Oil
950
Waste disposal cost of this event = $92,352.00
Page 2 of 3
Total for this event = 12116 gallons
February 10, 2014
HHW Event Report Event Lead Greg Edwards
Date of Event October 19, 2013 Location East Mesa Waste Storage Area Other Waste Collected
Appliances Collected
Ammunition
NA gallons
Air Conditioners
0
Batteries
2700 pounds
Clothes Dryers
0
Clothes Washers
0
Coolers
0
Dishwashers
0
Freezers
0
Other
0
Ranges
0
Refrigerators
0
Water Heaters
0
15 gallons
Water Softeners
0
70 5-gal / 20-lb tanks
Total for event
0
Carbon Monoxide Tanks
0
Compact Fluorescents Electronics 18427 pounds Fire Extinguishers Fluorescent Tubes Helium Tanks Latex Paint Oxygen Tanks Prescription Medication Propane Tanks
37 0 linear feet 11 6950 gallons 5
Smoke Detectors
9,930 Pounds
Tires w/ rims
37
Tires w/o rims
220
*may include Electronics
Number collected unless otherwise indicated
Total Gallons of Hazardous Waste Diverted = 19081 Hazardous Waste, Latex Paint, Ammunition & Prescription Drugs
Page 3 of 3
February 10, 2014
HHW Event Report Date of Event December 07, 2013
Event Lead Greg Edwards
Location Center Street Yard Vehicle Information Customers came from... Mesa
715
Gilbert
0
Chandler
0
County
0
Other
0
TOTAL
715
Hazardous Waste Collected DOT Description Aerosols, 2.1, UN1950 Ammonia solutions, corrosive, 8, 8, UN2672 Batteries, dry, containing potassium hydroxide solid, electric storage (Alkaline), 8, UN3028 Batteries, wet, non-spillable, electric storage, 8, UN2800
Gallons 606 55 120 20
Consumer Commodity, ORM-D
110
Corrosive liquid, acidic, inorganic, n.o.s., 8, UN3264
110
Corrosive liquid, basic, inorganic, n.o.s., 8, UN3266
75
Environmentally Hazardous substances, liquid, 9, UN3082
495
Flammable liquids, n.o.s., 3, UN1993
220
Fusee (railway or highway), 4.1, NA1325
5
Lighters, 2.1, UN1057
5
Lithium batteries, 9, UN3090
60
Lithium batteries, 9, UN3090
5
Mercury contained in manufactured articles, 8, UN2809
5
Methyl acetylene and propadiene mixtures, stabilized, 2.1, UN1060
5
Non-DOT Regulated Material
0
Non-DOT Regulated Material
110
Organic peroxide type E, liquid, 5.2, UN3107 Oxidizing liquid, n.o.s., 5.1, UN3139
Page 1 of 3
5 55
April 14, 2014
HHW Event Report Date of Event December 07, 2013
Event Lead Greg Edwards
Location Center Street Yard DOT Description
Gallons
Paint related material, 3, UN1263
2424
Propane, 2.1, UN1978
110
Regulated medical waste, 6.2, UN3291
60
Self-heating, solid, organic, 4.2, UN3088
30
Toxic liquids, flammable, organic, n.o.s., 6.1, 3, UN2929
495
Toxic solids, organic, n.o.s., 6.1, UN2811
404
Universal Waste
40
Used Oil
550
Water-reactive solid, n.o.s., 4.3, UN2813 Waste disposal cost of this event = $58,993.33
Page 2 of 3
5 Total for this event =
6184 gallons
April 14, 2014
HHW Event Report Date of Event December 07, 2013
Event Lead Greg Edwards
Location Center Street Yard Other Waste Collected
Appliances Collected
Ammunition
5 gallons
Air Conditioners
0
Batteries
29 pounds
Clothes Dryers
0
Clothes Washers
0
135 pounds
Coolers
0
Electronics 10291 pounds
Dishwashers
0
Freezers
0
Other
0
Ranges
0
Refrigerators
0
Water Heaters
0
10 gallons
Water Softeners
0
23 5-gal / 20-lb tanks
Total for event
0
Carbon Monoxide Tanks Compact Fluorescents Fire Extinguishers Other Fluorescent Tubes Helium Tanks Latex Paint Oxygen Tanks Prescription Medication Propane Tanks
0
14 180 pounds 0 2970 gallons 1
Smoke Detectors
7,140 Pounds
Tires w/ rims
111
Tires w/o rims
12
*may include Electronics
Number collected unless otherwise indicated
Total Gallons of Hazardous Waste Diverted = 9169 Hazardous Waste, Latex Paint, Ammunition & Prescription Drugs
Page 3 of 3
April 14, 2014
HHW Event Report Date of Event February 08, 2014
Event Lead Greg Edwards
Location East Mesa Waste Storage Area Vehicle Information Customers came from... Mesa
1388
Gilbert
0
Chandler
0
County
0
Other
0
TOTAL
1388
Hazardous Waste Collected DOT Description Aerosols, 2.1, UN1950
Gallons 1212
Batteries, wet, filled with alkali, electrict storage, 8, UN2795
90
Batteries, wet, filled with alkali, electrict storage, 8, UN2795
90
Batteries, wet, non-spillable, electric storage, 8, UN2800
30
Calcium carbide, 4.3, UN1402 Consumer Commodity, ORM-D
5 165
Corrosive liquid, acidic, inorganic, n.o.s., 8, UN3264
55
Corrosive liquid, acidic, inorganic, n.o.s., 8, UN3264
165
Corrosive liquid, basic, inorganic, n.o.s., 8, UN3266
220
Corrosive liquid, basic, inorganic, n.o.s., 8, UN3266
165
Environmentally Hazardous substance, solid, 9, UN3077
96
Environmentally Hazardous substance, solid, 9, UN3077
48
Environmentally Hazardous substance, solid, 9, UN3077
18
Environmentally Hazardous substance, solid, 9, UN3077
36
Environmentally Hazardous substances, liquid, 9, UN3082
220
Environmentally Hazardous substances, liquid, 9, UN3082
495
Flammable liquids, n.o.s., 3, UN1993
220
Flammable liquids, n.o.s., 3, UN1993
220
Flammable solids, inorganic, n.o.s., 4.1, UN3178
Page 1 of 3
5
April 08, 2014
HHW Event Report Date of Event February 08, 2014
Event Lead Greg Edwards
Location East Mesa Waste Storage Area DOT Description
Gallons
Fusee (railway or highway), 4.1, NA1325
5
Hydrofluoric acid, solution, 8, UN1790
5
Lighters, non-ressurized, 3, NA1057
5
Lithium batteries, 9, UN3090
5
Matches, safety, 4.1, UN1944
5
Mercury contained in manufactured articles, 8, UN2809
5
Methyl acetylene and propadiene mixtures, stabilized, 2.1, UN1060
5
Non-DOT Regulated Material
0
Non-DOT Regulated Material
55
Non-DOT Regulated Material
72
Non-DOT Regulated Material
220
Non-RCRA/Non-DOT Solid
5
Organic peroxide, Type E, solid, 5.2, UN3108
5
Oxidizing liquid, n.o.s., 5.1, UN3139
220
Paint related material, 3, UN1263
3029
Paint related material, 3, UN1263
1010
Pesticides, liquid, flammable, toxic, 3, 6.1, UN3021
165
Pesticides, liquid, flammable, toxic, 3, 6.1, UN3021
825
Propane, 2.1, UN1978
30
Propane, 2.1, UN1978
55
Refrigerant gases, n.o.s., 2.2, UN1078
5
Regulated medical waste, 6.2, UN3291
150
Toxic solids, organic, n.o.s., 6.1, UN2811
808
Used Oil
825
Waste disposal cost of this event = $96,842.24
Page 2 of 3
Total for this event = 11069 gallons
April 08, 2014
HHW Event Report Date of Event February 08, 2014
Event Lead Greg Edwards
Location East Mesa Waste Storage Area Other Waste Collected
Appliances Collected
Ammunition
5 gallons
Air Conditioners
0
Batteries
1293 pounds
Clothes Dryers
0
Clothes Washers
0
1500 pounds
Coolers
0
Electronics 20382 pounds
Dishwashers
0
Freezers
0
Other
0
Ranges
0
Refrigerators
0
Water Heaters
0
15 gallons
Water Softeners
0
63 5-gal / 20-lb tanks
Total for event
0
Carbon Monoxide Tanks Compact Fluorescents Fire Extinguishers Other Fluorescent Tubes Helium Tanks Latex Paint Oxygen Tanks Prescription Medication Propane Tanks
0
48 800 pounds 10 4835 gallons 1
Smoke Detectors
2
Tires w/ rims
34
Tires w/o rims
198
9,743 Pounds *may include Electronics
Number collected unless otherwise indicated
Total Gallons of Hazardous Waste Diverted = 15924 Hazardous Waste, Latex Paint, Ammunition & Prescription Drugs
Page 3 of 3
April 08, 2014
HHW Event Report Date of Event April 05, 2014
Event Lead Greg Edwards
Location Center Street Yard Vehicle Information Customers came from... Mesa
1030
Gilbert
0
Chandler
0
County
0
Other
0
TOTAL
1030
Hazardous Waste Collected DOT Description Acetylene, dissolved, 2.1, UN1001 Ammonia solutions, corrosive, 8, 8, UN2672 Batteries, dry, containing potassium hydroxide solid, electric storage (Alkaline), 8, UN3028 Batteries, wet, non-spillable, electric storage, 8, UN2800
Gallons 1 20 100 60
Consumer Commodity, ORM-D
165
Corrosive liquid, acidic, inorganic, n.o.s., 8, UN3264
220
Corrosive liquid, basic, inorganic, n.o.s., 8, UN3266
110
Environmentally Hazardous substance, solid, 9, UN3077
30
Environmentally Hazardous substance, solid, 9, UN3077
175
Environmentally Hazardous substances, liquid, 9, UN3082
715
Flammable liquids, n.o.s., 3, UN1993
275
Flammable liquids, n.o.s., 3, UN1993
808
Flammable solids, organic, n.o.s., 4.1, UN1325
5
Fusee (railway or highway), 4.1, NA1325
5
Lighters, non-ressurized, 3, NA1057
5
Liquified gas, flammable, n.o.s., 2.1, UN3161
5
Lithium batteries, 9, UN3090
20
Mercury contained in manufactured articles, 8, UN2809
55
Methyl acetylene and propadiene mixtures, stabilized, 2.1, UN1060
Page 1 of 3
5
June 16, 2014
HHW Event Report Date of Event April 05, 2014
Event Lead Greg Edwards
Location Center Street Yard DOT Description
Gallons
Nitrogen, compressed, 2.2, UN1066
1
Non-DOT Regulated Material
195
Oxidizing liquid, n.o.s., 5.1, UN3139
15
Paint related material, 3, UN1263
1010
Paint related material, 3, UN1263
2222
Pesticides, liquid, flammable, toxic, 3, 6.1, UN3021
770
Pesticides, solid, toxic, n.o.s., 6.1, UN2588
404
Propane, 2.1, UN1978
60
Refrigerant gases, n.o.s., 2.2, UN1078
10
Refrigerant gases, n.o.s., 2.2, UN1078
5
Regulated medical waste, 6.2, UN3291
90
Universal Waste
60
Used AntiFreeze
275
Used Oil
140
Used Oil
825
Waste Chlorodifluoromethane or Refrigerant Gas R22, 2.2, UN1018 Waste disposal cost of this event = $78,235.00
Page 2 of 3
Total for this event =
1 8862 gallons
June 16, 2014
HHW Event Report Date of Event April 05, 2014
Event Lead Greg Edwards
Location Center Street Yard Other Waste Collected
Appliances Collected
Ammunition
5 gallons
Air Conditioners
0
Batteries
1598 pounds
Clothes Dryers
0
Clothes Washers
0
250 pounds
Coolers
0
Electronics 13974 pounds
Dishwashers
0
Freezers
0
Other
0
Ranges
0
Refrigerators
0
Water Heaters
0
Water Softeners
0
Total for event
0
Carbon Monoxide Tanks Compact Fluorescents Fire Extinguishers Other Fluorescent Tubes Helium Tanks Latex Paint Oxygen Tanks Prescription Medication Propane Tanks
1
28 750 pounds 9 4400 gallons 4 5 gallons 39 5-gal / 20-lb tanks
Smoke Detectors
1
Tires w/ rims
50
Tires w/o rims
293
7,083 Pounds *may include Electronics
Number collected unless otherwise indicated
Total Gallons of Hazardous Waste Diverted = 13272 Hazardous Waste, Latex Paint, Ammunition & Prescription Drugs
Page 3 of 3
June 16, 2014
ATTACHMENT C ANNUAL EXPENDITURE REPORTS
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City of Mesa Stormwater Program Budget vs Expenditures for Budget Fiscal Year 2013/2014 Budget Storm Drain Maintenance • • • • • •
$
1,554,987
$
864,552
$
5,216,985
$
5,175,015
$
2,499,386
$
1,317,402
$
346,101
$
64,010
$
217,711
$
391,031
Repair of Damaged Facilities Sediment Removal from Catch Basins Clearing Debris from Inlet/Outlets Regrading and Stabilizing Earthen Channels Installation of Erosion Control Measures Silt Removal from Retention Basins
Retention Basin Maintenance • • • •
Expenses
Regular Litter and Debris Removal Turf Maintenance Erosion Control and Bank Stabilization Repair of Damaged Facilities
Street Cleaning • Sweeping of Arterial Streets • Sweeping of Residential Streets
Emergency Response • Spill Clean-Up • Material Dumping Clean-Up
Household Hazardous Waste Management Program
818,858
Administration, Inspection and Enforcement, Monitoring Program • • • • • •
653,956
General Program Management Annual Field Screening Inspection of Construction and Industrial Sites Preparation of Annual Program Summaries Public Information and Education Soil Stabilization Activities (Personal and Professional Services)
Total Proposed Annual Expenditures
Annual Expenditure/Budget Report
$
10,654,028
$
8,465,966
Page 1 of 2
City of Mesa Stormwater Program Proposed Budget for Fiscal Year 2014/2015 Proposed Budget $
1,911,000
$
6,125,541
$
2,713,408
$
178,112
Household Hazardous Waste Management Program
$
330,000
Administration, Inspection and Enforcement, Monitoring Program
$
1,181,120
$
12,439,181
Storm Drain Maintenance • • • • • •
Repair of Damaged Facilities Sediment Removal from Catch Basins Clearing Debris from Inlet/Outlets Regrading and Stabilizing Earthen Channels Installation of Erosion Control Measures Silt Removal from Retention Basins
Retention Basin Maintenance • • • •
Regular Litter and Debris Removal Turf Maintenance Erosion Control and Bank Stabilization Repair of Damaged Facilities
Street Cleaning • Sweeping of Arterial Streets • Sweeping of Residential Streets
Emergency Response • Spill Clean-Up • Material Dumping Clean-Up
• • • • • •
General Program Management Annual Field Screening Inspection of Construction and Industrial Sites Preparation of Annual Program Summaries Public Information and Education Soil Stabilization Activities (Personal and Professional Services)
Total Proposed Annual Budget
Annual Expenditure/Budget Report
Page 2 of 2