Paper Bio-degradation in Composting Systems: Analyzing Environmental Impact and Process Optimization

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International Research Journal of Engineering and Technology (IRJET) e-ISSN:2395-0056

Volume: 11 Issue: 10 | Oct 2024 www.irjet.net p-ISSN:2395-0072

Paper Bio-degradation in Composting Systems: Analyzing Environmental Impact and Process Optimization

1Student, Department of Civil Engineering, Kavikulguru Institute of Technology & Science, Ramtek.

2Student, Department of Civil Engineering, Kavikulguru Institute of Technology & Science, Ramtek.

3Student, Department of Civil Engineering, Kavikulguru Institute of Technology & Science, Ramtek.

4Assistant Professor, Department of Civil Engineering, Kavikulguru Institute of Technology & Science, Ramtek.

Abstract - The biodegradability of different types of paper was tested in compost environments. Newsprint without ink degraded fully in 18 days, while inked newsprint degraded slowerduetoligninandmetal-basedinks. Glossyandrecycled papers degraded faster, within 14 and 16 days, respectively. Compostingpaperwithmanuretransformscarbonintostable forms, enriching soil health. Nitrogen is converted into plantavailable forms, aiding long-term soil fertility. Compost stability increases as more resistant organic materials are synthesized. Composting reduces landfill waste, methane emissions, and air pollution, while promoting recycling. It is economically viable and crucial for waste management sustainability.Combiningpaperwastewithactivatedcharcoal and vermicomposting produces nutrient-rich fertilizers, especially inIndia, andcanbeusedforsustainableagriculture. Research shows that most paper types, including white and recycled paper, do not meet biodegradation standards within 45 days, requiring longer composting times to fully decompose. Anaerobic digestion is the most efficient waste treatment method for biodegradable materials, combining energy recovery with soil conditioning. Composting can sometimes emit more greenhouse gases than landfilling, though it avoids methane production. Lignin content reduces paper biodegradability. Optimal degradation occurs at 4050°C, aidedbythermophilicfungi. Themanufacturingprocess of paper affects its degradation rates. Organic matter in compost stabilizes as easily degradable compounds break down. Composting mixtures of green waste, bio waste, and paper require a balance for optimal organic matter stabilization. Composting reduces methane emissions compared to landfilling, which is a major source of global greenhouse gases. While both systems have environmental impacts, composting is generally more proactive in reducing emissions. Vermicomposting producesfinercompostparticles with lower nutrient content but is more efficient in managing paper waste. Windrow composting yields higher nutrient levels but has more heavy metals, affecting its application in agriculture. Different waste types emit varying levels of CO2 and ammonia during composting. Food waste generates the highestemissions, while mixedpaperwasteproducestheleast. This helps predict environmental impacts of composting different materials. Composting organic materials like manure, orange peels, and wheat straw can improve soil healthandsuppressplantdiseases.Itisaneffectivealternative

to peat-based substrates in organic farming. Paper sludge, a byproduct of paper de-inking, can be composted to improve soilorganic matter. However, itrequirescarefulmanagement to avoid nutrient immobilization and the presence of contaminants, which are reduced during composting.

In summary, paper waste can be effectively composted to improve soil health, though factors such as ink, lignin, and contamination levels affect biodegradability. Composting reduces greenhouse gasemissionscomparedtolandfillingand is a sustainable waste management solution.

Key Words: Biodegradation, Composting, Vermicomposting, Paper waste, Green waste, Greenhouse Gas, Methane Emission

1. INTRODUCTION

In recent years, researchers have explored the environmental benefits of composting, particularly with paperproductsandorganicwaste.Compostingturnsorganic waste into valuable soil amendments, helping to reduce landfill use, lower greenhouse gas emissions, and create nutrient-richfertilizers.However, differenttypesofpaper andorganicwastedegradeatvaryingrates,dependingon factors like the presence of ink, lignin content, and the composting process used. Studies have shown that newsprint paper, especially with ink, decomposes slower than glossy or recycled papers due to its chemical composition.Inkandligninresistbiodegradation,especially in nutrient-rich environments. Other research focuses on composting's ability to stabilize organic matter, releasing nutrientsgraduallyandsupportinglong-termsoilhealth.

Moreover,integratingwastepaperintocompostingsystems, particularly when combined with organic materials like animal manure, has been proven to improve the soil’s nutrient content and reduce environmental pollutants. Compostingiswidelyrecognizedasasustainablealternative totraditionalwastedisposalmethodslikelandfilling,which contributes significantly to methane emissions. While composting can emit some greenhouse gases, its overall environmental impact is less harmful than landfills, especiallywhencombinedwitheffectivewastemanagement strategies. Composting paper waste not only reduces the

Volume: 11 Issue: 10 | Oct 2024 www.irjet.net p-ISSN:2395-0072

environmentalburdenofwastedisposalbutalsoprovidesa sustainable solution for enhancing soil health and agriculturalproductivity.

2. LITERATURE REVIEW

S. Ahmed et al. (2018) The study investigated the biodegradationofdifferenttypesofpaper(newsprintwith and without ink, recycled paper, and glossy paper) in a compost environment. Paper strips were buried in a nutrient-richcompostmixtureandsampledatintervalsto measuredegradationthroughtensilestrengthtests.

KeyFindings:

 Newsprintwithoutinkbiodegradedfullyin18days.

 Newsprintwithinktooklongerthan21daysanddidnot fullydegrade.

 Glossypaperandrecycledpaperdegradedfaster,within 14and16days,respectively.

Theslowerdegradationofinkednewsprintisattributedto thelignininthepaperandthemetalsintheink,whichresist breakdownandincreasecompostacidity.

T. Pare et al. (1998) Composting animal manure and shreddedpapertransformscarbonandnitrogenintostable forms that enhance soil. Initially, carbon content drops quickly as it converts to carbon dioxide, stabilizing after about a month. Nitrogen is converted into plant-available formslikeammoniumandnitrate,thoughsomeislostduring composting. The study found that a significant portion of carbon is easily accessible to microbes early on, but as compost matures, it becomes less degradable, releasing nutrientsmoreslowlywhenaddedtosoil,whichsupports long-termsoilhealth.

Saleh Ali Tweib et al. (2011) Composting is an environmentallysustainablepracticethatoffersasuperior alternativetosimplydumpingorganicwasteintotheearth. Ratherthancontributingtolandfills,compostingtransforms organicwasteintovaluableproductswithmultiplebenefits. Theseincludereducinglandfillspace,minimizingtheriskof surface and groundwater contamination, cutting down on methane emissions, lowering transportation costs, and decreasingair pollution fromburning waste.Additionally, composting enhances the overall flexibility of waste management,promotesrecycling,andcanbeimplemented with minimal capital and operating costs. By converting waste into a resource, composting plays a crucial role in protecting our environment and fostering a circular economy.

A.K. Raj Kumar et al. (2020) Paper waste can be repurposed into organic compost, reducing reliance on harmfulchemicalfertilizers.InIndia,wherepaperwasteis plentiful, combining it with activated charcoal and vermicomposting through anaerobic digestion creates

Keyfindingsinclude: International Research Journal of Engineering and Technology (IRJET) e-ISSN:2395-0056

nutrient-richfertilizersthatenhancesoilhealth.Labresults showtheanaerobiccomposthasapHof8.3,highermoisture content, and slightly better nutrient levels than aerobic compost. Both types are free from pathogens and heavy metals, making them safe and effective for sustainable agriculture.

J. V. Lopez Alvarez et al. (2009) Spain's municipal solid waste(MSW)managementproduces17.3milliontonnesof organic waste annually, with compost quality often compromisedduetohighlevelsofwastepaper(12–27%). Researchindicatesthatnoneofthetested papers,suchas white, cardboard, or Kraft, reach the 70% biodegradation standardwithin45days,mainlyduetonon-biodegradable componentslikelignin.Onlywhiteandrecycledpapersmay biodegradeeffectivelyifcompostedlonger,over110days. These findings underscore the need for improved compostingtechniquesandselectivewastemanagementto enhancecompostquality.

B.G.Hermannetal.(2011) Inthisarticlewecomparedthe carbon and energy footprints from forty peso waste treatmentofbiodegradablematerials.NotAllmaterialare suitable for all types of biological treatment, PLA For exampledoesnotdegradeinhomecompostingintemperate ClimatesandPBATandmechanicalpulpdonotdegradein anaerobicdigestion.Intermsowastetreatmenttypes,we focussed on Industrial composting, home composting in temperate climates, Anaerobic digestion and waste incineration.Ofthesewastetreatmentoptions,digestionis themostfavourableforbiodegradableMaterialsforthetime being because it combines energy recovery With the production of digestive, which can be used data soil Conditioner. Home composting is roughly equal to incineration with energy recovery, with small differences acrossmaterials;Industrialcompostingisworsethanhome composting because Lower credits are assigned to the resultingcompost.

M.Vikmanetal.(2002) Astrongcorrelationbetweenlignin contentinpaperproductsandtheirbiodegradability.Higher ligninlevelstypicallyreducebiodegradation,particularlyat higher composting temperatures like 58°C. Optimal lignin degradationoccursattemperaturesbetween40°Cand50°C, facilitated by thermophilic fungi. Paper products' biodegradability also depends on their manufacturing process,withmechanicalpulpbeingmoredegradablethan other types with similar lignin content. The European standardEN13432nowrecognizeschemicallyunmodified paper products as biodegradable, though they must still meetspecificdisintegrationandecotoxicitycriteria.

Cedric Francou et al. (2008)The study investigated how varyingproportionsofgreenwaste,biowaste,andpapercardboardincompostmixturesaffectorganicmatter(OM) evolutionduringcomposting.

International Research Journal of Engineering and Technology (IRJET) e-ISSN:2395-0056

Volume: 11 Issue: 10 | Oct 2024 www.irjet.net p-ISSN:2395-0072

 OM stabilization during composting involves the degradation of easily biodegradable materials (cellulose,hemicellulose),therelativeincreaseofmore resistant compounds (lignin), microbial synthesis of resistantbiomolecules,andunificationprocesses.

 GreenwasteshowedminimalOMstabilizationduetoits highlignincontent.

 Moderate amounts of paper-cardboard (20–40%) allowed for favourable OM stabilization, while larger amounts(over50%)hinderedstabilization,likelydueto nitrogendeficiency.

Biowastesimpactedcompostingmainlyatthestartdueto theirhighlevelsofeasilybiodegradablematerial.

X. F. Lou & J. Nair (2009) The impact of various waste management (WM) strategies on greenhouse gas (GHG) emissions. Prior to the mid-1990s, waste management focusedmainlyonpublichealthandsafetyandoptimizing landfill gas capture. Recently, the emphasis has shifted to addressing the role of waste in GHG emissions, as waste management now accounts for about 5% of global GHG emissions, primarily methane (CH4) from landfills and carbondioxide(CO2)fromwastewater.

ThepaperdiscussesthecommonWMpracticeoflandfilling anditsassociatedGHGemissionscomparedtocomposting. Landfills produce significant CH4 due to anaerobic decomposition, contributing more to GHG emissions than composting. Although landfill mitigation strategies like energy recovery and aeration can reduce emissions, composting is generally more effective in reducing GHG emissionsbecauseitavoidstheproductionofCH4.

The review notes that while composting is proactive and aimstominimizenegativeenvironmentalimpacts,landfilling often serves as a reactive measure. However, operational emissions can vary, with composting potentially emitting more GHGs than landfills in some cases. Despite improvementsinwastemanagement,landfillswillremain necessary for some waste. Therefore, reducing waste productionanddivertingwastetoappropriatemanagement facilities are crucial for minimizing overall environmental impact.

Jim Frederickson et al. (2007) This research paper compares the effectiveness of two composting systems: a combined system of in-vessel thermophilic composting followedbyvermicomposting,andatraditionalsystemofinvessel composting followed by windrow composting. Key findingsinclude:

NutrientandPhysico-ChemicalProperties:Vermicomposting producedcompostwithahigherproportionoffineparticles andlowerpHcomparedtowindrowcomposting.Windrow composthadhigherlevelsoftotalnitrogen(N),phosphorus (P),potassium(K),andelectricalconductivity(EC),butalso higherconcentrationsofsomeheavymetals.

Plant Growth Performance: When used in growing media, both compost types showed similar effectiveness for growingtomatoes,marigolds,andradishes,providedthey wereadjustedfornutrientlevelsandEC.However,highEC in windrow compost negatively affected plant growth in sometrials.

Operational Efficiency: Vermicomposting effectively transformedpaper-basedwasteintofinercompostparticles andhadloweroverallnutrientandpotentialtoxicelement (PTE)levelscomparedtowindrowcomposting.

Overall, while both methods produced compost with comparablegrowthperformancewhenadjusted,thechoice betweenthemmaydependonspecificnutrientneedsand regulatoryconsiderations.

Dimitris P. Komilis (2006) Composting municipal solid waste(MSW)caneitherpre-treatwastebeforelandfillingor produce soil amendments. The two main gases emitted duringcompostingarecarbondioxide(CO2),agreenhouse gas,andammonia(NH3),whichisbothanairpollutantand malodorous.Keycontributorstotheseemissionsarepaper, food,andyardwastes,whicharetheprimarybiodegradable componentsofMSW.Studieshavefocusedonmeasuringthe reduction of organic materials and the capture of emitted gases.Variousexperimentshavebeenconductedtomeasure CO2 and NH3 from different organic waste mixtures, employing laboratory-scale digesters and different substrates,includingpaper,food,andyardwastes.

Recent studies aimed to quantify CO2 and NH3 emissions from these main waste components and their mixtures to develop a predictive model. This model, based on experimental data, helps estimate emissions from various MSWcompositions.Thefindingsshowthatfoodwaste(FW) generatesthehighestCO2andNH3emissions,followedby yardwaste(YW)andmixedpaperwaste(MXP),withMXP producing the least. The model developed allows for predictingemissionsfromdifferentMSWmixtures,aidingin theassessmentoftheirenvironmentalimpact.Overall,the studyconcludesthatwhiletheCO2emissionsarelinearwith respect to the amount of each component, NH3 emissions depend heavily on the initial nitrogen content and are influenced by the interaction between different waste components.

MichaelRavivetal.(2005) Thisresearchexaminestheuse of compost as an alternative substrate to soil for organic farming, particularly in areas where fertile soil is scarce. Traditionally,organicfarmingreliesheavilyonsoil,which can present challenges due to nutrient limitations or diseases. However, compost has the potential to not only replacesoilbutalsosupplyessentialnutrientsandsuppress diseases.

Thestudyinvolvedmixingfreshcowmanurewithdifferent organic materials such as orange peels, grape marc, and

International Research Journal of Engineering and Technology (IRJET) e-ISSN:2395-0056

Volume: 11 Issue: 10 | Oct 2024 www.irjet.net p-ISSN:2395-0072

wheat straw to create composts with varying properties. Thesecompostsweretestedfortheirphysical,chemical,and horticultural characteristics. Results demonstrated that compost,especiallythosemadewithorangepeelsorwheat straw,canreleasesignificantamountsofnitrogen,improving plant growth and yields when compared to conventional peat-based substrates. Additionally, compost showed promisingresultsinsuppressingpestslikenematodesand pathogensthatcauserootandcrownrotincherrytomatoes. Overall, the study suggests that compost can be a viable substitute for soil in organic farming, offering both nutritionalanddisease-suppressingbenefits.

Chantal J. Beauchamp et al. (2002) Reid (1997) reports thatinCanada,significantamountsofpulpandpaperwaste weredisposedofviacombustionorlandfilling.Specifically, Quebec produced substantial amounts of de-inking paper sludge (DPS), which contains organic carbon and various contaminants.

2.De-inkingPaperSludge(DPS)Composition:Latva-Somppi et al. (1994) found DPS contains 45-85% organic carbon, primarily cellulose fibers, which impacts its ability to enhance soil organic matter. However, its high C:N ratio meansitinitiallyimmobilizesnitrogenandphosphorus in soil.Chantignyetal.(1999)notedthatDPScanimprovesoil but requires proper management to avoid nutrient immobilization.

3.CompostingProcessandEffects:Brouilletteetal.(1996) explainthatcompostinginvolvesmicrobialdegradationof organic matter, including sugars and cellulose in DPS, leading to stabilized compost. Chong and Cline (1991) emphasize that composting increases temperature and microbialactivity,whicharecrucialforbreakingdownDPS components.

4.ContaminantsinDPSandCompost:YuandMohn(1991) foundthatresin-andfattyacidsinDPSaredegradedduring composting, with most disappearing within 24 weeks, leavingonlyresidualcompoundslikeabieticacid.Menzieet al.(1992)highlightedthatpolycyclicaromatichydrocarbons (PAHs)inDPSdecreaseovertime,withnonedetectedafter 24weeksofcomposting,indicatingeffectivedegradation. 5. Environmental Impact and Management: Bellamy et al. (1995) suggest that while DPS contains potentially toxic compounds like resin acids and PAHs, proper composting and management reduce their environmental impact. CanadianEnvironmental QualityGuidelines(CCME,1999) providethresholdsforcontaminantssuchasnaphthalene, underscoringtheneedtomonitorandmanageDPScompost applicationstoavoidexceedingsoilqualitystandards.

While DPS has beneficial uses in soil amendment, careful management and composting are crucial to mitigate potentialenvironmentalrisks.

3. CONCLUSIONS

Papers like newsprint without ink, recycled paper, and glossypaperdegradeincompostenvironmentswithin14to 21 days, though inked newsprint degrades slower due to lignin and metal content. Glossy and recycled papers degradefasterthannewsprint.Compostingorganicwaste, includingpaper,providesmultipleenvironmentalbenefits, such as reducing landfill space, minimizing methane emissions, and producing nutrient-rich compost for soil enhancement. Composting paper waste, in particular, can replace chemical fertilizers and improve soil quality sustainably. High lignin content in paper slows down its biodegradation, and municipal solid waste (MSW) with papercontentoftenfallsshortofbiodegradationstandards. Composting can emit greenhouse gases like CO2 and ammonia,thoughemissionsaregenerallylowerthanthose fromlandfilling.Vermicompostingandanaerobicdigestion areeffectivemethodsfortreatingpaperandorganicwaste. Vermicompostingproducesfinercompostwithlowerheavy metals,whileanaerobicdigestionofferstheaddedbenefitof energyrecovery.Compostqualitydependsonthebalanceof green and paper waste in mixtures. Composting helps mitigategreenhousegasemissionscomparedtolandfilling, though it requires proper management to minimize emissionsandoptimizecompostquality.

In conclusion, while paper waste can be effectively composted,factorslikelignincontent,ink,andcomposting conditions influence biodegradation rates. Composting remains a sustainable method for waste management, provided that it is carefully controlled to maximize environmentalbenefitsandminimizepotentialrisks.

4. REFERENCES

[1] S.Ahmed,“BiodegradationofDifferentTypesofPaperin aCompostEnvironment”,InternationalConferenceon Natural Sciences and Technology (ICNST’18), http://www.researchgate.net/publication/341050000, 2018.

[2] T.Pare,“Transformationsofcarbonandnitrogenduring composting of animal manure and shredded paper”, Springer-Verlag, BiolFertileSoils,1998.

[3] Saleh Ali Tweib, “A literature review on composting”, InternationalConferenceonEnvironmentandIndustrial Innovations,2011.

[4] A. K. Raj Kumar, “Utilization of Paper Waste for the ProductionofOrganicCompost”,InternationalJournalof Innovative Research in Science, Engineering and Technology,2020.

International Research Journal of Engineering and Technology (IRJET) e-ISSN:2395-0056

Volume: 11 Issue: 10 | Oct 2024 www.irjet.net p-ISSN:2395-0072

[5] J. V. Lopez Alvarez, “Biodegradation of paper waste under controlled composting conditions”, Waste Management29(1),p1514-1519,2009

[6] B.G.Hermann,“ToCompostornottocompost:Carbon andenergyfootprintsofbiodegradablematerialswaste treatment”, Polymer Degradation and Stability 96 (2011)p1159-1171.

[7] M. Vikman, “The Influence of lignin content and temperatureonthe biodegadation oflignocellulosein composting conditions”, Appl Microbiol Biotechnol (2002)59p591-598 http://doi.org/10.1007/s00253002-1029-1.

[8] CedricFrancou,“Influenceofgreenwaste,biowasteand paper-cardboard initial ratios on organic matter transformations during composting”, Bioresourse Technology99(2008)p8926-8934.

[9] X.F. Lou & J. Nair, “The impact of landfilling and compostingongreenhousegasemissions”,Bioresource Technology100(2009)3792–3798.

[10] JimFrederickson,GrahamHowell,AndrewM.Hobson, “Effect of pre-composting and vermicomposting on compost characteristics”, European Journal of Soil Biology43(2007)S320-S326

[11] Dimitris P. Komilis, “A kinetic analysis of solid waste compostingatoptimalconditions”,WasteManagement 26(2006)82–91.

[12] Michael Raviv, Yuji Oka, Jaacov Katan, Yitzhak Hadar, Anat Yogev, Shlomit Medina, Arkady Krasnovsky, HammamZiadna,“High-nitrogencompostasamedium for organic container-grown crops”, Bioresource Technology96(2005)419–427.

[13] Chantal J. Beauchamp, Marie-Helene Charest, Andre Gosselin,“Examinationofenvironmentalqualityofraw andcompostingde-inkingpapersludge”,Chemosphere 46(2002)887–895.

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