BE
King Abdullah University of Science and Technology
اململكة العربية السعودية، ثول
at Thuwal, Kingdom of Saudi Arabia
October 2010 / Shawwal 1431 Issue No. 2
the
CON
recommended in
JEDDAH Hot tips, cool places and more! Turn to p.4-5
www.kaust.edu.sa
3D-reconstruction of the membrane porosity
Dr. Mustafa Al-Ali
Ten New Partnerships Global Collaborative Research (GCR) has recently signed agreements with universities in countries such as Australia, Ireland and Switzerland for the first time. Smaller in scale than those secured during the early days of the university, these collaborations have been arranged at the faculty level. The new partners include Trinity College Dublin, Harvard, the University of Kentucky, Clemson University in South Carolina, Australia’s U n i v e r s i t y o f Wo l l o n g o n g , École Polytechnique Fédérale de Lausanne of Switzerland, and Széchenyi István University in Hungary. “All early partnerships were established at the institutional level,” GCR director Dr. Mustafa Al-Ali told The Beacon. The existing, larger-scale partnerships including the Woods Hole Oceanographic Institution, Stanford, Cornell, Oxford, National Taiwan University and HKUST were secured before work on building the campus began. With the university in Thuwal now in its second year, a "bottom-up approach" is being encouraged by senior leadership, Dr Al-Ali explained, "...the faculty should drive future partnerships based on needs and KAUST’s strategic research directions. “So we have introduced a competitive program. We asked our faculty to submit proposals for activities, with their own choice of partners, that are connected and complementary so that each project includes research both inside and outside the Kingdom”. The program attracted a strong response from faculty; ten partnerships were awarded from the 50 proposals submitted. “The proposals went through the peer review process and the selection panel (Continued on p.2)
INSIDE:
Better
MEMBRANES
– adversity drives innovation
In an inspiring example of overcoming the early challenges of getting their lab up and running, scientists in the Advanced Membranes and Porous Materials C enter, working with researchers in the Nanofabrication, Imaging a nd Characterization Lab, have made an important discovery. As reported in a recent issue of Macromolecules, they have d eveloped an improved and lower-cost method for producing n anoporous films which have extremely high pore density and r egularity. Their work advances the capability for large-scale production of high quality membranes for water purification, m edical and pharmaceutical applications as well as improvements to templates for the electronics industry. Whilst awaiting the completion of their own research lab and not wishing to remain idle, Drs. Suzana Nunes and Klaus-Viktor Peinemann chose this project knowing they had the full support o f the Core Labs. Ironically, if their “own research lab had been available when they started working at KAUST,” they told The Beacon, they “probably would not have approached this particular problem.” Having worked with membranes and polymer solutions for a long time, they identified a problem which was fascinating from a scientific point of
News 2-3
view, relevant for membrane technology and, perhaps most importantly, could be tackled with the resources then available to them at KAUST. This is a tangible example of finding the silver lining in the cloud of our startup challenges. In practical use for more than fifty years, membranes have evolved over time, driven by end-user needs for improved p erformance. Separation techniques have continuously improved, making the membranes more selective and able to remove finer p articles. New breakthroughs have enabled lower energy c onsumption, reduced costs, increased membrane life span and, above all, significant benefits to end-users. As an example, patients with renal failure can spend up to eight hours daily undergoing hemodialysis in order to remove waste products from their blood. This involves diffusion of solutes across a semi-permeable membrane. Due to their enhanced and more precise filtration capability, high flux membranes (i.e. those with a high rate of throughput) with improved control of the pore size and distribution have the potential to substantially shorten the time a patient needs to be on a dialysis machine. Microbial and chemical contamination of water resources significantly
Out and About 4-5
impacts human health around the world and new threats, such as pharmaceuticals in drinking water, are constantly emerging. Commercial membranes for water purification, for the most part, still resemble those developed in the 1960s. The required increase in the effectiveness of decontamination requires much higher fluxes and a membrane with uniform pore size distribution in the nano range, i.e. ultrafiltration. While high flux is relatively easy to build into a membrane, the challenge is to ensure that the pores are evenly sized and d istributed. The KAUST researchers addressed this problem by taking a unique approach to the development of nanoporous films inspired by block copolymers, metal-directed supramolecular chemistry and nonsolvent induced phase separation. Block copolymers are composed of at least two long sequences of monomer units which are quite different from each other but are covalently bound. By diluting with a selective solvent, one of the polymers tends to avoid solvent contact, assembling into complex morphologies or forms. This offers numerous possibilities for tailoring nano-structures.
In Depth 6-7
Technology 7
Suzana and Klaus used metal-polymer complexation as a m ethod for directing self-assembly, stabilizing micelles (which are a submicroscopic aggregation of molecules) in solution a nd providing intermicellar crosslinking. Using a series of advanced microscopy methods and the expertise of core lab s cientists, they experimented with a number of different solvents. This helped to d etermine the self-assembly in solution and its influence on the mechanism of pore formation, ultimately to find the one which formed the most orderly and even distribution of micelles. However, micelles and vesicles that are formed in solution are dynamic, and evaporation immediately transforms the morphology. The challenge for the researchers was to control and stabilize the morphologies quickly to enable bottom-up nanostructure fabrication. Film morphology is dependent upon n ot only the thermodynamic interaction between copolymers, but also upon other factors such as viscosity and the presence of impurities which could dramatically influence the kinetics of phase separation and self-assembly. (Continued on p.2)
Community 8