基化三 ch2試讀

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

2Ͳ1 ⍵ㅱ忇䌯⭂⼳

! !!!!!!!!!ϸᔈೲ౗!

1.⭂佑: ġ ġ ╖ỵ㗪攻ℏˬϸᔈ‫઻੃ޑނ‬ໆ˭ㆾ╖ỵ㗪攻ℏˬғԋ‫ޑނ‬ғԋໆ˭炻䧙䁢⍵ㅱ忇䌯ˤẍ r 䁢 ẋ嘇ˤ ⍵ㅱ忇䌯(R)=

཯᠕≀ⓗᾘ⪖㔞 ⏕ᡂ≀ⓗ⏕ᡂ㔞 ㆾ

⍵ㅱ䴻忶䘬㗪攻 ⍵ㅱ䴻忶䘬㗪攻

2.╖ỵ: (1)㗪攻╖ỵ:ὅ⍵ㅱ忇䌯䘬⾓ㄊ炻⎗䓐⽖䥺ˣ㮓䥺ˣ䥺ˣ↮ˣ㗪ˣ㖍ˣ㚰ˣ⸜…..䁢╖ỵˤ (2)⍵ㅱᷕ䈑岒嬲⊾慷䘬╖ỵˤ ġ a.⚢橼ㆾ㵚橼烉 ġ b.㯋橼烉 ġ c.㯜㹞㵚烉 3.⍵ㅱ䲣ᷕ⎬䈑岒⍵ㅱ忇䌯䘬斄Ὢ: ẍ aA為bBÆcC為dD 䁢ἳ;)aˣbˣcˣd 䁢Ὢ㔠* (1) A 䘬㴰便忇䌯烉 B 䘬㴰便忇䌯烉 C 䘬䓇ㆸ忇䌯烉 D 䘬䓇ㆸ忇䌯烉

(2)ὅ㒂⊾⬠⍵ㅱ忶䦳ᷕ炻⎬䈑岒卓 卓俛㔠嬲⊾慷䘬㭼䫱㕤⍵ㅱ⺷䘬Ὢ Ὢ㔠㭼炻⎗⼿Ļġ

(3)⭂㹓⭂⭡ᶳ炻㯋ン䈑岒䘬⍵ㅱ忇䌯⎗䓐⡻≃䘬嬲⊾䌯堐䣢ˤ

89

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

!

1.㯗㯋↮妋䘬⍵ㅱ䁢 Cl2(g) ɦ 2Cl(g)炻㚱斄℞⍵ㅱ忇䌯䘬斄Ὢ⺷炻ỽ侭㬋䡢烎ġ

)烐*

烌

ġ )烑*

)烓*

烌

ġ

烌

ġ )烒*

烌

ġ

2.⑰㝷㱽墥㯐ᷳ⍵ㅱ烉N2(g)為3H2(g) ї 2NH3(g)炻 ℞⍵ㅱ忇䌯 r 烌a

烌b

烌c

炻⇯ a烉b烉c ㅱ䁢ỽ烎ġ

)烐* 1烉3烉2ġ )烑* 1烉1烉1ġ )烒* 6烉2烉3ġ )烓* 2烉3烉1

3/⍵ㅱX+YїZ(Ὢ㔠㛒⸛堉)炻⛐䚠⎴㗪攻ℏ炻䓙xˣyˣz䘬㽫⹎嬲⊾慷㷔⼿⍵ㅱ忇䌯炻劍堐䣢

=Ͳk ㆸr 烌Ͳk =Ͳk 炻⇯k :K :k =? !!!!!!!!!!!!!!!!!!!!!!!!!!!!!!

4.ᶳ↿ỽ侭ᶵ㗗⍵ㅱ忇䌯䘬╖ỵ? (A)atm/min (B)g/sec (C)mol 炽L炽s (D) L炽s

4.䧖栆: (1)⸛⛯⍵ㅱ忇䌯: ╖ỵ㗪攻ᷳ㗪攻攻昼庫攟ᷳ⍵ㅱ忇䌯炻

(2)䝔㗪⍵ㅱ忇䌯烉╖ỵ㗪攻ᷳ㗪攻攻昼嵐役㕤暞ᷳ⍵ㅱ忇䌯炻

90

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

1.㚱ᶨ⍵ㅱ⺷䁢 2䓚為ḁ ї ᷁為3ᶩ炻ᶼ䓚䘬㽫⹎冯⍵ㅱ㗪攻ᷳ斄Ὢἄ⚾⤪ᶳ炻Q 溆䘬↯䶂

炻A炷0炻15炸 炻B炷60炻0炸 炻Q炷20炻10炸ˤᶳ↿㔀徘ỽ侭㬋䡢烎ġ (烐)⛐ Q 溆㗪炻䓚䘬忇䌯䁢炼5.0 M min炼1ġ (烑)⛐ Q 溆㗪炻䓚䘬忇䌯䁢 2.0 M min炼1ġ (烒)⛐ Q 溆㗪炻ḁ䘬忇䌯䁢 3.0 M min炼1ġ (烓)⛐ Q 溆㗪炻᷁䘬忇䌯䁢 0.25 M min炼1ġ (烔)⛐ Q 溆㗪炻᷁䘬忇䌯䁢 0.125 M min炼1ˤġ

2.⍵ㅱ 4HBr(g)為O2(g) ɦ 2H2O(g)為2Br2(g) ⛐⭂㹓䘬 10 L ⭡☐ᷕ炻2 min 㴰便 0.8 mol HBr炻⚆䫼 ᶳ↿⓷柴烉 )烀* HBr ᷳ㴰便忇䌯䁢劍⸚ M min炼1烎

M min炼1烎 )烁* Br2 ᷳ䓇ㆸ忇䌯䁢劍⸚

3.⍵ㅱ⺷烉BrO3炼(aq)為5Br炼(aq)為6H為(aq) ɦ 3Br2(aq)為3H2O(")炻ᶳ↿⎬䈑岒䘬㽫⹎嬲⊾⚾炻ỽ侭 㬋䡢烎ġ )烐*

ġ )烑*

ġ )烒*

ġ )烓*

4.⭂㹓ᶳ炻N2(g)為3H2(g) ɦ 2NH3(g) ᷳ⍵ㅱ忇䌯斄Ὢ⺷炻ỽ侭㬋䡢烎ġ )烐* )烓*

烌 烌

ġ )烑* ġ )烔*

烌 烌

ġ )烒*

烌

ġ

91

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

1.扩䰱冯忶㯗愠扐䘬㶟⎰䈑⎗䓐䁢䀓䭕㍐忚☐䘬䅫㕁炻℞⍵ㅱ⺷⤪ᶳ烉 !!!)ࡰԵ* 3Al(s)為3NH4ClO4(s) ɦ Al2O3(s)為AlCl3(s)為3NO(g)為6H2O(g)為2677 kJ ⮯扩䰱冯忶㯗愠扐⎬ 1.0 mol炻㓦ℍᶨᾳ橼䧵䁢 1.0 Lˣ㹓⹎䁢 400 K 䘬⭂橼䧵⿮㹓⍵ㅱ㦥 ℏ⍵ㅱ炻᷎㷔慷㦥ℏ㯋橼䷥⡻≃晐㗪攻䘬嬲⊾炻⼿ℑ侭䘬斄Ὢ⤪ᶳ⚾ˤ 炷`姕℞㯋橼䁢䎮 ゛㯋橼炸

㟡㒂ᶲ⚾炻⚆䫼ᶳ↿⓷柴烉 )烀*㯪↢扩䰱ᷳ㴰便忇䌯ˤ )烁*妰䬿扩䰱⛐ 5 min ℏ䘬㴰便慷ˤ )烂*㬌⍵ㅱ⛐ 5 min ℏ㓦↢⣂⮹䅙慷烎

2.N2O3(g) ὅ N2O3(g) ɦ NO2(g)為NO(g) ↮妋ˤ㕤⭂㹓ᶳ炻⭂⭡䘬⭡☐ℏ墅ℍ 100 mmHg 䘬 N2O3(g)炻⽆墅ℍ N2O3(g) 攳⥳䬿崟炻䫔 75 䥺㷔⼿⭡☐ℏ䘬㯋橼⡻≃䁢 130 mmHgˤ㯪 0 焍 75 炼 䥺攻䘬 N2O3(g) 䘬⸛⛯↮妋忇䌯炷mmHg s 1炸䁢ỽ烎ġ )烐* 0.4ġ )烑*

ġ )烒* 1.33ġ

)烓* 2.00

3.⛐ 45 ɗ䘬⿮㹓㦥ᷕ≈ℍ 2 M N2O5 㹞㵚 2 L炻忚埴 2N2O5(aq) ɦ 4NO2(g)為O2(g) ⍵ㅱ 20 min ⼴ 炻䓊䓇 0.36 mol 䘬㯏㯋炻⚆䫼ᶳ↿⓷柴烉 )烀* N2O5 䘬㹞㵚㽫⹎嬲䁢⣂⮹ M烎 )烁*ẍ N2O5 䘬㽫⹎堐䣢炻㚨⇅ 20 min 䘬⍵ㅱ忇䌯䁢ỽ烎ġ

炼 4.᷁䂟⬴ℐ䅫䅺㗪炻劍 O2 䘬㴰便忇䌯㗗 11.2 L min 1炷⛐ STP ᶳ炸炻⚆䫼ᶳ↿⓷柴烉 )烀* C3H8 䘬⍵ㅱ忇䌯䁢劍⸚ mol min炼1烎 )烁* CO2 䘬䓇ㆸ忇䌯䁢劍⸚ mol s炼1烎

92

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

΋ǵൂᒧᚒ Ȑ! ! ! ȑIJį⛐ᶨ䄁曏⮎槿䭙ᷕ炻㷔⼿䄁曏䘬ᷣ天ㆸ↮䁢 RHˣNOˣNO2ˣ O3ˣPAN炻℞ᷕ RH ⏓ CˣH炻侴 PAN ⏓ CˣHˣOˣN炻⎬ 䧖䈑岒䘬䚠⮵㽫⹎晐㗪攻䘬㴰攟炻姀抬㕤旬⚾ᷕ炻㟡㒂⚾ ᷕ㔠㒂炻ᶳ↿㍐婾炻ỽ侭㚨ᶵ⎰䎮烎ġ (A)NO 㴰⣙䘬忇䌯 㭼 RH ⾓ġ (B)NO 䓇ㆸ NO2ġ (C)RH ⍲ NO2 䓇ㆸ PAN ⍲ O3ġ (D)O3 䓇ㆸ PANˤ

炷ġ ġ ġ 炸ijį⛐⑰㝷㱽墥㯐䘬⍵ㅱᷕ烉N2(g)為3H2(g)o2NH3(g)炻℞⍵ㅱ忇䌯 r烌炼x

'[N 2 ] '[H 2 ] 烌炼y 烌z 't 't

'[NH 3 ] 炻⇯ x烉y烉z ㅱ䁢ġ (A)1烉1烉1ġ (B)6烉2烉3ġ (C)1烉3烉2ġ (D)2烉3烉1ˤ 't 炷ġ ġ ġ 炸Ĵį⭌㹓ᶳ炻ḁ愯䅫䅺䓇ㆸḴ㯏⊾䡛␴㯜ˤ劍⶚䞍ḁ愯䘬㴰便忇䌯䁢 0.1 mol/min炻⇯㯏䘬㴰便忇 䌯䁢劍⸚ mol/min烎ġ (A)0.1ġ (B)0.2ġ (C)0.3ġ (D)0.6ˤ 炷ġ ġ ġ 炸ĵį冕㯏䘤䓇☐ℏ䘤䓇 3O2o2O3 ᷳ⍵ㅱ炻℞⍵ㅱ忇䌯⎗ẍ䓐ᶳ↿ℑ⺷堐䣢烉忇䌯 r1烌炼 忇䌯 r2烌

'[O 2 ] 炻 't

'[O3 ] 3 2 炻⇯ r1 ␴ r2 䘬斄Ὢ⤪ỽ烎ġ (A)r1烌r2ġ (B)r1烌3r2ġ (C)r1烌 r2ġ (D)r1烌 r2ˤ 't 2 3

炷ġ ġ ġ 炸Ķį㝸㯋橼⍵ㅱ䲣 A為2BoC為D炻䴻㷔⼿䈑䲣崟⥳䷥⡻≃㷃⮹忇䌯䁢 P mmHg/min炻⇯ B 㯋橼ᷳ崟 ⥳㴰便忇䌯炼

'PB P P (mmHg/min)䁢ġ (A) ġ (B) ġ (C)Pġ (D)2Pˤ 't 3 2

炷ġ ġ ġ 炸ķį⛐ 25ɗ㗪炻㝸㽫⹎ᷳ H2O2(aq)100 mL ᷕ≈⮹慷 MnO2炻⛐ NTP ᶳ(1 atm炻25ɗ)10 ↮揀ℏ䓊䓇 O2 炼 炼 炼 炼 炼 49 mL炻⇯ H2O2 ᷳ⸛⛯↮妋忇䌯䁢劍⸚ mol L 1 min 1烎ġ (A)4.4u10 3ġ (B)4u10 3ġ (C)2u10 3ġ

(D)1.66u10 3ˤ 炼

炷ġ ġ ġ 炸ĸį㚱ᶨ⍵ㅱ⺷䁢 2 䓚為ḁo᷁為3 ᶩ炻ᶼ䓚䘬㽫⹎冯⍵ㅱ㗪攻ἄ⚾⤪旬⚾㇨䣢炻Q 溆䘬↯䶂 AB炻 A(0炻15)炻B(60炻0)炻Q(20炻10)炻⇯ᶳ↿㔀徘ỽ侭㬋䡢烎ġ (A)⛐ Q 溆㗪䓚䘬忇䌯䁢炼50 mol/L

minġ (B)⛐ Q 溆㗪䓚䘬忇䌯䁢炼2.0 mol/L minġ (C)⛐ Q 溆㗪ḁ䘬忇䌯䁢為3.0 mol/L minġ (D) ⛐ Q 溆㗪᷁䘬忇䌯䁢為0.125 mol/L minˤ

93

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

炷ġ ġ ġ 炸Ĺį㝸㹓⹎㗪炻劍 1 L ⭮攱⭡☐ᷕ㚱 10 卓俛㯓␴ 5 卓俛㯏炻⍵ㅱ䓇ㆸ㯜炻10 ↮揀⼴炻⭡☐ᷕ∑ᶳ 3 卓俛䘬㯏炻⇯㯓䘬⸛⛯⍵ㅱ忇䌯䁢ġ (A)0.2ġ (B)0.4ġ (C)2ġ (D)4ġ M/minˤ 炷ġ ġ ġ 炸ĺį⛐怑䔞㡅ẞᶳ炻N2(g)為3H2(g)o2NH3(g)⍵ㅱᷕ炻㯖䘬㴰便忇䌯䁢 100mmHg s 1炻⇯ᶳ↿㔀徘ỽ侭 炼

㬋䡢烎ġ (A)㯓䘬㴰便忇䌯䁢 100 mmHg s 1ġ (B)㯐䘬䓇ㆸ忇䌯䁢 300 mmHg s 1ġ (C)䲣䴙䷥⡻ 炼

炼

䘬㷃⮹忇䌯䁢 200 mmHg s 1ġ (D)䲣䴙䷥⡻䘬⡆≈忇䌯䁢 100 mmHg s 1ˤ 炼

炷ġ ġ ġ 炸IJıįCH4(g)為2O2(g)oCO2(g)為2H2O(g)炻⶚䞍 O2 䘬㴰便忇䌯 r O 2 烌 忇䌯 rtotal烌

炼

炼'PO2 't

烌0.1 atm/s炻⇯䷥⡻≃䘬嬲⊾

'Ptotal 烌ġ (A)炼0.05ġ (B)0.075ġ (C)0.025ġ (D)0ġ atm/sˤ 't

炷ġ ġ ġ 炸IJIJį姕⛐ 328 K 㗪炻2N2O5(g)o4NO2(g)為O2(g)䈑䲣䷥⡻≃⡆≈忇䌯 rtotal烌R炻⇯ġ (A)N2O5(g)↮⡻≃䘬㷃 ⮹忇䌯 r N 2 O 5 烌

2 4 Rġ (B)NO2(g)↮⡻≃䘬⡆≈忇䌯䁢 r NO2 烌 Rġ (C)O2 ↮⡻≃䘬⡆≈忇䌯 r O 2 烌 5 5

R ġ (D)r N 2 O 5 烌r NO 2 烌r O 2 烌Rˤ 3

炷ġ ġ ġ 炸IJijį⮵㕤⍵ㅱ烉3A為Bo2C為2D炻ᶳ↿斄㕤⍵ㅱ忇䌯䘬堐䣢㱽ᷕ炻ỽ侭䁢㚨⾓ᷳ⍵ㅱ烎ġ (A)rA烌0.6 mol/sġ (B)rB烌0.45 mol/sġ (C)rC烌2.40 mol/minġ (D)rD烌0.45 mol/s炷s 堐䥺炻min 堐↮揀炸 ˤ

΋ǵൂᒧᚒ IJįD ijįB ĴįC ĵįC ĶįD ķįB ĸįD ĹįB ĺįC IJıįD IJIJįC IJijįB

! ! ! ! ! ! !

94

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

!!!!!!!!!! !!!!!!!!!ϸᔈೲ౗ϐෳ‫!ۓ‬

1.㭼刚㱽烉⍵ㅱ⇵⼴㚱柷刚㓡嬲㗪炻⎗䓐㭼刚㱽Ἦ㷔⭂℞柷刚嬲⊾慷炻⼿䞍⍵ㅱ忇䌯ˤ (1)

N 2 O 4(g )

䃉

2NO 2(g)

䲭㡽

(2)

FeSCN 2 (aq)

Fe3 (aq) SCN (aq )

湫墸 䃉 埨䲭

2.㰱㽙烉⍵ㅱ䲣ᷕ㚱㰱㽙䓇ㆸ㗪炻⎗䓐㰱㽙慷ᷳ嬲⊾Ἦ㷔⭂⍵ㅱ忇䌯ˤ

AgNO3(aq) NaCl(aq)

AgCl(s) NaNO3(aq)

3.㹞㵚ᷳ pH ῤ烉⍵ㅱᷕ㚱愠渤嬲⊾㗪炻⎗䓐㹞㵚ᷳ pH ῤ嬲⊾炻Ἦ㷔⭂⍵ㅱ忇䌯ˤ

CH 3COOH (aq) C 2 H 5 OH (aq ) 愠⿏

ᷕ⿏

CH 3 COOC 2 H 5(l) H 2 O (l)

ᷕ⿏

4.⮶暣⹎㱽烉⍵ㅱ⇵⼴⮶暣⹎㚱㖶栗嬲⊾侭炻⎗䓐⮶暣⹎嬲⊾炻Ἦ㷔⭂⍵ㅱ忇䌯ˤ

H 2SO 4(aq ) Ba(OH) 2(aq )

Æ

BaSO 4(s) 2H 2 O(l)

5.㯋㲉ᷳ䓊䓇: 奨⮇⍵ㅱᷕ㯋㲉䓊䓇䘬∯䁰冯⏎ẍ⇌㕟℞忇䌯⾓ㄊˤ

CaCO 3( s ) +2HCl ( aq ) ÆCaCl 2 ( aq ) +H 2 O (l ) +CO 2( g )

6.⡻≃ㆾ橼䧵烉⍵ㅱ⇵⼴㚱㯋橼卓俛㔠嬲⊾㗪炻⎗䓐⭂⭡ᶳᷳ⡻≃嬲⊾ㆾ⭂⡻ᶳᷳ橼䧵嬲⊾Ἦ㷔⭂ ⍵ㅱ忇䌯ˤ (1)

CaCO3(s) N 2 O5(g )

CaO(s) CO 2(g )

⇑䓐⭂㹓⭂⡻ᶳᷳ CO2 橼䧵嬲⊾䌯

1 2NO 2(g ) O 2(g ) 2 ⇑䓐⭂㹓⭂⭡ᶳᷳ㯋橼䷥⡻嬲⊾䌯

95

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

(2)劍䭕嘇ℑ怲㯋橼䈑岒䘬Ὢ㔠␴䚠䫱炻⇯ᶵ傥䓐橼䧵䘬嬲⊾ㆾ䷥⡻≃䘬嬲⊾Ἦ 㷔℞⍵ㅱ忇䌯ˤ

H 2(g) I 2(g)

2HI(g )

CO(g) + NO2(g)

CO2(g) + NO(g)

!!

1.ᶳ↿⍵ㅱᷕ炻ỽ侭ᶵ傥䓐䷥⡻䘬嬲⊾Ἦ㷔℞⍵ㅱ忇䌯烎ġ (A)CO(g)為NO2(g) ĺ CO2(g)為NO(g)ġ (B) N2O4(g) ĺ 2NO2(g)ġ (C) N2(g)為3H2(g) ĺ 2NH3(g)ġ (D) H2(g)為I2(g) ĺ 2HI(g)ġ (E) 2NO(g)為2H2(g) ĺ N2(g)為2H2O(g)ġ (F) 4HBr(g)為O2(g) ĺ 2Br2(g)為2H2O(g) (G)CaCO3(s)ĺCaO(s)為CO2(g) (H)CH4(g) 為2O2(g) ĺ CO2(g) 為2H2O(g) (I) N2(g)為O2(g) ĺ 2NO(g) (J)Ag 為Br ĺAgBr(s) (K)4PH3(g) ĺP4(g)為6H2(g)

2.㫚⽆ᶳ↿⎬䧖ね㱩炻Ḯ妋⍵ㅱ忇䌯ᷳ⾓ㄊ炻䚠斄㔀徘ỽ侭㬋䡢烎ġ (A) N2O4(g) ĺ 2NO2(g) (䲣䴙䷥⡻) (B)CO(g)為NO2(g) ĺ CO2(g)為NO(g) (柷刚) (C)H2CO3(aq)為Ca(OH)2(aq) ĺ CaCO3(s)為2H2O(") (⮶暣⹎) (D)CO(g)為NO2(g) ĺ CO2(g)為NO(g) (䲣䴙䷥⡻) (E) AgNO3(aq)為HCl(aq) ĺ AgCl(s)為HNO3(aq) (愠⹎) (F) H2(g)為I2(g) ĺ 2HI(g) (⭂㹓⭂⭡ᶳᷳ㯋橼䷥⡻嬲⊾) (G)4PH3(g) ĺP4(g)為6H2(g) (⭂㹓⭂⡻ᶳᷳ橼䧵嬲⊾) (H) CaCO3(s)ĺCaO(s)為CO2(g) (⭂㹓⭂⭡ᶳᷳ㯋橼䷥⡻嬲⊾) (I) N2O4(g) ĺ 2NO2(g) (柷刚) (J) 2N2O5(g) ĺ 4NO2(g)為O2(g) (䲣䴙䷥⡻) (K) Ag 為Br ĺAgBr(s) (㰱㽙䘬慷) (L)HCl(aq)+NaOH(aq)ĺ NaCl(aq)+ H2O(") (pH ῤ) +2H ĺSO2(g) 為H2O(")為S(s) (㰱㽙䘬慷) (M)S2O

96

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

΋ǵൂᒧᚒ Ȑ! ! ! ȑIJįᶳ↿⒒ᶨ枭⍵ㅱᶵ ᶵ傥䓐炷ġ 炸ℏ㇨䣢䘬嬲⊾㷔℞⍵ㅱ忇䌯烎ġ (A)N2O4(g)ɦ2NO2(g)炷柷刚炸ġ (B)CO(g)為NO2(g)ɦCO2(g)為NO(g)炷橼䧵炸ġ (C)H2SO4(aq)為Ba(OH)2(aq)ɦBaSO4(s)為2H2O(l)炷⮶暣⹎炸ġ ˤ (D)AgNO3(aq)為NaBr(aq)ɦAgBr(s)為NaNO3(aq)炷㰱㽙慷炸ġ (E)CaCO3(s)ɦCaO(s)為CO2(g)炷䷥⡻炸 ᶵ傥䓐䷥⡻≃䘬嬲⊾Ἦ㷔慷⍵ㅱ忇䌯烎炷⍵ㅱ⺷㛒⸛堉炸ġ 炷ġ ġ ġ 炸ijįᶳ↿⍵ㅱᷕ炻ỽ侭ᶵ (A)NO2(g)為H2(g)ɦN2(g)為H2O(g)ġ (B)PH3(g)ɦP4(g)為H2(g)ġ (C)N2O4(g)ɦNO2(g)ġ (D)H2(g)為I2(g)ɦHI(g)ġ (E)N2(g)為3H2(g)ɦ2NH3(g)ˤ 炷ġ ġ ġ 炸Ĵį⎗ẍ䓐炷ġ 炸ℏ䘬嬲⊾Ἦ”㷔⍵ㅱ忇䌯䘬㗗ġ (A)N2為O2o2NO炷柷刚炸ġ (B)AgNO3為HCloAgCl為HNO3炷pH ῤ炸ġ (C)H2CO3為Ba(OH)2oBaCO3為2H2O炷㰱㽙慷炸ġ (D)H2(g)為I2(g)o2HI(g)炷㯋橼⡻≃炸 ˤ 炷ġ ġ ġ 炸ĵįᶳ↿⒒ᶨᾳ⍵ㅱ⎗䓙柷刚嬲⊾㷔℞⍵ㅱ忇䌯烎ġ (A)2NO(g)為O2(g)ɦ2NO2(g)ġ (B)2SO2(g)為O2(g)ɦ2SO3(g)ġ (C)3O2(g)ɦ2O3(g)ġ (D)NaCl(aq)為AgNO3(aq)ɦAgCl(s)為NaNO3(s)ġ (E)NH3(g)為HCl(g)ɦNH4Cl(s)ˤ ᶵ傥䓐䷥⡻≃䘬嬲⊾Ἦ㷔慷⍵ㅱ忇䌯烎炷㛒⸛堉炸ġ (A)H2(g)為Cl2(g)ɦHCl(g)ġ 炷ġ ġ ġ 炸Ķįᶳ↿⍵ㅱᷕ炻ỽ侭ᶵ (B)N2O5(g)ɦNO2(g)為O2(g)ġ (C)NH3(g)為HCl(g)ɦNH4Cl(s)ġ (D)CaCO3(s)ɦCaO(s)為CO2(g)ġ (E)NH3(g)ɦN2(g)為H2(g)ˤ ġ

Βǵӭᒧᚒ Ȑ! ! ! ȑIJį⭂㹓㗪炻ᶳ↿⎬⍵ㅱỽ侭⎗䓐⭂⡻ᶳ㯋橼橼䧵䘬嬲⊾Ἦ㷔慷⍵ㅱ忇䌯烎ġ 為

(A)Ag

(aq)為Br (aq)oAgBr(s)ġ 炼

(B)N2(g)為O2(g)o2NO(g)ġ (C)4HBr(g)為O2(g)o2H2O(g)為2Br2(g)ġ

(D)2NO(g)為O2(g)o2NO2(g)ġ (E)2KClO3(s)o2KCl(s)為3O2(g)ˤ 炷ġ ġ ġ 炸ijįᶳ↿⍵ㅱ⺷ỽ侭⎗䓐炷ġ 炸ᷕᷳ嬲⊾Ἦ㷔↢℞⍵ㅱ忇䌯烎ġ (A)C(s)為CO2(g)ɦ2CO(g)炷⭂㹓⭂⭡ᶳ㷔䷥⡻炸ġ (B)HCl(aq)為AgNO3(aq)ɦAgCl(s)為HNO3(aq)炷㷔⮶暣 ⹎炸ġ (C)H2(g)為Cl2(g)ɦ2HCl(g)炷⭂㹓⭂⡻ᶳ㷔橼䧵炸ġ (D)H2(g)為I2(g)

2HI(g)炷㷔柷刚炸ġ

ˤ (E)Na2S2O3(aq)為2HCl(aq)ɦ2NaCl(aq)為S(s)為SO2(g)為H2O炷㷔㰱㽙慷炸 炷ġ ġ ġ 炸Ĵį⭂㹓ᶳ炻2N2O5(g)ɦ4NO2(g)為O2(g)⎗⇑䓐ᶳ↿ỽ䧖⿏岒㷔℞⍵ㅱ忇䌯烎ġ (A)⭂⭡ᶳ㷔⡻≃嬲⊾ġ (B)⭂⡻ᶳ㷔橼䧵嬲⊾ġ (C)㷔柷刚ġ (D)㷔⮶暣⹎ġ (E)㷔䷥岒慷嬲⊾ˤ 炷ġ ġ ġ 炸ĵį⭂㹓㗪炻ᶳ↿⎬⍵ㅱỽ侭⎗䓐⭂⭡ᶳ㷔䷥⡻䘬嬲⊾Ἦ㷔⍵ㅱ忇䌯烎ġ (A)NH3(g)為HCl(g)ɦNH4Cl(s)ġ (B)N2O4(g)ɦ2NO2(g)ġ (C)2HI(g)ɦH2(g)為I2(g)ġ (D)HCl(aq)為NaOH(aq)ɦNaCl(aq)為H2O(l)ġ (E)Na2S2O3(aq)為2HCl(aq)ɦ2NaCl(aq)為S(s)為SO2(g)為H2O(l)ˤ 炷ġ ġ ġ 炸Ķįᶳ↿⎬⍵ㅱ炻ỽ侭⎗䓐(ġ )ℏ䘬嬲⊾慷㷔⭂℞⍵ㅱ忇䌯烎ġ (A)N2O4(g)o2NO2(g)炷䲣䴙䷥⡻炸ġ (B)H2C2O4(aq)為Ba(OH)2(aq)oBaC2O4(s)為2H2O(l)炷⮶暣⹎炸ġ (C)CO(g)為NO2(g)oCO2(g)為NO(g)炷䲣䴙䷥ ⡻炸ġ (D)CO(g)為NO2(g)oCO2(g)為NO(g)炷柷刚炸ġ (E)AgNO3(aq)為HCl(aq)oAgCl(s)為HNO3(aq)炷愠⹎炸 ˤ

΋ǵൂᒧᚒ IJįB ijįD ĴįC ĵįA ĶįA Βǵӭᒧᚒ IJįCDE ijįABDE ĴįABC ĵįABE ĶįABD

97

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

!!!!!!!!!! !!!!!!!!!ϸᔈೲ౗‫ࡓۓ‬Ԅ!

1.⍵ㅱ忇䌯⭂⼳⺷䘬シ佑烉 㽫⹎⮵⍵ㅱ忇䌯㚫㚱⼙枧炻䴻䓙⮎槿㷔⭂⍵ㅱ忇䌯冯㽫⹎攻䘬㔠⬠斄Ὢ⺷炻䧙䁢忇䌯⭂⼳⺷ˤ 2.忇䌯⭂⼳䘬堐䣢㱽烉 ⤪㝄⍵ㅱ㕡䦳⺷䁢 a A為b B ÆcC炻℞⍵ㅱ忇䌯冯⍵ㅱ䈑㽫⹎㝸㫉㕡ㆸ㬋㭼炻忇䌯⭂⼳⺷⎗ ẍ堐䣢ㆸ烉__________ (1)m 冯 n 䧙䁢⍵ㅱ䳂㔠ˤ a.⮵⍵ㅱ䈑 A 侴妨䁢___䳂ˤ b.⮵⍵ㅱ䈑 B 侴妨䁢___䳂ˤ c.⮵ℐ⍵ㅱ侴妨䁢_______䳂炻 ℞ῤ劍䫱㕤 0 㗪炻䧙䁢暞䳂⍵ㅱ烊 劍䫱㕤 1 㗪炻䧙䁢ᶨ䳂⍵ㅱ烊 劍䫱㕤 2 㗪炻䧙䁢Ḵ䳂⍵ㅱˤ

ჴᡍ 1 2 3

[A] [B] ȐMȑ ȐMȑ 0.60 0.20 0.20

0.15 0.60 0.15

C! ‫ޑ‬ғԋೲ౗ ɡ ȐM! min 1ȑ ɡ 6.3! Ø! 10 3 ɡ 2.8! Ø! 10 3 ɡ 7.0! Ø! 10 4

(2)m 冯 n 天䓙________炻冯㕡䦳⺷ᷳὪ㔠ᶵᶨ⭂䚠䫱ˤ (3)m 冯 n ⎗傥䫱㕤 0ˣ㔜㔠ㆾ↮㔠ㆾ屈㔠炻Ữ㚨ⷠ夳怬㗗 1ˣ2 䘬㬋㔜㔠ˤ (4)劍⍵ㅱ䈑䁢㯋橼炻Ṏ⎗䓐↮⡻堐䣢忇䌯⭂⼳烉 3.⍵ㅱ忇䌯ⷠ㔠 k: (1)⼙枧⚈䳈 a.⍵ㅱ䈑䘬㛔岒烉⌛⍵ㅱ䘬䧖栆ˤ b.㹓⹎烉㹓⹎グ檀炻k ῤグ⣏ˤ c.㹞∹烉⌛⍵ㅱ䘬䑘⠫ˤ d.⁔⊾∹烉⁔⊾∹ἧ k ῤ嬲⣏炻⍵ㅱ忇䌯嬲⾓ˤ (2) k ῤ䘬╖ỵ烉冯⍵ㅱ䳂㔠㚱斄(ߚࡡ‫ۓ‬ǴᒿᐚࡋϐᏈԛБ‫ׯ‬ᡂ) ⍵ㅱ䳂㔠

㽫⹎ M

⡻≃ atm

0

1

2

4.慵天奨⾝㔜䎮: (1)⍵ㅱ忇䌯⎗↮⇍㚱 rAˣrBˣrCˣrtotal 堐䣢炻䃉婾ẍỽ侭堐䣢⍵ㅱ忇䌯炻ᶵ㓡嬲℞冯[A] m [B] n ᷳ斄Ὢ炻ⶖ⇍⎒⛐______ˤ (2)㚱⍵ㅱ⺷ a A為b B ÆcC ⎗䞍炻rA:rB:rC=____________________

98

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

!

1.⛐㹓⹎ 1100 K炻2 H2(g)為2 NO(g) 炼ɦ 2 H2O(g)為N2(g) 䘬⍵ㅱ忇䌯䁢 r烌k[H2][NO]2炻⇯ᶳ↿ 㔀徘ỽ侭拗婌烎 (A) k 䁢忇䌯ⷠ㔠炻冯㹓⹎㚱斄ġ (B)⍵ㅱ䷥䳂㔠䁢 3ġ (C)⮯ H2 䘬↮⡻⡆≈ 1 ᾵炻⍵ㅱ忇 䌯㚫≈᾵ġ (D)⮯ NO 䘬↮⡻⡆≈ 1 ᾵炻⍵ㅱ忇䌯㚫≈᾵ (E)⡻䷖ἧ橼䧵嬲䁢⍇Ἦ䘬ᶨ ⋲炻⍵ㅱ忇䌯嬲䁢⍇Ἦ䘬ℓ᾵ (F) k 㗗忇䌯ⷠ㔠炻⚈℞䁢ⷠ㔠炻㓭℞㔠ῤᶵ晐╖ỵᷳ㓡 嬲侴㓡嬲 (G)⍵ㅱ䳂㔠グ檀炻堐䣢⍵ㅱ忇䌯⍿㽫⹎⼙枧䘬㓰ㅱグ栗叿 (H)⍵ㅱ䳂㔠グ 檀炻⍵ㅱ忇䌯グ⾓ (I) k ῤᶵ晐叿䓇ㆸ䈑䘬㽫⹎ㆾ↮⡻䘬⣏⮷㓡嬲

2.㝸⍵ㅱ2A為2B ɦ C為2D ᷳ⍵ㅱ忇䌯㔠㒂⤪ᶳ烉 ⍵ㅱ䈑⇅㽫⹎炷M炸

⮎槿 㫉㔠 [B]0 [A]0 炷M s炼1炸 炼 炼 2 ǘ 10炼3 6 ǘ 10 3 1 ǘ 10 3 1 6 ǘ 10炼3 2 ǘ 10炼3 4 ǘ 10炼3 2 炼 炼 1.5 ǘ 10炼3 3 ǘ 10 3 3 ǘ 10 3 3 ⚆䫼ᶳ↿⓷柴烉! )烀*⮓↢忇䌯㕡䦳⺷ˤ )烁*忇䌯ⷠ㔠 k ῤˤ 炷枰≈╖ỵ炸 )烂*劍[A]烌[B]烌4.0 ǘ 10炼3 M炻⇯

䁢⣂⮹烎炷枰≈╖ỵ炸ġ

3.⛐25 ɗ㗪炻䓙 AˣB ⍵ㅱ䓇ㆸ C烉A(aq)為2B(aq) ɦ 3C(aq) 䘬⮎槿㔠㒂⤪ᶳ烉 ⮎ C 䓇ㆸ忇䌯 [A] [B] 炷M炸 炷M min炼1炸 槿 炷M炸 炼 3.0 ǘ 10 4 1 0.20 0.20 炼 81.0 ǘ 10 4 2 0.60 0.60 炼 9.0 ǘ 10 4 3 0.60 0.20 ⚆䫼ᶳ↿⓷柴烉! )烀*⍵ㅱ忇䌯堐䣢㱽䁢ỽ烎 )烁*忇䌯ⷠ㔠䁢ỽ烎炷枰≈╖ỵ炸 )烂*⍵ㅱ䳂㔠䁢ỽ烎 )烃*⶚䞍㹓⹎㭷ᶲ⋯ 10 ɗ炻⍵ㅱ忇䌯⡆䁢⍇Ἦ䘬 2 ᾵ˤ⛐ 45 ɗᶳ炻劍 [A]烌0.30 M炻[B] 烌0.10 M 㗪炻㯪 [A] 䘬㴰便忇䌯䁢劍⸚烎炷╖ỵ烉M min炼1炸ġ

99

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

!

1.⶚䞍⍵ㅱ 2A為3B為C ɦ D為2E ᷳ⍵ㅱ䈑㽫⹎冯⍵ㅱ忇䌯䘬斄Ὢ⤪ᶳ堐烉 㫉㔠

[A] [B] [C] 炷M炸 炷M炸 炷M炸

炷M min 1炸 1 0.1 0.1 0.1 0.003 2 0.2 0.1 0.2 0.012 3 0.3 0.3 0.1 0.081 4 0.2 0.2 0.4 0.024 炷ġ 炸)烀*ᶲ堐㔠㒂ᷳ忇䌯ⷠ㔠 k ῤ䁢ỽ烎ġ )烐* 30ġ )烑* 6ġ )烒* 3ġ )烓* 0.3ˤ 炼

炷ġ 炸)烁*㈧䫔)烀*柴炻劍[A]烌0.4 M炻[B]烌0.2 M炻[C]烌0.2 M 㗪炻

䁢⣂⮹ M min

炼1

烎ġ )烐* 0.096ġ )烑* 0.288ġ )烒* 0.276ġ )烓* 0.192ˤġ

2.⶚䞍⍵ㅱ 2A(g)為3B(g)為C(g) ɦ D(g)為E(g)炻℞忇䌯冯⍵ㅱ㽫⹎ᷳ斄Ὢ⤪ᶳ堐烉 ⇅㽫⹎ M ǘ 102 ⍵ㅱ忇䌯 䶐 炼 嘇 [A] [B] [C] 炷M min 1炸 1 2 3 4 劍⍵ㅱ忇䌯 r烌

1.0 1.0 1.0 2.0

1.0 2.0 2.0 3.0

1.0 2.0 3.0 5.0

1.26 ǘ 10 2 炼 2.52 ǘ 10 2 2.52 ǘ 10炼2 炼 15.12 ǘ10 2 炼

烌k[A]x[B]y[C]z炻ᶳ↿㔀徘ỽ侭㬋䡢烎ġ )烐* x為y為z烌3炻℞ᷕ x烌2

炼 炼 炼 炼 ˣy烌1ˣz烌0ġ )烑* k烌2.1 ǘ 104 M 2 s 1ġ )烒* k烌1.26 ǘ 104 M 2 min 1ġ )烓* k烌2.52 ǘ 104 M炼2 s炼1ġ )烔*䔞 [A]烌0.05 Mˣ[B]烌0.6 Mˣ[C]烌2.0 M 㗪炻B 䘬㴰便忇䌯䁢 9.45 ǘ 10炼7 M s炼1 ˤġ

100

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

!

1.ẍ㹜愠㟡暊⫸冯㹜暊⫸⛐愠ᷕ䘬⍵ㅱ炻Ἦ㍊妶⇅⥳㽫⹎冯⇅⥳⍵ㅱ忇䌯斄Ὢ䘬⮎槿ᷕ炻℞ ⍵ㅱ⺷⍲⮎槿㔠㒂⤪ᶳ烉 BrO3炼(aq)為5Br炼(aq)為6H為(aq) ɦ 3Br2(aq)為3H2O(") )ࡰԵ* ⍵ㅱ䈑⇅⥳㽫⹎ ⇅⥳⍵ㅱ 炷M炸 忇䌯 ⮎槿㫉㔠 炼 炼 為 M s炼1 [BrO3 ] [Br ] [H ] 炼4 1 0.10 0.10 0.10 8.0 ǘ 10 炼3 2 0.20 0.10 0.10 1.6 ǘ 10 炼3 3 0.20 0.20 0.10 3.2 ǘ 10 炼3 4 0.10 0.10 0.20 3.2 ǘ 10 5 0.40 0.30 0.20 r )烀*㬌⍵ㅱ䘬⍵ㅱ䷥䳂㔠䁢⣂⮹烎 )烁*妰䬿㬌⍵ㅱ䘬忇䌯ⷠ㔠ˤ )烂*枸㷔⮎槿䫔 5 㫉䘬⇅⥳⍵ㅱ忇䌯 rˤġ

2.⛐㝸⚢⭂㹓⹎炻⊾⬠⍵ㅱ I炼(aq)為OCl炼(aq) ї OI炼(aq)為Cl炼(aq)䘬⍵ㅱ䈑⇅⥳㽫⹎ˣ㹞㵚ᷕ䘬㯓㯏 暊⫸⇅⥳㽫⹎⍲⇅⥳忇䌯攻䘬斄Ὢ⤪ᶳ堐㇨䣢烉 )ࡰԵ*ġ OH炼 I炼 䘬⇅⥳㽫 OCl炼 䘬⇅⥳ ⮎槿 䘬⇅⥳ ⇅⥳忇䌯炷 ⹎ 㽫⹎ 䶐嘇 㽫⹎炷 mol L炼1 s炼1炸 炷M炸 炷M炸 M炸 炼3 炼3 1.00 1 1.8 ǘ 10炼4 1.5 ǘ 10 2 ǘ 10 2 1.00 4 ǘ 10炼3 3.6 ǘ 10炼4 1.5 ǘ 10炼3 炼3 炼3 3 2.00 2 ǘ 10 3 ǘ 10 1.8 ǘ 10炼4 1.00 4 4 ǘ 10炼3 3 ǘ 10炼3 7.2 ǘ 10炼4

炷ġ 炸)烀*ᶲ徘⊾⬠⍵ㅱ䘬忇䌯ⷠ㔠炷k炸䁢ỽ炷s炼1炸烎ġ )烐* k烌0.1ġ )烑* k烌6ġ )烒* k烌10ġ )烓* k烌60ġ )烔* k烌600ˤġ 炷ġ 炸)烁*劍⮎槿䶐嘇 1 䘬℞Ṿ㽫⹎ᶵ嬲炻⮯㹞㵚䘬愠渤ῤ嬲㚜䁢 pH烌13炻⍵ㅱ䘬⇅ ⥳忇䌯䁢ỽ炷mol L炼1 s炼1炸烎ġ )烐* 1.8 ǘ 10炼2ġ )烑* 1.8 ǘ 10炼3ġ )烒* 1.8 ǘ 10炼4ġ )烓* 1.8 ǘ 10炼5ġ )烔* 1.8 ǘ 10炼6ˤġ

101

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

!

1.⭂㹓ᶳ炻4HBr(g)為O2(g) ɦ 2H2O(g)為2Br2(g) ᷳ⮎槿㔠㒂⤪ᶳ烉 ⮎槿 HBr ᷳ↮⡻ O2 ᷳ↮⡻炷 ䷥⡻ᷳ嬲⊾忇䌯 䶐嘇 炷mmHg炸 mmHg炸 炷mmHg min炼1炸 A 20 30 36 B 40 30 72 C 60 60 216

炷ġ 炸)烀*娚⮎槿ᷕ䘬ˬ䷥⡻ᷳ嬲⊾忇䌯˭冯ˬBr2(g) ↮⡻⡆≈忇䌯˭ᷳ㭼ㅱ䁢⣂⮹烎ġ )烐* 1烉1ġ )烑* 1烉2ġ )烒* 3烉2ġ )烓* 2烉1ˤ 炷ġ 炸)烁*劍

烌kPHBrx PO2y炻℞ᷕ炷x為y炸䫱㕤ỽῤ烎ġ

)烐* 1ġ )烑* 2ġ )烒* 3ġ )烓* 4ˤ 炷ġ 炸)烂*㈧䫔)烁*柴ᷕᷳ k ῤ䁢ỽ烎ġ )烐* 6.0 ǘ 10炼2 mmHg炼1 min炼1ġ )烑* 6.0 ǘ 10炼2 mmHg炼2 min炼1ġ )烒* 2.0 ǘ 10炼3 mmHg炼2 min炼1ġ )烓* 2.0 ǘ 10炼3 mmHg炼3 min炼1ˤ 炷ġ 炸)烃*劍

烌k' PHBrx PO2y炻℞ᷕ k' ῤ冯䫔)烁*柴ᷕᷳ k ῤ䘬斄Ὢ䁢ỽ烎ġ

)烐* k'烌kġ )烑* k'烌2kġ )烒* k'烌

ġ )烓* k'烌4kˤġ

2.㕤 25 ɗ㗪炻⍵ㅱ A為B ɦ C為D ᷳ忇䌯ⷠ㔠 k 䘬╖ỵ䁢 M炼1 s炼1炻ᶳ↿ỽ侭⎗傥䁢㬌⍵ㅱ䘬 忇䌯㕡䦳⺷烎ġ )烐* r烌k[A]ġ )烑* r烌k[B]ġ )烒* r烌k[A][B]ġ )烓* r烌k[A]2ġ )烔* r烌k[B]2ˤ

3.⶚䞍 2A(g)為E(g) ɦ 2G(g) 䘬⍵ㅱ䷥䳂㔠䁢暞䳂ˤᶳ↿㔀徘ỽ侭㬋䡢烎ġ )烐* A 䘬㽫⹎⡆⣏⎗傥ἧ⍵ㅱ忇䌯㷃⮷ġ )烑*⡆⣏ E 䘬㽫⹎炻⽭ᶵ㚫ἧ⍵ㅱ忇䌯⡆≈ġ )烒*娚⍵ㅱ䘬忇䌯㕡䦳⺷⽭䁢 r烌k[A]0ġ )烓*㬌⍵ㅱ䘬忇䌯ᶵ⍿㹓⹎䘬⼙枧

4.⍵ㅱ忇䌯⭂⼳⺷ R=k[A] m [B] n炻䔞[A]ᶵ嬲炻[B]㷃䁢⍇Ἦ䘬

㗪炻R 嬲䁢⍇Ἦ䘬

炻

ᶼ k=120M Ͳ2 s Ͳ1炻⇯ mˣn ῤὅ㫉䁢?

102

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

1.⶚䞍⍵ㅱ 2A(g)為3B(g) 2C(g) ᷳ忇䌯㕡䦳⺷䁢 r烌k[A][B]2炻䔞 A 䁢 2 molˣB 䁢 1 mol 㗪炻⍵ ㅱ忇䌯䁢 r炻ᶳ↿㔀徘ỽ侭㬋䡢烎ġ )烐*⭂㹓ˣ⭂⭡ᶳ炻ℵ≈ℍ 2 mol A炻⇯忇䌯䁢 )烑*⭂㹓ᶳ炻ℵ≈ℍ 2 mol B炻᷎⮯橼䧵㒜⣏

ġ 炻⇯忇䌯䁢

ġ

)烒*⭂㹓ˣ⭂⭡ᶳ炻ℵ≈ℍ 3 mol He炻⇯忇䌯䁢 rġ )烓*⭂㹓ˣ⭂⡻ᶳ炻ℵ≈ℍ 3 mol He炻⇯忇䌯䁢

ġ

)烔*⭂㹓ˣ⭂⡻ᶳ炻ℵ≈ℍ 6 mol B炻⇯忇䌯䁢

2.㕤 N2(g)為3H2(g) 2NH3(g) ᷳ⍵ㅱᷕ炻⶚䞍 r烌k[N2][H2]炻姕 N2 䁢 4 卓俛ˣH2 䁢 1 卓俛炻 ⍵ㅱ忇䌯䁢 a炻⇯烉 )烀*⛐⭂㹓ˣ⭂⭡ᶳ炻≈ℍ 5 卓俛 Ne(g)炻㯪 r ῤ䁢ỽ烎 )烁*⛐⭂㹓ˣ⭂⡻ᶳ炻≈ℍ 5 卓俛 Ne(g)炻㯪 r ῤ䁢ỽ烎 )烂*⛐⭂㹓ˣ⭂⭡ᶳ炻≈ℍ 5 卓俛 N2(g)炻㯪 r ῤ䁢ỽ烎 )烃*⛐⭂㹓ˣ⭂⡻ᶳ炻≈ℍ 5 卓俛 N2(g)炻㯪 r ῤ䁢ỽ烎ġ

3.⊾⎰䈑 A(g) 冯 B(g) ⍵ㅱ䓇ㆸ C(g)炻℞⍵ㅱ⺷⤪ᶳ烉2A(g)為2B(g) ɦ 3C(g)炷⶚䞍㬌忇䌯䘬忇䌯㕡 䦳⺷⎗堐䣢䁢 r烌k[A]2[B]炸 ˤ䌳⎴⬠ Ḯℑ㫉⮎槿ˤ䫔ᶨ㫉⮯⊾⎰䈑 A(g) ⍲ B(g) ⎬ 0.1 卓俛伖 㕤ᶨᾳ 500 㮓⋯䘬⭡☐ᷕ⍵ㅱˤ⛐䚠⎴䘬㹓⹎ᶳ炻 䫔Ḵ㫉⮎槿炻⮯ 0.2 卓俛⊾⎰䈑 A(g) ⍲ 0.1 卓俛⊾⎰䈑 B(g) 伖㕤ᶨᾳ 1000 㮓⋯䘬⭡☐⍵ㅱˤ䫔Ḵ㫉⮎槿䘬⍵ㅱ⇅忇䌯䁢䫔ᶨ㫉䘬 ⸦᾵烎ġ )烐*

ġ )烑*

ġ )烒*

ġ )烓*ᶵ嬲ġ )烔* 2 )ࡰԵ*!

103

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

1.⍵ㅱ 5Br炼(aq)為BrO3炼(aq)為6H為(aq) ɦ 3Br2(")為3H2O(") ᷳ忇䌯㕡䦳⺷䁢 r烌k[Br炼][BrO3炼]炻劍 100 mL 䘬 1 M KBr 冯 100 mL 䘬 0.1 M KBrO3 ⍲ 6 M H2SO4 㶟⎰ᷳ⍵ㅱ⇅忇䌯䁢 sˤ㯪⎴㹓ᶳ炻 䔞⍵ㅱ军∑检䘬 [KBrO3] 䁢 0.03 M 㗪炻⍵ㅱ忇䌯䁢ỽ烎ġ )烐* 0.48sġ )烑* 0.21sġ )烒* 0.14sġ )烓* 0.12s

2.㝸⍵ㅱ㦥ℏ㚱 WˣXˣYˣZ ⚃䧖㯋橼炻℞↮⡻↮⇍䁢 100ˣ1ˣ10ˣ100 㮓䰛㰆㞙ˤ⤪㝄㬌 䲣䴙ᷕ㚱ᶳ↿ᶱᾳḴ䳂⍵ㅱ炷⮵⎬⍵ㅱ䈑䁢ᶨ䳂⍵ㅱ炸 炻℞⍵ㅱ忇䌯ⷠ㔠↮⇍䁢 kˣ0.5kˣ 0.01k烉)烀* W為X

䓚ġ )烁* W為Y

ḁġ )烂* 2W為Z

᷁ˤ⇯⛐⍵ㅱ

⇅㛇炻ỽ䧖䓊䈑㚨⣂烎ġ )烐*䓚ġ )烑*ḁġ )烒*᷁ġ )烓*䓚ḁ᷁ᶨ㧋⣂!

104

[卓㕗⇑檀ᷕ冒䃞䥹⬠] ➢䢶⊾⬠(ᶱ) 䫔Ḵ䪈 ⍵ㅱ忇䌯

΋ǵൂᒧᚒ Ȑ! ! ! ȑIJį⊾⎰䈑 A(g)冯 B(g)⍵ㅱ䓇ㆸ C(g)炻℞⍵ㅱ⺷⤪ᶳ烉2 A(g)為 2 B(g )ї 3 C(g)炷⶚䞍㬌⍵ㅱ䘬⍵ㅱ忇䌯 ˤ䌳⎴⬠ Ḯℑ㫉⮎槿ˤ䫔ᶨ㫉⮯⊾⎰䈑 A(g)⍲ B(g)⎬ 0.1 卓俛伖㕤ᶨ ⎗堐䣢䁢 r 烌 k [A] 2 [B]炸 ᾳ 500 㮓⋯䘬⭡☐ᷕ⍵ㅱˤ⛐䚠⎴䘬㹓⹎ᶳ炻 䫔Ḵ㫉⮎槿炻⮯ 0.2 卓俛䘬⊾⎰䈑 A(g)⍲ 0.1 卓俛䘬⊾⎰䈑 B(g)伖㕤ᶨᾳ 1000 㮓⋯䘬⭡☐ᷕ⍵ㅱˤ娎⓷䫔Ḵ㫉⮎槿䘬⍵ㅱ⇅忇䌯䁢䫔ᶨ㫉

1 1 1 䘬⸦᾵烎ġ (A) ġ (B) ġ (C) ġ (D)ᶵ嬲ġ (E)2ˤ 8 4 2 炷ġ ġ ġ 炸ijį⶚䞍 A(g)為B(g)oC(g)炻r烌kPAPBˤṲ⮯ B(g)䘬卓俛㔠≈᾵炻ᶼ㕤㹓⹎ᶵ嬲䘬ね㱩ᶳ炻⮯橼䧵㒜⣏䁢 ⍇Ἦ䘬

4 2 9 9 ᾵炻⇯⍵ㅱ忇䌯嬲䁢⍇Ἦ䘬劍⸚᾵烎ġ (A)2ġ (B) ġ (C) ġ (D) ˤ 3 3 8 16

炷ġ ġ ġ 炸Ĵį㝸⍵ㅱ䁢 aA為bBocC為dD炻℞⍵ㅱ忇䌯⭂⼳⺷ r烌k[A]m[B]n炻⇯ᶵ㚫⼙枧忇䌯ⷠ㔠 k 䘬⚈䳈䁢 ỽ烎ġ (A)⍵ㅱ䈑 AˣB ᷳ㛔⿏ġ (B)⍵ㅱ䈑 AˣB ᷳ㽫⹎ġ (C)䲣䴙ᷳ㹓⹎ġ (D)㚱䃉≈ℍ⁔⊾∹ˤ 炷ġ ġ ġ 炸ĵį⶚䞍 4HBr(g)為O2(g)o2H2O(g)為2Br2(g)䘬 r烌kPHBr PO2 炻℞⛐ 400ɗˣ䷥⡻ 1 atm 㗪⏓ 3 mol HBr ⍲ 1 mol O2 䘬⍵ㅱ忇䌯䁢 S炻⇯⛐⎴㹓ᶳ≈ℍ 8 mol He炻䵕㊩䷥⡻ 1 atm 㗪ᷳ⍵ㅱ忇䌯䁢ġ (A)Sġ (B)

1 1 1 Sġ (C) Sġ (D) Sˤ 3 4 9 炷ġ ġ ġ 炸Ķį⍵ㅱ 2A為4BoC ᷕ炻劍ảシ㗪⇣ A 䘬㽫⹎⮵㗪攻ἄ⚾⤪旬 ⚾㇨䣢炻⇯⯙⍵ㅱ䈑 A 侴妨炻℞⍵ㅱ䳂㔠䁢ġ (A)暞䳂ġ (B) ᶨ䳂ġ (C)Ḵ䳂ġ (D)䃉㱽㰢⭂ˤ 炷ġ ġ ġ 炸ķį⶚䞍㝸⍵ㅱ䘬⍵ㅱ忇䌯 r烌k[P]m[Q]n炻ᶼ k 䘬╖ỵ䁢 M 2s 炼

炼

1

炻䔞[P]ᶵ嬲㗪炻[Q]㷃䁢⍇Ἦ䘬ᶨ⋲炻r Ṏ嬲䁢⍇Ἦ䘬ᶨ⋲炻

⇯㔠⮵(m炻n)䘬ῤ䁢ġ (A)(2炻2)ġ (B)(1炻2)ġ (C)(2炻1)ġ (D)(1炻1)ˤ 炷ġ ġ ġ 炸ĸį⍵ㅱ 3X(g)為2Y(g)o4Z(g)䘬忇䌯⭂⼳䁢 r烌k[X]2[Y]炻姕⍫冯⍵ㅱ䘬 X(g)䁢 3 卓俛炻Y(g)䁢 2 卓俛㗪炻 ⍵ㅱ⇅忇䌯䁢 R烊劍⛐㹓⹎⍲䷥⡻≃䵕㊩ᶵ嬲䘬ね㱩ᶳ炻⍫冯⍵ㅱ䘬 X(g)⡆䁢 8 卓俛炻侴 Y(g) 䘬卓俛㔠ᶵ嬲炻⇯⍵ㅱ⇅忇䌯⮯䁢劍⸚烎ġ (A)

8 8 4 16 Rġ (B) Rġ (C) Rġ (D) Rˤ 3 9 9 3

炷ġ ġ ġ 炸Ĺį⍵ㅱ 2X(g)為2Y(g)oZ(g)䘬忇䌯⭂⼳䁢 r烌k[X]2[Y]炻劍⍵ㅱ䈑 X烌1 mol炻Y烌2 mol 㗪炻⍵ㅱ忇䌯䁢 r炻䎦劍㹓⹎⍲䷥⡻ᶵ嬲䘬ね㱩ᶳ炻⍵ㅱ䈑 X烌1 mol炻Y烌5 mol炻⇯⍵ㅱ忇䌯嬲䁢ġ (A)

5 rġ (B) 8

5 5 4 rġ (C) rġ (D) rˤ 16 2 25 炷ġ ġ ġ 炸ĺį⍵ㅱ烉2A(g)為B(g)oC(g)為D(g)炻℞⍵ㅱ忇䌯⭂⼳䁢 r烌k[A]2[B]炻℞ᷕ k 䁢忇䌯ⷠ㔠炻⇯ᶳ↿㔀徘 ỽ侭㬋䡢烎ġ (A)k ῤᶵ㚫晐⍵ㅱ䈑䘬㽫⹎侴嬲⊾ġ (B)A 䘬㽫⹎≈᾵炻℞Ṿ䘬䉨㱩䵕㊩ᶵ嬲炻⇯ ⍵ㅱ忇䌯≈᾵ġ (C)ᶲ徘䘬⍵ㅱ䁢Ḵ䳂⍵ㅱġ (D)ᶲ徘⍵ㅱ傥䘤䓇⽭⭂㓦䅙ˤ

105