P17-19

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Optical Properties of ZnO Nanoparticles Prepared by Chemical Method Rajesh Kumar

1 Meena* ,

Pragati

2 Fageria

and Neelu

3 Chouhan*

1,3Department

of Pure and Applied Chemistry, University of Kota, Kota-324005 2Department of Chemistry, University of Rajasthan, jaipur Corresponding Email Address: 1988rajeshmeena@gmail.com CHARACTERIZATION

INTRODUCTION

Scanning electron microscopy

Ø A simple and conventional method for the synthesis of the ZnO

(A)

Nanoparticles like Nanolotus and Nanoflakes for further these synthesized NPs using as a Photocatalyst in water splitting and organic pollutant degradation reactions.

ØThe structure and morphology of the formation of ZnO nanoparticles

A. FESEM image of ZnO Nanoparticles like Nanoflakes

like Nanolotus and Nanoflakes was evidenced by UV-Vis, X-ray diffraction, FTIR and energy-dispersive spectroscopy techniques. The size, shape of metal like Nanolotus and Nanoflakes nanoparticles was systematically investigated by SEM analysis.

(B)

Ø The photo response of the prepared samples has been explored by using a model reaction for Eco-friendly Hydrogen Production.

FTIR METHOD

B. FESEM image of ZnO Nanoparticles like Nanorods at 3h

C. FESEM image of ZnO Nanoparticles like Nanolotus at 5h UV-Vis DRS Plot CONCLUSIONS

The schematic diagram for preparation of Nanolotus ZnO nanoparticles

NaOH pH= 8

Stirring

Refluxing for 3h without Stirring

1h

At 60oC ZnO Nanoflakes

The schematic diagram for preparation of Nanoflakes ZnO nanoparticles

PL- Spectroscopy

ØThe conventional synthesis method and mechanism for the formation of the ZnO Nanoparticles like Nanolotus and Nanoflakes nanoparticles (NPs) using as a Photocatalyst in water splitting reaction for Eco-friendly Hydrogen Production. ØThe as synthesized samples ZnO NPs, using as a Photocatalyst in organic pollutant degradation reactions. ØFuture efforts are being directed toward other nanocamposite nanoparticles synthesis with longterm stability as well as the reactivity.

REFERENCES Acknowledgement We are thankful to the DST, New Delhi for funding through SERB wing And Prof. S.C. Ameta, Director, Pacific University, Udaipur, India., Prof. M. L. Kalra MLSU, Udaipur, India, Prof. Run-Shi Liu, NTU, Taipei, Taiwan, Prof. K. H. Chen, IAMS, Taiwan, Prof. ShuFen Hu, NTNU Taipei, Taiwan, for their valuable encouragements.

XRD Plot

EDS

References: [1] Yousefi R, Kamluddin B, 2012 Solid State Sciences 12 252-256. [2] Choi K, Kang T, Oh S G, 2012 Materials Letters 75 240-243. [3] Kim, S.; Choi, J. Electrochem. Commun. 2008, 10, 175-179. [4] Zhang, J.; Sun, L.; Liao, C.; Yan, C. Chem. Commun. 2002, 262-263.


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