AGROCHEMICALS Surfactants Everywhere
EXOLagroline
TM
TM EXOLagroline TM
INTRODUCTION PCC Exol SA was created by merge of PCC Exol SA and Surfactants Business Unit of PCC Rokita SA. The Company’s core scope of operation is the manufacture and sale of surfactants. The company is headquartered in Brzeg Dolny, where is located manufacturing unit of anionic and nonionic surfactants. Moreover, in 2011, there was start-up of new production unit of nonionic surfactants (ethoxylation plant) in Płock. The flexibility of production allows to offer a wide range of anionic and nonionic surfactants according to the current needs of our customers. As one of the leading manufacturers of chemical products, the company is continuing to undertake investment activities with using modern technologies and based on the principle of sustainable development. Our strategic investor is the German company PCC SE, which operates internationally in three divisions: Chemicals, Energy and Logistics. Today, more than 70 subsidiaries and associated companies working within the PCC Group employ about 2,500 staff in 16 countries. Group strategy is focused on growth and profitability in the core activities as well as on diversification into new segments. PCC GROUP (Poland)
Chemicals
PCC Consumer Products SA (Warsaw, Poland)
PCC Consumer Product Kosmet Sp. z o.o. (Brzeg Dolny Poland)
PCC Prodex Sp. z o.o. (Warsaw, Poland)
Navigator (Belarus)
Logistics
PCC Exol SA - Brzeg Dolny, Poland - Płock, Poland
PCC Rokita SA (Brzeg Dolny, Poland)
FZ „Czechowice” SA (Czechowice, Poland)
Kosmet Navigator JLtd. (Belarus)
Energy
Tensis Sp. z o.o. (Brzeg Dolny, Poland)
PCC Sytneza SA
PCC Chemax, Inc. (S.C.) (Piedmont, USA)
S.C. EURO URETHANE SRL
PCC Exol Kimya Sanayi (Turkey)
PCC Exol Philippines Inc.
PCC Consumer Products (Russia)
Surfactants offered by our company have very wide industrial applications. In addition to AGROCHEMICAL and household chemicals, personal care, textile industry, are widely used as wetting agents, emulsifiers, adiuvants in the paper industry, metallurgical and many others. Over the years, PCC Exol has developed core competencies in manufacturing specialty surfactants. We meet our customers’ needs with a unique and versatile product portfolio, a broad expertise in surfactants chemistry and a high degree of flexibility. Through intimate customer relationships and by maximising synergies of customers’ application experience and our chemistry knowledge, we continuously strive to offer tailor-made products and system solutions that contribute to your success. We are continuously expanding our product range with new surfactants, focusing on safe chemistry, friendly to people and environment. One of the most important goals of PCC Exol is to make agrochemical formulations more efficient for the mutual benefit of manufacturers, end-users on a lot of the world’s markets. PCC Exol. The solid platform of chemical business!
AGROLINE/02
EXOLagroline
TM
DIVERSITY OF FORMULATIONS EXOLagroline ™ is our proposition of products for applications in crop protecion. PCC Exol offers wide portfolio of additives for various agrochemical formulations. The following table shows the different product groups and their main applications by formulation type. Product group Alkyl Sulfates Alkylbenzene Sulfonates Alkyl Ether Sulfates Sulfosuccinates Fatty Amine Ethoxylates Nonylphenol Ethoxylates Fatty Alcohol Ethoxylates Sorbitan Esters Sorbitan Esters Ethoxylates EO/PO Alcohol Alkoxylates Castor Oil Ethoxylates EO/PO Block Copolymers
EC
SC
SE
EW
ME
OD
SL
WG
WP
RTU
GB
FS
EO
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Formulation codes: EC = Emulsifiable Concentrate
WG = Water Soluble Granules
SC = Suspension Concentrate
WP = Water Soluble Powders
SE = Suspo-Emulsion
RTU = Ready to Use
EW = Emulsion (Oil-in-Water)
GB = Granular Baits
ME = Microemulsion
FS = Flowable Suspension
OD = Oil Dispersion
EO = Emulsion Water in Oil
SL = Soluble Concentrate
Important information : Using products of Nonylphenol ethoxylates group is restricted by Directive 2003/53/EC effective from 17th January 2005. See the following website: http://eur-lex.europa.eu/LexUriServ/LexUriServ.do?uri=OJ:L:2003:178:0024:0027:en:PDF According to Regulation (EC) No. 1907/2006 (REACH), the manufacture or import of chemical substances in volumes exceeding 1 ton per year must be registered at the European Chemicals Agency (ECHA) in Helsinki. REACH registration is related to substances and not products, e.g. preparations/formulations of substances. Production, import and marketing of a REACH-substance will be restricted to those uses evaluated in its registration dossier. The REACH process starts with preregistration (1st June 2008 until 1st December 2008), which ensures the availability of preregistered substances to the registration date. The date of registration depends on the production volume of the substance and lies between 2010 and 2018. We confirm that we will, pursuant to REACH requirements, pre-register all substances manufactured by PCC EXOL SA Functional Chemicals Division in the EU or imported in the EU, that are relevant for the products listed in this brochure. However, no guarantee can be given that PCC EXOL SA will offer all listed products in the future. If REACH registration requirements lead to unacceptable costs, PCC Exol SA will contact its customers to find an appropriate solution.
AGROLINE/03
EXOLagroline
TM
ADIUVANTS DESCRIPTION Aforementioned enhancing biological performance of pesticides products are becoming more and more crucial in Crop Protection in order to optimize the amount of pesticide applied, improve handling and safety by applicators and consumers. Adiuvants are used to aid or modify the action of an agrochemical or its physical characteristics. In pesticides, they are often used for wetting, spreading, deposit building, emulsifying, deflocculating or water modifying. Adiuvants must be matched with the pesticides, the crop species, the weed species and the prevailing environment for maximum effectiveness.
Side view of leaf - without adiuvants
Side view of leaf - with adiuvants
Surfactants are adiuvants that reduce surface tension within the external surface layers of water. Surfactants work by improving contact between spray droplets and plant surfaces, and enhance absorption by: 1. Making the spray solution spread more uniformly on the plant 2. Increasing retention (or ‘sticking’) of spray droplets on the plant 3. Increasing penetration through hairs, scales, or other leaf surface structures 4. Preventing crystallization of spray deposits 5. Slowing drying and increasing water retention in the spray droplets BENEFITS • improving biological performance of a pesticides • enhancing penetration into a leaf or soil • improving rainfastness, spreader and sticker • reducing drift Adiuvants are already included in the formulations of some herbicides available for sale or they may be purchased separately and added into a tank mix prior to use. In this way adding an appropriate adiuvant can decrease the amount of herbicide applied and lower total costs for weed control.
AGROLINE/04
EXOLagroline
TM
ADIUVANTS - PRODUCT LIST Products group
Product characteristic
• •
•
CAS number
Ionic character
127087-87-0
N
Oily liquid
12.5
Nonylphenol + 9 EO
min. 99.0
48-56 A
61791-14-8
N
Liquid
15.5
Cocamine + 15 EO
min. 97.0
63-73 2)
•
9.8
Tallow Amine + 5.8 EO
min. 99.0
105-110 2)
•
12.4
Tallow Amine + 8 EO
min. 99.0
75-80 2)
•
12.5
Tallow Amine + 11 EO
min. 99.0
70-75 2)
•
min. 99.0
Physical form
HLB
Description
Fatty alcohol ethoxylates
LOXEmin C™
Fatty amine ethoxylates
LOXEnac 8™
Active content (%)
Nonylphenol ethoxylates
Adiuvant - leaf penetration aid Adiuvant - rainfastness aid Oil adiuvant emulsifier Adiuvant - spreading aid Spray retention aid Compatible with Glyphosate
Product
Cloud point [°C] Saponification value1) [mgKOH/g] Amine value2) [mgKOH/g] Hydroxyl value3) [mgKOH/g]
LOXEmin T5™
•
61791-26-2
N
Liquid/Semi-liquid paste
LOXEmin T8™
•
61791-26-2
N
Viscous liquid
LOXEmin T11™
•
61791-26-2
N
LOXEmin T15™ LOXEmin T25™ LOXEdin B13™ LOXEdin B15™ LOXEdin B17™ LOXEnit 13™ LOXEnit 15™ LOXEnit 16™ LOXEnit 17™ LOXEnit 18™
• •
61791-26-2
N
Liquid/Semi-liquid Paste Liquid/Paste
14.5
Tallow Amine + 15 EO
61791-26-2
N
Paste
16.1
Tallow Amine + 22 EO
min. 99.0
37-45 2)
68131-39-5
N
Liquid/Paste
7.8
Alcohols, C12-15 + 3 EO
min. 99.7
164-172 3)
68131-39-5
N
Liquid
10.2
Alcohols, C12-15 + 5 EO
min. 99.5
65-72 D
68131-39-5
N
Liquid/Paste
12.0
Alcohols, C12-15 + 7 EO
min. 99.5
100-114 3)
69011-36-5
N
Liquid
8.0
Alcohols, C13, branched + 3 EO
min. 99.0
48-51 D
• • • • • •
69011-36-5
N
Liquid
10.5
Alcohols, C13, branched + 5 EO
min. 99.5
60-62 E
69011-36-5
N
Liquid
11.4
Alcohols, C13, branched + 6 EO
min. 99.5
69-72 D
69011-36-5
N
Liquid
12.1
Alcohols, C13, branched + 7 EO
min. 99.0
65-70 E
69011-36-5
N
12.8
Alcohols, C13, branched + 8 EO
min. 99.5
76-78 D
•
69011-36-5
N
Liquid/Paste Oily liquid/ Paste
• • • • • • • •
13.2
Alcohols, C13, branched + 9 EO
min. 99.0
56-60 A
•
• • • • • • •
LOXEnit 19™
62
2)
• •
LOXEnit 12™
•
69011-36-5
N
Liquid/Paste
14.5
Alcohols, C13, branched + 12 EO
min. 99.0
79-85 A
•
LOXEnic C18™
•
9005-04-3
N
Paste/Wax
16.3
Alcohols, C16-18 unsaturated + 18 EO
min. 99.0
74-79 C
•
min. 99.5
74-79 C
•
LOXEnic C21™
•
LOXEnic 10™
•
9005-04-3
N
Paste/Wax
16.5
Alcohols, C16-18 unsaturated + 21 EO
68002-97-1
N
Liquid
10.0
Alcohols, C12-14 + 4 EO
min. 99.5
59-63 E
•
N
Liquid
11.6
Alcohols, C9-11 + 5 EO
min. 99.5
33-39 A
•
N
Liquid
12.5
Alcohols, C9-11 + 6 EO
min. 99.5
50-57 A
•
7.1
Alcohols, C16-18 unsaturated + 22 EO
min. 99.0
37-41 E
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16.3
Alcohols, C16-18 unsaturated + 18 EO
min. 99.0
70-74 C
•
LOXEnic 95™
• •
160901-09-7
LOXEnic 96™
• •
160901-09-7
LOXEnic 30™ LOXEnic 810™
• 9004-98-2 •
9004-98-2
N N
Liquid Paste
A 1 g in 100 g deionized water B 1 g in 100 g NaCl (50 g/l) C 1 g in 100 g NaCl (100 g/l) D 5 g in 45 g butyldiglycol 25% E 5 g in 25 g butyldiglycol 25%
AGROLINE/05
EXOLagroline
TM
WETTING AGENTS DESCRIPTION Wetting agents are substances that decrease the surface tension of water to permit it to spread drops onto a surface, increasing the spreading abilities of a liquid. Reducing the surface tension lowers the energy required to spread drops onto a film, thus weakening the cohesive properties of the liquid and strengthening its adhesive properties.
BENEFITS • enable wetting of dusty or hard to wet plants • decrease the surface tension of water, allowing spread and penetrate • allow reduction of spray volumes • greater or equal up-take of pesticide in shorter time, thus enhance rainfastness
AGROLINE/06
EXOLagroline
TM
WETTING AGENTS - PRODUCT LIST Product characteristic
Products group Alkyl ether sulfates Sulfosuccinates Sorbitan esters ethoxylates EO/PO alcohol alkoxylates Fatty alcohol ethoxylates Fatty amine ethoxylates Nonylphenol ethoxylates Castor oil ethoxylates EO/PO block copolymers Alkylbenzene sulfonates
Cloud point [°C] Cloud point [°C] Tanaka1) Saponification value2) [mgKOH/g] Amine value3) [mgKOH/g] Hydroxyl value4) [mgKOH/g]
CAS number
Ionic character
LOXEvul S50™
68411-30-3
A
Paste
–
LOXEmer 200™
9003-11-6
N
Liquid
2.4
PEG/PPG - Copolymer
min. 99.0
23-27 A
LOXEmer 260™
9003-11-6
N
Liquid
5.6
PEG/PPG - Copolymer
min. 99.0
33-37 E
8.1
PEG/PPG - Copolymer
min. 99.0
54-60 A
• •
Product
Physical form
HLB
Description
Active content (%)
Sodium Dodecylbenzene48-52 sulfonate
–
•
•
•
LOXEmer 80™
9003-11-6
N
Viscous liquid/ semi liquid paste
LOXEmer 16™
9003-11-6
N
Wax
16.6 PEG/PPG - Copolymer
min. 99.0
—
LOXEpor 11™
61791-12-6
N
6.9
Castor oil + 11 EO
min. 99.0
45-50 A
LOXEnac 3™
127087-87-0
N
8.0
Nonylphenol + 3 EO
min. 99.0
25-30 E
•
LOXEnac 4™
127087-87-0
N
8.9
Nonylphenol + 4 EO
min. 99.0
31-36 E
•
LOXEnac 8™
127087-87-0
N
12.5 Nonylphenol + 9 EO
min. 99.0
48-56 A
•
LOXEnac 9™
127087-87-0
N
12.8 Nonylphenol + 9 EO
min. 99.9
58-61 A
•
LOXEnac 10™
127087-87-0
N
13.3 Nonylphenol + 10 EO
min. 99.0
62-65 A
•
LOXEmin T8™
61791-26-2
N
Liquid Oily liquid Oily liquid Oily liquid Oily liquid Oily liquid Viscous liquid
12.4 Tallow Amine + 10 EO
min. 99.0
75-80 3)
•
LOXEmin T11™
61791-26-2
N
Liquid/Semi-liquid 12.5 Tallow Amine + 11 EO paste
min. 99.0
70-75 3)
•
LOXEnic 20™
68002-96-0
N
Liquid
min. 99.5
30-39 A
LOXEdin B13™
68131-39-5
N
LOXEdin B15™
68131-39-5
N
LOXEdin B17™
68131-39-5
N
LOXEdin BW17™
68131-39-5
N
LOXEdin 50™
68439-45-2
N
Liquid/ Paste Liquid Liquid/ Paste Oily liquid Liquid
LOXEdin 70™
68439-45-2
N
LOXEdin 80™
68439-45-2
N
LOXEnit 13™
69011-36-5
N
Liquid
LOXEnit 15™
69011-36-5
N
Liquid
LOXEnit 16™
69011-36-5
N
Liquid
LOXEnit 17™
69011-36-5
N
LOXEnit W17™
69011-36-5
N
LOXEnit 18™
69011-36-5
N
LOXEnit 19™
69011-36-5
N
6.7
Alcohols, C16-18 + EO/PO
7.8
Alcohols, C12-15 + 3 EO min. 99.7
•
•
164-172 4)
•
10.5 Alcohols, C12-15 + 5 EO min. 99.5
65-72 D
•
12.0 Alcohols, C12-15 + 7 EO min. 99.5
100-114 4)
•
12.0 Alcohols, C12-15 + 7 EO 90-93
48-52 A
•
11.7 Alcohols, C10 + 5 EO
min. 99.5
66-69 E
•
Liquid
13.2 Alcohols, C10 + 7 EO
min. 99.5
56-62 A
•
Liquid
13.8 Alcohols, C10 + 8 EO Alcohols, C13, branched 8.0 + 3 EO Alcohols, C13, branched 10.5 + 5 EO
min. 99.5
65-68 A
•
min. 99.0
48-51 D
•
min. 99.5
60-62 E
•
min. 99.5
69-72 D
•
min. 99.0
65-70 E
•
89-91
65-70 E
•
min. 99.5
76-78 D
•
min. 99
56-60 A
•
11.4
Alcohols, C13, branched + 6 EO
Alcohols, C13, branched + 7 EO Alcohols, C13, branched Liquid 12.1 + 7 EO Liquid/ Alcohols, C13, branched 12.8 Paste + 8 EO Alcohols, C13, branched Oily liquid/ 13.3 Paste + 9 EO Liquid
12.1
AGROLINE/07
EXOLagroline
TM
WETTING AGENTS - PRODUCT LIST Product characteristic
Ionic character
LOXEnit 12™
69011-36-5
N
LOXEnic C5™
9005-04-3
N
LOXEnic C7™
9005-04-3
N
LOXEnic 10™
68002-97-1
N
Liquid/ Paste Liquid/ Paste Semi-liquid paste Liquid
LOXEpal 9™
68439-51-0
N
Liquid
LOXEpal 10™
68439-51-0
N
Liquid
LOXEnic 63™
68439-50-9
N
LOXEnic 80™
68002-97-1
N
Liquid Liquid/ Paste
LOXEpal 10™
68439-51-0
N
Liquid
6.0
LOXEpal 8™
37251-67-5
N
Liquid
6.3
LOXEpal 18™
68551-13-3
N
Liquid
3.5
LOXEnic 93™
68439-46-3
N
Liquid
8.5
LOXEnic 95™
160901-09-7
N
Liquid
LOXEnic 96™
160901-09-7
N
Liquid
LOXEnic 98™
160901-09-7
N
LOXEpal 12™
154518-36-2
N
LOXEnic 30™
9004-98-2
LOXEnic 12™
Physical form
HLB
14.5 9.2 10.8
Active content (%)
Cloud point [°C] Cloud point [°C] Tanaka1) Saponification value2) [mgKOH/g] Amine value3) [mgKOH/g] Hydroxyl value4) [mgKOH/g]
min. 99.5
79-85 A
•
min. 99.0
7.0-8.5 1)
•
min. 99.5
9.0-10.5 1)
•
min. 99.5
59-63 E
•
min. 99.5
98-108
min. 99.5
27-31 A
min. 99.9
192-204 4)
•
Alcohols, C12-14 + 3 EO min. 99.8
165-173 4)
•
Description
Alcohols, C13, branched + 12 EO Alcohols, C16-18 unsaturated + 5 EO Alcohols, C16-18 unsaturated + 7 EO
10.0 Alcohols, C12-14 + 4 EO Alcohols, C12-14 5.3 + EO/PO Alcohols, C12-14 6.0 + EO/PO 6.2 Alcohols, C12-14 + 2 EO 7.8
Alcohols, C12-14 + EO/PO Alcohols, C10 + EO/PO Alcohols, C12-14 + EO/PO Alcohols, C9-11 + 3 EO
Alkyl ether sulfates Sulfosuccinates Sorbitan esters ethoxylates EO/PO alcohol alkoxylates Fatty alcohol ethoxylates Fatty amine ethoxylates Nonylphenol ethoxylates Castor oil ethoxylates EO/PO block copolymers Alkylbenzene sulfonates
CAS number
Product
Products group
•
4)
•
min. 99.5
25-31 A
•
min. 99.5
20-24 A
•
min. 99.5
25-29 E
•
min. 99.8
185-193 4)
•
11.6 Alcohols, C9-11 + 5 EO
min. 99.5
33-39 A
•
12.5 Alcohols, C9-11 + 6 EO
min. 99.5
50-57 A
•
Liquid
15.7 Alcohols, C9-11 + 8 EO
min. 99.5
78-85 A
•
Liquid
9.5
min. 99.0
38-48 A
N
Liquid
7.1
min. 99.0
37-41 E
•
68439-49-6
N
Wax
13.5
min. 99.5
85-100 A
•
LOXEnic 511™
127036-24-2
N
Liquid
11.0
min. 99.5
60-65 E
•
LOXEnic 711™
127036-24-2
N
Liquid
12.3
min. 99.0
51-56 A
•
LOXEbit S20™
9005-67-8
N
Liquid/ Paste
14.9
min. 99.0
45-55 2)
•
min. 99.0
45-55 2)
•
min. 60.0
—
25-27
—
•
68-72
—
•
26-28
—
•
68-72
—
•
Alcohols, C9-11 + EO/PO Alcohols, C16-18 unsaturated + 3 EO Alcohols, C16-18 + 12 EO Alcohols, C11, branched + 5 EO Alcohols, C11, branched + 7 EO Sorbitan Monostearate + 20 EO
LOXEbit O20™
9005-65-6
N
Liquid/SeSorbitan Monooleate mi-liquid 15.0 + 20 EO paste
LOXEvul BD™
577-11-7
A
Liquid
—
LOXEvul 20™
68891-38-3
A
Viscous liquid
—
LOXEvul 25™
68891-38-3
A
Paste/ Liquid gel
—
LOXEvul 30™
125301-92-0
A
Liquid
—
LOXEvul 35™
13150-00-0
A
Paste/ Liquid gel
—
Di (2-ethylhexyl)
Sulfosuccinic acid, sodium salt
Sodium Laureth Sulfate + 2 EO Sodium Laureth Sulfate + 2 EO Sodium Pareth Sulfate + 3 EO Sodium Laureth Sulfate + 3 EO
A 1 g in 100 g deionized water
D 5 g in 45 g butyldiglycol 25%
B 1 g in 100 g NaCl (50 g/l)
E 5 g in 25 g butyldiglycol 25%
C 1 g in 100 g NaCl (100 g/l)
AGROLINE/08
•
•
EXOLagroline
TM
EMULSIFIERS DESCRIPTION Agents that promote the formation of an emulsion. An emulsifier involves water soluble hydrophilic parts and oil-soluble lipophilic parts within its. Adding an emulsifier to a mixture of water and oil, the emulsifier is arranged on the interface, anchoring its hydrophilic part into water and its lipophilic part into oil. On the interface surface of water, the hydrophilic part and the lipophilic part are adsorbed and arranged around the interface. It reduces interfacial tension. The result is that oil and water is easily mixed. The hydrophilicity and lipophilicity are different among emulsifiers, and the balance between the two is called HLB value (ranges from 0 to 40). An emulsifier with higher lipophilicity shows a lower HLB whereas higher hydrophilicity has high HLB.
W/O
Low HLB surfactants
O/W
High HLB surfactants
BENEFITS • enable wetting and dispersion of the oil phase into the aqueous phase by decreasing interfacial tension • facilitate dispersion of the oil-phase upon addition into water • introduce electrostatic and steric stabilization to the fine droplets; preventing coalescence or flocculation • improve compatibility with other components in the aqueous phase
AGROLINE/09
EXOLagroline
TM
EMULSIFIERS - PRODUCT LIST Product characteristic
LOXEvul S50™
CAS number
68411-30-3
Ionic character
A
Physical form
Paste
HLB
Description
—
Sodium Dodecylbenzenesulfonate
Active content (%)
48-52
Cloud point [°C] Cloud point [°C] Tanaka1) Saponification value2) [mgKOH/g] Amine value3) [mgKOH/g] Hydroxyl value4) [mgKOH/g] —
Sulfosuccinates Sorbitan esters ethoxylates EO/PO alcohol alkoxylates Fatty alcohol ethoxylates Fatty amine ethoxylates EO/PO nonylphenol alkoxylates Nonylphenol ethoxylates Castor oil ethoxylates EO/PO block copolymers Alkylbenzene sulfonates
Product
Products group
•
LOXEmer 200™
9003-11-6
N
Liquid
2.4
PEG/PPG - Copolymer
min. 99.0
23-27 A
•
LOXEmer 260™
9003-11-6
N
Liquid
5.6
PEG/PPG - Copolymer
min. 99.0
16-20 A
•
LOXEmer 80™
9003-11-6
N
4.9
PEG/PPG - Copolymer
min. 99.0
21-26 A
•
LOXEmer 16™
9003-11-6
N
8.1
PEG/PPG - Copolymer
min. 99.0
54-60 A
•
LOXEmer 20™
9003-11-6
N
Wax
16.6 PEG/PPG - Copolymer
min. 99.0
—
•
Viscous liquid Viscous liquid/ Semi liquid paste
2)
•
LOXEpor O™
9004-96-0
N
Liquid
10.6 Oleate + 7 EO
min. 99.0
86-96
LOXEpor 11™
61791-12-6
N
Liquid
6.9
Castor oil + 11 EO
min. 99.0
45-50 A
•
2)
•
LOXEpor 26™
61791-12-6
N
Liquid
11.0 Castor oil + 26 EO
min. 99.5
74-82
LOXEpor 40™
61791-12-6
N
Paste
13.0 Castor oil + 40 EO
min. 99.0
55-64 2)
•
LOXEpor 70™
61791-12-6
N
Paste
15.4 Castor oil + 70 EO
min. 99.0
40-45
2)
•
LOXEpor 50™
61791-12-6
N
Solid
18.5 Castor oil + 250 EO
min. 99.0
65-70 C
•
LOXEpor 17™
70914-02-2
N
Oily liquid
min. 99.0
90-110 2)
•
LOXEpor 7™
9004-99-3
N
Paste
10.6 Stearate + 7 EO
min. 99.0
92-97
2)
•
LOXEpor 24™
9004-99-3
N
Wax
15.8 Stearate + 24 EO
min. 99.0
40-45
2)
•
8.8
Nonylphenol + 4 EO
min. 99.0
31-36 E
•
10.0 Nonylphenol + 5 EO
min. 99.0
48-52 E
•
11.0 Nonylphenol + 6 EO
min. 99.0
60-65 E
•
5.2
min. 99.0
17-20 A
12.5 Nonylphenol + 9 EO
min. 99.0
48-56 A
•
12.8 Nonylphenol + 9 EO
min. 99.9
58-61 A
•
13.3 Nonylphenol + 10 EO
min. 99.0
62-65 A
•
15.0 Nonylphenol + 15 EO
min. 99.0
60-65 C
•
16.2 Nonylphenol + 22 EO
min. 99.0
71-76 C
•
Oily liquid Oily liquid Oily liquid Oily liquid Oily liquid Oily liquid Oily liquid Semi-liquid Paste Paste/ Wax
—
Rape oil + 17 EO
LOXEnac 4™
127087-87-0
N
LOXEnac 5™
127087-87-0
N
LOXEnac 6™
127087-87-0
N
LOXEnac P10™
37251-69-7
N
LOXEnac 8™
127087-87-0
N
LOXEnac 9™
127087-87-0
N
LOXEnac 10™
127087-87-0
N
LOXEnac 14™
127087-87-0
N
LOXEnac 22™
127087-87-0
N
LOXEnac 52™
127087-87-0
N
Liquid
16.2 Nonylphenol + 22 EO
25-26.5
71-76 C
•
LOXEnac 100™
127087-87-0
N
Liquid
17.8 Nonylphenol + 30 EO
69-71
73-79 C
•
LOXEnac 40™
127087-87-0
N
Wax
17.8 Nonylphenol + 40 EO
min. 99.0
72-76 C
•
LOXEmin C™
61791-14-8
N
Liquid
15.5 Cocamine + 15 EO
min. 97.0
63-73 3)
min. 99.0
30-39 A
LOXEnic 20™
68002-96-0
N
Liquid
6.7
Nonylphenol + EO/PO
Alcohols, C16-18 + EO/PO
AGROLINE/10
•
• •
EXOLagroline
TM
EMULSIFIERS - PRODUCT LIST Product characteristic
Physical form
HLB
LOXEdin 15™
68002-97-1
N
Liquid
11.9
LOXEdin 17™
68002-97-1
N
Liquid
13.1
LOXEdin B13™
68131-39-5
N
Liquid/ Paste
7.8
LOXEdin B15™
68131-39-5
N
Liquid
10.2
LOXEdin B17™
68131-39-5
N
LOXEdin BW17™
68131-39-5
N
Liquid/ Paste Oily liquid
12.0 12.0
Active content (%)
Cloud point [°C] Cloud point [°C] Tanaka1) Saponification value2) [mgKOH/g] Amine value3) [mgKOH/g] Hydroxyl value4) [mgKOH/g]
min. 99.5
40-43 A
•
min. 99.5
73-76 A
•
min. 99.7
164-172 4)
•
min. 99.5
65-72 D
•
min. 99.5
100-114 4)
•
90-93
48-52 A
•
88-92
60-64 C
•
Description
Alcohols, C10-16 + 5 EO Alcohols, C10-16 + 7 EO Alcohols, C12-15 + 3 EO Alcohols, C12-15 + 5 EO Alcohols, C12-15 + 7 EO Alcohols, C12-15 + 7 EO
Sulfosuccinates Sorbitan esters ethoxylates EO/PO alcohol alkoxylates Fatty alcohol ethoxylates Fatty amine ethoxylates EO/PO nonylphenol alkoxylates Nonylphenol ethoxylates Castor oil ethoxylates EO/PO block copolymers Alkylbenzene sulfonates
Product
Ionic chaCAS number racter
Products group
LOXEdin BW11™
68131-39-5
N
Oily liquid/ Paste
LOXEdin 70™
68439-45-2
N
Liquid
13.2 Alcohols, C10- + 7 EO
min. 99.5
56-62 A
•
LOXEdin 80™
68439-45-2
N
Liquid
13.8 Alcohols, C10- + 8 EO
min. 99.5
65-68 A
•
min. 99.0
48-51 D
•
min. 99.5
60-62 E
•
min. 99.5
69-72 D
•
min. 99.0
65-70 E
•
89-91
65-70 E
•
min. 99.5
76-78 D
•
min. 99.0
56-60 A
•
89-92
58-62 A
•
min. 99.0
79-85 A
•
min. 99.0
4.2-5.1 1)
•
min. 99.0
7.0-8.5 1)
•
min. 99.0
74-79 C
•
min. 99.5
74-79 C
•
min. 99.7
53-55 E
•
min. 99.5
59-63 E
•
min. 99.5
98-108 4)
•
min. 99.5
27-31 A
•
13.6
LOXEnit 13™
69011-36-5
N
Liquid
8.0
LOXEnit 15™
69011-36-5
N
Liquid
10.5
LOXEnit 16™
69011-36-5
N
Liquid
11.4
LOXEnit 17™
69011-36-5
N
Liquid
12.1
LOXEnit W17™
69011-36-5
N
Liquid
12.1
LOXEnit 18™
69011-36-5
N
LOXEnit 19™
69011-36-5
N
LOXEnit W19™
69011-36-5
N
Liquid
LOXEnit 12™
69011-36-5
N
Liquid/ Paste Semi-liquid paste
Liquid/ Paste Oily liquid/ Paste
LOXEnic 12™
68920-66-1
N
LOXEnic C5™
9005-04-3
N
LOXEnic C18™
9005-04-3
N
LOXEnic C21™
9005-04-3
N
LOXEnic A80™
68551-12-2
N
Liquid
LOXEnic 10™
68002-97-1
N
Liquid
LOXEpal 9™
68439-51-0
N
Liquid
LOXEpal 10™
68439-51-0
N
Liquid
Liquid/ Paste Paste/ Wax Paste/ Wax
12.8 13.2
Alcohols, C12-15 + 11 EO
Alcohols, C13, branched + 3 EO Alcohols, C13, branched + 5 EO Alcohols, C13, branched + 6 EO Alcohols, C13, branched + 7 EO Alcohols, C13, branched + 7 EO Alcohols, C13, branched + 8 EO Alcohols, C13, branched + 9 EO
Alcohols, C13, branched + 9 EO Alcohols, C13, 14.5 branched + 12 EO 13.2
7.0
Alcohols, C16-18 unsaturated + 3 EO
Alcohols, C16-18 unsaturated + 5 EO Alcohols, C16-18 16.3 unsaturated + 18 EO Alcohols, C16-18 16.5 unsaturated + 21 EO Alcohols, C12-16 8.0 + 3 EO Alcohols, C12-14 10.0 + 4 EO Alcohols, C12-14 5.3 + EO/PO Alcohols, C12-14 6.0 + EO/PO 9.2
AGROLINE/11
EXOLagroline
TM
EMULSIFIERS - PRODUCT LIST Product characteristic
CAS number
Ionic character
Physical form
HLB
12.3
LOXEnic 129™
68002-97-1
N
Liquid
LOXEnic W129™
68002-97-1
N
Liquid
LOXEnic W138™
6540-99-4
N
Paste
LOXEnic 80™
68002-97-1
N
Liquid/ Paste
LOXEpal 10™
68439-51-0
N
Liquid
LOXEpal 8™
37251-67-5
N
Liquid
6.3
LOXEpal 18™
68551-13-3
N
Liquid
3.5
LOXEpal 12™
154518-36-2
N
Liquid
9.5
LOXEnic 30™
9004-98-2
N
Liquid
7.1
LOXEnic 810™
9004-98-2
N
Paste
16.3
LOXEnic 200™
9004-98-2
N
Paste
16.3
LOXEnic 100™
9004-98-2
N
Wax
18.8
LOXEnic 6™
68439-49-6
N
Wax
10.0
LOXEEnic 10™
68439-49-6
N
Wax
13.0
LOXEnic 12™
68439-49-6
N
Wax
13.5
LOXEnic 18™
68439-49-6
N
Wax
16.3
LOXEnic 511™
127036-24-2
N
Liquid
11.0
LOXEnic 711™
127036-24-2
N
Liquid
12.3
LOXEbit S™
1338-41-6
N
LOXEbit O™
1338-43-8
N
LOXEbit S20™
9005-67-8
N
LOXEbit O20™
9005-65-6
N
LOXEvul BD™
577-11-7
EXOemul A60™ EXOemul A70™
Solid wax Oily liquid Liquid/ Paste
Active content (%)
Cloud point [°C] Cloud point [°C] Tanaka1) Saponification value2) [mgKOH/g] Amine value3) [mgKOH/g] Hydroxyl value4) [mgKOH/g]
min. 99.5
30-40 C
•
89-92
30-40 C
•
min. 99.7
59-63 C
•
min. 99.7
165-173 4)
•
min. 99.5
25-31 A
•
min. 99.5
20-24 A
•
min. 99.5
25-29 E
•
min. 99.0
38-48 A
•
min. 99.0
37-41 E
•
min. 99.0
70-74 C
•
min. 99.0
71-76 C
•
min. 99.0
—
•
min. 99.5
105-115 4)
•
min. 99.5
85-95 4)
•
min. 99.5
85-100 A
•
min. 99.0
74-77 C
•
min. 99.5
60-65 E
•
min. 99.0
51-56 A
•
Description
Alcohols, C12-14 + 7 EO Alcohols, C12-14 12.3 + 7 EO Alcohols, C12-14 13.8 + 10 EO Alcohols, C12-14 7.8 + 3 EO Alcohols, C12-14 6.0 + EO/PO Alcohols, C10 + EO/PO Alcohols, C12-15 + EO/PO Alcohols, C9-11 + EO/PO Alcohols, C16-18 unsaturated + 3 EO Alcohols, C16-18 unsaturated + 18 EO Alcohols, C16-18 unsaturated + 20 EO Alcohol, C16-18 unsaturated + 100 EO Alcohols, C16-18 + 6 EO Alcohols, C16-18 + 10 EO Alcohols, C16-18 + 12 EO Alcohols, C16-18 + 22 EO Alcohols, C11, branched + 5 EO Alcohols, C11, branched + 7 EO
Sulfosuccinates Sorbitan esters EO/PO alcohol alkoxylates Fatty alcohol ethoxylates Fatty amine ethoxylates EO/PO nonylphenol alkoxylates Nonylphenol ethoxylates Castor oil ethoxylates EO/PO block copolymers Alkylbenzene sulfonates
Product
Products group
4.7
Sorbitan Monostearate
min. 98.5
145-160 2)
•
4.3
Sorbitan Monooleate
min. 98.5
145-170 2)
•
14.9
Sorbitan Monostearate + 20 EO
min. 99.0
45-55 2)
•
Liquid/ Semi-liquid paste
15.0
Sorbitan Monooleate + 20 EO
min. 99.0
45-55 2)
•
A
Liquid
—
min. 60.0
—
mixture
A
Liquid
—
min. 60.0
—
•
mixture
A
Liquid
—
min. 70.0
—
•
Di (2-ethylhexyl) Sulfosuccinic acid, sodium salt CaDDBS in 2-ethylhexanol CaDDBS in n-butanol
A 1 g in 100 g deionized water
D 5 g in 45 g butyldiglycol 25%
B 1 g in 100 g NaCl (50 g/l)
E 5 g in 25 g butyldiglycol 25%
C 1 g in 100 g NaCl (100 g/l)
AGROLINE/12
•
EXOLagroline
TM
LOW FOAMING AGENTS DESCRIPTION This group of surfactants has high-performance and show excellent low foam characteristics (inhibits bubbles forming in an agitated liquid by reducing the surface tension), chemical stability and a long list of other valuable performance properties. They are made by polymerizing ethylene oxide (EO), propylene oxide (PO) in the same molecule. The ratio and order of oxide addition, together with the choice of initiator, regulate the chemical and physical properties.
BENEFITS • prevent formation of foam • combination of low foaming properties with other functions (wetting, emulsifying)
AGROLINE/13
EXOLagroline
TM
LOW FOAMING AGENTS - PRODUCT LIST Products group
Product characteristic
Ionic character
Physical form
HLB
Description
Active content (%)
EO/PO alcohol alkoxylates
CAS number
EO/PO block copolymers
Product
Cloud point [°C] Saponification value1) [mgKOH/g] Hydroxyl value2) [mgKOH/g]
LOXEmer 200™
9003-11-6
N
Liquid
2.4
PEG/PPG- Copolymer
min. 99.0
23-27 A
•
LOXEmer 260™
9003-11-6
N
Liquid
5.6
PEG/PPG-Copolymer
min. 99.0
16-20 A
•
LOXEmer 80™
9003-11-6
N
Viscous liquid
4.9
PEG/PPG-Copolymer
min. 99.0
21-26 A
•
LOXEmer 16™
9003-11-6
N
Viscous liquid/Semi liquid paste
8.1
PEG/PPG-Copolymer
min. 99.0
54-60 A
•
LOXEmer 20™
9003-11-6
N
Wax
16.6
PEG/PPG-Copolymer
min. 99.0
—
•
LOXEpal 9™
68439-51-0
N
Liquid
5.3
Alcohols, C12-14 + EO/PO
min. 99.5
98-108 2)
•
LOXEpal 10™
68439-51-0
N
Liquid
6.0
Alcohols, C12-14 + EO/PO
min. 99.5
27-31 A
•
LOXEpal 10™
68439-51-0
N
Liquid
6.0
Alcohols, C12-14 + EO/PO
min. 99.5
25-31 A
•
LOXEpal 8™
37251-67-5
N
Liquid
6.3
Alcohols, C10 + EO/PO
min. 99.5
20-24 A
•
LOXEpal 18™
68551-13-3
N
Liquid
3.5
Alcohols, C12-14 + EO/PO
min. 99.5
25-29 E
•
LOXEpal 12™
154518-36-2
N
Liquid
9.5
Alcohols, C9-11 + EO/PO
min. 99.0
38-48 A
•
LOXEpal 15™
68002-96-0
N
Liquid
—
Alcohols, C16-18 + EO/PO
min. 99.0
23-27 E
•
A 1 g in 100 g deionized water B 1 g in 100 g NaCl (50 g/l) C 1 g in 100 g NaCl (100 g/l) D 5 g in 45 g butyldiglycol 25% E 5 g in 25 g butyldiglycol 25%
AGROLINE/14
EXOLagroline
TM
OTHER PRODUCTS Product characteristic
LOXEvul LS™
LOXEvul A™
LOXEmin T25™
Functions
CAS number
This is a high active anionic surfactant used in a variety of 85586-07-8 agricultural delivery systems Providing excellent compatibility with other anionic, 85536-14-7 amphoteric and nonionic surfactants Good leaf penetrant for herbicides such as glyphosate, 61791-26-2 electrolyte tolerant surfactant
Ionic character
Physical form
HLB
A
Liquid
—
Sodium Lauryl 27.5-30 Sulfate
—
A
Liquid
—
Dodecylbenzene Sulfonic Acid
min. 96.0
—
N
Paste
16.1
Tallow Amine + 25 EO
min. 99.0
37-45 3)
min. 99.0
60-62 E
•
min. 99.0
4.2-5.1 1)
•
min. 99.0
70-74 C
•
min. 99.0
71-76 C
•
min. 99.0
—
•
min. 99.5
98-108 4)
•
min. 99.5
27-31 A
•
min. 99.5
25-31 A
•
min. 99.5
20-24 A
•
min. 99.5
25-29 E
•
min. 99.5
70-73 D
min. 99.0
92-97 2)
•
min. 99.0
40-45 2)
•
LOXEnit 15™
Spreading aid
69011-36-5
N
Liquid 10.5
LOXEnic 12™
Co-emulsifier
9005-04-03
N
Semi-liquid paste
7.0
LOXEnic 810™
Aqueous dispersant
9004-98-2
N
Paste
16.3
LOXEnic 200™
Aqueous dispersant
9004-98-2
N
Paste
16.3
LOXEnic 100™
Aqueous dispersant
9004-98-2
N
Wax
18.8
LOXEpal 9™
Spreaders improved fluidity
68439-51-0
N
Liquid
5.3
LOXEpal 10™
Spreaders improved fluidity
68439-51-0
N
Liquid
6.0
LOXEpal 10™
Spreaders improved fluidity
68439-51-0
N
Liquid
6.0
LOXEpal 8™
Spreaders improved fluidity
37251-67-5
N
Liquid
6.3
LOXEpal 18™
Spreaders improved fluidity
68551-13-3
N
Liquid
3.5
LOXEnic 10™
Compatibility agent
68439-49-6
N
Wax
11.7
LOXEpor 7™
Solubilizer
9004-99-3
N
Paste
10.6
LOXEpor 24™
Solubilizer
9004-99-3
N
Wax
15.8
A 1 g in 100 g deionized water B 1 g in 100 g NaCl (50 g/l) C 1 g in 100 g NaCl (100 g/l) D 5 g in 45 g butyldiglycol 25% E 5 g in 25 g butyldiglycol 25%
AGROLINE/15
Description
Alcohols, C13 + 5 EO Alcohols, C1618 unsaturated + 3 EO Alcohols, C1618 unsaturated + 18 EO Alcohols, C1618 unsaturated + 18 EO Alcohol, C1618 unsaturated + 100 EO Alcohols, C1214 + EO/PO Alcohols, C1214 + EO/PO Alcohols, C1214 + EO/PO Alcohols, C10 + EO/PO Alcohols, C1214 + EO/PO Alcohols, C1618 + 10 EO Stearate + 7 EO Stearate + 24 EO
Active content (%)
Castor oil ethoxylates EO/PO alcohol alkoxylates Fatty alcohol ethoxylates Fatty amine ethoxylates Alkylbenzene sulfonates Alkyl sulfates
Product
Products group Cloud point [°C] Cloud point [°C] Tanaka 1) Saponification value2) [mgKOH/g] Amine value3) [mgKOH/g] Hydroxyl value4) [mgKOH/g]
•
•
•
•
EXOLagroline
TM
PARAMETERS DESCRIPTION HLB (Hydrophilic - Lipophilic Balance) HLB is a parameter defining the ratio of the content of the hydrophilic and hydrophobic group of the molecule. The HLB range for non-ionic surfactants is between 0 and 20 and expresses the percentage of the hydrophilic part of the molecule. HLB by Griffin: weight of hydrophilic part HLB=20 * molecular molecular weight of the product
HLB for ester-type compounds (ethoxylated fatty acids):
HLB=20 * (1 - SV ) AV where: SV - saponification value of the product of ethoxylation in mgKOH/g AV - acid value of acids subjected to ethoxylation in mgKOH/g
The table shows indicative values of required HLB`s for the most common applications HLB value
Surfactants properties
0-3
anti-foaming agent
4-6
W/O (water in oil) emulsifier
7-9
wetting agent
8-18
O/W (oil in water) emulsifier
13-15
detergents
> 15
solubilizer or hydrotrope
Cloud point An indicator determining the behaviour of nonionic surfactants (obtained in the process of condensation with ethylene oxide) in water or in mixtures consisting of water and organic solvents. In water or in mixtures of water and organic solvents, solutions of surfactants become cloudy at certain temperature when heated. The process is reversible and the substance becomes clear when cooled is referred to as the cloud point. Depending on the temperature at which the solution becomes cloudy, there are five methods of determination of cloud point: Method A – aqueous solution (10-90°C) Method B – 50 g/l NaCl solution (>90°C) Method C – 100 g/l NaCl solution (>90°C) Method D – 5 g + 45 g of 25% butyldiglycol / aqueous solution (<10°C) Method E – 5 g + 25 g of 25% butyldiglycol / aqueous solution (<10°C)
AGROLINE/16
EXOLagroline
TM
Amine value Reflects the amount of hydrochloric acid (HCl) necessary to neutralize the primary, secondary and tertiary amines of the analysed sample. Expressed in mg KOH/g.
Hydroxyl value It is the measure of the content of the hydroxyl group (-OH) or, indirectly, of the amount of hydroxyl compounds in the substance under analysis. The number amount of milligrams of potassium hydroxide (KOH), expressed in mg KOH/mg, necessary to neutralize acetic acid (CH3COOH) involved in the acetylation reaction.
Saponification value An indication of the content of esterfied and free carboxyl groups in 1g of the substance under analysis. It is expressed as the amount of mg of potassium hydroxide (KOH) necessary to neutralize 1 g of the substance under analysis.
AGROLINE/17
EXOLagroline
TM
REACH Regulation deals with the safe use of chemicals by Registration, Evaluation and in some cases Authorization and restriction of trade in some Chemicals. REACH Regulation has already come into force. It is considered one of the greatest and most complex legal acts ever implemented in Europe. Not only did it cause significant changes in the Polish chemical industry, but it also affects the activity of other users of chemicals and it obliges them to take appropriate actions. REACH package is designed to broaden our knowledge about the chemical substances we use, oblige the manufacturers to prove that the chemical substance is safe for use and even prohibit the use of the most hazardous chemicals. PCC Exol SA, as a large chemical company, will meet this new challenge. Not only do we provide declarations that we have already pre-registered and registered the substances we manufacture and distribute, but we also actively participate in Substance Information Exchange Forum (SIEF) and form consortia with other chemical companies with a view to joint submission of registration dossier. We are the exclusive representative of the chemical manufacturers in UE Community and we are in constant contact with our suppliers and customers. According to Regulation (EC) No. 1907/2006 (REACH), the manufacture or import of chemical substances in volumes exceeding 1 ton per year must be registered at the European Chemicals Agency (ECHA) in Helsinki. REACH registration is related to substances and not products, e.g. preparations/formulations of substances. Production, import and marketing of a REACH-substance will be restricted to those uses evaluated in its registration dossier. The REACH process starts with preregistration (1st June 2008 until 1st December 2008), which ensures the availability of preregistered substances to the registration date. The date of registration depends on the production volume of the substance and lies between 2010 and 2018. We confirm that we will, pursuant to REACH requirements, pre-register all substances manufactured by PCC Exol SA Functional Chemicals Division in the EU or imported in the EU, that are relevant for the products listed in this brochure. However, no guarantee can be given that PCC Exol SA will offer all listed products in the future, if REACH registration requirements lead to unacceptable costs, PCC Exol SA will contact its customers to find an appropriate solution.
AGROLINE/18
EXOLagroline
TM
CERTIFICATES AND ORGANISATIONS MEMBERSHIP IPPC – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC directive - EU directive - for the integrated avoidance and reduction of environmental contamination) EN ISO 14001 – (European environmental management standard) certification since 2011
ENN ISO 9001 – (European quality management standard) certification since 2011
CESIO/CEFIC membership
RSPO membership (2-0327-12-000-00)
CLP - Classification, Labelling and Packaging of substances and mixtures CLP Regulation - Regulation (EC) No. 1272/2008 of the European Parliament and of the Council as of 16th December 2008 on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC, and amending Regulation (EC) No. 1907/2006. The regulation entered into force 20 days after its publication, i.e. on January 20, 2009. From this moment, Title XI of the Reach Regulation ceased to be binding. Harmonized classification contained in Attachment I to the Hazardous Substances Directive was transferred to Table 3.2. in Attachment VI to the CLP Regulation. CLP introduces the elements of GHS (Globally Harmonised System of Classification and Labelling of Chemicals). PCC Exol SA participates actively in implementing the CLP Regulation. We classify chemicals encompassed by the above legal status and perform changes in data sheets and on labels within the required deadlines, as well as notify new classification and labelling to the Classification and Labelling Inventory of the European Chemicals Agency. Quality Management Systems Since our operations are conducted in full compliance with legal and other requirements, including environmental requirements, the design, production and sale of large volumes of specialist, often unique, chemical products for further processing requires coordinated cooperation of many services at the Company’s disposal. And here the certified quality management system and environmental management system prove very useful. These are two systems, currently integrated, which enable our employees to be aware of their roles in reaching quality and environmental targets. They know that in the end, carrying out their tasks in accordance with procedures applicable to their positions and other internal regulations, they provide our clients with exactly what they expect from us, acting in conditions of reasonable and legal usage of the environment. Obtained certificates of the quality management system and environmental management system which we present on our website are important as they confirm our competences within quality and environmental management; however, the only thing that really counts is how we can secure the interests of our clients, and the quality management system in use in PCC Exol SA, supported with the environmental management system, provides us with a lot of tools aiding us in reaching this goal.
AGROLINE/19
Brzeg Dolny
www.pcc-exol.eu
PCC EXOL SA Sienkiewicza St. 4 56-120 Brzeg Dolny Poland www.pcc-exol.eu phone: +48 71 794 21 27 fax: +48 71 794 25 50 agroline@pcc.eu