17 minute read
The future of battery production is in automated metrology technology
Lithium ion batteries can store energy efficiently for long periods of time, making this technology essential to many everyday devices, from mobile phones to electric vehicles.
Lithium ion cells are also the most common battery storage choice for grid operations today, supplying more than 90% of the world’s markets. In fact, 74% of the world’s mined lithium goes into battery production alone.
However, the available reserves of lithium that are required for battery manufacture are close to depletion, prompting the exploration of alternative battery chemistries that will be able to supplement or replace lithium in the near future.
Despite their advantages, many of these technologies cannot currently provide the required energy densities, compact form factor or affordability to rival lithium ion batteries, and some are also difficult to scale up for commercial production. This makes it ever more important to maximize the usage of available lithium stocks, and to reduce wastage as much as possible during the manufacturing process.
Making sense of the shortage
The reasons behind the lithium shortfall are multifaceted. First of all, contrary to what you may think, lithium is not a rare metal; it is simply buried deep in the Earth’s crust, making it hard to access.
New mines take many years to be brought online and environmental objectives are making it harder for companies to gain permission to explore potential new sites.
This means that, even though lithium is still plentiful in nature, new sources won’t be available for use in batteries for quite some time, creating a pressing need for technologies that will enhance process efficiencies and minimize the loss of existing raw material during battery fabrication.
To understand how we got to the current state, we need to go back sev- eral years. Between 2017 and 2020, the prices of lithium and lithium compounds plummeted by around 60%, hitting an all-time low worldwide, largely in reaction to a supply glut and a lack of demand.
This sudden drawdown forced miners to cut back on their lithium extraction operations and call off the exploration of new mines, with the result that today only a few active mines are bringing new material into circulation. Exploration for new lithium mines is once again on the increase, but it will be years before they contribute to the current supply.
This issue is being compounded by the fact that EVs — from scooters to aeroplanes — are rapidly gaining in popularity.
Of course, EVs rely on large rechargeable batteries for their power, and these are almost all lithium ion based at the moment. This rapid surge of interest in EVs over the last couple of years is therefore draining the existing stocks of lithium, with the trend only set to continue as EVs become more affordable.
The reduced mining capacity caused by the low prices of a few years ago is now limiting the industry’s ability to supply battery manufacturers with the raw material they need to ramp up their production and meet the needs of the growing EV market.
The combination of depleted supplies and low mining capacity has inevitably led to lithium and its compounds becoming incredibly expensive since the start of 2021.
For example, lithium carbonate is now 10x the cost it was at the beginning of 2020, at around $72,155 per tonne, with lithium hydroxide prices sitting even higher at $75,000 per tonne.
This sudden price hike is proving challenging for many battery manufacturers, forcing them to cut the amount of raw material they purchase and thereby limiting the quantity of lithium ion batteries they can produce for the EV market.
Fortunately, there is some scope for recycling to address some of this gap between supply and demand. However, there are currently no wide-scale systems in place to collect and process scrap materials such as used lithium ion batteries.
The absence of an effective recycling infrastructure means that, eventually, much of the lithium originally mined out of the ground goes right back where it came from, but locked away in landfill.
This adds up to a tremendous amount of lithium wastage every year. Reversing this trend and rescuing material that has already been thrown away would contribute to a much more sustainable, circular economy.
Optimizing Li usage in battery production
Suitable and widely available alternatives to lithium ion batteries are still some way away and, with supply constraints looming, better management of existing resources is critical. Improving the efficiency of the battery manufacturing process in order to reduce lithium wastage is key.
In particular, coating variations during the electrode coating process can both be detrimental to battery performance and reduce product yield, leading to lithium wastage.
The safety, longevity and cost-effectiveness of lithium ion batteries are dependent on achieving consistent coating uniformity for the anode and cathode during the manufacturing process.
In-line metrology systems can be used to provide automated measurement of the electrode coating throughout the entire production process. (Image 1).
This non-contact, non-destructive measurement equipment enables manufacturers to continuously monitor production through real-time analysis of coating uniformity, providing rapid detection of any defects. This allows issues to be identified as early as possible in the cell manufacturing process and traced back to their source, ensuring defective or out-of-specification material can be segregated before it is incorporated into the final product.
In-line metrology systems can be combined with automatic profile control (APC) to further reduce coating variability and raw material wastage through the elimination of human error.
Closing the loop between measurement and adjustment
Until recently, most optimization processes in battery production lines were performed manually, but this makes it difficult to regulate coating uniformity and reliably identify production line defects.
In-line coating measurement gauges represent a development in automated production, scanning moving reels of coated electrodes to monitor coating thickness in real-time to ensure that coating defects are detected. (Image 2).
Sensor selection is a key consideration when using in-line metrology during lithium ion battery manufacture.
A variety of sensor technologies are available for different applications, including beta and X-ray sensors for measuring coating weight during the coating process and confocal laser sensors for measuring coating thickness during the calendering process.
Sensor quality is determined by factors such as resolution, precision and beam size, and is crucial for precisely and reliably measuring defects during electrode production.
Following the scanning stage, the next step is to feed the collected data back into the production process. This helps to optimize the electrode coating procedure by modifying fabrication variables like slurry thickness or volume.
In manual workflows, sensor-generated data is made visible to machine operators, allowing them to make informed adjustments to the coating stage, whereas, in more advanced production lines, a feedback loop can be programmed to connect process measurement and control.
For example, electrode coating using automated slot-dies is controlled by thermal die bolts, which expand or reduce dispensing volumes based on downstream measurements. (Image 3).
Using APC algorithms to automatically fine-tune the thickness and uniformity of electrode coatings increases production speed and efficiency by eliminating common issues, such as high error frequency, delays, and raw material wastage.
This metrology solution also allows for data storage, recall and analysis, so that manufacturers can resolve future issues in production lines and keep up with the growing global demands for lithium ion batteries. (Image 4).
The outlook for the future
In 2020 it was calculated that lithium demand is on course to more than triple in the five years leading up to 2025, rising to a million tonnes and outpacing supply by an estimated 200,000 tonnes.
This spike is largely driven by the growing need for more EV and energy storage battery cells, as well as the global push towards carbon neutrality, with EVs expected to exceed 50% of total vehicle sales as early as 2030.
However, current mining operations cannot keep pace with this sudden uptick in demand due to a combination of factors, including lack of mine capacity and depleted reserves, which are helping to send the price of lithium sky-high.
Consequently, some manufacturers are now struggling to afford what lithium there is available on the market. There is also a lack of recycling, causing this precious element to be wasted in alarming quantities.
As a result, quickly and precisely detecting flaws in electrode coatings using in-line metrology solutions is becoming increasingly important for reducing the wastage of lithium and enhancing the efficiency and sustainability of battery manufacturing in the years to come.
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Geneva, Switzerland
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Birmingham, UK
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Brussels, Belgium
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Messe Frankfurt, Germany
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August 8 – 10
Guangzhou, China
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September 5 – 7
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8TH International Secondary Lead and Battery Recycling Conference — Recycle100
September 4–5
Siem Reap, Cambodia
Fourteen years ago, the first Secondary Lead Conference was held in Macau, China, bringing together all aspects of the leadacid battery recycling and smelting industry. It has successfully brought the industry together to discuss, debate and learn.
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September 5–8
Siem Reap, Cambodia
The Asian Battery Conference has a long and proud history of bringing together the world’s leading battery industry C-level executives, marketers, technical staff and sales teams biennially to remain updated on new and emerging technologies, understand future directions, meet new suppliers, conduct business and network with industry peers.
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September 6 – 8
Valencia Spain
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Novi, MI. USA
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September 27 – 28
Gothenburg, Sweden
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October 10 – 13
Lyon, France
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October 15 – 17
Londrina, Brazil
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October 18
Prague, Czech Republic
Central Europe is rapidly emerging as a key location in the Battery Technology landscape. With a well-established and rapidly developing automotive industry, and a growing number of gigafactories both in operation and planned to come on-stream, the next few years will see a rapid expansion in battery production capacity in the region.
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November 6 – 7
Tysons Corner, Virginia, USA
The Annual Battery Safety Summit will bring together the key players from around the world to present the latest R&D advancements for integrating and implementing LIB safety to meet ever-increasing energy demands.
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San Diego, California, USA
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