Msds004 diesel oil

Material Safety Data Sheet Issue Date: Feb. 01, 2008

DIESEL OIL

Section-1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NAME: DIESEL OIL SYNONYMS: Diesel oil, Gas oil, Fuel oil no. 2.

PROPER SHIPPING NAME: Gas oil PRODUCT USE: Domestic and industrial heating, power for heavy units (ships, trucks, trains), source of synthesis gas, drilling muds, mosquito control SUPPLIER: Reliance Industries Limited Emergency Coordination Centre contact details: Vadodara Division

OCG

+91 265-6696525/+91 265-6693869

Nagothane Division

OCG

+91 2194-668033/+91 2194-668034

Dahej Division

OCG

+91 2641 301601

Jamnagar Division

Fire control room

+91288512400

Hazira Division

SSM Office

+91 2612835050/+912612835056

Patalganga Division

SSM Office

+91 2192-257600

OCG: Operation Control Group, SSM: Site Shift manager Section 2 – HAZARD IDENTIFICATION

Health Acute Toxicity -inhalation– Category 4 Oral/dermal-Category 4 Eye Corrosion - Category 4 Skin Corrosion – Category NA Skin Sensitization – Category NA Mutagenicity – Category NA Carcinogenicity – Category Not a carcinogen Reproductive/Developmental – Category NA Target Organ Toxicity (Repeated) – Category NA NA: Not available

Environmental Aquatic Toxicity – Category- NA

Physical Flammable – Category 2

Category table for reference: Study Acute Oral Acute Dermal

Category I > 50 mg/kg > 200 mg/kg

Category II >50-500 mg/kg >200-2000 mg/kg

Category IV >5000 mg/kg >5000 mg/kg

>200-2000 mg/liter Corneal involvement or irritation clearing in 8-20 days

Category III >500-5000 mg/kg >2000-5000 mg/kg >2000-5000 mg/liter Corneal involvement or irritation clearing in < 7 days

Acute Inhalation

> 0.05 mg/liter

Eye Irritation

Skin Irritation

Corrosive or corneal involvement or irritation persisting >20 days Corrosive

Severe irritation > 72 hrs WARNING

Moderate irritation > 72 hrs CAUTION

Mild or slight irritation CAUTION

Signal Word

DANGER

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>5000 mg/liter Minimal effects clearing < 24 hrs

Material Safety Data Sheet Issue Date: Feb. 01, 2008

DIESEL OIL

GHS Label: Symbols: flame, warning, corrosion, health hazard, pollution

Hazard Statements Extremely flammable, Irritating to eyes, skin and respiratory organs.

Precautionary Statements Do not eat, drink or use tobacco when using this product.

Prevent contact with eye, and body parts.

Use respiratory protection, body and eye protection, Wash body part with plenty of water if exposed

Hazard ratings: NFPA HAZARD CODES HEALTH: 0 FLAMMABILITY: 2 REACTIVITY: 0

Route of entry: Skin Contact

HMIS HAZARD CODES HEALTH: 0 FLAMMABILITY: 2 REACTIVITY: 0 CONTACT RATING:

Skin Absorption

RATINGS SYSTEM 0 = No Hazard 1 = Slight Hazard 2 = Moderate Hazard 3 = Serious Hazard 4 = Severe Hazard

Eye Contact

Inhalation

Ingestion

Yes

Yes

Yes

Yes Yes Health effects: Protective equipments: HANDS EYES

BODY

RESPIRATORY

Health hazards: Carcinogenicity NTP listed?

IARC cancer review group? OSHA Regulated?

Insufficient data No No No DATA REFERENCE: Toxic release inventory (TRI) basis of Occupational Safety and Health Administration (OSHA) carcinogen, National Toxicological program (NTP), International Agency for Research on Cancer (IARC), http://toxnet.nlm.nih.gov/cgibin/sis/search.

Inhalation: Inhalation causes headache and slight giddiness. Pulmonary irritation secondary to exhalation of solvent; Aspiration causes severe lung irritation with coughing, gagging, dyspnea, substernal distress, and rapidly developing pulmonary edema; later, signs of bronchopneumonia and pneumonitis.

Ingestion: Ingestion causes nausea, vomiting, and cramping; depression of central nervous system ranging from mild headache to anesthesia, coma, and death; Skin contact: Highly irritating to skin.

Eye contact: Highly irritating to eyes.

Chronic exposure: overexposure: weakness, coughing, laboured breathing, headache Confusion nausea/vomiting convulsions heart rate and pulse variations coma respiratory failure Aggravations to pre existing conditions: Those with history of lung diseases, or skin problems may be more susceptible to the effects of this substance.

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Material Safety Data Sheet Issue Date: Feb. 01, 2008

DIESEL OIL

Section 3 – COMPOSITION & INFORMATION ON INGREDIENTS Ingredients / Hazardous Diesel oil (Fuel oin no.2)/Yes

CAS No. 68476-30-2

Percentage 100%

Section 4 - FIRST AID MEASURES After inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration. If breathing is difficult, give oxygen.

After skin contact: In case of contact, immediately wash skin with soap and copious amounts of water.

After eye contact: Contamination of the eyes should be treated by immediate and prolonged irrigation with copious amounts of water. Assure adequate flushing of the eyes by separating the eyelids with fingers.

After ingestion: If swallowed, wash out mouth with water provided person is conscious. Call a physician.

Advice to physician: Treat according to symptoms Section 5 – FIRE FIGHTING MEASURES

Suitable extinguishing media: If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped. Use water in flooding quantities as fog.

Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide.

Specific hazards: When heated to decompose it emits acrid smoke and fumes Unusual fire and explosion Hazards: During fire container may explode.

Specific personal protective equipments for fire fighters: Wear selfcontained breathing air apparatus and protective clothing to prevent contact with skin and eyes.

Fire fighting procedures: Remain upwind while fire fighting.

Section 6 –ACCIDENTAL RELEASE MEASURES Personal protection procedure to be followed in case of leak or spill: Evacuate area and keep personnel upwind. Shut off leak if there is no risk.

Procedure of personal precaution: Wear self-contained breathing air apparatus, rubber boots, and heavy rubber gloves.

Methods for cleaning up: Spills and leakage: Section 7 –HANDLING AND STORAGE Handling: Prevent breathing vapours. Prevent contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.

Storage: Store in a cool place, away from heat and flame.

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Material Safety Data Sheet Issue Date: Feb. 01, 2008

DIESEL OIL

Section 8 â&#x20AC;&#x201C;EXPOSURE CONTROL AND PERSONAL PROTECTION

Occupational Exposure Limits: Data not established Material Source Type ppm mg/m3

Notation

Diesel oil

ACGIH TWA NA ACGIH STEL NA ACGIH SKIN_DES TWA NA NIOSH IDLH NA OSHA TWA NA OSHA STEL NA NA: Data not available DATA REFERENCE: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and http://toxnet.nlm.nih.gov/cgi-bin/sis/search.

Engineering measures: Maintain eye wash fountain and quick-drench facilities in work area. Warning: suck-back into container may cause rupture. Use back-flowpreventive device in piping. Generation of electrostatic charge may occur. Provide emergency suck off system.

Respiratory Protection: During fire if the exposure limit is exceeded and engineering controls are not feasible, wear a supplied air full-facepiece respirator, airline hood, or full-facepiece self-contained breathing air apparatus.

Eye Protection: Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain in work area.

Hand Protection: Wear gloves of impervious material.

Body Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.

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Material Safety Data Sheet Issue Date: Feb. 01, 2008

DIESEL OIL

Section 9 –PHYSICAL AND CHEMICAL PROPERTIES

Appearance Amber coloured distillate oil Odour Gasoline like Solubility in water Insoluble Relative Density (H2O=1) 0.86 Boiling Point °C NA Melting Point °C NA Relative Vapour Density (Air=1) NA Flash point °C 57.78°C Auto ignition °C 256.7°C Vapour pressure (mmHg) @ 0 °C NA Molecular weight NA Explosive limits in air % by volume NA pH NA Viscosity cP @20 °C NA Pour point <-18°C Evaporation rate (water=1) NA Octanol/water partition coefficient log Kow NA % volatile NA NA: NOT AVAILABLE DATA REFERENCE: National Institute for Occupational Safety and Health guide to chemical hazards and International Chemical Safety Cards (WHO/IPCS/ILO) and "http://ptcl.chem.ox.ac.uk/" is http://toxnet.nlm.nih.gov/cgi-bin/sis/search: maintained by the Safety Officer in Physical Chemistry at Oxford University, http://toxnet.nlm.nih.gov/cgi-bin/sis/search.

Section 10 –CHEMICAL STABILITY AND REACTIVITY INFORMATION Stability: Stable.

Conditions to avoid: Heat and flame.

Incompatible materials to avoid: Very dangerous fire hazard when exposed to flame Decomposition products: When heated to decompose it emits acrid smoke and fumes Polymerization: Do not occur Section 11 –TOXICOLOGICAL INFORMATION

Acute toxicity data: Parameter Route Species Values Exposure period LD50 Oral Rat 12 g/Kg Not applicable Data Reference: "http://ptcl.chem.ox.ac.uk/" is maintained by the Safety Officer in Physical Chemistry at Oxford University, http://toxnet.nlm.nih.gov/cgibin/sis/search.

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Material Safety Data Sheet Issue Date: Feb. 01, 2008

DIESEL OIL

Section 12 –ECOLOGICAL INFORMATION

Environmental Fate: Volatilization from water is fast, expected to strongly adsorb to sediment and suspended organic matter and may bioconcentrate in aquatic organisms Ecotoxicity data: No data available Data Reference: "http://ptcl.chem.ox.ac.uk/" is maintained by the Safety Officer in Physical Chemistry at Oxford University, http://toxnet.nlm.nih.gov/cgibin/sis/search Section 13 –DISPOSAL CONSIDERATIONS Local Legislation: Disposal should be in accordance with applicable regional, national, and local laws and regulations. This product should not be dumped, spilled, rinsed or washed into sewers or public waterways.

Section 14– TRANSPORT INFORMATION Shipping Name/ Number DOT/UN/NA/IMO: UN 1202; Gas oil IMO 3.3; Gas oil Section 15– REGULATORY INFORMATION MSDS format on a 16 Section based on guidance provided in: Indian Regulation: Manufacture, Storage and Import of Hazardous Chemicals Rule, 1989.

The Factories Act 1948 International Regulations: European SDS Directive ANSIZ400 MSDS Standard ISO 11014-1:1994 WHMIS Requirements United States Hazard Communication Standard Canada Hazardous Products Act and Controlled Products Regulations Europe Dangerous Substance and Preparations Directives Australia National Model Regulations for the Control of Workplace Hazardous Substances The Globally Harmonized System of Classification and Labeling of Chemicals endorsed by The UN Economic and Social Council

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Material Safety Data Sheet Issue Date: Feb. 01, 2008

DIESEL OIL

*RISK PHRASES: R10 Flammable *SAFETY PHRASES: S9 Keep container in a well-ventilated place, S16 Keep away from sources of ignition, S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice *These standard risk and safety phrases for use when interpreting Material Safety data Sheets are derived from the European Union Regulation, CHIP Regulations Chemicals (Hazard Information and Packaging for Supply). They are required to be used in Materials Safety Data Sheets to identify potential hazards and offer safe handling advice.

Section 16â&#x20AC;&#x201C; OTHER INFORMATION This MSDS is issued by the Centre for HSE Excellence, Reliance Industries Limited Contact Details: For any enquiry/comment regarding this Material Safety Data Sheet, kindly contact the Centre for HSE Excellence at HSE.ExcellenceCentre@ril.com Disclaimer: Reliance Industries Ltd, believes that the information and recommendations contained herein (including data and statements) are accurate as of the date hereof.

NO WARRANTY OF FITNESS FOR ANY PARTICULAR PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information provided herein relates only to the specific product designated and may not be applicable where such product is used in combination with any other materials or in any process. Company will not take any warrantee if this product is used in a manner inconsistent with its labeling. Further, since the conditions and methods of use are beyond the control of RIL, expressly disclaims any and all liability as to any results obtained or arising from any use of the product or reliance on such information.

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