www.biochar.ac.uk | biochar@ed.ac.uk
WSP550
Standard biochar specification sheet – Version 1.0 | November 2014
Feedstock: Wheat Straw Pellets | Production: Pilot-scale rotary kiln pyrolysis unit, nominal peak temperature550°C
•
Reproducible
•
Extensively characterised
•
Readily available
Basic Utility Properties
Biochar C stability compared to a set of 92 biochar
wt% (a.r.)
1.88
0.08 (7)
wt% (d.b.)
68.26
1.10 (6)
H
wt% (d.b.)
2.10
0.25 (6)
O (by difference)
wt% (d.b.)
6.92
0.33 (6)
H:Ctot
Molar ratio
0.37
0.05 (6)
O:Ctot
Molar ratio
0.08
0.00 (6)
Corg
wt% (d.b.)
tbd
tbd
H:Corg
Molar ratio
tbd
tbd
Total ash(a)
wt% (d.b.)
21.25
1.09 (7)
Total N
wt% (d.b.)
1.39
0.10 (6)
[-]
9.94
0.16 (4)
Electric conductivity
dS/m
1.70
0.43 (4)
Liming (if pH above 7)
% CaCO3
tbd
tbd
Biochar C stability
% C-basis
96.51
0.30 (5)
(b)
Production parameters
Mineral N (ammonium & nitrate)
Mean
Run-to-Run Variation, SD(n)
°C
550
- (1)
°C
550
- (1)
Max. char HTT Heating rate
- (6)
Total P(c)
wt% (d.b.)
0.14
0.02 (4)
Mean time at HTT
Total K(c)
wt% (d.b.)
1.56
0.35 (4)
Biochar yield
mg/kg (d.b.)
tbd
tbd
wt% (d.b.)
10.55
0.86 (7)
Total Surface Area
m2/g (d.b.)
26.40
- (1)
External Surface Area
m2/g (d.b.)
tbd
tbd
Toxicant Reporting - Total Content
°C
-
- (1)
°C/min
80
- (1)
min
15
- (1)
Kiln residence time
min
5
- (1)
wt% (d.b.)
24.11
1.08 (6)
Pyrolysis liquid yield
wt% (d.b.)
42.68
- (1)
Pyrolysis gas yield
wt% (d.b.)
31.60
- (1)
Pyrolysis liquid HHV
MJ/kg
1.56
- (1)
Pyrolysis gas HHV
MJ/kg
9.41
- (1)
Mean
Germination Inhibition Assay
Run-to-Run Variation, SD(n)
pass/fail
tbd
tbd
Polycyclic Aromatic Hydrocarbons (EPA16)(d)
mg/kg dry wt
0.40
0.28 (6)
Dioxin/ Furan (PCDD/ Fs)
ng/kg dry wt
4.30
- (1)
ng/kg dry wt
0.013
- (1)
mg/kg dry wt
1.16
0.21 (3)
mg/kg dry wt
3.15
1.14 (3)
mg/kg dry wt
bdl
- (3)
mg/kg dry wt
1.54
0.60 (3)
mg/kg dry wt
3.63
0.39 (3)
(e)
As Cd Cr Co Cu Pb Hg Mo Ni Se Zn
modified dry ashing followed by ICP-OES
Polychlorinated Biphenyls (PCBs)(f)
Run-to-Run Variation, SD(n)
Reactor wall temp.
<3
Available P
Mean
Nominal HTT
mg/kg (d.b.)
Volatile Matter(a)
Run-to-Run Variation, SD(n)
Ctot
pH
Advanced Analysis & Soil Enhancement Properties
Mean
Moisture
(a)
IBI comparison vs. recommended standard thresholds+
Key features:
6-20
EBC
BQM
4
20
(premium) (high grade)
9
20
20
0.2-0.5
0.2
0.50
12-100
n/a
10
1.4-39
1
3
64-1200
80
15
40-150
n/a
n/a
63-1500
100
40
70-500
120
60
1-17
1
1
5-20
n/a
10
mg/kg dry wt
bdl
- (3)
mg/kg dry wt
bdl
- (3)
mg/kg dry wt
0.84
0.20 (3)
mg/kg dry wt
1.00
0.74 (3)
47-600
30
10
mg/kg dry wt
bdl
- (3)
1-36
n/a
5
mg/kg dry wt
10.50
2.90 (3)
200-7000
400
150
Notes: HTT=highest treatment temperature, HHV = higher heating value, tbd = to be defined in next version, bdl. = below detection limit, SD = standard deviation (refers to run-to-run consistency, not analytical error) + available standards related to biochar (IBI = International Biochar Initiative, EBC = European Biochar Standard, BQM = Biochar Quality Mandate), e as TEQ (toxic equivalent) values vere bdl, total (tetra to octa chlorinated) dioxin/furan content is reported instead. (a) TGA, (b) Cross A, Sohi SP (2013), (c) Aqua Regia digestion followed by ICP, (d) Soxhlet extraction (toluene, 6h) determination by GCMS, (e) US EPA 1613, (f) AES O84 (based on US EPA 1668)
For full details please go to: http://www.charchive.org/record.php?record_id=100