SURFACTANS FOR COSMETICS & PERSONAL CARE PRODUCTS Sustainable technologies
EXOLcareline version 2015.1
EXOLcareline TM
PCC EXOL Specialized surfactants used in the production of personal care products and cosmetics.
Surfactant...sounding strange, sophisticated word. Besides, hides so many surprising contents. Accompanies us in everyday life, making them better, healthier, more enjoyable. Surfactants are an integral part of our lives and influence its quality. They are used in composing various goods, being indicators of modern lifestyle. We use them during daily activities such as bathing or relaxing care of body and hair. This is the part of the world of chemistry that surrounds us from all sides, always...
EXOLCARELINE/02
EXOLcareline TM TM
INTRODUCTION PCC Exol SA was created by merge of PCC Exol SA and Surfactants Business Unit of PCC Rokita SA. The Company’s core scope of operation is the manufacture and sale of surfactants. The company is headquartered in Brzeg Dolny, where is located manufacturing unit of anionic and nonionic surfactants. Moreover, in 2011, there was start-up of new production unit of nonionic surfactants (ethoxylation plant) in Płock. The flexibility of production allows to offer a wide range of anionic and nonionic surfactants according to the current needs of our customers. As one of the leading manufacturers of chemical products, the company is continuing to undertake investment activities with using modern technologies and based on the principle of sustainable development. Our strategic investor is the German company PCC SE, which operates internationally in three divisions: Chemicals, Energy and Logistics. Today, more than 70 subsidiaries and associated companies working within the PCC Group employ about 2 500 staff in 16 countries. Group strategy is focused on growth and profitability in the core activities as well as on diversification into new segments.
PCC GROUP (Poland)
Chemicals
PCC Consumer Products SA (Warsaw, Poland)
PCC Consumer Product Kosmet Sp. z o.o. (Brzeg Dolny, Poland)
PCC Prodex Sp. z o.o. (Warsaw, Poland)
Navigator (Belarus)
Logistics
PCC Exol SA - Brzeg Dolny, Poland - Płock, Poland
PCC Rokita SA (Brzeg Dolny, Poland)
FZ „Czechowice” SA (Czechowice, Poland)
Kosmet Navigator JLtd. (Belarus)
Energy
Tensis Sp. z o.o. (Brzeg Dolny, Poland)
PCC Synteza SA
PCC Chemax, Inc. (S.C.) (Piedmont, USA)
S.C. EURO URETHANE SRL
PCC Exol Kimya Sanayi (Turkey)
PCC Exol Philippines Inc.
PCC Consumer Products (Russia)
Surfactants offered by our company are widely used in various industries applications. In addition to use in personal care and cosmetics industry, our surfactants are used in different branches such as: household chemicals, textile, agrochemicals, metalworking, oilfield industry, construction industry, paints & coatings, pulp and paper, and the other. Over the years, PCC Exol has developed core competencies in manufacturing specialty surfactants. We meet our customers’ needs with a unique and versatile product portfolio, a broad expertise in surfactants chemistry and a high degree of flexibility. Through intimate customer relationships and by maximising synergies of customers’ application experience and our chemistry knowledge, we continuously strive to offer tailor-made products and system solutions that contribute to your success. We are continuously expanding our product range with new surfactants, focusing on safe chemistry, friendly to people and environment.
EXOLCARELINE/03
EXOLcareline TM
ESSENTIAL ADDITIVES FOR EVERYDAY PRODUCTS Personal Care market is rapidly changing. Use of wide range of personal hygiene products is nowdays inextricably linked with our lifestyle. Growing number of new type of formulations requires new range of ingredients ensuring satisfying effect in the formulation and ultimately, safety to the customer. PCC Exols EXOLcareline range was created, and is continously expanding to enable our clients to create formulations tailor made to market trends and client needs. ADDITIVES FOR EVERYDAY PRODUCTS
Ceteareth-6
ROKAnol T10
Ceteareth-10
ROKAnol T12
Ceteareth-12
ROKAnol T18
Ceteareth-18
ROKAnol O3
Oleth-3
ROKAnol O18
Oleth-18
Others
• • • • • •
•
•
• • • • • •
• • • •
•
•
•
•
•
•
•
•
• Shaving Cream/Foam
Face Cleansing
Baby Bath Wash
Bath products
• • • • • • • • • • • • • • • •
Liquid Soap
• • • • • •
•
•
•
•
•
•
•
•
•
•
• •
•
•
ROKAnol T6
ROKAnol NL8P4
Baby shampoo
• • • • • • • • •
•
C12-C15 Pareth-7
•
ROKAnol DB7W
•
C12-C15 Pareth-7
•
ROKAnol DB7
•
Deceth-3
-
EXOLCARELINE/04
•
Laureth-10
ROKAnol D3W
•
ROKAnol L10/80
•
Laureth-10
•
Laureth-7
ROKAnol L10
•
ROKAnol L7W
•
Laureth-7 C12-C16 Pareth-7
•
ROKAnol L7A
•
ROKAnol L7
Laureth-4 C12-C16 Pareth-5
•
ROKAnol L5A
•
ROKAnol L4
•
C12-C16 Pareth-3
•
Laureth-3
ROKAnol L3A
•
ROKAnol LK3
•
Laureth-2
•
Laureth-2
ROKAnol LK2A
•
ROKAnol LK2
•
Laureth-1
•
ROKAnol LK1
•
Disodium Laureth-3 Sulfosuccinate
•
Sodium Laureth-3 Sulfate
SULFOSUCCINATE L3/40
•
SULFOROKAnol L370/1
•
Sodium Laureth-3 Sulfate
•
Sodium Laureth-3 Sulfate
SULFOROKAnol L370
•
SULFOROKAnol L327
•
Sodium Laureth-2 Sulfate
•
Sodium Laureth-2 Sulfate
SULFOROKAnol L270/1A
•
SULFOROKAnol L270/1
•
Sodium Laureth-2 Sulfate
•
Sodium Laureth-1 Sulfate
SULFOROKAnol L225/1
•
SULFOROKAnol L170/1
•
Ammonium Lauryl Sulfate
•
Sodium Decyl Sulfate
ROSULFAN A
•
ROSULFAN D
•
Sodium Lauryl Sulfate
Face
•
ROSULFAN L
INCI Name
Body
•
Product
Shampoo
Hair
EXOLcareline TM
ADDITIVES FOR EVERYDAY PRODUCTS
Others
•
•
•
•
Shaving Cream/Foam
Face Cleansing
•
•
•
•
•
•
•
Baby Bath Wash
Bath products
Liquid Soap
Baby shampoo
•
• • • • •
• • • •
•
•
Cetearyl alcohol
ExoAlc 1698 pills
Cetyl alcohol
•
•
•
•
•
•
•
•
•
•
•
•
•
•
•
• • • •
•
• •
•
•
•
•
•
•
• •
ExoAlc 1618 pills
•
Sodium Laureth Sulfate, Cocamidopropyl Betaine, Coco-Glucoside
•
EXOcare PC60
•
Sodium Laureth Sulfate, Cocamide DEA, Glycol Distearate
•
EXOpearl
•
Cocamidopropyl Betaine
•
ROKAmina K40HC
•
Cocamidopropyl Betaine
•
ROKAmina K40
•
Cocamidopropyl Betaine
•
ROKAmina K30E
•
Coco Betaine
•
ROKAmina K30B
•
Cocamidopropyl Betaine
•
ROKAmina K30
•
Oleamide DEA
•
ROKAmid RAD
•
Cocamide DEA
•
ROKAmid KAD
•
PEG-8
•
POLIkol 400
•
PEG-6
•
POLIkol 300
•
PEG-4
•
POLIkol 200
•
PEG-20 sorbitan monooleate
•
ROKwinol 80
•
PEG-20 sorbitan monostearate
•
ROKwinol 60
•
Sorbitan monooleate
•
ROKwin 80
•
Sorbitan monostearate
•
ROKwin 60
•
PEG-7 Glyceryl Cocoate
•
ROKAcet KO300G
•
PEG-24 Stearate
•
ROKAcet S24
•
PEG-7 Stearate
•
ROKAcet S7
•
PEG-75 Lanolin
•
ROKAnol LN75/50
•
PPG-5 Laureth-5
•
ROKAnol L5P5
•
PPG-4 Laureth-5
Face
•
ROKAnol L4P5
Body
•
-
•
ROKAnol LP2529
•
-
•
ROKAnol LP2024
•
-
•
ROKAnol LP27
•
INCI Name
•
Product
Shampoo
Hair
EXOLCARELINE/05
EXOLcareline TM
The specific function of the surfactant in the formulation stems from its chemical structure. Portion and structure of hydrophilic and lypophilic parts of surfactant - intrictic for every surface active agent enables classification into different application function. Below table divides main surfactants classes, that form PCC Exol portfolio into funcion it plays in the end product.
ADDITIVES FOR EVERYDAY PRODUCTS
Viscosity Modifier
• •
Foam Booster
• •
Stabilizing Agent
Wetting Agent
Solubilizer
Humectant
Delivery System
•
Emolient
Dispersant
•
W/O Emulsifier
• •
•
•
•
•
• •
•
•
•
•
• • •
•
• •
•
• • •
•
• •
•
• •
•
EXOLCARELINE/06
•
Alcohols
•
Polyoxyethylene Glycols (PEGs)
•
Betaines
O/W Emulsifier
Co-Surfactants
Sorbitan Esters
•
Ethoxylated Fatty Acids
•
Ethoxylated Fatty Alcohols
•
Sulfosuccinates
•
•
Sulfated Ethoxylated Fatty Alcohols
•
Sulfated Fatty Alcohols
•
Product
Base Surfactants
Function in formulation
EXOLcareline TM
PRIMARY SURFACTANTS AND FOAMING AGENTS PRIMARY SURFACTANTS AND FOAMING AGENTS
-
SULFOROKAnol L225/1
68891-38-3
A
Liquid
-
SULFOROKAnol L270/1
68891-38-3
A
Paste/liquid gel
-
SULFOROKAnol L270/1A
68891-38-3
A
Paste/liquid gel
-
SULFOROKAnol L327
125301-92-0
A
Liquid
-
SULFOROKAnol L327/1
13150-00-0
A
Liquid
SULFOROKAnol L370
125301-92-0
A
SULFOROKAnol L370/1
13150-00-0
ROSULfan A
Sodium Laureth Sulfate + 1 EO Sodium Laureth Sulfate + 2 EO Sodium Laureth Sulfate + 2 EO Sodium Laureth Sulfate + 2 EO
68-72
-
•
25-27
-
•
68-72
-
•
68-72
-
•
Sodium Pareth Sulfate + 3 EO
26-28
-
•
-
Sodium Laureth Sulfate + 3 EO
27-29
-
•
Paste/liquid gel
-
Sodium Pareth Sulfate + 3 EO
68-72
-
•
A
Paste/liquid gel
-
Sodium Laureth Sulfate + 3 EO
68-72
-
•
90583-11-2
A
Liquid
-
Ammonium Lauryl Sulfate
ROSULfan D
142-87-0
A
Liquid
-
Sodium Decyl Sulfate
ROSULfan L
85586-07-8
A
Liquid
-
SULFOSUCCINATE L3/40
68815-56-5
A
Liquid
-
N
Liquid
ROKAmid KAD
-
•
35-40
-
•
Sodium Lauryl Sulfate
27.5 – 30.0
-
•
-
Disodium Laureth Sulfosuccinate
min. 25.0
-
-
Cocamide DEA
min. 90.0
-
26-28
Sorbitan esters
Paste/liquid gel
Fatty amines ethoxylated
A
Fatty acid amide ethoxylated
68891-38-3
Polyethylene Glycols
SULFOROKAnol L170/1
Description
Ethoxylated fatty acids
HLB
Betaines
Physical form
Alkoxylated fatty alcohols
Ionic character
Sulphosuccinates
CAS number
Product
Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]
Alkylsulphates
Product group
Alkylethersulphates
Product characteristic
• •
Production of reach and long lasting foam accompanies all hygiene activities and is perceived as a sign of cleansing action. Foamability and stability of foam is related to surfactant structure and is a domain of base surfactants. Products belonging to this class are a basic ingredient of all wash-off formulations and make cleansing products what they are.
EXOLCARELINE/07
EXOLcareline TM
SECONDARY SURFACTANTS AND EMULSIFIERS SECONDARY SURFACTANTS AND EMULSIFIERS
Description
68815-56-5
A
Liquid
-
Disodium Laureth Sulfosuccinate
min. 25.0
-
ROKAmina K30
-
Amph
Liquid
-
Cocamidopropyl Betaine
29-32
-
•
ROKAmina K30B
-
Amph
Liquid
-
Coco Betaine
29-32
-
•
ROKAmina K30E
-
Amph
Liquid
-
Cocamidopropyl Betaine
29-32
-
•
ROKAmina K40
-
Amph
Liquid
-
Cocamidopropyl Betaine
min. 37.0
-
•
ROKAmina K40HC
-
Amph
Liquid
-
Cocamidopropyl Betaine
min. 37.0
-
•
ROKAnol C7
68213-23-0
N
Liquid
11.9
Alcohols, C1218 + 7 EO
min. 95.5
106-112 4)
•
ROKAnol DB3
68131-33-5
N
Liquid/ Paste
7.8
Alcohols, C1215 + 3 EO
min. 99.7
164-172 3)
•
ROKAnol DB5
68131-33-5
N
Liquid
10.2
Alcohols, C1215 + 5 EO
min. 99.5
65-72 D
•
ROKAnol DB7
68131-39-5
N
Liquid/ Paste
12.0
Alcohols, C1215 + 7 EO
min. 99.5
100-114 3)
•
ROKAnol DB7W
68131-39-5
N
Oily liquid
12.0
Alcohols, C1215 + 7 EO
min. 90.0
100-114 3)
•
min. 99.5
50-57 A
•
min. 99.0
78-85 A
•
min. 99.0
43-48 E
•
min. 99.0
60-65 E
•
min. 99.0
51-56 A
•
SULFOSUCCINATE L3/40
ROKAnol NL6
68439-45-2
N
Liquid
12.3
ROKAnol NL8
68439-45-2
N
Liquid
13.8
ROKAnol UD3
127036-24-2
N
Liquid
8.7
ROKAnol UD5
127036-24-2
N
Liquid
11.0
ROKAnol UD7
127036-24-2
N
Liquid
12.3
Alcohols, C911, branched and linear + 6 EO Alcohols, C911, branched and linear + 8 EO Alcohols, C11, branched + 3 EO Alcohols, C11, branched + 5 EO Alcohols, C11, branched, + 7 EO
EXOLCARELINE/08
•
Sorbitan esters
HLB
Fatty amines ethoxylated
Physical form
Fatty acid amide ethoxylated
Ionic character
Polyethylene Glycols
CAS number
Product
Ethoxylated fatty acids
Betaines
Alkoxylated fatty alcohols
Sulphosuccinates
Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]
Alkylsulphates
Product group
Alkylethersulphates
Product characteristic
EXOLcareline TM
Differentiation of products and obtaining specific applications and aesthetic properties is achieved through use of co-surfactants. Application of secondary surfactant can have a synergistic effect on foaming, foam stability, rheology building properties and improve mildness of the formulation. Dispersion of hydrophobic ingredients in water solution is achieved through application of surface tension reducers. Emulsifiers arrange themselves at the water/oil interfaces and allow solubilization of oils.
SECONDARY SURFACTANTS AND EMULSIFIERS
Description
ROKAnol LK2
68439-50-9
N
Liquid
6.3
Alcohols, C1214 + 2 EO
min. 99.7
192-204 4)
•
ROKAnol LK2A
68439-50-9
N
Liquid
6.2
Alcohols, C1216 + 2 EO
min. 99.9
196-204 4)
•
ROKAnol LK3
68002-97-1
N
Liquid/ Paste
8.0
Alcohols, C1214 + 3 EO
min. 99.5
165-173 4)
•
ROKAnol L7
103819-01-8
N
Liquid
12.9
Alcohols, C1214 + 7 EO
min. 99.5
30-40 C
•
ROKAnol L7A
68551-12-2
N
Liquid
12.9
Alcohols, C1216 + 7 EO
min. 99.5
56-62 A
•
ROKAnol L7W
103819-01-8
N
Liquid
12.9
Alcohols, C1214 + 7 EO
89-92
30-40 C
•
ROKAnol L3A
68551-12-2
N
Liquid
8.0
Alcohols, C1216 + 3 EO
min. 99.5
53-55 E
•
ROKAnol L4
68002-97-1
N
Liquid
10.0
Alcohols, C1214 + 4 EO
min. 99.5
59-63 E
•
ROKAnol L10
68551-12-2
N
Paste
13.8
Alcohols, C1216 + 10 EO
min. 99.7
59-63 C
•
ROKAnol L10/80
6540-99-4
N
Viscous liquid
13.8
Alcohols, C1214 + 10 EO
min. 80.0
59-63 C
•
ROKAnol L22
68551-12-2
N
Wax
17.0
Alcohols, C1214 + 22 EO
min. 99.7
46-52 4)
•
ROKAnol LN75/50
61790-81-6
N
Viscous liquid
17.8
Lanolin + 75 EO
48-52
-
•
ROKAnol LN75K
61790-81-6
N
Solid
17.8
Lanolin + 75 EO
min. 99.0
-
•
ROKAnol O3
9004-98-2
N
Liquid
min. 99.0
37-41 E
•
ROKAnol O18
9004-98-2
N
Paste
min. 99.0
70-74 C
•
ROKAnol T10
68439-49-6
N
Wax
min. 99.5
85-95 4)
•
Alcohols, C1618 unsaturated + 3 EO Alcohols, C1615.6 18 unsaturated + 22 EO 6.6
11.7
Alcohols, C1618, + 10 EO
EXOLCARELINE/09
Sorbitan esters
HLB
Fatty amines ethoxylated
Physical form
Fatty acid amide ethoxylated
Ionic character
Polyethylene Glycols
CAS number
Product
Ethoxylated fatty acids
Betaines
Alkoxylated fatty alcohols
Sulphosuccinates
Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]
Alkylsulphates
Product group
Alkylethersulphates
Product characteristic
EXOLcareline
SECONDARY SURFACTANTS AND EMULSIFIERS
HLB
Description
ROKAnol T12
68439-49-6
N
Wax
13.5
Alcohols, C1618, + 10 EO
min. 99.5
85-100 A
•
ROKAnol T18
68439-49-6
N
Wax
16.3
Alcohols, C1618, + 18 EO
min. 99.0
74-77 C
•
ROKAnol T6
68439-49-6
N
Wax
10.0
Alcohols, C1618, + 6 EO
min. 99.5
105-115 4)
•
ROKAcet S7
9004-99-3
N
Paste
10.6
Stearate + 7 EO
min. 99.0
92-97 2)
•
ROKAcet S24
9004-99-3
N
Wax
15.8
Stearate + 24 EO
min. 99.0
40-45 2)
•
Glycerides, coco monoand di-, ethoxylated
min. 99.0
90-100 2)
•
Alcohols
Physical form
Sorbitan esters
Ionic character
Fatty amines ethoxylated
CAS number
Product
Fatty acid amide ethoxylated
Polyethylene Glycols
Ethoxylated fatty acids
Betaines
Alkoxylated fatty alcohols
Sulphosuccinates
Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]
Alkylsulphates
Product group
Alkylethersulphates
Product characteristic
ROKAcet KO300G
68201-46-7
N
Liquid
-
ROKwin 60
1338-41-6
N
Solid
4.7
Sorbitan monostearate
min. 99.0
145-160 2)
•
ROKwinol 60
9005-67-8
N
Liquid
PEG-20 sorbi14.9 tan monostearate
min. 99.0
15-55 2)
•
ROKwin 80
1338-43-8
N
Liquid
4.3
Sorbitan monooleate
min. 99.0
145-170 2)
•
ROKwinol 80
9005-65-6
N
Liquid
PEG-20 15.0 sorbitan monooleate
min. 99.0
45-55 2)
•
ExoAlc 1618 pills
67762-27-0
N
Solid in pills form
-
Alcohols, C1618 (30/70)
min. 99.0
210-220 4)
•
ExoAlc 1698 pills
36653-82-4
N
Solid in pills form
-
Alcohol C16
min. 99.0
228-233 4)
•
EXOLCARELINE/10
EXOLcareline
THICKENERS AND RHEOLOGY MODIFIERS For some products, due to composition of surfactant system and/or specific requirements of the formulation use of special thickeners is required. The example could be delicate formulations like baby care products, where low concentration of sodium chloride and Sulfate free formulations are a market standard. Rheology modifying products find an application where high viscosity of the formulation is required in order to achieve desirable effect. These are perlizers, capsule or shimmer suspensions and soap dispensers. THICKENERS AND RHEOLOGY MODIFIERS – PRODUCT LIST
Alcohols
Sorbitan esters
Fatty amines ethoxylated
Fatty acid amide ethoxylated
Polyethylene Glycols
Ethoxylated fatty acids
Betaines
Alkoxylated fatty alcohols
Sulphosuccinates
Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]
Alkylethersulphates
Product group
Alkylsulphates
Product characteristic
CAS number
Ionic character
Physical form
HLB
Description
ROKAnol LK2
68439-50-9
N
Liquid
6.3
Alcohols, C1214 + 2 EO
min. 99.7
192-204 4)
•
ROKAnol LK2A
68439-50-9
N
Liquid
6.2
Alcohols, C1216 + 2 EO
min. 99.9
196-204 4)
•
ROKAnol LK3
68002-97-1
N
Liquid/Paste
8.0
Alcohols, C1214 + 3 EO
min. 99.5
165-173 4)
•
ROKAcet K7
61791-29-5
N
Liquid
11.6
Cocoate + 7 EO
min. 99.0
104-112 4)
•
ROKAcet R40
61791-12-6
N
Paste
13.0
Castor oil + 40 EO
min. 99.0
55-64 4)
•
ROKAmid KAD
-
N
Liquid
-
Cocamide DEA
min. 99.0
-
•
ROKAmid RAD
68603-38-3
N
Liquid
-
Oleamide DEA
min. 90.0
-
•
ROKwin 60
1338-41-6
N
Solid
4.7
Sorbitan monostearate
min. 99.0
145-160 2)
•
ROKwinol 60
9005-67-8
N
Liquid
14.9
PEG-20 sorbitan monostearate
min. 99.0
15-55 2)
•
ROKwin 80
1338-43-8
N
Liquid
4.3
Sorbitan monooleate
min. 99.0
145-170 2)
•
ROKwinol 80
9005-65-6
N
Liquid
15.0
PEG-20 sorbitan monooleate
min. 99.0
45-55 2)
•
ExoAlc 1618 pills
67762-27-0
N
Solid in pills form
-
Alcohols, C1618 (30/70)
min. 99.0
210-220 4)
•
ExoAlc 1698 pills
36653-82-4
N
Solid in pills form
-
Alcohol C16
min. 99.0
228-233 4)
•
Product
EXOLCARELINE/11
EXOLcareline
WETTING AGENTS AND OTHER ADDITIVES Activity in lowering surface tension between solids and liquids is achieved by application of wetting agents. This is necessary in various types of formulations such as shampoos or colourisation compositions. Better spreading of the dying product on hair ensures good pigment distribution and better final effect. From the other side, good hair wetting efficiency results in satisfying washing and supplementation as well if applied in hair care products. WETTING AGENTS AND OTHER ADDITIVES – PRODUCT LIST
Paste
-
ROKAnol D3W
68002-97-1
N
Liquid
8.6
Alcohol C10 + 3 EO
min. 90.0
190-205 4)
•
ROKAnol NL8P4
154518-36-2
N
Liquid
9.5
Alcohols, C911-iso, C10rich + EO/PO
min. 99.0
38-48 A
•
ROKAnol LP2024
37251-67-5
N
Liquid
6.3
Alcohols, C10 + EO/PO
min. 99.0
20-24 A
•
ROKAnol LP2529
68551-13-3
N
Liquid
3.5
Alcohols, C1215 + EO/PO
min. 99.0
25-29 A
•
ROKAnol LP27
68439-51-0
N
Liquid
6.0
Alcohols, C1214 + EO/PO
min. 99.0
27-31 A
•
ROKAnol L4P5
68439-51-0
N
Liquid
5.3
Alcohols, C1214 + EO/PO
min. 99.0
98-108 4)
•
ROKAnol L5P5
68439-51-0
N
Liquid
6.0
Alcohols, C1214 + EO/PO
min. 99.0
27-31 A
•
POLIkol 200
25322-68-3
N
Liquid
-
Polyoxyethylene glycol
min. 99.0
530-590 4)
•
POLIkol 300
25322-68-3
N
Liquid
-
Polyoxyethylene glycol
min. 99.0
360-390 4)
•
POLIkol 400
25322-68-3
N
Liquid
-
Polyoxyethylene glycol
min. 99.0
270-300 4)
•
EXOLCARELINE/12
•
Sorbitan esters
•
-
EXOpearl
Fatty amines ethoxylated
-
-
Sodium Laureth Sulfate, Cocamide DEA, Glycol Distearate
Fatty acid amide ethoxylated
min. 40 % (dry matter)
Polyethylene Glycols
Description
Ethoxylated fatty acids
HLB
Betaines
Physical form
Alkoxylated fatty alcohols
Ionic character
Sulphosuccinates
CAS number
Cloud point [˚C], Cloud point Tanaka [˚C]1); SaponiActive fication value2) content [mgKOH/g]; (%) Amine value 3) [mgKOH/g]; Hydroxyl value4) [mgKOH/g]
Alkylsulphates
Product
Product group
Alkylethersulphates
Product characteristic
EXOLcareline
BETAINES Betaines are surfactants belonging to a class of amphoteric surface active agents displaying excellent skin mildness profile, very good foam characteristics and viscosity building properties. A combination of favourable application parameters like abundant foam formation, compatibility with a wide range of surfactant systems and an increased safety made betaines one of the most widely used surfactants in all wash-off applications. Following market trends and an ever-growing interest in surfactants displaying mildness to skin and efficiency in cosmetic formulations, Rokamina product range was developed. A cutting edge technology applied by PCC Exol in the production process allows achieving unparalleled quality parameters that meet the highest standards of customer safety.
Function in formulation
Application
Co-surfactants
Baby Shampoo
Foam booster
Liquid Soap
Viscosity modifier
Bubble Baths
Shampoo
Mild Shower Gels Baby Bath Wash Face Cleansing Shaving Cream/Foam
Added value in formulating
Benefits
Reduces irritancy of surfactants
Foam boosting
Good skin compatibility in combination with anionic surfactants
Hair and skin conditioning effects
Mild surfactant (cleansing effect)
Better skin feel, soft and smooth Richer and more luxurious foam High performance viscosity builder in Ether sulfate based formulations
EXOLCARELINE/13
Exceptionally effective viscosity increasing agent (highly responsive to salt) Readily biodegradable Compatible with anionic cationic amphoteric and nonionic surfactant
EXOLcareline
PCC EXOL SA has developed two classes of betaines surfactants: Cocamidopropyl Betaines and Coco-Betaine whose parameters are summarized in the below table. Rokamina K30, K30E, K40, and K40HC belong to the same chemical class, whereas Rokamina K30B is a single representative of another class. The single thing in common for Rokamina K30B, K30E and K40HC is their supreme purity making them suitable for all products where the sensitiveness of the product is paramount. These products find application in: - cosmetics for babies, - dermocosmetics, - high quality cosmetics.
INCI
Active matter (%)
Physical state
pH*
Surface tension (mN/m)
ROKAmina K30
Cocamidopropyl Betaine
29-32
Liquid
5.0-7.0
31
Free
76.3%
Market Benchmark
ROKAmina K30E
Cocamidopropyl Betaine
29-32
Liquid
4.0-5.5
28
Sodium benzoate
76.3%
Supreme Quality
ROKAmina K30B
Coco Betaine
29-32
Liquid
4.5-7.5
30
Free
Expected to be biodegradable based on the literature data
Supreme Quality
ROKAmina K40HC
Cocamidopropyl Betaine
37-42
Liquid
4.5-5.5
25
Free
76.3%
Supreme Quality
ROKAmina K40
Cocamidopropyl Betaine
37-42
Liquid
4.5-5.5
28
Free
76.3%
Market Benchmark
Product name
* 1% solution **According EU ECC C.4-E Closed Bottle Test
EXOLCARELINE/14
Preservative Biodegradability**
Purity
EXOLcareline
THICKENING PROPERTY Addition of betaines to a standard anionic surfactant system not only optimizes a viscosity profile and a response to salt but also improves cleansing power and mildness of the final formulation. A synergistic effect of an anionic surfactant-betaines system gives a formulator a powerful tool in creating value added formulations. Viscosity building properties of a surfactant system comprising of Sodium Laureth Sulfate and different Betaines types was plotted on the below graph as a function of salt concentration.
Basic Formulation Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)
13%
Rokamina (K30B, K30E, K40HC) (Coco-Betaine, Cocamidopropyl Betaine)
8%
NaCl
1-3%
Water
up to 100%
Thickening ability 35000
30000
Viscosity, cP
25000
20000
15000
10000
5000
0 1.0%
1.2%
1.4%
1.6%
1.8%
2.0%
2.2%
2.4%
2.6%
2.8%
3.0%
% NaCl Rokamina K30B
Rokamina K40HC
Rokamina K30E
Reference, Coco-Betaine, 30%
Reference, Cocamidopropyl Betaine, 40%
Reference, Cocamidopropyl Betaine, 30%
EXOLCARELINE/15
EXOLcareline
FOAMING CAPABILITY There is a wide possibility to formulate products that are characterized by outstanding foam using blends of anionic and amphoteric surfactants. It also implies that the surfactant system has different foam properties than the anionic alone. This explains why betaines are so commonly used in personal care formulation. They improve foam - an attribute that is very important to the consumer. Determination of the foaming capability was preformed according to PN-ISO 696:1994 (the modified Ross-Miles method) for the betaines solutions with a concentration of 1.0 g/l in distilled water at a temperature of 25째C.
Foaming capability in distilled water for betaines
Rokamina K40HC
300 s 180 s Rokamina K30B 30 s
Rokamina K30E
250
260
270
280
290
300
310
320
330
340
Foam volume [ml]
Foaming capability in hard water for betaines
Rokamina K40HC
300 s 180 s Rokamina K30B 30 s
Rokamina K30E
0
50
100
150
200
Foam volume [ml]
EXOLCARELINE/16
250
300
350
EXOLcareline
The foaming property of a basic formulation is shown in a graph below.
Basic Formulation Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)
13%
Rokamina (K30B, K30E, K40HC), (Coco-Betaine, Cocamidopropyl Betaine)
8%
NaCl
1.4-2.6%
Water
up to 100%
Foaming capability for basic formulation with Coco-Betaine
Reference product, 30%
300 s 30 s Rokamina K30B
240
250
260
270
280
290
300
310
Foam volume [ml]
Foaming capability for basic formulation with Cocamidopropyl Betaine
Reference product, 40%
Rokamina K40HC 300 s 30 s
Reference product, 30%
Rokamina K30E
240
250
260
270
280
Foam volume [ml]
EXOLCARELINE/17
290
300
310
EXOLcareline
SURFACE TENSION Surface tension according to PN-EN 14370:2004, determined with a use of the Wilhelmy plate method, at a temperature of 25°C, concentration of 0.1%.
Surface tension [mN/m] Product name Demineralized water
Hard water (17°d)
ROKAmina K30E
28
28
ROKAmina K30B
30
30
ROKAmina K40HC
25
25
Pure water has a relatively high surface tension at room temperature (~72.4 mN/m) and hence cleans poorly. In the cleaning process, surface tension must be reduced so water can spread and wet surfaces. Addition of a surfactant decreases the surface tension and consequently increases solubilisation. Surfactants are said to make water “wetter”. The lower the surface tension the better the wettability, hence the ability to dissolve and remove residues.
WETTING CAPABILITY In a large number of applications (especially for shampoos) the capability of effective wetting is a desirable property of surfactants. The shorter the time of wetting the better the wetting and cleaning agent. The capability of wetting a cotton fabric was determined according to EN 1772:2001. The wetting time (time in seconds necessary for wetting the textile material) was measured for a betaines solution with concentration of 1.0 g/l, 2.0 g/l and 5.0 g/l in deionized water at a temperature of 20°C.
Rokamina K40HC
5.0 g/l Rokamina K30B
2.0 g/l 1.0 g/l
Rokamina K30E
0
50
100
150
200
Wetting time [s]
EXOLCARELINE/18
250
300
350
EXOLcareline
EXAMPLE FORMULATIONS Cleansing gel Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)
13.00 %
Rokamina K40HC (Cocamidopropyl Betaine)
6.00%
Rokamid KAD (Cocamide DEA)
1.50%
Rokacet KO300G (PEG-7 Glyceryl Cocoate)
0.30%
Glycerine
2.50%
Citric acid
0.50%
EDTA
0.20%
NaCl
1.20%
Water
74.30%
Viscosity, cP
~7 400
Liquid hand soap Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)
13.00 %
Rokamina K30B (Coco-Betaine)
6.00%
Rokanol LN75/50 (PEG-75 Lanolin)
3.00%
Rokamid KAD (Cocamide DEA)
2.00%
EDTA
0.10%
Urea
1.00%
NaCl
1.00%
Demineralized Water Viscosity, cP
73.90% 2 000 - 3 000
Shampoo Sulforokanol L270/1 (Sodium Laureth Sulfate, 70%)
13.50 %
Rokamina K30B (Coco-Betaine)
6.00%
Rokamid KAD (Cocamide DEA)
1.50%
EDTA
0.10%
Citric acid
0.05%
NaCl
1.00%
Water
77.85%
Viscosity, cP
~6 100
EXOLCARELINE/19
EXOLcareline
EXOcare PC60 MULTIFUNCTIONAL SURFACTANTS BLEND FOR COSMETIC CLEANSING FORMULATION EXOcare PC60 was developed to meet expectations of our customers for universal and cost effective product in the area of personal care applications. Carefully selected and formulated blend of Alkyl Glucoside, Cocamidopropyl Betaine and Laureth Sulfate gave a unique product suitable as a primary surfactant for all cleansing applications.
Laureth-2 Sulfate Cocamidopropyl Betaine Alkyl Glucoside
Favorable dermatological properties, excellent foaming and thickening properties make EXOcare PC60 surfactant of choice where mildness and outstanding performance in final formulation is required. The product was formulated in a form of a viscous liquid ensuring ease of handling and formulation into a final preparation whether shampoo, shower gel, bubble bath or any other skin and hair cleansing product.
Product Specifications: Active Substance, (m/m)
60-63%
Apperance (20-25°C)
Paste
Anionic Substance, (m/m)
42-45%
Color
Colorless to Light Yellow
Specific Gravity
0.9-1.19 g/ml at 20°C
Water Solubility
Completely Soluble
pH(a)
10.0-11.5
Viscosity, cP
3000 – 8000 Brookfield
(a) 10% Aqueous Solution
Viscosity Profile EXOcare PC60: Water 6000
Viscosity, cP
5000
4000
3000
2000
1000
0 10:90
20:80
30:70
EXOcare PC60: Water
EXOLCARELINE/20
40:60
EXOLcareline
Viscosity Profile 20째C vs Salt Concentration (EXOcare PC60:Water 30:70) 35000
30000
Viscosity, cP
25000
20000
15000
10000
5000
0 0.00
0.50
1.00
2.00
1.50
% NaCl
Viscosity Profile 20째C vs Salt Concentration (EXOcare PC60:Water 30:70) 35000
30000
Viscosity, cP
25000
20000
15000
10000
5000
0 0.00
0.50
1.00
1.20
1.40
% NaCl
EXOLCARELINE/21
1.50
2.00
EXOLcareline
Example Formulation: Liquid Shampoo: PCC Exol recommends to use EXOcare PC60 in the concentration ranging from 20-30% (w/w). The exact dose of our product depends on the individual characteristics of the product, that formulator would like to achieve.
Part A: Demineralized Water Citric Acid DiSodium EDTA
60% 0.05% 0.1%
Part B: Demineralized Water 11% Rokacet KO300G 0.6% ExoAlc 1698 1.1%
Part C: EXOcare PC60
25%
Part D: Natural Extracts Colors
0.35% 0.09%
Part E: Sodium Chloride
1.55%
Procedure: Add demineralized water to the mixing kettle. Begin mixing. Add remaining part A. Heat the mixing kettle contents to 77-79°C. Add part B Ingredients to the mixing kettle. Reduce mixer speed, Mix until uniform. Maintain temperature at 77-79°C. Once the batch is uniform, turn off the heat. Cool the batch to 42-47°C. Premix and separately add ingredients from part D. Add part E – mix until uniform and cool to 30-35°C
pH
Viscosity (Brookfield S34, 4 RPM)
6
7500 cP
Product parameters:
The given data are suggestions without any guarantee aimed to support customers’ development. PCC Exol doesn’t assume any liability or risk involved in the use of its products as the conditions of use are beyond its control. The information on product specification provided in this document is binding to the extent confirmed in a written sales agreement.
EXOLCARELINE/22
EXOLcareline
NOTES FOR GUIDANCE CONCERNING THE FUNCTIONAL PARAMETERS AND NOTATION USED IN THE CATALOGUE HLB
The Hydrophilic-Lipophilic Balance (HLB) is a parameter defining the ratio of the content of the hydrophilic and hydrophobic group of the molecule. The HLB range for non-ionic surfactants is between 0 and 20 and expresses the percentage of the hydrophilic part of the molecule.
HLB by Griffin:
HLB=20 *
molecular weight of hydrophilic part molecular weight of the product
HLB for ester-type compounds (ethoxylated fatty acids):
HLB=20 * (1 - SV ) AV where: SV AV - acid value of acids subjected to ethoxylation in mgKOH/g HLB value
Content of EO in product %
Product application
1-3
5-15
Antifoamer
4-6
20-30
W/O emulsifier
7-11
35-55
Wetting agent
8-18
40-90
O/W emulsifier
10-15
50-75
Detergent
10-18
50-90
Solubilizer
Cloud point An indicator determining the behaviour of nonionic surfactants (obtained in the process of condensation with ethylene oxide) in water or in mixtures consisting of water and organic solvents. In water or in mixtures of water and organic solvents, solutions of surfactants become cloudy at certain temperaturewhen heated. The process is reversible and the substance becomes clear when cooled is referred to as the cloud point. Depending on the temperature at which the solution becomes cloudy, there are five methods of determination of cloud point: Method A – aqueous solution (10-90°C) Method B – 50 g/l NaCl solution (>90°C) Method C – 100 g/l NaCl solution (>90°C) Method D – 5 g + 45 g of 25% butyldiglycol / aqueous solution (<10°C) Method E – 5 g + 25 g of 25% butyldiglycol / aqueous solution (<10°C)
EXOLCARELINE/23
EXOLcareline
REACH Regulation deals with the safe use of chemicals by Registration, Evaluation and in some cases Authorization and restriction of trade in some Chemicals. REACH Regulation has already come into force. It is considered one of the greatest and most complex legal acts ever implemented in Europe. Not only did it cause significant changes in the polish chemical industry, but it also affects the activity of other users of chemicals and it obliges them to take appropriate actions. REACH package is designed to broaden our knowledge about the chemical substances we use, oblige the manufacturersto prove that the chemical substance is safe for use and even prohibit the use of the most hazardous chemicals. PCC Exol SA, as a large chemical company, will meet this new challenge. Not only we do provide declarations that we have already pre-registered and registered the substances we manufacture and distribute, but we also actively participate in Substance Information Exchange Forum (SIEF) and form consortia with other chemical companies with a view to joint submission of registration dossier. We are the exclusive representative of the chemical manufacturers in UE Community and we are in constant contact with our suppliers and customers. According to Regulation (EC) No. 1907/2006 (REACH), the manufacture or import of chemical substances in volumesexceeding 1 ton per year must be registered at the European Chemicals Agency (ECHA) in Helsinki. REACH registration is related to substances and not products, e.g. preparations/formulations of substances. Production, import and marketing of a REACH-substance will be restricted to those uses evaluated in its registration dossier. The REACH process starts with preregistration (1st June 2008 until 1st December 2008), which ensures the availability of preregistered substances to the registration date. The date of registration depends on the production volume of the substance and lies between 2010 and 2018. We confirm that we will, pursuant to REACH requirements, pre-register all substances manufactured by PCC Exol SA Functional Chemicals Division in the EU or imported in the EU, that are relevant for the products listed in this brochure. However, no guarantee can be given that PCC Exol SA will offer all listed products in the future, if REACH registration requirements lead to unacceptable costs, PCC Exol SA will contact its customers to find an appropriate solution.
EXOLCARELINE/24
EXOLcareline EXOLcareline TM
CERTIFICATES & PROGRAMS CERTIFICATES EXOLcareline TM
EXOLcareline TM EXOLcareline TM
CERTIFICATES CERTIFICATES CERTIFICATES
IPPC/IED – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC directive - EU directive - for the integrated avoidance and reduction of environmental contamination)
IPPC – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC directive - EU directive - for the integrated avoidance and reduction of environmental contamination) EN ISO 14001
ISO 14001
IPPC 14001 – Integrated Pollution Prevention and Control – management integrated approvals since 2007 certification (IPPC direcEN ISO – (European environmental standard) since 2011
CERTYFIKAT
ENN ISO 9001tive
ISO
- EU directive - for the integrated avoidance and reduction of environmental contamination)
9001:2008 CERTYFIKAT
IPPC – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC direcCESIO/CEFIC membership EN ISO – Integrated Pollution Prevention and Control – integrated approvals since 2007 (IPPC directive -IPPC EU directive - for14001 the integrated avoidance and reduction of environmental contamination) tive - EU directive - for the integrated avoidance and reduction of environmental contamination)
ISO 14001
CERT YF IK AT
ISO 14001
ISO 14001
CERT YF IKAT
ENN ISO 9001 – (European quality management standard) certification since 2011
RSPO membership (2-0327-12-000-00)
EN ISO 14001 ENN ISO 9001 ISO 9001:2008 EN ISO 14001
CERT YF IK AT
CERT YF IKAT
ISO
ENN ISO 9001 CESIO/CEFIC membership
es
CLP 9001:2008 Regulation - Regulation (EC) No. ISO 1272/2008 ENN 9001 of the European Parliament and of the Council as of 16th December C E R T Y F I K AISO T es, amending and repealing Directives 67/548/EEC 9001:2008 CERT YF IKAT and 1999/45/EC, and amending Regulation (EC) No. 1907/2006.
CESIO/CEFIC membership
CESIO/CEFICRSPO membership membership (2-0327-12-000-00)
The regulation entered into force 20 days after its publication, i.e. on January 20, 2009. From this moment, Title XI of the CESIO/CEFIC membership dous Substances Directive was transferred to Table 3.2. in Attachment VI to the CLP Regulation.
RSPO membership (2-0327-12-000-00) RSPO membership (2-0327-12-000-00) RSPO membership (2-0327-12-000-00) es
SA participates actively in implementing the CLP Regulation. We classify chemicals encompassed by the above PCC Exol SA legal status perform changes in data sheets andNo. on labels within the CLPand Regulation - Regulation (EC) 1272/2008 ofr the European Parliament and of the Council as opean Chemicals Agency. es, amending and repealing
of 16th December Directives 67/548/EEC es Qualityand Management Systems 1999/45/EC, and amending Regulation (EC)knowledge. No. 1907/2006. esapplication and basic paramThe information included in this publication reflects our up-to-date It describes the CLP Regulation - Regulation (EC) as No. 1272/2008 of reserve the European Parliament and ofasthe Council as of 16th December eters products, and is given estimate We right makerequirements, any changes a result of technological S of the ince our operations are conducted in values. full compliance withthe legal and other including environmental reUN Global Compact - tomembership since 2013 The regulation entered into 20 days after publication, i.e. on January 20, 2009.Directives From moment, Title XI of the progress or developments. CLP Regulation - Regulation No.force theits European Parliament of the Council as of this 16th December es, amending and repealing 67/548/EEC quirements, the design, production(EC) and sale of1272/2008 large volumes of of specialist, often unique, chemical and products for further processdous Substances es,and amending and repealing Directives 67/548/EEC and 1999/45/EC, andnotamending Regulation (EC) specifi No. 1907/2006. The data should be interpreted as guaranteed cuseful. product qualities. The health currently environmental system and environmental management system prove very These areVI two systems, integrated, requirements, which enable Directive was transferred to Table 3.2. inNo. Attachment to the CLP Regulation. and 1999/45/EC, and amending Regulation (EC) 1907/2006. as well as user safety instructions, are included in material safety data sheets, available at request. Guaranteed quality paour employees to be aware of their20 roles in reaching quality and environmental They20, know that inFrom the end, carrying out The regulation entered into force days aftercations. its publication, i.e. ontargets. January moment, rameters in Technical Product Specifi The sale of and products in this2009. publication isthis subject to the Title XI of the their tasksare in included accordance with procedures applicable to their positions other included internal regulations, they provide our clients General Sales Terms and Conditions at PCC Exol SA. Exol SA. The regulation entered into force 20 days after its publication, i.e. on January 20, 2009. From this moment, Title XI of the dous Substances with exactly what they expect from us, acting in conditions of legal usage of the envi ronment. Responsible &reasonable Care and - mambership since 2014 dous Substances Directive was PCC transferred to Table 3.2. in Attachment VI to the CLP Regulation. SA participates actively in implementing the CLP Regulation. We classify chemicals Exol SA ment system which we present on encompassed by the above Directive legal was transferred Table 3.2. in Attachment VI toand theon CLP Regulation. status and to perform changes in data sheets labels within the r thing that really counts is how we can secure the interests of our clients, and the quality management system in use in PCC Exol
opean Chemicals Agency. SA, supported with the environmental management system, provides us with a lot of tools aiding us in reaching this goal. SA-participates actively inLabelling implementingand the CLP Regulation. We chemicalsand encompassed by the above PCC Exol SA CLP Classification, Packaging of classify substances mixtures Quality Management Systems SAperform participates actively ininimplementing the CLP Regulation. chemicals encompassed by the above Exoland SA legalPCC status changes in data sheets and on labels within the r We classify - basic paramThe information included this publication refl ects our up-to-date knowledge. It describes the application and legal status and perform changes inisdata sheets and onvalues. labels within the r theChemicals opean Agency. eters of the products, and given as estimate We reserve right to make any changes as a result of technological S ince our operations are(EC) conducted in full compliance and otherParliament requirements,and including environmental reCLP Regulation - Regulation No. 1272/2008 of with thelegal European of the Council as of 16th December 2008 progress or developments. opean Chemicals Agency. quirements, the design, production and sale of large volumes of specialist, often unique, chemical products for further processQuality Management Systems on classification, labelling and packaging of substances and mixtures, amending and repealing Directives 67/548/EEC and The information included in this publication reflects our up-to-date knowledge. It describes the application and basic paramQuality Management Systems The data should not be interpreted as guaranteed specifi c product qualities. The health and environmental requirements, eters of the products, and is given as estimate values. We reserve the right to make any changes as a result of technological 1999/45/EC, and amending Regulation (EC) No. 1907/2006. The information included in this publication refl ects our up-to-date knowledge. It describes the application and basic paramand environmental management system prove very useful. These are two systems, currently integrated, S incesystem our operations are conducted in full compliance with legal and other requirements, including environmental re- which enable as well as user safety instructions, are included in material safety data sheets, available request. quality out paprogress or developments. EXOLCARELINE/15 eters products, and is as We right to make any changes asatknow afor result ofGuaranteed technological our employees to begiven aware ofestimate their roles incompliance reaching quality and environmental targets. They that in the end, recarrying quirements, the design, production and sale of large volumes ofreserve specialist, often unique, chemical products further processS of the ince our operations are conducted in values. full withthe legal and other requirements, including environmental rameters are included in Technical Product Specifi cations. The sale of products included in this publication is subject to the progress or developments. their tasks in accordance with procedures applicable to their positions and other internal regulations, they provide our clients quirements, the design, production and sale ofat large of specialist, often unique, i.e. chemical further processTheshould regulation entered force 20 days after its publication, on products Januaryfor 20, 2009. From this moment, Title XI of the General Sales Terms andexpect Conditions PCCvolumes Exol SA. Exol SA. The data be interpreted asinto guaranteed qualities. The health and environmental requirements, withnot exactly what they fromprove us, specifi acting inproduct conditions of andcurrently legal usage of the envi ronment. system and environmental management system very cuseful. These arereasonable two systems, integrated, which enable Reach Regulation ceased to be binding. Harmonized classification contained in Attachment I to the Hazardous Substances as well as user safety instructions, are included in material safety data sheets, available at request. Guaranteed quality padata should not beofinterpreted guaranteed specifi product qualities. The health and environmental requirements, our The employees toenvironmental be aware their roles inasreaching and targets. They know that in integrated, the end, carrying system and management systemquality prove very cenvironmental useful. These are two systems, currently whichout enable rameters are included in Technical Product Specifi cations. The sale of products included in this publication is subject to the as well as user safety instructions, are included in material safety data sheets, available at request. Guaranteed quality pament system which we present on Directive was transferred to Table 3.2 in Attachment VI to the CLP Regulation. theirour tasks in accordance with procedures applicable to their positions and other internal provide ourcarrying clients out employees to be aware of their roles in reaching quality and environmental targets.regulations, They know they that in the end, General Saleswhat Terms andexpect Conditions at acting PCC Exol SA. cations. Exol SA. in Technical Product Specifi The sale ofand products included in envi thisronment. publication is subject to the withrameters exactly they fromprocedures us, in conditions reasonable legal usage of the their tasksare in included accordance with applicable to of their positions and other internal regulations, they provide our clients General Sales Terms andexpect Conditions at acting PCC Exol SA. the interests Exol SA. thing thatthey really counts is how we can of our clients, andusage the quality management in use in PCC Exol with exactly what from us, insecure conditions of reasonable and legal of theClassification environment. system CLP introduces of GHS (Globally Harmonised andon Labelling SA, supportedthe withelements the environmental management system, provides usSystem with ament lotof ofsystem tools which aiding we us in reaching this goal. of Chemicals). present ment system which we present on thing that really counts how we can secure the interests of our clients, and theCLP quality managementWe system in use inchemicals PCC Exol PCC Exol SA isparticipates actively in implementing the Regulation. classify encompassed by the above legal SA, supported with the environmental management system, provides us with a lot tools management aiding us in reaching this goal. thing that really is howchanges we can secure the interests of our clients, theof quality systemdeadlines, in use in PCC Exol status andcounts perform in data sheets and on and labels within the required as well as notify new classification SA, supported with the environmental management system, provides us with a lot of tools aiding us in reaching this goal.
and labelling to the Classification and Labelling Inventory of the European Chemicals Agency.
The information included in this publication reflects our up-to-date knowledge. It describes the application and basic paramEXOLCARELINE/15 eters of the products, and is given as estimate values. We reserve the right to make any changes as a result of technological progress or developments. EXOLCARELINE/15
The data should not be interpretedEXOLCARELINE/15 as guaranteed specific product qualities. The health and environmental requirements, as well as user safety instructions, are included in material safety data sheets, available at request. Guaranteed quality parameters are included in Technical Product Specifications. The sale of products included in this publication is subject to the General Sales Terms and Conditions at PCC Exol SA.
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EXOLcareline
GMP FOR COSMETIC INGREDIENTS The ingredients of cosmetics are first and foremost the result of the efforts of many people. Specialised companies invent and produce ingredients. Carefully tested substances are then sold to cosmetics manufacturers. For purchased ingredients to find themselves in cosmetics, they must undergo many tests, have adequate quality and be completely safe for humans. Cosmetic ingredients give cosmetics many defined and specific properties. For example, UV filters help protect the skin and hair against the harmful effects of UV rays. Additives in the form of surfactants provide washing and cleansing properties. They create an active foam during use of shampoos or body wash products such as soap or shower gels. Surfactants also have excellent thickening properties. They are used in the production of various types of emulsions and concentrates used in cosmetics. Similarly to ready cosmetics, Good Manufacturing Practices are also applied in relation to raw materials and additives used in the production thereof. Manufacturers of cosmetics and personal hygiene products place great importance on the quality and properties of the ingredients that will affect the safety of use of the finished product. Therefore, cosmetics companies require manufacturers of raw materials to confirm that they use Good Manufacturing Practices. This provides assurance that the components used in their formulations are safe and are always of the same quality, irrespective of the batch number.
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EXOLcareline
GOOD MANUFACTURING PRACTICES AT PCC EXOL SA GMP EFfCI Certificate Number: FR14/19163 / Brzeg Dolny GMP EFfCI Certificate Number: FR14/19164 / Płock
Why do we use Good Manufacturing Practices at our company? One of the key priorities of PCC EXOL SA is focusing on the customers’ needs. Meeting their needs in the area of product variety, quality and safety is a major determinant of the use of Best Practices in the production of surfactants supplied to our customers in the cosmetics industry.
Good Manufacturing Practices at our plants are used to: •
ensure repeatability and homogenity of subsequent product batches
•
eliminate any situations that could potentially contaminate the product with foreign physical and chemical substances and bodies, and harmful microflora
•
prevent any accidental actions in the production processes and ensure that these processes are carried out in accordance with strict requirements in the form of instructions and procedures
The most important reason why we have implemented Good Manufacturing Practices (GMPs) in our company is to ensure the safety of users using cosmetics containing surfactants manufactured at our production plants. The use of GMP standards gives consumers greater peace of mind and assurance as to the quality and safety of the final product.
The given data are suggestions without any guarantee aimed to support customers’ development. PCC Exol doesn’t assume any liability or risk involved in the use of its products as the conditions of use are beyond its control. The information on product specification provided in this document is binding to the extent confirmed in a written sales agreement.
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PCC EXOL Sustainable technology for beauty... Manufactured in one of PCC EXOL SA’s state of the art installations, ROKAmina K30 B and ROKAmina K40 HC are innovative products which belong to the amphoteric surface active substances group. Specially selected raw materials and cutting-edge production technology make ROKAmina the perfect components for both adults’ and children’s shampoos. It combines with other ingredients to ensure soft and radiant hair. ROKAmina possesses excellent foam-forming properties and maintains a mild impact on skin, which ensures using shampoos is safe and highly convenient. Meeting the highest standards of quality and safety, the products manufactured by PCC EXOL SA are the base components of personal care products for many prestigious global cosmetic brands.
EXOLcareline
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Taking care for the environment, this publication of PCC Exol SA was printed on Cocoon Silk - an ecological both side coated matt paper. This paper is made of 100% wastepaper by an environment-friendly technology. FSC速 sources.
TEXT PAGES Cocoon Silk
Brand Grammage
200
Number of pages
28
COVER PAGES Cocoon Silk
Brand Grammage
250
Number of pages
4
PUBLICATION Size (cm)
21 x 29.7
Quantity
300
By using Cocoon Silk rather than a non-recycled paper, the environmental impact was reduced by:
56 8 76 2,062 129 92
kg of kg CO2 and greenhouse gases km travel in the average European car litres of water kWh of energy kg of wood
Carbon f ootprint data evaluated b y Labelia C onseil in a ccordance with t he B ilan Carbone速 methodology. Calculations are based on a comparison between the recycled paper used versus
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