College Level Chemistry

Page 75

of energy (potential or heat energy) gained by another aspect of the reaction (because of the law of conservation of energy). As mentioned earlier in this course, chemical reactions can be exothermic and will give off heat, or endothermic and will store or take on energy. Some chemical reactions can be written in such a way as to account for the heat given off by stating that there is heat as part of the equation. A thermochemical equation is one that has heat put into it or given off as a byproduct of the reaction. An example of an endothermic reaction is that of turning solid H2O to liquid H2O. This reaction requires the input of heat and is said to be endothermic.

LAWS OF THERMODYNAMICS There are three laws of thermodynamics that apply to all physical and chemical systems. The first law has been described, which is that energy cannot be created or destroyed. In chemistry, it also involves the concept that in all systems, the tendency of all chemical (and nonchemical) systems is to move toward the state of the lowest possible energy (which in chemistry, is the most stable system). This means that potential energy is more likely to become kinetic energy. In biochemical systems, catabolic reactions are those that take a bigger molecule (which stores energy in its chemical bonding) to be metabolized into smaller molecules plus CO2 and water. Because these are biological systems, however, the energy is given off as heat to a mild degree but goes into creating high-energy molecules like adenosine triphosphate or ATP, so that the energy is not destroyed or created but is transferred into another form of potential energy, although these molecules, too, will go on to become lower energy molecules. Even the building of molecules like glucose from CO2 and water, which are endothermic, requires the input of energy from the universe in the form of photons of light energy from the sun to make photosynthetic organisms build glucose and other molecules. In such cases, this is an open system because it requires the input of energy (photons) from the universe. In such cases, energy is not created because energy from the universe is necessary.

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Summary

6min
pages 242-245

Quiz

2min
pages 238-241

Key Takeaways

0
page 237

Lipids

0
pages 235-236

Carbohydrates

2min
pages 228-231

Nucleic Acids

1min
pages 232-234

Proteins

1min
pages 226-227

Benzene Derivatives

0
page 218

Basics of Biochemistry

0
page 225

Structural Isomerism

2min
pages 220-222

Isomerism

0
page 219

Alkenes and Alkynes

0
page 217

Nernst Equation

2min
pages 205-206

Quiz

3min
pages 209-212

Key Takeaways

0
page 208

Cycloalkanes

1min
page 216

Electromotive Force

1min
page 207

Quiz

3min
pages 193-196

Key Takeaways

0
page 192

Faraday’s Law

1min
page 204

Hydrolysis

2min
pages 190-191

Buffers

1min
page 189

pH Scale

1min
pages 185-186

Quiz

3min
pages 176-179

Quiz

3min
pages 165-168

Key Takeaways

0
page 175

Redox Reactions in Common Situations

1min
page 174

Key Takeaways

0
page 164

Crystals

3min
pages 133-136

Colloids

1min
pages 162-163

Anomalous Colligative Properties

1min
page 159

Colligative Properties

1min
page 158

Quiz

3min
pages 144-147

Liquid Forces

5min
pages 139-142

Liquids

2min
pages 137-138

Water Condensation, Boiling, and Evaporation

7min
pages 129-132

Key Takeaways

0
page 120

Chemical Equilibrium

4min
pages 117-119

Quiz

3min
pages 121-124

Energy of Activation

1min
page 116

Rates of Reactions

1min
page 115

Limiting Reagents

1min
page 114

Writing Reactions

4min
pages 111-113

Types of Chemical Reactions

1min
page 110

Quiz

2min
pages 105-107

Key Takeaways

0
page 104

Hydrogen Bonding

0
page 102

Bonding in Metals

1min
page 103

Shapes of Molecules

3min
pages 99-101

Covalence

1min
pages 96-97

Molecular Orbital Theory

1min
page 98

Quiz

3min
pages 85-88

Key Takeaways

0
page 84

Rules of Thermochemistry

1min
page 83

Enthalpy and Energy

3min
pages 81-82

Calorimetry

2min
pages 79-80

Heat Capacity

3min
pages 77-78

Laws of Thermodynamics

3min
pages 75-76

Properties of Heat in Chemistry

2min
page 74

Quiz

3min
pages 69-72

Graham’s Law of Effusion

1min
page 67

Key Takeaways

0
page 68

Kinetic Theory

1min
page 66

Partial Pressures in Gases

1min
page 65

Boyle’s Gas Law

1min
page 62

Gas laws

1min
page 61

Pressures and Gases

1min
page 60

Quiz

2min
pages 51-54

Magnetic Properties in Atoms

1min
page 49

Electronegativity

1min
page 46

Key Takeaways

0
page 50

Electron Affinity

3min
pages 44-45

Quiz

2min
pages 32-35

Ionization Energy

1min
page 26

Atomic Mass Number

1min
page 17

Equivalent Weight and Mole Ratio

1min
page 30

Isotopes

1min
page 18

Key Takeaways

0
page 31

Atomic Number

2min
pages 15-16

Preface

6min
pages 9-12

Atomic Radius

1min
page 25
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