There is more than one technique to fit a set of points or a function over a range. In the first case, the use of the sum properties yields to the minimized error and in the second case the use of the integral formulation is necessary to develop the final normal form of the approximation. The difference between both techniques is the way or criterion chosen in order to minimize a function. One of the useful is the least-square criterion. If one have an over determined problem, the left multiplication by the transposed system is equivalent to the least-square approximation. If one has a set of points of real numbers over a range, the use of orthogonal polynomials gives a very stable function that fit the set of points. In the case of complex numbers, a more elaborated methodology is needed. In this paper, the vector fitting technique is used to fit a set of complex over determined set of numbers to solve an ordinary differential equation system (ODES).